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Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry最新文献

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Synthesis, Spectral Characterisation and Pharmacological Studies on Co(II), Ni(II), Cu(II) and Zn(II) Bis-Schiff Base Complexes Derived From 4-hydroxybenzohydrazide 4-羟基苯并肼衍生的Co(II)、Ni(II)、Cu(II)和Zn(II)双希夫碱配合物的合成、光谱表征和药理研究
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-09-22 DOI: 10.56042/ijca.v60i7.46073
{"title":"Synthesis, Spectral Characterisation and Pharmacological Studies on Co(II), Ni(II), Cu(II) and Zn(II) Bis-Schiff Base Complexes Derived From 4-hydroxybenzohydrazide","authors":"","doi":"10.56042/ijca.v60i7.46073","DOIUrl":"https://doi.org/10.56042/ijca.v60i7.46073","url":null,"abstract":"","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88471868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electron transfer study on newly synthesized Ti(IV)/Zr(IV) complexes of amide and oxime functionality: A pulse radiolytic and theoretical revelation 新合成Ti(IV)/Zr(IV)酰胺和肟官能团配合物的电子转移研究:脉冲辐射分解和理论启示
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.39627
Raji Thomasa, Densely Doseb, Nelson Joseph, Pc, R. T. Pardasanid, T. Mukherjeee
{"title":"Electron transfer study on newly synthesized Ti(IV)/Zr(IV) complexes of amide and oxime functionality: A pulse radiolytic and theoretical revelation","authors":"Raji Thomasa, Densely Doseb, Nelson Joseph, Pc, R. T. Pardasanid, T. Mukherjeee","doi":"10.56042/ijca.v60i3.39627","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.39627","url":null,"abstract":"Raji Thomas*, Densely Dose, Nelson Joseph P, R T Pardasani & T Mukherjee aDepartment of Chemistry, School of Science and Humanities, Sreenidhi Institute of Science & Technology, Hyderabad 501 301, India bDepartment of Chemistry, Mar Athanasius College, Kothamangalam, Kerala, India cDepartment of Chemistry, Union Christian college, Aluva, Kerala, India dDepartment of Chemistry, Central University of Rajasthan, Bandar Sindri, Rajasthan, India eChemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085, India *E-mail: rajithomas28@yahoo.com","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72951278","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
One pot synthesis of luminescent Mn doped ZnSe nanoparticles and its silica based water dispersible formulation for targeted delivery of doxorubicin 一锅法合成发光Mn掺杂ZnSe纳米粒子及其二氧化硅基水分散剂靶向递送阿霉素
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.39450
K. SHARMAa, Ashraf Alib, Prasad P Phadnisa, Chandan Kumarc, Anand Ballalc, Ashutosh Dashc, R. K. Vatsaa
{"title":"One pot synthesis of luminescent Mn doped ZnSe nanoparticles and its silica based water dispersible formulation for targeted delivery of doxorubicin","authors":"K. SHARMAa, Ashraf Alib, Prasad P Phadnisa, Chandan Kumarc, Anand Ballalc, Ashutosh Dashc, R. K. Vatsaa","doi":"10.56042/ijca.v60i3.39450","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.39450","url":null,"abstract":"The manganese doped zinc selenide nanoparticles (ZnSe:Mn NPs) have been synthesized by thermolysis method using oleic acid and oleylamine as capping agents, and 1-octadecene as solvent. Coating of mesoporous silica is done on ZnSe:Mn (ZnSe:Mn@mSilica) which is further functionalized with amine functional groups by treating with (3-aminopropyl)trimethoxysilane. Further pegylation is done to achieve water dispersibility by conjugating carboxyl groups of poly(ethylene glycol) diacid with the amine groups. These pegylated NPs are subsequently treated with ethylenediamine followed by acrylic acid. Conjugation of tris-(hydroxymethyl-aminomethane) is performed by Michael-type addition reaction to afford ZnSe:Mn@mSilica-PEG-Tris-OH. These tris functionalized NPs have exhibited broad emission ranging from 590-620 nm that is an indicative for their suitability in diagnosis and monitoring progress of cancer treatment. To explore the usefulness of increased surface area because of mesoporosity, doxorubicin is loaded on ZnSe:Mn@mSilica-PEG-Tris-OH NPs through silyl ether linkage and evaluated for cytotoxicity against WEHI-164 mouse fibrosarcoma and RAJI human hematopoietic origin cancer cell lines. A decrease in 12% of cell viability of WEHI-164 cells while 30% decrease in RAJI cell lines (IC 50 ≈ 45 nM) are observed. This shows that our formulation has more cytotoxic in RAJI cancer cell lines than that of WEHI-164 cancer cells. These results reveal that the formulation has potential for the application in drug delivery and diagnosis in chemotherapeutics.","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87210610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ethanol condensation to butanol and higher alcohols over nickel and cobalt decorated Ce-Al mixed oxide catalysts 乙醇在镍和钴修饰的铈铝混合氧化物催化剂上缩合成丁醇和高级醇
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.36718
{"title":"Ethanol condensation to butanol and higher alcohols over nickel and cobalt decorated Ce-Al mixed oxide catalysts","authors":"","doi":"10.56042/ijca.v60i3.36718","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.36718","url":null,"abstract":"","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85104125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterization, antimicrobial and DNA cleavage study of organoantimony(III) and organoarsenic(III) complexes with monofunctional bidentate Schiff base 单能双齿席夫碱有机锑(III)和有机砷(III)配合物的合成、表征、抗菌和DNA裂解研究
