发布求助
文献互助 智能选刊 最新文献

Inorganic Reaction Mechanisms最新文献

筛选
英文 中文
Mechanism of Nitric Oxide Release. I. Two-electron Reduction of Sodium Nitroprusside by l -cysteine in Aqueous Solution 一氧化氮释放机制。1 .水溶液中1 -半胱氨酸对硝普钠的双电子还原
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/10286620210352
James N. Smith, T. Dasgupta
{"title":"Mechanism of Nitric Oxide Release. I. Two-electron Reduction of Sodium Nitroprusside by l -cysteine in Aqueous Solution","authors":"James N. Smith, T. Dasgupta","doi":"10.1080/10286620210352","DOIUrl":"https://doi.org/10.1080/10286620210352","url":null,"abstract":"Sodium nitroprusside (SNP) is a well-known vasodilator, which activates the cytosolic isozyme guanylate cyclase. It is quite stable by itself in aqueous solution and in the dark, but produces nitric oxide spontaneously under the appropriate reducing conditions. Both the neutral nitric oxide (NO) and the nitroxyl anion (NO m ) can be produced from SNP depending on the condition employed. NO release is favored at lower pH and cysteine concentration while NO m formation is more likely to occur at higher pH (>7) and cysteine concentration. NO was measured by electrochemical method and the chemical detection of NH 2 OH and NO 2 m are evidences of NO m formation. The mechanism of the reaction was found to be very complicated and involved three clear stages. NO and NO m are postulated to form in the first and third stages, respectively. All three stages showed cysteine dependence and were also affected by the pH of the solution. The first two stages resembled stepwise reversible two-electron reduction of NO + to...","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"3 1","pages":"181-195"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Kinetic and Mechanistic Studies of the Interaction of Hydroxopentaaquarhodium(III) Ion with Potassium Hexacyanoferrate(III) 羟基戊二钠(III)离子与六氰高铁酸钾(III)相互作用的动力学和机理研究
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/10286620290034719
G. Brahma, P. Mohanty
{"title":"Kinetic and Mechanistic Studies of the Interaction of Hydroxopentaaquarhodium(III) Ion with Potassium Hexacyanoferrate(III)","authors":"G. Brahma, P. Mohanty","doi":"10.1080/10286620290034719","DOIUrl":"https://doi.org/10.1080/10286620290034719","url":null,"abstract":"The substitution reaction of potassium hexacyanoferrate(III) with hydroxopentaaquarhodium(III) has been studied spectrophotometrically as a function of pH, [substrate] and [Fe(CN) 6 3 m ] by following the absorption of Fe(III) substituted product at 355 nm. The rate of the reaction increases with the increase in [Fe(CN) 6 3 m ] but decreases with the increase in [H + ] and ionic strength of the medium. The activation parameters, j H # (36.5, 42.5) kJ mol m 1 and j S # ( m 191.0, m 133.0)J K m 1 mol m 1 for k S and k f paths respectively, have been calculated form the Eyring plots and were compared with the aqua exchange and analogous ligand substitution reactions. j G 0 , j H 0 and j S 0 for the outer-sphere association ( K OS ) path have been calculated, both from kinetic as well as the experimentally obtained equilibrium constant values. The mechanistic pathway for the substitution reaction within the outer-sphere complex is consistent with an associative interchange (Ia) type of phenomenon.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"3 1","pages":"233-238"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Ruthenium(III) Mediated Cerium(IV) Oxidation of Thallium(I) in Aqueous Sulphuric Acid--A Kinetic and Mechanistic Study 钌(III)介导的铈(IV)在硫酸水溶液中氧化铊(I)的动力学和机理研究
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/1028662021000062563
S. Chimatadar, T. Basavaraj, S. Nandibewoor
