{"title":"Rejection of trace organic compounds by membrane processes: mechanisms, challenges, and opportunities","authors":"O. Mahlangu, M. Motsa, T. Nkambule, B. Mamba","doi":"10.1515/revce-2021-0046","DOIUrl":"https://doi.org/10.1515/revce-2021-0046","url":null,"abstract":"Abstract This work critically reviews the application of various membrane separation processes (MSPs) in treating water polluted with trace organic compounds (TOrCs) paying attention to nanofiltration (NF), reverse osmosis (RO), membrane bioreactor (MBR), forward osmosis (FO), and membrane distillation (MD). Furthermore, the focus is on loopholes that exist when investigating mechanisms through which membranes reject/retain TOrCs, with the emphasis on the characteristics of the model TOrCs which would facilitate the identification of all the potential mechanisms of rejection. An explanation is also given as to why it is important to investigate rejection using real water samples, especially when aiming for industrial application of membranes with novel materials. MSPs such as NF and RO are prone to fouling which often leads to lower permeate flux and solute rejection, presumably due to cake-enhanced concentration polarisation (CECP) effects. This review demonstrates why CECP effects are not always the reason behind the observed decline in the rejection of TOrCs by fouled membranes. To mitigate for fouling, researchers have often modified the membrane surfaces by incorporating nanoparticles. This review also attempts to explain why nano-engineered membranes have not seen a breakthrough at industrial scale. Finally, insight is provided into the possibility of harnessing solar and wind energy to drive energy intensive MSPs. Focus is also paid into how low-grade energy could be stored and applied to recover diluted draw solutions in FO mode.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"875 - 910"},"PeriodicalIF":4.7,"publicationDate":"2022-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42871811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Wang, Ziyu Huang, Xiaohui Yang, Lukas Rogée, Xiaowen Huang, Xuming Zhang, S. Lau
{"title":"Review on optofluidic microreactors for photocatalysis","authors":"Lei Wang, Ziyu Huang, Xiaohui Yang, Lukas Rogée, Xiaowen Huang, Xuming Zhang, S. Lau","doi":"10.1515/revce-2021-0068","DOIUrl":"https://doi.org/10.1515/revce-2021-0068","url":null,"abstract":"Abstract Four interrelated issues have been arising with the development of modern industry, namely environmental pollution, the energy crisis, the greenhouse effect and the global food crisis. Photocatalysis is one of the most promising methods to solve them in the future. To promote high photocatalytic reaction efficiency and utilize solar energy to its fullest, a well-designed photoreactor is vital. Photocatalytic optofluidic microreactors, a promising technology that brings the merits of microfluidics to photocatalysis, offer the advantages of a large surface-to-volume ratio, a short molecular diffusion length and high reaction efficiency, providing a potential method for mitigating the aforementioned crises in the future. Although various photocatalytic optofluidic microreactors have been reported, a comprehensive review of microreactors applied to these four fields is still lacking. In this paper, we review the typical design and development of photocatalytic microreactors in the fields of water purification, water splitting, CO2 fixation and coenzyme regeneration in the past few years. As the most promising tool for solar energy utilization, we believe that the increasing innovation of photocatalytic optofluidic microreactors will drive rapid development of related fields in the future.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"765 - 782"},"PeriodicalIF":4.7,"publicationDate":"2022-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47334879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Siti Aisha Ab Rahman, A. Pang, A. Arsad, A. Sidek, A. Saidu, N. Awang, R. Mohsin, M. Abdurrahman
{"title":"The chemistry insight: epoxy sealant as an alternative remedial operation for well integrity","authors":"Siti Aisha Ab Rahman, A. Pang, A. Arsad, A. Sidek, A. Saidu, N. Awang, R. Mohsin, M. Abdurrahman","doi":"10.1515/revce-2022-0003","DOIUrl":"https://doi.org/10.1515/revce-2022-0003","url":null,"abstract":"Abstract Epoxy resin is commonly used in the oil and gas industry due to its excellent toughness, low shrinkage, good adhesive strength, and relatively good thermal resistance. It is used for water shutoff, zonal isolation, cementing, enhanced oil recovery, and preventing leakage in wells. This paper reviews the chemistry aspect of using an epoxy resin system as a sealant to prevent well leakage and it offers insights into the chemistry of the epoxy resin system, as applied in previous studies. The paper also unveils the reasons for the application of this system from the chemistry perspective, allowing this aspect to be better understood. Success in the investigated cases depended on the formulation design. The epoxide and hydroxyl functional groups have been found to contribute substantially to the excellent performance of the sealant system. Furthermore, the amine curing agent triggers the abrupt reaction of the oxirane ring to stabilise when the cured sealant is perfectly applied. Based on the findings, it is suggested that other types of epoxies, namely epoxidised oils, require further study. Finally, in terms of safety and sustainable energy, it is suggested that more curing agent and diluent studies are undertaken.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"857 - 873"},"PeriodicalIF":4.7,"publicationDate":"2022-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47725743","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cody O Crosby, Brett Stern, Nikhith Kalkunte, Shahar Pedahzur, Shreya Ramesh, Janet Zoldan