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.31459
{"title":"Synthesis, characterization, antimicrobial and DNA cleavage study of organoantimony(III) and organoarsenic(III) complexes with monofunctional bidentate Schiff base","authors":"","doi":"10.56042/ijca.v60i3.31459","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.31459","url":null,"abstract":"","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87740789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of Schiff bases of pyrazole aldehyde and their metal complexes of Cu(II), Ni(II) and Co(II) 吡唑醛席夫碱及其金属配合物Cu(II)、Ni(II)、Co(II)的合成与表征
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.34009
{"title":"Synthesis and characterization of Schiff bases of pyrazole aldehyde and their metal complexes of Cu(II), Ni(II) and Co(II)","authors":"","doi":"10.56042/ijca.v60i3.34009","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.34009","url":null,"abstract":"","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81007050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
New Mixed Ligand Saccharin Complexes with o-Phenylenediamine Schiff Base and Antioxidant Investigations 邻苯二胺希夫碱混合配体糖精配合物及其抗氧化研究
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.41294
{"title":"New Mixed Ligand Saccharin Complexes with o-Phenylenediamine Schiff Base and Antioxidant Investigations","authors":"","doi":"10.56042/ijca.v60i3.41294","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.41294","url":null,"abstract":"","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74823826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A DFT study on Electronic Excitations, Charge Transfer and NLO Properties of Visible Absorbing Squaraine and Thiosquaraine dyes 可见吸收方卡因和硫代方卡因染料的电子激发、电荷转移和NLO性质的DFT研究
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.35034
Prabhakar Chetti, A. Tripathi, Ritu Mittal, A. Chaskar
{"title":"A DFT study on Electronic Excitations, Charge Transfer and NLO Properties of Visible Absorbing Squaraine and Thiosquaraine dyes","authors":"Prabhakar Chetti, A. Tripathi, Ritu Mittal, A. Chaskar","doi":"10.56042/ijca.v60i3.35034","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.35034","url":null,"abstract":"Density functional calculations have been performed to see the effect of sulfur substitution in place of oxygen at central four membered acceptor squarate ring on electronic excitations, charge transfer and second order non-linear optical properties in visible absorbing squaraines (SQ). Molecules oxy-thiosquaraines (OSQ) and thiosquaraines (SSQ) have shown red shift in absorption as compared to their corresponding SQ molecules. The lowest five electronic excitations for all the molecules have been calculated by using TDDFT method. Further, effect of electron donating and electron withdrawing groups on absorption maxima have been studied. The large red shifts in case of electron withdrawing group within the same series of molecules (SQ, OSQ and SSQ) are due to destabilization of HOMO and stabilization of LUMO levels. Charge transfers in these molecules are reported by using VMOdes. Second hyperpolarizabilities (  γ  ) for these molecules are calculated by SOS method. This study may be helpful in synthesizing new C-N bonding SQ, OSQ and SSQ dyes which are further useful in","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72403452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
1D and 2D Cobalt(II) coordination polymers with dipicolinic acid ligands and photocatalytic CO2 reduction 具有二吡啶酸配体的1D和2D钴(II)配位聚合物和光催化CO2还原
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-07 DOI: 10.56042/ijca.v60i3.35219
{"title":"1D and 2D Cobalt(II) coordination polymers with dipicolinic acid ligands and photocatalytic CO2 reduction","authors":"","doi":"10.56042/ijca.v60i3.35219","DOIUrl":"https://doi.org/10.56042/ijca.v60i3.35219","url":null,"abstract":"","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84788744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, spectral elucidation, antibacterial, antioxidant and DNA studies of ONNO tetradentate Schiff base metal(II) complexes derived from Benzene-1,4-dicarboxaldehyde 苯-1,4-二甲醛衍生ONNO四齿希夫碱金属配合物的合成、光谱解析、抗菌、抗氧化和DNA研究
IF 0.4 4区 化学
Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry Pub Date : 2021-07-01 DOI: 10.56042/ijca.v60i5.30505
{"title":"Synthesis, spectral elucidation, antibacterial, antioxidant and DNA studies of ONNO tetradentate Schiff base metal(II) complexes derived from Benzene-1,4-dicarboxaldehyde","authors":"","doi":"10.56042/ijca.v60i5.30505","DOIUrl":"https://doi.org/10.56042/ijca.v60i5.30505","url":null,"abstract":"","PeriodicalId":54992,"journal":{"name":"Indian Journal of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2021-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75608125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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