{"title":"Ruthenium(III) Mediated Cerium(IV) Oxidation of Thallium(I) in Aqueous Sulphuric Acid--A Kinetic and Mechanistic Study","authors":"S. Chimatadar, T. Basavaraj, S. Nandibewoor","doi":"10.1080/1028662021000062563","DOIUrl":"https://doi.org/10.1080/1028662021000062563","url":null,"abstract":"The cerium(IV) oxidation of thallium(I) has been studied in an aqueous sulphuric acid medium. A minute amount (10 m 6 mol dm m 3 ) of ruthenium(III) is sufficient to catalyse the reaction. The reaction is first order in [cerium(IV)] in the presence of ruthenium(III) catalyst. The order in [thallium(I)] varies from zero to unity, whereas that in [ruthenium(III)] is unity. Increase in sulphuric acid concentration accelerates the reaction rate. The added products cerium(III) and thallium(III) do not significantly effect the reaction rate. The active catalyst, substrate and oxidant species are [Ru(H 2 O) 6 ] 3+ , Tl(SO 4 ) m and H 3 Ce( SO 4 ) 4 m , respectively. Possible mechanisms are proposed and the reaction constants involved have been determined.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"4 1","pages":"209-219"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/1028662021000062563","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 22
Kinetics and Mechanism of Oxidation of Mannitol by Sulphato-cerium(IV) Species in Aqueous Acid Medium 硫酸铈(IV)在酸性水溶液中氧化甘露醇的动力学及机理
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/1028662021000062617
Anju Agarwal, Gayatri Sharma, C. L. Khandelwal, P. Sharma
{"title":"Kinetics and Mechanism of Oxidation of Mannitol by Sulphato-cerium(IV) Species in Aqueous Acid Medium","authors":"Anju Agarwal, Gayatri Sharma, C. L. Khandelwal, P. Sharma","doi":"10.1080/1028662021000062617","DOIUrl":"https://doi.org/10.1080/1028662021000062617","url":null,"abstract":"The kinetics of oxidation of mannitol by cerium(IV) in sulphuric acid medium have been studied. The spectral analysis of hydrazone derivative of the product indicates the product to be an aldehyde. The substrate forms an intermediate complex with the oxidant as is observed both kinetically and spectrophotometrically. Ce(SO 4 ) 2 has been considered to be the reactive sulphato-cerium(IV) species. The proposed mechanism corresponds to the rate law m d[Ce(IV)] d t = 2 kK [RCH 2 OH][Ce(IV)] (1+ K [RCH 2 OH])(1+ K 3 [ HSO 4 m ]) where R=CH 2 OH(CHOH) 4 . All the rate parameters have been evaluated.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"37 1","pages":"233-239"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/1028662021000062617","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Kinetics and Stereochemistry of Base Hydrolysis of trans - and Λ- cis -[Co(en) 2 (py)Cl] 2+ 反式-和Λ-顺式-[Co(en) 2 (py)Cl] 2+碱水解动力学和立体化学
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/1028662021000062545
W. Jackson, Josephine A McKeon, W. Marty
{"title":"Kinetics and Stereochemistry of Base Hydrolysis of trans - and Λ- cis -[Co(en) 2 (py)Cl] 2+","authors":"W. Jackson, Josephine A McKeon, W. Marty","doi":"10.1080/1028662021000062545","DOIUrl":"https://doi.org/10.1080/1028662021000062545","url":null,"abstract":"The rates and steric course of base hydrolysis for v - cis - and trans -[Co(en) 2 (py)Cl] 2+ have been carefully determined. Values of k OH are 81 - 4 and 914 - 23 M m 1 s m 1 for the cis and trans ions respectively, and both are appreciably larger than their alkylamine analogues. Thus pyridine enhances the reactivity in base, but for these particular species the effect is no more cis or trans specific than it is for other \"non-displaced\" ligands. The steric course, 59% trans -product from trans -reactant, and 90% cis -product from cis -reactant, is likewise not unusual, but the net activity (8.3%) for the cis -product derived from v - or j - cis -reactant is anomalously low ( ca . 49% v , 41% j ). The results are discussed in terms of Nordmeyer's 1969 model which is reconsidered in the light of these and other new results.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"4 1","pages":"125-132"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Thermo-kinetic and Spectral Studies of Cobalt(II), Nickel(II) and Copper(II) Complexes With Di(3-chloro-4-methylphenyl)carbazone 钴(II)、镍(II)和铜(II)与二(3-氯-4-甲基苯基)咔唑配合物的热力学和光谱研究
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/1028662021000062473
A. Siddalingaiah, S. Naik