{"title":"Interpenetrating polymer network hydrogels as bioactive scaffolds for tissue engineering.","authors":"Cody O Crosby, Brett Stern, Nikhith Kalkunte, Shahar Pedahzur, Shreya Ramesh, Janet Zoldan","doi":"10.1515/revce-2020-0039","DOIUrl":"10.1515/revce-2020-0039","url":null,"abstract":"<p><p>Tissue engineering, after decades of exciting progress and monumental breakthroughs, has yet to make a significant impact on patient health. It has become apparent that a dearth of biomaterial scaffolds that possess the material properties of human tissue while remaining bioactive and cytocompatible has been partly responsible for this lack of clinical translation. Herein, we propose the development of interpenetrating polymer network hydrogels as materials that can provide cells with an adhesive extracellular matrix-like 3D microenvironment while possessing the mechanical integrity to withstand physiological forces. These hydrogels can be synthesized from biologically-derived or synthetic polymers, the former polymer offering preservation of adhesion, degradability, and microstructure and the latter polymer offering tunability and superior mechanical properties. We review critical advances in the enhancement of mechanical strength, substrate-scale stiffness, electrical conductivity, and degradation in IPN hydrogels intended as bioactive scaffolds in the past five years. We also highlight the exciting incorporation of IPN hydrogels into state-of-the-art tissue engineering technologies, such as organ-on-a-chip and bioprinting platforms. These materials will be critical in the engineering of functional tissue for transplant, disease modeling, and drug screening.</p>","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"38 1","pages":"347-361"},"PeriodicalIF":4.9,"publicationDate":"2022-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8993131/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44654791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A comprehensive review of the application of DEM in the investigation of batch solid mixers","authors":"B. Jadidi, M. Ebrahimi, F. Ein‐Mozaffari, A. Lohi","doi":"10.1515/revce-2021-0049","DOIUrl":"https://doi.org/10.1515/revce-2021-0049","url":null,"abstract":"Abstract Powder mixing is a vital operation in a wide range of industries, such as food, pharmaceutical, and cosmetics. Despite the common use of mixing systems in various industries, often due to the complex nature of mixing systems, the effects of operating and design parameters on the mixers’ performance and final blend are not fully known, and therefore optimal parameters are selected through experience or trial and error. Experimental and numerical techniques have been widely used to analyze mixing systems and to gain a detailed understanding of mixing processes. The limitations associated with experimental techniques, however, have made discrete element method (DEM) a valuable complementary tool to obtain comprehensive particle level information about mixing systems. In the present study, the fundamentals of solid-solid mixing, segregation, and characteristics of different types of batch solid mixers are briefly reviewed. Previously published papers related to the application of DEM in studying mixing quality and assessing the influence of operating and design parameters on the mixing performance of various batch mixing systems are summarized in detail. The challenges with regards to the DEM simulation of mixing systems, the available solutions to address those challenges and our recommendations for future simulations of solid mixing are also presented and discussed.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"729 - 764"},"PeriodicalIF":4.7,"publicationDate":"2022-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46486391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Review of applications of electrical resistance tomography to chemical engineering","authors":"M. Sharifi, B. Young","doi":"10.1515/revce-2021-0072","DOIUrl":"https://doi.org/10.1515/revce-2021-0072","url":null,"abstract":"Abstract In spite of decades of study and investigation, the research on tomography and electrical resistance tomography (ERT) in particular, remains to be focus of immense scientific significance. ERT provides the ability to measure conductivity distribution inside a process plant and delivers time evolving multidimensional information. Such important and otherwise inaccessible information enhances critical process knowledge whilst improving the design and function of the process equipment. ERT has been employed in a variety of fields including chemical engineering. This paper reviews previous research carried out on the application of ERT within the chemical engineering arena. The applications are classified based on the objective of ERT measurements, the unit operations ERT has been utilized on, the media under examination, and also other technologies and data processing techniques used in combination with ERT. The objective of this taxonomy is to offer the reader with a broad insight into the current situation of ERT related research and developed applications in the chemical engineering field and to assist in the identification of research gaps for future investigation.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"567 - 599"},"PeriodicalIF":4.7,"publicationDate":"2022-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41477051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Research trends in the development of anodes for electrochemical oxidation of wastewater","authors":"Devendra K. Rai, Shishir Sinha","doi":"10.1515/revce-2021-0067","DOIUrl":"https://doi.org/10.1515/revce-2021-0067","url":null,"abstract":"Abstract The review focuses on the recent development in anode materials and their synthesis approach, focusing on their compatibility for treating actual industrial wastewater, improving selectivity, electrocatalytic activity, stability at higher concentration, and thereby reducing the mineralization cost for organic pollutant degradation. The advancement in sol–gel technique, including the Pechini method, is discussed in the first section. A