Mariana Sontag-González , Bo Li , Kieran O'Gorman , Basran Burhan , Budianto Hakim , Adam Brumm , Richard G. Roberts
{"title":"Survival of the brightest? pIRIR dating of volcanic sediments in Sulawesi, Indonesia, using micro-aliquots of K-rich feldspar","authors":"Mariana Sontag-González , Bo Li , Kieran O'Gorman , Basran Burhan , Budianto Hakim , Adam Brumm , Richard G. Roberts","doi":"10.1016/j.quageo.2024.101638","DOIUrl":"10.1016/j.quageo.2024.101638","url":null,"abstract":"<div><div>Volcanic sediments are challenging to date with luminescence-based methods. Both main minerals used for dating—quartz and K-rich feldspar—commonly have suboptimal luminescence properties when of volcanic origins, primarily a low signal intensity and, for K-rich feldspars, high rates of anomalous fading. The present work provides a case study of sediment samples from the Leang Bulu Bettue (LBB) archaeological site in Indonesia, a key site in our understanding of the early human occupation of the island of Sulawesi. We show that currently available state-of-the-art methods can provide robust optical ages for volcanic sediments. Through various reliability tests, we establish the suitability of a post-IR IR stimulated luminescence (pIRIR) standardised growth curve (SGC) procedure for D<sub>e</sub> estimation of ‘micro-aliquots’ containing 5–10 grains of K-rich feldspar, and then combine this method with estimates of environmental dose rate to determine 10 new reliable and finite optical ages for the sedimentary deposits at LBB. Furthermore, by applying the L<sub>n</sub>T<sub>n</sub> method to circumvent truncation of the D<sub>e</sub> distribution caused by the non-linearity of the dose response curve in the higher dose range, we could extend the site's luminescence-based chronology to span the interval ∼15–210 ka. The new chronology is in keeping with previous radiocarbon and U-series ages for the site's upper layers. We show that the low fading rate of micro-aliquots relative to using large aliquots composed of hundreds of grains lies in a brightness-based selection. By targeting bright grains with low fading rates, the need for fading corrections is greatly reduced and they can be made with a smaller uncertainty propagated through into the final age estimate, resulting in optical ages of improved accuracy and precision for volcanic sediments.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101638"},"PeriodicalIF":1.7,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Su-Chin Chang , Mei-Fei Chu , Wen-Shan Chen , Stephen E. Cox , Sidney R. Hemming
{"title":"Novel age constraints on offshore islets around Taiwan with implications for the northern Taiwan volcanic zone","authors":"Su-Chin Chang , Mei-Fei Chu , Wen-Shan Chen , Stephen E. Cox , Sidney R. Hemming","doi":"10.1016/j.quageo.2024.101636","DOIUrl":"10.1016/j.quageo.2024.101636","url":null,"abstract":"<div><div>Determining the exact age of volcanic activity in the Northern Taiwan Volcanic Zone (NTVZ) is essential for comprehending Taiwan's tectonic evolution. The timing and duration of the volcanic processes that formed the NTVZ remain uncertain despite the availability of geochronological, geochemical, and geophysical data. While extensive efforts have been directed towards investigating the age of the Tatun Volcanic Group, the primary feature of the NTVZ, many other aspects require further examination. This study concentrates on two offshore islets in the northern region of the NTVZ. We present new <sup>40</sup>Ar/<sup>39</sup>Ar ages of 0.252 ± 0.018 Ma for a lava flow, representing an early stage of volcanic activity, and 0.118 ± 0.012 Ma for a dike, representing the latest stage of volcanic activity around Pengjia Islet. A sample collected from Mianhua Islet did not yield a reasonable age due to high uncertainty, likely attributable to young and low radiogenic argon. Field observations support the interpretation that volcanic activity on both islets is considerably younger than previously estimated. This study corroborates the hypothesis from geophysical studies that submarine NTVZ features to record a potentially active magmatic reservoir offshore of northern Taiwan. By refining our understanding of spatio-temporal patterns in volcanic activity, this study contributes to volcanic hazard assessment in Taiwan and surrounding areas.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101636"},"PeriodicalIF":1.7,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142552475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xingshuo Xu , Chuanyi Wei , Gongming Yin , Hao Ji , Chunru Liu , Lin Zhao , Huili Yang , Guang Yang
