S. A. Klymenko, M. O. Bondarenko, S. O. Ivakhnenko, V. V. Lysakovskyi, M. Yu. Kopieikina, T. V. Kovalenko, O. O. Zanevskyy
{"title":"Surface Roughness and Lateral Forces on the Faces of Type Ib and IIa Diamond Single Crystals","authors":"S. A. Klymenko, M. O. Bondarenko, S. O. Ivakhnenko, V. V. Lysakovskyi, M. Yu. Kopieikina, T. V. Kovalenko, O. O. Zanevskyy","doi":"10.3103/S1063457625010058","DOIUrl":"10.3103/S1063457625010058","url":null,"abstract":"<p>This study presents the results of research on the roughness height parameters and lateral forces on the faces of cubes and octahedra of diamond single crystals and constructs maps of their distribution. The research was conducted using atomic force microscopy (AFM) and lateral force microscopy (LFM) using samples of type Ib and IIa diamond single crystals, grown using the high temperature and high pressure (HTHP) method. It was found that for type Ib diamond single crystals, the surface roughness (<i>Ra</i> parameter) of the cube faces is 3.3 times smaller, and that of the octahedron faces is 1.5 times smaller than for type IIa diamond single crystals. Additionally, for type Ib diamond single crystals, the lateral forces on the cube faces are, on average, 3.5 times smaller, while those on the octahedron faces are, on average, 9.5 times larger than for type IIa diamond single crystals. The results suggest that the level of lateral forces on the faces of diamond single crystals is determined by the roughness of their surfaces.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"47 1","pages":"81 - 84"},"PeriodicalIF":1.2,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. M. Prokopiv, O. V. Kharchenko, Yu. P. Uschapovskyi, I. V. Lisovska, I. M. Zakiev
{"title":"Hard WС–(Ті,W)C–10Со Alloy with Increased Hardness and Strength","authors":"M. M. Prokopiv, O. V. Kharchenko, Yu. P. Uschapovskyi, I. V. Lisovska, I. M. Zakiev","doi":"10.3103/S1063457625010083","DOIUrl":"10.3103/S1063457625010083","url":null,"abstract":"<p>Some characteristics are reported for modified hard alloy T5K10 formed under the conditions of purposeful control over the thermokinetic free vacuum sintering parameters minimizing the processes of solid- and liquid-phase interaction between tungsten carbide and cobalt, which determine the redistribution and recrystallization of carbide grains. The synthesized WС–(Ті,W)C–10Со hard alloy is characterized by a homogeneous finely grained structure, a high density (ρ = 12.98 g/cm<sup>3</sup>), a low level of residual microporosity, a bimodal composition of WC grains, and bridges between carbide grains. As compared to the commercial analogue, the synthesized hard alloy has a 2.4 GPa higher hardness (<i>Н</i><sub>V</sub> = 15), a 270 MPa higher mechanical bending strength, a 1.4 MPa m<sup>0.5</sup> higher fracture toughness, and 1.5 times higher wear resistance. The modification of sintering technology and structural transformations in the synthesized WС–(Ті,W)C–10Со hard alloy have result in a 2.5-fold increase in its service durability during rough steel turning (forged axles of a railway wagons platform) and, in the case of deep soil chiseling, an increase in abrasion resistance is 48%.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"47 1","pages":"20 - 29"},"PeriodicalIF":1.2,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143749222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B. T. Ratov, V. A. Mechnik, N. A. Bondarenko, V. M. Kolodnitskyi, E. S. Hevorkian, V. A. Chishkala, N. S. Akhmetova, S. P. Starik, V. V. Bilorusets, P. S. Sundetova
{"title":"Structure of Fe–Cr–Cu–Ni–Sn Matrices with Different ZrO2 Contents for Sintered Diamond-Containing Composites","authors":"B. T. Ratov, V. A. Mechnik, N. A. Bondarenko, V. M. Kolodnitskyi, E. S. Hevorkian, V. A. Chishkala, N. S. Akhmetova, S. P. Starik, V. V. Bilorusets, P. S. Sundetova","doi":"10.3103/S1063457624060078","DOIUrl":"10.3103/S1063457624060078","url":null,"abstract":"<p>The possibility to create materials for use as a matrix of sintered composite diamond-containing materials (CDMs) is shown. The results of experimental studies on the dependence of the structure of 26Fe–25Cr–32Cu–9Ni–8Sn CDM matrices manufactured by spark plasma sintering on the ZrO<sub>2</sub> additive content (ranged from 0 to 10%) are presented. The development of metal matric composites based on Fe–Cr–Cu–Ni–Sn matrices with ZrO<sub>2</sub> additives is a new approach to replacing the basic materials, which are commonly used in tools for stone processing industry. In the initial state, a 26Fe–25Cr–32Cu–9Ni–8Sn composite sample has a nonuniform distribution of elements. It is shown that the addition of ZrO<sub>2</sub> micropowder to the 26Fe–25Cr–32Cu–9Ni–8Sn composite makes it possible to form a structure, whose parameters can be purposefully controlled by changing its concentration. Under such conditions, the composites containing the ZrO<sub>2</sub> additive have a more uniform distribution of elements. Stable correlations have been established between the ZrO<sub>2</sub> additive content and the microstructure parameters.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"421 - 431"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. A. Petasyuk, V. I. Lavrinenko, V. G. Poltoratskyi, O. O. Pasichnyi, O. U. Petasyuk
