Journal of Chemical Thermodynamics最新文献

{"title":"Study of the solid-phase equilibria in the GeTe-Bi2Te3-Te system and thermodynamic properties of GeTe-rich germanium bismuth tellurides","authors":"E.N. Orujlu ,&nbsp;D.M. Babanly ,&nbsp;T.M. Alakbarova ,&nbsp;N.I. Orujov ,&nbsp;M.B. Babanly","doi":"10.1016/j.jct.2024.107323","DOIUrl":"https://doi.org/10.1016/j.jct.2024.107323","url":null,"abstract":"<div><p>A set of self-consistent thermodynamic parameters of the GeTe-rich germanium-bismuth tellurides were determined using an electromotive force (EMF) method with a glycerol electrolyte in a temperature range from 300 to 450 K. The solid-phase equilibrium diagram of the GeTe-Bi₂Te₃-Te system at 400 K was constructed using X-ray diffraction (XRD) and scanning electron miscroscope (SEM) techniques of synthesized electrode alloys, as well as available literature data. It is found that all telluride phases in GeTe-Bi₂Te₃ pseudo-binary section have a tie-line connection with elemental tellurium. The relative partial thermodynamic functions of GeTe in alloys were calculated using data from EMF measurements of concentration cells relative to the GeTe electrode. These findings together with the corresponding thermodynamic functions of GeTe and Bi₂Te₃ were used to calculate the relative partial molar functions of germanium in alloys, and also the standard thermodynamic functions of formation and standard entropies of the ternary compounds, namely Ge₂Bi₂Te₅, Ge₃Bi₂Te₆ and Ge₄Bi₂Te₇.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"196 ","pages":"Article 107323"},"PeriodicalIF":2.6,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140901156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Research on triamterene equilibrium solubility in mono-solvents and aqueous solutions according to solvent effect, models, thermodynamic analysis and quantum chemical calculation","authors":"Fulin Mao ,&nbsp;Weizhong Shi ,&nbsp;Hongkun Zhao ,&nbsp;Wanxin Li ,&nbsp;Abolghasem Jouyban ,&nbsp;Ali Farajtabar","doi":"10.1016/j.jct.2024.107324","DOIUrl":"https://doi.org/10.1016/j.jct.2024.107324","url":null,"abstract":"<div><p>The equilibrium solubilities of triamterene in pure solvents {isopropanol, methanol, <em>n</em>-propanol, water, 1,2-dichloroethane, 2-methoxyethanol, ethyl acetate, acetonitrile, <em>N</em>-methylformamide (NMF), <em>n</em>-butanol, isobutanol and dimethylsulfoxide (DMSO)}, as well as solvent mixtures of methanol/DMSO + water, were determined by dint of the saturation shake-flask technique. Triamterene solubility (10⁵<em>x</em>) rose as the determination temperature rose and fell in the order at 298.15 K: 2-methoxyethanol (453.9) &gt; DMSO (281.3) &gt; NMF (142.6) &gt; methanol (8.424) &gt; <em>n</em>-propanol (1.432) &gt; <em>n</em>-butanol (1.152) &gt; ethyl acetate (0.9441) &gt; isobutanol (0.8738) &gt; acetonitrile (0.7991) &gt; isopropanol (0.7419) &gt; 1,2-dichloroethane (0.5232) &gt; water (0.1795). No crystal transition or solvation in the trial process was shown via X -ray power diffraction patterns. The solvent effects, in which the interactions of solvent–solvent and solvent–solute were considered, were studied via linear solvation energy relationship. Using equations such as Wilson, Apelblat, <em>λh</em>, and NRTL for mono-solvents and Jouyban-Acree as well as modified van't Hoff-Jouyban-Acree for solvent mixtures, the magnitudes of equilibrium solubility were associated. The greatest relative average deviation of 5.787 × 10⁻² and the maximum deviation value of root mean square of 219.1 × 10⁻⁴ were computed for neat solvents. According to the solubility information in pure solvents, the Wilson equation was used to compute the mixing solution parameters. At 298.15 K, the inverse Kirkwood-Buff integral was utilized here to examine the preferred solvation of triamterene. In blends of DMSO/methanol + water with middle and rich DMSO/methanol compositions, the parameters of preferred solvation for DMSO/methanol were positive, indicating the preferential solvation of triamterene by DMSO/methanol. In addition, the electrostatic acidity-basicity properties were demonstrated using the lowest negative electrostatic potential in company with the minimum m local ionization energy of molecular surface. The <img>N<img> in ring of the triamterene is the preferential target for electrophilic assault; and –NH₂ of the triamterene, for nucleophilic assault. The weak triamterene-solvent interactions were graphically displayed by the use of the independent gradient approach on the basis of Hirshfeld partition analysis.