{"title":"Application of multiple-centers ESR dating to middle Pleistocene fluviolacustrine sediments and insights into the dose underestimation from the Ti–H center at high equivalent doses","authors":"Xingshuo Xu , Chuanyi Wei , Gongming Yin , Hao Ji , Chunru Liu , Lin Zhao , Huili Yang , Guang Yang","doi":"10.1016/j.quageo.2024.101635","DOIUrl":"10.1016/j.quageo.2024.101635","url":null,"abstract":"<div><div>The Ti–H center exhibits rapid and complete optical bleaching properties, meaning it has significant potential for dating applications. However, the equivalent dose of Ti–H centers is underestimated when total doses received by quartz during its geological history reaches a higher level, and there appears to be linked to saturation of the equivalent dose obtained from Ti–H centers. To investigate this phenomenon, a series of samples were analyzed from two sections at Ximachi in Heqing County, China, which have strong Ti–H signals. The sample ages were obtained using the electron spin resonance (ESR) multiple-centers approach, and the reliability of the ages was validated by comparison with optically simulated luminescence (OSL) ages and between different paramagnetic centers. The ESR data demonstrate that the Ti–H centers can provide accurate dose estimates up to 750–950 Gy, with varying degrees of underestimation at high doses. Combined with previously published Ti–H data, it is evident that the upper threshold of the accurate data obtained from Ti–H centers depends on the sample, and may be positively correlated with the Ti–H/(Ti–Li + Ti–H) ratio (option C/D). According to the provenance significance of the Ti–H/(Ti–Li + Ti–H) ratio, we propose that the Ximachi samples have high Ti–H/(Ti–Li + Ti–H) ratios and then equivalent dose saturation values of Ti–H centers, which may be related to the thermal history of the analyzed quartz grains.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101635"},"PeriodicalIF":1.7,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142552476","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Luke A. Gliganic , Jo McDonald , Caroline Mather , Lloyd T. White
{"title":"A method to date rock engravings using luminescence – tested at Murujuga, Western Australia","authors":"Luke A. Gliganic , Jo McDonald , Caroline Mather , Lloyd T. White","doi":"10.1016/j.quageo.2024.101633","DOIUrl":"10.1016/j.quageo.2024.101633","url":null,"abstract":"<div><div>Rock engravings are globally ubiquitous, provide evidence for symbolic behaviours, and demonstrate connections to country and the desire to communicate with other humans. However, rock engravings have proven difficult to date. The development of luminescence rock surface dating approaches has the potential to address this deficiency in applicable dating techniques. Specifically, luminescence rock surface exposure dating methods can be used to tell how long a rock surface has been exposed to sunlight, thus providing a potential avenue to date rock engravings. Here, we present results from laboratory and field bleaching experiments from the Murujuga rock art complex in Western Australia. Four major art-bearing lithologies are petrographically characterised and tested for useable luminescence signals. Three bleaching experiments are conducted: two in the laboratory and one at the study area. The gabbro and microgranite lithologies are shown to be bleachable and show potential for rock surface burial dating. The microgranite can be used to accurately estimate exposure duration over the timescales tested in all experiments, demonstrating promising potential to date rock engravings.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101633"},"PeriodicalIF":1.7,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142441910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gustav Firla , Christopher Lüthgens , Stephanie Neuhuber , Clemens Schmalfuss , Ernst Kroemer , Frank Preusser , Markus Fiebig