{"title":"Investigation of the Correlation between Technological Properties of Cubonite Grinding Powders with Combined Coatings and the Performance Characteristics of Grinding Wheels Fabricated from These Powders","authors":"G. A. Petasyuk, V. I. Lavrinenko, V. G. Poltoratskyi, O. O. Pasichnyi, O. U. Petasyuk","doi":"10.3103/S1063457624060066","DOIUrl":"10.3103/S1063457624060066","url":null,"abstract":"<p>A quantitative analysis of the correlation between the technological properties of cubic boron nitride (cubonite) grinding powders, modified with a combined coating, and the performance characteristics of grinding wheels made with such powders has been conducted. The values of the paired correlation coefficients were obtained between the relative loss of abrasive and the surface roughness (parameter <i>Ra</i>) of the treated surface (dependent factors), the technological parameters of the coating, the processing efficiency, and certain morphometric characteristics and technological properties of the modified grinding powders (independent factors). Factors exerting the greatest effect on the relative consumption of cubonite grinding powder in wheels during grinding are the processing efficiency (correlation coefficient of 0.884) and certain morphometric characteristics, such as the roughness of the grain projection (correlation coefficient of 0.28 and 0.294). In the case of surface roughness (parameter <i>Ra</i>), the most significant factors are also the processing efficiency, with a correlation coefficient of 0.856, and the specific perimeter of the grain projection, with a correlation coefficient of 0.12. Recommendations for applying these results are presented.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"482 - 491"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of Magnesium–Aluminum Spinel at High Pressures and High Temperatures in the Mg2B2O5–Al, MgO–Al2O3, and MgO–Al2O3–Al Systems","authors":"Y. Y. Rumiantseva, T. Polczyk, S. O. Lysovenko","doi":"10.3103/S106345762406008X","DOIUrl":"10.3103/S106345762406008X","url":null,"abstract":"<p>The possibility of MgAl<sub>2</sub>O<sub>4</sub> synthesis at high pressures and high temperatures (by the HPHT method) has been studied for за Mg<sub>2</sub>B<sub>2</sub>O<sub>5</sub>–Al, MgO–Al<sub>2</sub>O<sub>3</sub>, and MgO–Al<sub>2</sub>O<sub>3</sub>–Al systems. It has been established that, for the Mg<sub>2</sub>B<sub>2</sub>O<sub>5</sub>–Al system, the highest quantity of MgAl<sub>2</sub>O<sub>4</sub> is observed at a pressure of 2GPa and a temperature of 1600°C. A further increase in temperature and pressure leads to a growth in the content of boron-containing phases. For the MgO–Al<sub>2</sub>O<sub>3</sub> and MgO–Al<sub>2</sub>O<sub>3</sub>–Al systems, as well as for the Mg<sub>2</sub>B<sub>2</sub>O<sub>5</sub>–Al system, the MgAl<sub>2</sub>O<sub>4</sub> phase content is observed to decrease with an increase in the compaction pressure. It’s indicate that an increase in pressure suppresses the interaction between the initial components for all the systems. The addition of aluminum as a liquid-phase component makes it possible to extend the pressure range, within which the MgAl<sub>2</sub>O<sub>4</sub> phase is observed to form, to evidence that this approach to MgAl<sub>2</sub>O<sub>4</sub> synthesis is promising for further application.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"415 - 420"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Z. Turkevych, O. O. Matviichuk, Li Decheng, D. V. Turkevych
{"title":"Thermodynamic Modeling of the Sintering of Diamond Hard-Alloy Plates in the C–Co–W System at a Pressure of 6 GPa","authors":"V. Z. Turkevych, O. O. Matviichuk, Li Decheng, D. V. Turkevych","doi":"10.3103/S1063457624060091","DOIUrl":"10.3103/S1063457624060091","url":null,"abstract":"<p>In the carbon–cobalt–tungsten phase diagram, polythermal sections were calculated at pressures of 0.1 and 6 GPa for the phase composition of the diamond layer of diamond hard-alloy plates within the models of phenomenological thermodynamics by using the Thermo-Calc software, literature data on interaction parameters, and equations of states for competing phases. The comparison of calculation results with experimental studied on the phase composition of diamond hard-alloy plates demonstrated their agreement.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"492 - 495"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Danhui Han, Chong Peng, Guangtong Zhou, Bingtao Hu