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"196 ","pages":"Article 107324"},"PeriodicalIF":2.6,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140894443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solubility determination, Hansen solubility parameter, molecular simulation and thermodynamic properties of 2-anilino-6-(dibutylamino)-3-methylfluoran in four binary solvent mixtures from 283.15 K to 323.15 K","authors":"Wenjun Xie ,&nbsp;Xin Huang ,&nbsp;Shouxiang Jiang ,&nbsp;Xiangyu Sun ,&nbsp;Chengfei Wang ,&nbsp;Haoran Li ,&nbsp;Xia Jiang ,&nbsp;Yongjin Zou ,&nbsp;Gengxiu Zheng ,&nbsp;Guan Wang","doi":"10.1016/j.jct.2024.107314","DOIUrl":"https://doi.org/10.1016/j.jct.2024.107314","url":null,"abstract":"<div><p>The laser monitoring method was used to assess the solubility of 2-Anilino-6-(dibutylamino)-3-methylfluoran (ODB-2) in four binary solvent systems (methyl acetate, ethyl acetate, n-propyl acetate, n-butyl acetate + acetonitrile) at temperatures ranging from 283.15 K to 323.15 K. The results indicated that the solubility of ODB-2 increased with the increasing temperature and molar fraction of the ester solvent. Five models, including the Apelblat model, λh model, CNIBS/R-K model, Ma model, and Sun model, were applied to fit the experimental ODB-2 solubility data. Among these models, the Apelblat model and CNIBS/R-K model performed significantly better than the other models. Moreover, it was found that the Hansen solubility parameter played a significant role in explaining the dissolving behavior of ODB-2 in the four binary solvents. The intermolecular interactions between solute and solvent, as well as between solvent molecules themselves, were studied using the radial distribution function obtained through molecular dynamics simulations. The findings suggested that the dissolving behavior of ODB-2 was closely related to the intermolecular forces among solute–solvent and solvent–solvent. The thermodynamic properties of the dissolution process, including enthalpy and entropy changes, were calculated using the modified van't Hoff equation. These results demonstrated that the dissolution of ODB-2 was an endothermic process driven by entropy.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"196 ","pages":"Article 107314"},"PeriodicalIF":2.6,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140815929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thermodynamics of acidic dissociation of ammonium ion in concentrated aqueous solutions of ammonium nitrate","authors":"Dmitrii Pyreu ,&nbsp;Sergei Gridchin ,&nbsp;Eugenii Kozlovskii","doi":"10.1016/j.jct.2024.107309","DOIUrl":"https://doi.org/10.1016/j.jct.2024.107309","url":null,"abstract":"<div><p>Based on pH-metric measurements, the equilibrium constants for ammonia protonation at 298.15 K and ionic strengths <em>I</em> = 5–9, supported by ammonium nitrate, were calculated. Using direct calorimetric measurements, the enthalpies of this process were determined at 288.15, 298.15 and 303.15 K and <em>I</em> = 5–9 and its full thermodynamic parameters were calculated. The sharp increase in exothermicity and decrease in entropy of this process observed at high ionic strengths are explained by decrease in the contribution of desolvation of reagents in the region of deficiency of solvent molecules and the influence of association of ions of background electrolyte. The obtained thermodynamic characteristics of ammonia protonation clearly indicate that a change in solvation state of reaction participants at high ionic strengths changes the nature of this reaction.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"196 ","pages":"Article 107309"},"PeriodicalIF":2.6,"publicationDate":"2024-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140822671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enthalpy of mixing of solid solution rhomboclase – Indium-substituted rhomboclase (H3O) Fe1−xInx(SO4)2·nH2O","authors":"Franz Bärthel,&nbsp;Juraj Majzlan","doi":"10.1016/j.jct.2024.107308","DOIUrl":"10.1016/j.jct.2024.107308","url":null,"abstract":"<div><p>Solid solution of rhomboclase [nominally (H₃O) Fe(SO₄)₂·3H₂O] with Fe-In substitution was synthesized by coprecipitation and hydrothermal treatment and investigated by chemical, X-ray diffraction, and thermodynamic analysis in this study. The solid solution is continuous over the whole stoichiometric range despite significant differences in ionic radii between Fe³⁺ and In³⁺. Enthalpy of formation of rhomboclase and enthalpies of mixing of solid solution rhomboclase – indium-substituted rhomboclase were determined by acid-solution calorimetry in 5 mol<span><math><mrow><mo>·</mo></mrow></math></span>dm⁻¹ HCl at T = 298.15 K and p = 1 bar. The actual compositions of the studied synthetic end members are (H₃O)_0.798Fe(SO₄)_1.899·3.078H₂O (rhomboclase with molecular mass of 308.8719 g<span><math><mrow><mo>·</mo></mrow></math></span>mol⁻¹) and (H₃O)_1.067In(SO₄)_2.034·3.017H₂O (indium-substituted rhomboclase with molecular mass of 384.8377 g<span><math><mrow><mo>·</mo></mrow></math></span>mol⁻¹). The enthalpies of mixing were obtained for a series of four indium-incorporating rhomboclase synthetic samples with molar In/(In + Fe) ratios of 0.115, 0.226, 0.537, and 0.733. The enthalpy of formation from elements in their standard state at T = 298.15 K and p = 1 bar obtained in this study by thermochemical cycle for (H₃O)_0.798Fe(SO₄)_1.899·3.078H₂O is: <span><math><mrow><msub><mrow><mi>Δ</mi></mrow><mrow><mi>f</mi></mrow></msub><msub><mrow><mi>H</mi></mrow><mrow><mn>298.15</mn></mrow></msub><mi>°</mi><mo>=</mo><mo>-</mo><mn>2815.2</mn><mo>±</mo><mn>2.8</mn></mrow></math></span> kJ<span><math><mrow><mo>·</mo></mrow></math></span>mol⁻¹. Mean measured enthalpies of dissolution for (H₃O)_0.798Fe(SO₄)_1.899·3.078H₂O and (H₃O)_1.067In(SO₄)_2.034·3.017H₂O are: <span><math><mrow><msub><mrow><mi>Δ</mi></mrow><mrow><mi>diss</mi></mrow></msub><mi>H</mi><mi>°</mi><mo>=</mo><mn>14.47</mn><mo>±</mo><mn>0.42</mn></mrow></math></span> kJ<span><math><mrow><mo>·</mo></mrow></math></span>mol⁻¹ and <span><math><mrow><mo>-</mo><mn>6.68</mn><mo>±</mo><mn>0.27</mn></mrow></math></span> kJ <span><math><mrow><mo>·</mo></mrow></math></span> mol⁻¹, respectively. Enthalpies of mixing<span><math><mrow><msub><mrow><mi>Δ</mi></mrow><mrow><mi>mix</mi></mrow></msub><mi>H</mi><mi>°</mi></mrow></math></span> have small positive values and can be fitted by a regular solid solution model with a mixing parameter <span><math><mrow><mi>W</mi><mo>=</mo><mn>4.26</mn><mo>±</mo><mn>0.32</mn></mrow></math></span> kJ<span><math><mrow><mo>·</mo></mrow></math></span>mol⁻¹.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"195 ","pages":"Article 107308"},"PeriodicalIF":2.6,"publicationDate":"2024-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0021961424000612/pdfft?md5=cb151d4c37f4d5f80c001e734dcc430e&pid=1-s2.0-S0021961424000612-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140765276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Excess properties and intermolecular interactions of 2-methoxyethanol + ethylenediamine binary system: Density, viscosity, spectral analyses, computational chemistry, and CO2 absorption property","authors":"Rui Cao ,&nbsp;Xiaoyu Wang ,&nbsp;Wenjie Zhai ,&nbsp;Liming Chai ,&nbsp;Enna Wang ,&nbsp;Yuting Wang ,&nbsp;Kai Ma ,&nbsp;Jianbin Zhang","doi":"10.1016/j.jct.2024.107313","DOIUrl":"https://doi.org/10.1016/j.jct.2024.107313","url":null,"abstract":"<div><p>To examine the fundamental physicochemical properties as well as intermolecular interactions for the 2-methoxyethanol (EGME) (1) + ethylenediamine (EDA) (2) binary system, this work systemically measured the density (<span><math><mrow><mi>ρ</mi></mrow></math></span>) and viscosity (<span><math><mrow><mi>η</mi></mrow></math></span>) values of the binary system with various mole ratios at <em>P</em> = 100.5 kPa and <em>T</em> = (298.15–318.15) K with the growth gap of 5 K. The as-measured values of the pure substances were compared with literature data. Multiple semi-empirical formulas were used to fit <span><math><mrow><mi>ρ</mi></mrow></math></span> and <em>η</em> values, and the absolute average deviations (AAD%) were calculated. After that, the excess molar volume (<span><math><mrow><msubsup><mtext>V</mtext><mrow><mtext>m</mtext></mrow><mtext>E</mtext></msubsup></mrow></math></span>), partial molar volume (<span><math><mrow><mover><mrow><mi>V</mi></mrow><mrow><mo>¯</mo></mrow></mover></mrow></math></span>), apparent molar volume (<span><math><mrow><msub><mtext>V</mtext><mi>φ</mi></msub></mrow></math></span>), viscosity deviation (<span><math><mrow><mi>Δ</mi><mtext>η</mtext></mrow></math></span>), excess activation of Gibbs free energy (<span><math><mrow><mi>Δ</mi><msup><mrow><mi>G</mi></mrow><mrow><mo>∗</mo><mi>E</mi></mrow></msup></mrow></math></span>), and several thermodynamic properties of the binary system were systemically analyzed. According to analysis results, it has been proven that the interaction exists between EGME and EDA molecules. And then, excess properties were fitted to the Redlich-Kister equation using multi-parametric nonlinear regression analyses, and standard deviations (<span><math><mrow><mi>σ</mi></mrow></math></span>) were calculated. In addition, based on various characterization methods including Raman, ultraviolet (UV), and nuclear magnetic resonance hydrogen (¹H NMR) spectral analyses and density functional theory (DFT) calculation results, it is demonstrated that there is intermolecular hydrogen bonds in EGME (1) + EDA (2) binary system as the form of –OH⋯NH₂–, which was consistent with the existence forms of intermolecular hydrogen bonds in different alcohol-amine systems from references. Finally, CO₂ absorption capacity by pure EDA, pure EGME, and the EGME (1) + EDA (2) binary system were severally determined.