{"title":"Analyzing complex single grain feldspar equivalent dose distributions for luminescence dating of glacially derived sediments","authors":"Gustav Firla , Christopher Lüthgens , Stephanie Neuhuber , Clemens Schmalfuss , Ernst Kroemer , Frank Preusser , Markus Fiebig","doi":"10.1016/j.quageo.2024.101627","DOIUrl":"10.1016/j.quageo.2024.101627","url":null,"abstract":"<div><div>Overdeepened valleys are structures scoured into the underlying substrate by glaciers that have been subsequently filled with sediment, which recorded the environmental history of the adjacent landscape. Investigated here is an overdeepened structure that was formed beneath the Salzach Paleoglacier west of Freilassing, Bavaria (southern Germany). In a previous study, infinite infrared stimulated luminescence (IRSL) ages have been determined for the lower part of the core using a multi-grain approach. Applying single-grain feldspar luminescence dating allows to identify the unsaturated signals, previously masked by multi-grain signal averaging. Identification of the normally distributed leading edge in equivalent dose (D<sub>e</sub>) distributions allows for the dismissal of low value D<sub>e</sub> (LOVED) grains that appear to reflect underestimating outliers. Measurement of eleven samples distributed along the entire length of the core yielded two distinct age clusters, for which fading corrected IRSL<sub>50</sub> and uncorrected pIRIR<sub>225</sub> ages agree within uncertainties. Whereas the younger age cluster at the top of the sequence is attributed to Marine Isotope Stage (MIS) 3, the older age cluster is assigned to MIS 6. It is shown that single grain pIRIR measurements will allow to resolve the infill chronology of overdeepened structures in the Alps, at least for the last ca. 200 ka. Overall, the present study represents a further step towards understanding and handling complex D<sub>e</sub> distributions often encountered in single grain feldspar luminescence dating. This contributes to better understand the frequently observed age offset between single grain and single-aliquot measurements.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101627"},"PeriodicalIF":1.7,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142428163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Arbaz N. Pathan , Rabiul H. Biswas , Benjamin Lehmann , Georgina E. King , Frédéric Herman
{"title":"Towards accurate modelling of rock surface exposure dating using luminescence to estimate post-exposure erosion rate","authors":"Arbaz N. Pathan , Rabiul H. Biswas , Benjamin Lehmann , Georgina E. King , Frédéric Herman","doi":"10.1016/j.quageo.2024.101634","DOIUrl":"10.1016/j.quageo.2024.101634","url":null,"abstract":"<div><div>Depth-dependent luminescence in the top few millimetres of rock surface emerges as a potential tool to estimate rock surface exposure age and post-exposure erosion rate. It relies on the principle that the luminescence depth profile (LDP) propagates deeper with the time of sunlight exposure and moves to shallower depth with the erosion rate. The propagation of LDP is generally assumed to follow the first-order kinetic (FOK) model, except for a few recent studies. The FOK model predicts an exponential decay of infrared stimulated luminescence (IRSL) signal with light exposure time, which rarely corroborates experimental observation; IRSL signal decay is much slower than exponential decay. The faster decay of IRSL, predicted by the FOK model, results in faster propagation of LDP and thus always underestimates the exposure age and translates into a higher erosion rate. Interestingly, the slower-than-exponential decay of the IRSL signal can be better explained by general order kinetics (GOK). Thus, recent studies on rock surface luminescence dating have employed the GOK model. However, the GOK model is yet to be explored to predict post-exposure erosion rates. Here, we apply the GOK model and theoretically demonstrate the impact of the order of kinetics on the calibration and propagation of LDP in the presence of erosion and how the LDP's transient to steady state transition depends on the order of kinetics. We have performed a series of synthetic tests to assess the impact of selecting an incorrect model on the prediction of erosion rate. Finally, using the revised rate equation, the erosion rates are recalculated for natural samples (data available in the literature: Lehmann et al. (2019b)) and the impact of GOK on the predicted erosion rate is discussed.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101634"},"PeriodicalIF":1.7,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142428164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kate M. Swanger , Jennifer L. Lamp , Joerg M. Schaefer , Gisela Winckler , Irene Schimmelpfennig