{"title":"Rapid synthesis of Nanodiamond/rGO Composites by Utilizing the Explosive Characteristics of Graphene Oxide","authors":"Danhui Han, Chong Peng, Guangtong Zhou, Bingtao Hu","doi":"10.3103/S1063457624060030","DOIUrl":"10.3103/S1063457624060030","url":null,"abstract":"<p>Nanodiamond particles and graphene oxide (GO) powders were used as raw materials to construct nanodiamond/reduced GO (rGO) composites by utilizing the explosive reaction of GO. The XRD, FTIR, and XPS results indicate that rapid heating can induce explosive reactions in GO. GO was rapidly reduced to graphene by this explosive reaction. The SEM results indicate that GO undergone obvious expansion and peeling, and the nanodiamond particles were fully loaded onto the rGO sheets.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"496 - 498"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Effect of Holding Time on the Properties of N-Vacancy Diffused High-Entropy Nitride Ceramics (Ti0.25V0.25Cr0.25Nb0.25)N0.825","authors":"Peixun Wang, Jiuyang Li, Luyu Yang, Yi Wu","doi":"10.3103/S1063457624060108","DOIUrl":"10.3103/S1063457624060108","url":null,"abstract":"<p>High-entropy ceramics (HECs) have garnered significant attention due to their unique microstructure, desirable properties, and vast compositional space. In this study, we utilized homemade TiN<sub>0.3</sub> with anionic vacancies as a sintering aid, equimolarly mixed with VN, CrN, and NbN. Our results demonstrate the following: Firstly, high-entropy nitride ceramics with a single rock salt phase were successfully synthesized within a holding time of 5 min. Secondly, the samples exhibited their maximum hardness, flexural strength, and fracture toughness values at a holding time of 15 min-measuring at 21.51 ± 1.50 GPa, 1271 ± 24 MPa, and 3.63 ± 0.35 MPa m<sup>1/2</sup>, respectively.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"432 - 439"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jun Zhang, Kai Li, Zhe Zhang, Jiarong Chen, Peicheng Mo, Xiaoyi Pan, Qiaofan Hu, Chao Chen
{"title":"Effect of Cu–Sn–Ti Solder Alloy on Morphology, Bonding Interface, and Mechanical Properties of Brazed Diamond Grits","authors":"Jun Zhang, Kai Li, Zhe Zhang, Jiarong Chen, Peicheng Mo, Xiaoyi Pan, Qiaofan Hu, Chao Chen","doi":"10.3103/S106345762406011X","DOIUrl":"10.3103/S106345762406011X","url":null,"abstract":"<p>The present study focused on characterizing Cu<sub>70</sub>–Sn<sub>20</sub>–Ti<sub>10</sub> solder alloy powder used for brazing diamond grits in a vacuum at 960°C for 20 min. The study covered the macroscopic and microscopic morphology of Cu–Sn–Ti/diamond, the products and thickness of the interfacial reaction layer, the surface morphology of diamond grits, and the phase and morphology of surface attachments after reaction. Additionally, the effects of graphitization and compressive strength of the diamond after the reaction were also studied. The study’s results revealed that the solder alloy could climb up to the diamond grits effectively and exhibited excellent wettability. Microscopically, a TiC reaction layer was observed at the interface between them, and the thickness of the reaction layer was about 1.92 μm, leading to the realization of a chemical metallurgical combination. After brazing, the uncovered surface of diamond grits appeared smooth and did not show graphitization, except for slight graphitization in a few corrosion pits. Moreover, no significant change was observed in the compressive strength of the diamond before and after brazing.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"440 - 449"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Theoretical Evaluation of the Brittle Strength of cBN–TiN Two-Phase Ceramics","authors":"V. I. Kushch, A. S. Manohin, S. A. Klimenko","doi":"10.3103/S1063457624060042","DOIUrl":"10.3103/S1063457624060042","url":null,"abstract":"<p>This study presents a theoretical approach for assessing the brittle strength of multiphase polycrystalline materials and demonstrates its application to two-phase cBN–TiN ceramics.</p>","PeriodicalId":670,"journal":{"name":"Journal of Superhard Materials","volume":"46 6","pages":"458 - 461"},"PeriodicalIF":1.2,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143108832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}