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"195 ","pages":"Article 107313"},"PeriodicalIF":2.6,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140646992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Measurement, correlation and thermodynamic analysis of the solubility of dicyandiamide in three binary solvents","authors":"Yinhu Pan ,&nbsp;Yan Wang ,&nbsp;Shichao Du ,&nbsp;Qilei Sun ,&nbsp;Fumin Xue","doi":"10.1016/j.jct.2024.107312","DOIUrl":"10.1016/j.jct.2024.107312","url":null,"abstract":"<div><p>Dicyandiamide (DCD) is an important chemical raw material. The solid–liquid equilibrium solubility of DCD in three kinds of binary solvent mixtures (N,N-dimethylformamide (DMF) + ethanol, DMF + acetonitrile, DMF + acetone) at <em>T</em> = (283.15–323.15) K was determined by gravimetric method. The thermodynamic parameters of DCD dissolution in solvents were studied. The solubility of DCD in the three groups of binary mixed solvents increases with the increase of temperature. In three binary mixed solvents, the solubility of DCD increases monotonically with the increase of DMF composition. The modified Apelblat model, van’t Hoff model, <em>λh</em> model, the nonrandom two-liquid (NRTL) model and the Apelblat-Jouyban-Acree model were used to correlate the solubility data. The results show that the modified Apelblat model have the best correlation with the solubility of DCD. The calculation of thermodynamic parameters during the dissolution process indicates that dissolution is exothermic and driven by both enthalpy and entropy. This work can provide reference for improving the crystallization process of DCD, as well as for improving the chemical production process using DCD as raw material.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"196 ","pages":"Article 107312"},"PeriodicalIF":2.6,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140764303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Theoretical study of the thermochemistry of Formation, acidity and basicity of 2- and 8-Hydroxy azaazulene and their mercapto analogues","authors":"Abrar S. Hussein,&nbsp;Mohammed T. Abdel-Aal,&nbsp;Ahmed M. El-Nahas,&nbsp;Asmaa B. El-Meligy","doi":"10.1016/j.jct.2024.107310","DOIUrl":"10.1016/j.jct.2024.107310","url":null,"abstract":"<div><p>The gas phase standard enthalpies of formation <span><math><mfenced><mrow><msub><mi>Δ</mi><mi>f</mi></msub><msubsup><mi>H</mi><mrow><mi>gas</mi></mrow><mo>°</mo></msubsup></mrow></mfenced></math></span> for the tautomers and rotamers of 2- and 8-hydroxy azaazulene and their mercapto analogues have been estimated at B3LYP/6–311 + G(d,p) and M06-2X/6–311++G(2d,2p) levels of theory. The G3MP2 composite method has also been utilized to obtain more accurate correlated computational results. By using atomization and isodesmic reactions, it has been possible to calculate the theoretical enthalpies of formation for the structures under study. Depending on the enthalpies of formation results, the stability of the examined tautomers and rotamers has been discussed. The gas-phase basicity (GB), proton affinities (PA) of the N and O/S atoms, and the deprotonation enthalpies (DPE) of the NH and OH/SH bonds for the investigated system have been determined at the three levels of theory as well.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"196 ","pages":"Article 107310"},"PeriodicalIF":2.6,"publicationDate":"2024-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140768047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thermodynamic studies on the formation of ion-pair cobalt complexes in acetone–water mixtures","authors":"","doi":"10.1016/j.jct.2024.107305","DOIUrl":"10.1016/j.jct.2024.107305","url":null,"abstract":"&lt;div&gt;&lt;p&gt;Dicarboxylic acids are stronoger acids than moncraboxylic acids and more soluble in water due to the presence of two carboxylic (–COOH) groups which are industrially important in producing polyester, polyamides, and polyols and as a pioneer to pharmaceutical additives. Succinic acid is one of the most prosperous chemicals