{"title":"Pleistocene glacial advances and exposure age scatter in the Olympus Range, Antarctica: A study of cosmogenic 36Cl/3He in dolerites and 10Be in sandstones","authors":"Kate M. Swanger , Jennifer L. Lamp , Joerg M. Schaefer , Gisela Winckler , Irene Schimmelpfennig","doi":"10.1016/j.quageo.2024.101632","DOIUrl":"10.1016/j.quageo.2024.101632","url":null,"abstract":"<div><div>In three cirques in the western Olympus Range of the McMurdo Dry Valleys, Antarctica, previous advances of cirque glaciers are recorded by a sequence of three drifts in each of the cirques. We dated drift limits and the deposits on modern glaciers in two of these cirques, Dean and Dipboye, via cosmogenic <sup>3</sup>He in pyroxene from 41 dolerite boulders, <sup>36</sup>Cl in pyroxene from 12 of those dolerites, and <sup>10</sup>Be in quartz from 11 sandstone boulders. Exposure age scatter is high on all deposits. The <sup>3</sup>He exposure ages across all deposits range from ∼35 to ∼2300 ka and <sup>10</sup>Be exposure ages range from ∼7 to ∼435 ka. Coupled <sup>36</sup>Cl/<sup>3</sup>He from dolerites support constant exposure with erosion for nine of the 12 samples, while the other three might have experienced complex exposure-burial histories. Due to the mesa-butte topography and slow bedrock erosion rates, nuclide inheritance is the primary cause of age scatter in dolerites, accounting for >1 Myr of exposure age error. Mean exposure ages from sandstones are 2–7 times younger than those from dolerites for the same deposits, indicating that inheritance is less common in sandstones in this region. Weathering analyses of sandstone boulders show an increase in average siliceous crust thickness and rock strength with deposit age, an example of case hardening. Based on both relative and exposure age dating, drift age increases with distance from the modern glaciers in both Dean and Dipboye cirques, with three advances during the past <700 ka. However, due to high exposure age scatter, it cannot be determined if the three drifts are temporally correlated across the two cirques and therefore the drifts might record different glacial advances in Dean Cirque vs. Dipboye Cirque despite the apparent stratigraphic correlation of the drifts. This study has implications for drift depositional processes of cold-based glaciers and the importance of source-bedrock lithology and geomorphology on nuclide inheritance in Antarctica.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101632"},"PeriodicalIF":1.7,"publicationDate":"2024-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142441911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Robin B. Trayler , Lauren E. Lopes , Patricia A. Holroyd , Sora L. Kim , John R. Southon
{"title":"Rapid, effective screening of tar seep fossils for radiocarbon and stable isotope analysis","authors":"Robin B. Trayler , Lauren E. Lopes , Patricia A. Holroyd , Sora L. Kim , John R. Southon","doi":"10.1016/j.quageo.2024.101631","DOIUrl":"10.1016/j.quageo.2024.101631","url":null,"abstract":"<div><div>Tar seeps trap and preserve diverse fossil assemblages that reflect unique environmental histories. While the macro preservation of the fossils is usually good, preservation of organic bone collagen is often variable. Radiocarbon dating and stable isotope analysis of tar seep taxa can reveal distinct paleoecological insights but are complicated by the contamination from tar infiltration. Additionally, the removal of tar is complex and time-consuming. Therefore identifying fossils with preserved collagen prior to further investigation minimizes unnecessary damage to fossil collections and improves success rates for analyses that require organic preservation.</div><div>We used tar pit fossils where the collagen preservation state was independently known to test non-destructive (visual inspection) and minimally-destructive (infrared spectroscopy; FTIR) methods to determine the most reliable methods to identify bones with well preserved collagen. We found that while collagen is less often preserved in heavily weathered bones, visual cues alone are not a reliable indicator. Instead, the Water-Amide-on-Phosphate FTIR index is highly sensitive and specific at identifying fossils suitable for radiocarbon dating and stable isotope analysis. While our protocol and analysis code were developed using fossils from two California tar seep localities (McKittrick and Rancho La Brea), they are likely to be broadly applicable to other tar seep localities that have yielded fewer fossils, thus requiring even greater care when selecting specimens for further analysis.