{"title":"Thermo-kinetic and Spectral Studies of Cobalt(II), Nickel(II) and Copper(II) Complexes With Di(3-chloro-4-methylphenyl)carbazone","authors":"A. Siddalingaiah, S. Naik","doi":"10.1080/1028662021000062473","DOIUrl":"https://doi.org/10.1080/1028662021000062473","url":null,"abstract":"New complexes of Co(II), Ni(II) and Cu(II) with di(3-chloro-4-methylphenyl) carbazone having the general formula [M(DCMPC) 2 ] [where M=Co(II), Ni(II) or Cu(II); DCMPC=di(3-chloro-4-methylphenyl)carbazone] have been synthesized and characterized by elemental analyses, magnetic moment measurements, Uv-Vis., IR, EPR and thermal studies. The DCMPC behaves as a bidentate monoanionic ligand coordinating through the ketonic oxygen and azo nitrogen. The interpretation, mathematical analyses of the thermoanalytical data (TG and DTA) and evaluation of kinetic parameters are presented in this communication. The energy of activation for the two clear-cut steps of decomposition for all the complexes are compared by employing the Freeman-Carroll equation, the integration method using the Coats-Redfern equation and the approximation method using the Horowitz-Metzger equation. The Coats-Redfern equation was extended to evaluate other kinetic parameters such as pre-exponential factor and entropy of activation.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"4 1","pages":"89-93"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
13 C NMR Studies of the Redox and Exchange Reactions of Gold(I) Thiomalate with Diselenides 硫代酸金与二硒化物氧化还原和交换反应的13c核磁共振研究
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/1028662021000062482
S. Ahmad, A. Isab, M. Wazeer
{"title":"13 C NMR Studies of the Redox and Exchange Reactions of Gold(I) Thiomalate with Diselenides","authors":"S. Ahmad, A. Isab, M. Wazeer","doi":"10.1080/1028662021000062482","DOIUrl":"https://doi.org/10.1080/1028662021000062482","url":null,"abstract":"Exchange reactions of gold(I) thiomalate (AuStm) n with two diselenides (RSe-SeR), selenocystine and selenocystamine have been studied in D 2 O by 13 C NMR spectroscopy. Upon interaction of diselenides with (AuStm) n , the Se-Se bond is broken, resulting in the formation of RSe-Stm and (AuSeR) n species. RSe-Stm on further decomposition leads to the formation of thiomalic disufide (Stm) 2 . The second order rate constant was determined for the decomposition of RSe-Stm species and is found to be 3.21 2 10 m 4 l mol m 1 s m 1 . The intensity of thiomalic disulfide resonances increases, while the intensity of RSe-Stm resonances decreases with time. The end result of both reactions is the formation of (Stm) 2 and the deposition of metallic gold and brown ppts. In both cases exchange takes place immediately, however, the overall reaction of (AuStm) n with selenocystamine was faster than with selenocystine.","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"4 1","pages":"95-102"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/1028662021000062482","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Kinetics and Mechanism of Ligand Substitution in Octahedral Salen Complexes of Iron(III) in Alcohol Media: Solvolysis and Intermediate Ligand Rearrangement Controlling the Substitution Process 醇介质中铁(III)八面体Salen配合物中配体取代的动力学和机理:溶剂溶解和中间配体重排控制取代过程
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/10286620213670
Gerhard Gumbel, H. Elias
{"title":"Kinetics and Mechanism of Ligand Substitution in Octahedral Salen Complexes of Iron(III) in Alcohol Media: Solvolysis and Intermediate Ligand Rearrangement Controlling the Substitution Process","authors":"Gerhard Gumbel, H. Elias","doi":"10.1080/10286620213670","DOIUrl":"https://doi.org/10.1080/10286620213670","url":null,"abstract":"Conventional and stopped-flow spectrophotometry was used to study the kinetics of ligand substitution in a number of mono g -diketone salen iron(III) complexes, [Fe(salen)(O 7 O)], by 8-hydroxyquinoline (=HO 7 N) in alcohol media (O 7 O m =anion of the g -diketones pentane-2,4-dione, 2,6-dimethylheptane-3,5-dione, 2,2,6,6-tetramethylheptane-3,5-dione, 1-phenylbutane-1,3-dione, 1,3-diphenylpropane-1,3-dione, and 1-(2-thienyl)-4,4,4-trifluorobutane-1,3-dione; salen=anion of N , N '-disalicylideneethylenediamine). As shown by spectrophotometry and conductometry, the solutions of complexes [Fe(salen)(O 7 O)] in alcohols ROH are subject to solvolytic dissociation, leading to neutral and charged solvento species [Fe(salen)S 2 ] (S=RO m and ROH, respectively). The dissociation constants K D for the systems [Fe(salen)(O 7 O)]/ROH, as determined by concentration-jump experiments as well as by dilution experiments, range from 3 2 10 m 5 M to 1 2 10 m 3 M. The reaction of complexes [Fe(salen)(O 7 O)] with HO 7 N in ...","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"3 1","pages":"221-232"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Deactivation of the chlorosulfonate ion coordinated to pentaamminecobalt(III) 五胺钴配位氯磺酸盐离子的失活(ⅲ)