that can be generated from renewable resources which can be used in the industries of antiseptics, cosmetics, sutures, drugs, solvents, detergents, herbicides, fungicides, synthetic resins, and inks. The ion–pair formation is very important in diferent applications, used widely for inorganic analysis by liquid chromatography and used for the heavy metal removal from waste water, so studing the ion-pair association constant (K&lt;sub&gt;A&lt;/sub&gt;) formed between chloropentamminecobalt(III) cation [CpX&lt;sup&gt;2+&lt;/sup&gt;] and a different ligands of dicarboxylate anions (AC&lt;sup&gt;2-&lt;/sup&gt;), have been determined by EMF technique in different compositions of acetone aqueous media (0–44.20 wt% acetone) for succinic acid and for the other dicarboxylic acids (Maleic, Malonic and Malic) in the same solvent composition (40 wt% acetone) with in temperature range (30 – 60 °C). The thermodynamic association properties (&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;G&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;H&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;S&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;) have been estimated and discussed. Extra thermodynamic correlations like &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;H&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;- &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;S&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;G&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;- &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;G&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;I&lt;/mi&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mi&gt;o&lt;/mi&gt;&lt;mi&gt;r&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mi&gt;I&lt;/mi&gt;&lt;mi&gt;I&lt;/mi&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; (where I and II are mentioned for the first and second dissociation constant of the dicarboxylic acids) in different compositions of acetone aqueous media for succinic acid and in fixed solvent composition for the other dicarboxylic acids were examined in order to give more information about the behavior of solvent molecules and its effect on formation of the ion-pair molecules. In addition, The Gibbs free energy of transfer for the association process &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msubsup&gt;&lt;mrow&gt;&lt;mi&gt;Δ&lt;/mi&gt;&lt;mi&gt;G&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;/mrow&gt;&lt;mo&gt;°&lt;/mo&gt;&lt;/msubsup&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;(t) from water to acetone mixed solvents were calculated for succinic acid in order to indicate the spontaneous nature and the st","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"199 ","pages":"Article 107305"},"PeriodicalIF":2.2,"publicationDate":"2024-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140784667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Selective absorption of ionic liquids in separating R-1243zf or R-161 from refrigerant blends","authors":"Xiucan Jia,&nbsp;Yuhan Du,&nbsp;Xiaopo Wang","doi":"10.1016/j.jct.2024.107307","DOIUrl":"https://doi.org/10.1016/j.jct.2024.107307","url":null,"abstract":"<div><p>In order to recover and reuse pure refrigerants from the mixtures used in waste refrigeration facility, it is necessary to find a good way for separation. Due to the extremely low vapor pressure and good selectivity, ionic liquids (ILs) are regarded as promising entrainers for the extractive separation process of azeotropic or near-azeotropic mixtures. Phase behavior of refrigerant with ILs is the basic property in the design of selective absorption-separation process. In this work, the solubility of 3,3,3-trifluoropropene (R-1243zf) and ethyl fluoride (R-161) with trihexyltetradecylphosphonium chloride ([P_6,6,6,14][Cl]) were measured based on the isochoric saturation method. The experimental temperature range was from 283.15 K to 343.15 K. Five activity coefficient models, including Margules, van Laar, Scatchard-Hamer, Wilson and non-random two-liquid (NRTL) model, were used to correlate the experimental data, and the results were discussed. In addition, based on the literature data, the separation capacities of different ILs for refrigerant blends composed of R-1243zf or R-161 were investigated.</p></div>","PeriodicalId":54867,"journal":{"name":"Journal of Chemical Thermodynamics","volume":"196 ","pages":"Article 107307"},"PeriodicalIF":2.6,"publicationDate":"2024-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140555237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}