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101631"},"PeriodicalIF":1.7,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142428162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Luminescence dating of rock surfaces in challenging environments: The case of MIS5e gravelly transgressive lag deposit (Southern Sardinia, West Mediterranean Sea)","authors":"Giulia Cossu , Daniele Sechi , Reza Sohbati , Andrew Murray , Vincenzo Pascucci , Stefano Andreucci","doi":"10.1016/j.quageo.2024.101630","DOIUrl":"10.1016/j.quageo.2024.101630","url":null,"abstract":"<div><div>Determining the age of precise sea level markers such as marine terraces is often difficult because of the inherent limitation of traditional dating methods. A novel method based on Optical Stimulated Luminescence applicable to rock surfaces has been showing great promise in dating boulder and cobble surfaces from various environments. We performed Optically Stimulated Luminescence Rock Surface Dating (OSL RSD) on five cobbles from a basal transgressive lag deposit sealing a marine terrace referred to as the Last Interglacial (Marine Isotopic Stage 5e). We applied a consistent and highly selective 3-step acceptance criteria on five cobbles and obtained that only one was sufficiently well-bleached prior to burial. The resulting ages of 131 ± 8 ka and 127 ± 8 ka (obtained on 22 analyzed aliquots, n = 22) derived from the post-infrared infrared stimulated signal at 225<sup>o</sup>C (pIRIR<sub>225</sub>) and the preceding infrared stimulated signal at 50<sup>o</sup>C (pIR<sub>50/225</sub>), respectively, are consistent with each other as well as with the conventional luminescence age of ∼135 ka from the same sequence and with the U/Th age of ∼130 ka obtained from coral fragments. This work demonstrates that the RSD is a promising method for dating gravel veneer deposits overlaying marine terraces, enabling new chronologies for similar Quaternary deposits.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101630"},"PeriodicalIF":1.7,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junjie Zhang , Jennifer Klose , Denis Scholz , Norbert Marwan , Sebastian F.M. Breitenbach , Lutz Katzschmann , Dennis Kraemer , Sumiko Tsukamoto
{"title":"Isothermal thermoluminescence dating of speleothem growth – A case study from Bleßberg cave 2, Germany","authors":"Junjie Zhang , Jennifer Klose , Denis Scholz , Norbert Marwan , Sebastian F.M. Breitenbach , Lutz Katzschmann , Dennis Kraemer , Sumiko Tsukamoto","doi":"10.1016/j.quageo.2024.101628","DOIUrl":"10.1016/j.quageo.2024.101628","url":null,"abstract":"<div><div>Speleothems are a key archive of past climatic and environmental changes. <sup>230</sup>Th/U dating is the most commonly used method to determine speleothem ages. However, incorporation of non-radiogenic thorium may hamper <sup>230</sup>Th/U dating, and samples older than 600 ka also remain out-of-reach. Calcite exhibits a thermoluminescence (TL) signal at 280 °C with a high characteristic saturation dose, and provides significant potential to date carbonate samples over several million years. Hitherto, the application of TL dating for calcite has mainly been hindered by two factors: 1) a spurious TL signal occurring in the high temperature range, and 2) non-uniform dose rate due to U-series disequilibrium. Here we test an isothermal TL (ITL) dating method on a speleothem sample from Bleßberg cave 2, Germany. We show that the ITL signal measured at 240 °C can completely remove the 280 °C TL peak with a negligible TL contribution from the higher temperature range, thus reducing the influence from the spurious signal. The time-dependent dose rate variation can be simulated using the initial radioactivity of <sup>238</sup>U, <sup>234</sup>U, <sup>230</sup>Th and their decay constants. We use the <sup>230</sup>Th/U dating method to provide precise and accurate radiometric ages documenting that the speleothem grew between 425.5 ± 5.4 and 320.5 ± 9.7 ka. The ITL ages (421 ± 23 to 311 ± 23 ka) of four subsamples from the speleothem are consistent with the <sup>230</sup>Th/U ages at isochronous sampling positions, showing the general reliability of the ITL dating method. ITL dating provides a pathway to construct chronologies for palaeoclimate reconstructions for speleothems beyond the range of the <sup>230</sup>Th/U-method and for samples that are unsuitable for U-series dating methods.</div></div>","PeriodicalId":54516,"journal":{"name":"Quaternary Geochronology","volume":"85 ","pages":"Article 101628"},"PeriodicalIF":1.7,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142358951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}