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/1028662021000062626
D. Fairlie, B. Dutton, Josephine A McKeon, W. Jackson
{"title":"Deactivation of the chlorosulfonate ion coordinated to pentaamminecobalt(III)","authors":"D. Fairlie, B. Dutton, Josephine A McKeon, W. Jackson","doi":"10.1080/1028662021000062626","DOIUrl":"https://doi.org/10.1080/1028662021000062626","url":null,"abstract":"The synthesis and properties of [(NH 3 ) 5 CoOSO 2 Cl](ClO 4 ) 2 are described. This complex is one of the most reactive cobalt(III) species ever isolated ( t 1/2 10 s; 25°C; 0.1 M HClO 4 ). In water it yields [(NH 3 ) 5 CoOSO 3 ] + , [(NH 3 ) 5 CoOH 2 ] 3+ and [(NH 3 ) 5 CoCl] 2+ . The first two of these products come from the expected direct S-Cl and Co-O cleavages. The chloro complex arises via intramolecular linkage isomerisation to the transient [(NH 3 ) 5 Co-ClSO 3 ] 2+ species which then cleaves the S-Cl bond. Considerable attention is given to the characterisation of the Co-O 3 SCl species, including reaction in 17 O-H 2 O where the NMR spectra confirm Co- 17 OSO 3 , Co- 17 OH 2 and free 17 OSO 3 2 m products. The reactions have been studied also in aqueous base, 0.1 M HClO 4 and Me 2 SO where the same reactions are observed but in quite different proportions. In liquid ammonia, with or without added NH 4 + , no O-bonded sulphamate complex [(NH 3 ) 5 CoOSO 2 NH 2 ] 2+ arising from direct S-Cl clea...","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"4 1","pages":"197-208"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59827916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conversion of Manganate(VI) to Manganate(VII) By N -bromosuccinimide in Aqueous Alkaline Medium: A Kinetic and Mechanistic Approach 碱性水溶液中N -溴代琥珀酰亚胺将锰酸盐(VI)转化为锰酸盐(VII)的动力学和机理研究
Inorganic Reaction Mechanisms Pub Date : 2002-01-01 DOI: 10.1080/713931737
C. P. Kathari, P. D. Pol, S. Nandibewoor
{"title":"Conversion of Manganate(VI) to Manganate(VII) By N -bromosuccinimide in Aqueous Alkaline Medium: A Kinetic and Mechanistic Approach","authors":"C. P. Kathari, P. D. Pol, S. Nandibewoor","doi":"10.1080/713931737","DOIUrl":"https://doi.org/10.1080/713931737","url":null,"abstract":"N -bromosuccinimide oxidation of manganate(VI) was studied spectrophotometrically. The reaction showed first order kinetics in [ MnO 4 2 m ] and an apparent less than unit order dependence in [NBS] and rate of reaction decreases with increase in [alkali]. Initial addition of products had no significant effect on the rate of the reaction. The effect of ionic strength and dielectric constant of the reaction medium have been investigated. The results suggest that the reaction proceeds via formation of a complex between active species of oxidant and MnO 4 2 m , which subsequently decomposes in a rate determining step followed by a fast step to yield the products. A mechanism involving the HOBr as the reactive species of the oxidant has been proposed. The reaction constants involved in the mechanism have been computed. There is a good agreement between the observed and calculated rate constants under different experimental conditions. The activation parameters were calculated with respect to the slow step of t...","PeriodicalId":54977,"journal":{"name":"Inorganic Reaction Mechanisms","volume":"3 1","pages":"213-220"},"PeriodicalIF":0.0,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/713931737","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"60390085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
首页 上一页 下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：481959085
Book学术官方微信