separate discussion related to the selection of the electrodeposition method and its deciding parameters is also included. Furthermore, the effect of using advanced heating approaches, including microwave and laser deposition synthesis, is also discussed. Next, a separate discussion is provided on using different types of anode materials and their effect on active •OH radical generation, activity, and electrode stability in direct and indirect oxidation and future aspects. The effect of using different synthesis approaches, additives, and doping is discussed separately for each anode. Graphene, carbon nanotubes (CNTs), and metal doping enhance the number of active sites, electrochemical activity, and mineralization current efficiency (MCE) of the anode. While, microwave or laser heating approaches were proved to be an effective, cheaper, and fast alternative to conventional heating. The electrodeposition and nonaqueous solvent synthesis were convenient and environment-friendly techniques for conductive metallic and polymeric film deposition.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"807 - 855"},"PeriodicalIF":4.7,"publicationDate":"2022-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42124292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. J. Poormohammadian, F. Bahadoran, G. Vakili-Nezhaad
{"title":"Recent progress in homogeneous hydrogenation of carbon dioxide to methanol","authors":"S. J. Poormohammadian, F. Bahadoran, G. Vakili-Nezhaad","doi":"10.1515/revce-2021-0036","DOIUrl":"https://doi.org/10.1515/revce-2021-0036","url":null,"abstract":"Abstract The requirement of running a new generation of fuel production is inevitable due to the limitation of oil production from reservoirs. On the other hand, enhancing the CO2 concentration in the atmosphere brings global warming phenomenon and leads to catastrophic disasters such as drought and flooding. Conversion of carbon dioxide to methanol can compensate for the liquid fuel requirement and mitigate CO2 emissions to the atmosphere. In this review, we surveyed the recent works on homogeneous hydrogenation of CO2 to CH3OH and investigated the experimental results in detail. We categorized the CO2 hydrogenation works based on the environment of the reaction, including neutral, acidic, and basic conditions, and discussed the effects of solvents’ properties on the experimental results. This review provides a perspective on the previous studies in this field, which can assist the researchers in selecting the proper catalyst and solvent for homogenous hydrogenation of carbon dioxide to methanol.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"783 - 805"},"PeriodicalIF":4.7,"publicationDate":"2022-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42168597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Progress in the field of hydrotropy: mechanism, applications and green concepts","authors":"Akash D. Patel, Meghal A. Desai","doi":"10.1515/revce-2021-0012","DOIUrl":"https://doi.org/10.1515/revce-2021-0012","url":null,"abstract":"Abstract Sustainability and greenness are the concepts of growing interest in the area of research as well as industries. One of the frequently encountered challenges faced in research and industrial fields is the solubility of the hydrophobic compound. Conventionally organic solvents are used in various applications; however, their contribution to environmental pollution, the huge energy requirement for separation and higher consumption lead to unsustainable practice. We require solvents that curtail the usage of hazardous material, increase the competency of mass and energy and embrace the concept of recyclability or renewability. Hydrotropy is one of the approaches for fulfilling these requirements. The phenomenon of solubilizing hydrophobic compound using hydrotrope is termed hydrotropy. Researchers of various fields are attracted to hydrotropy due to its unique physicochemical properties. In this review article, fundamentals about hydrotropes and various mechanisms involved in hydrotropy have been discussed. Hydrotropes are widely used in separation, heterogeneous chemical reactions, natural product extraction and pharmaceuticals. Applications of hydrotropes in these fields are discussed at length. We have examined the significant outcomes and correlated them with green engineering and green chemistry principles, which could give an overall picture of hydrotropy as a green and sustainable approach for the above applications.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"601 - 630"},"PeriodicalIF":4.7,"publicationDate":"2022-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49405830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Recent developments in MIL-101 metal organic framework for heterogeneous catalysis","authors":"M. Taghizadeh, S. Tahami","doi":"10.1515/revce-2021-0050","DOIUrl":"https://doi.org/10.1515/revce-2021-0050","url":null,"abstract":"Abstract Metal organic frameworks (MOFs) are currently gaining considerable attention as heterogeneous catalysts. Since the functionality of the framework and the pore size of the MOFs can be adjusted over a wide range for various catalytic reactions, the usage of these materials as solid catalysts is attractive. One of the preferred catalytic mesoMOFs is MIL-101 (MIL: Material of Institute Lavoisier) family which has been mainly investigated. The large surface area, high pore volumes, and acceptable solvent/thermal stability (MIL-101(Cr) up to 300 °C) have led the MIL-101 family to be considered an ideal and widespread MOF for use as a great heterogeneous catalyst or solid support for a variety of reactions. The objective of this review is to present recent research on the use of the MIL-101 family for heterogeneous catalysis in gas and liquid phase reactions.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"707 - 728"},"PeriodicalIF":4.7,"publicationDate":"2022-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44379771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}