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Structure design for light‐extraction enhancement of UVC‐LED 紫外线 LED 光提取增强器的结构设计
Nano Select Pub Date : 2024-07-12 DOI: 10.1002/nano.202300179
Qixin Liu, An‐Chi Wei
{"title":"Structure design for light‐extraction enhancement of UVC‐LED","authors":"Qixin Liu, An‐Chi Wei","doi":"10.1002/nano.202300179","DOIUrl":"https://doi.org/10.1002/nano.202300179","url":null,"abstract":"UVC‐LEDs have drawn attention recently because of their benefits to sterilization, decontamination, etc. Since the internal quantum efficiency and light extraction efficiency (LEE) of UVC‐LEDs are low, their external quantum efficiency remains unsatisfied. To enhance the LEE, this study proposes an integration design with the features of substrate‐thickness optimization, substrate shaping, diffuse‐reflective coating, an index‐matching layer, and taper‐base optimization. In addition to optical modeling via ray tracing, thermal modeling is conducted to evaluate both the optical and thermal performances of each feature. The simulation results show that, by means of the combination of these features, the LEE of the chip can be raised from 18.5% to more than 40%, and the average temperature of the device can be lowered by 2.2°C via the design of the diffuse‐reflective coating.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"38 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141652321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Special Issue on Advances in Porous Materials 多孔材料进展》特刊
Nano Select Pub Date : 2024-07-12 DOI: 10.1002/nano.202400088
Hélder A. Santos
{"title":"Special Issue on Advances in Porous Materials","authors":"Hélder A. Santos","doi":"10.1002/nano.202400088","DOIUrl":"https://doi.org/10.1002/nano.202400088","url":null,"abstract":"This Special Issue is dedicated to current research activities on Advanced Porous Materials within the framework of “The NETPORE COST Action,” providing a collection of 12 outstanding contributions (four review papers and eight original research papers) from diverse research groups on the latest progresses regarding porous nano‐ and micro‐materials for diverse applications. The contributions herein address the impact of porous materials in basic science, batteries, biosensing, and translational and personalized medicine for the treatment of various diseases. Overall, this Special Issue is expected to provide important background and new knowledge on the latest advances in porous materials and their broad applications.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"66 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141653440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microwave‐Assisted Tragacanth Gum–Based Grafted Silver Nanocomposite Hydrogel for Sustained Release Formulations of Diclofenac Sodium and Antibacterial Assay 微波辅助黄胶接枝银纳米复合水凝胶用于双氯芬酸钠缓释制剂和抗菌检测
Nano Select Pub Date : 2024-07-09 DOI: 10.1002/nano.202300200
Sharnappa Chapi, G. Babaladimath, M. V. Murugendrappa, A. Raghu
{"title":"Microwave‐Assisted Tragacanth Gum–Based Grafted Silver Nanocomposite Hydrogel for Sustained Release Formulations of Diclofenac Sodium and Antibacterial Assay","authors":"Sharnappa Chapi, G. Babaladimath, M. V. Murugendrappa, A. Raghu","doi":"10.1002/nano.202300200","DOIUrl":"https://doi.org/10.1002/nano.202300200","url":null,"abstract":"In this work, novel tragacanth gum‐graft‐poly(2‐acrylamido‐2‐methylpropanesulfonic acid) (TG‐g‐PAMPS) hydrogel was synthesized via free radical copolymerization of TG, 2‐acrylamido‐2‐methylpropanesulfonic acid by using ammonium peroxodisulfate and N,N‐methylene‐bis‐acrylamide under microwave radiation, resulting in the cross‐linked graft copolymer network. Silver nanoparticles (SNs) were formed and stabilized by the reduction of silver nitrate using tri‐sodium citrate. The TG‐g‐PAMPS gel and its nanocomposite were characterized and confirmed using FTIR, TGA, XRD, SEM, EDS, and TEM techniques. It is observed that the presence of SNs significantly improves the swelling ability of the TG‐g‐PAMPS gel. Degradation studies of both hydrogels were studied using the soil burial method and determining the respective weight loss. The presence of SNs is found to impart significant antibacterial properties to the gel against Pseudomonas aeruginosa and Escherichia coli bacteria. Further, the TG‐g‐PAMPS gel and TG‐g‐PAMPS‐SN were evaluated as matrix materials for the release of the drug (diclofenac sodium) and the effect of SNs on the release was examined. The in‐vitro released data were analyzed using empirical equations to understand the mechanism of release. Among the various models, the released data were well fitted into the Korsmeyer–Peppas equation and the released kinetics followed non‐Fickian diffusion.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"55 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141663240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Production of Biodiesel from Crude Pittosporum resiniferum Oil Using Heterogeneous Solid Base Catalyst 利用异构固体基催化剂从粗海桐油中生产生物柴油
Nano Select Pub Date : 2024-07-02 DOI: 10.1002/nano.202300132
Rogers Kipkoech, Mohammed Takase
{"title":"Production of Biodiesel from Crude Pittosporum resiniferum Oil Using Heterogeneous Solid Base Catalyst","authors":"Rogers Kipkoech, Mohammed Takase","doi":"10.1002/nano.202300132","DOIUrl":"https://doi.org/10.1002/nano.202300132","url":null,"abstract":"Pittosporum resiniferum oil was extracted from the seed and the oil together with methanol was use for the production of biodiesel through transesterification process using novel solid base catalyst (K2CO3 supported on MgO). 0.6:5 (K2CO3 loaded on MgO), a 5 h calcination time, 600°C calcination temperatures were the optimum conditions under which the catalyst was prepared. FTIR, SEM, CO2‐TPD, XRD, N2 adsorption‐desorption, Hammett indicators and other techniques were used to characterize the catalyst. The molar ratio of methanol‐to‐oil, the catalyst amount, time of the reaction as well as the temperature of the reaction were examined. The study found that 16:1 methanol‐to‐oil molar ratio, 5% catalyst loading amount, a reaction time of 2.0 h, and a reaction temperature of 60°C were sufficient for a maximum yield of 97.4%. With relative high activity, the catalyst can perhaps be used again possibly for five times. The characteristics of the biodiesel produced were consistent with international standards.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"360 14","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141686412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interplay of superconductivity and magnetism in the Fe1+yTe1‐xSex iron‐based superconductor: A theoretical study 铁基超导体 Fe1+yTe1-xSex 中超导性与磁性的相互作用:理论研究
Nano Select Pub Date : 2024-06-14 DOI: 10.1002/nano.202400038
Kefale Ayalew, Dagne Atnafu Shiferaw, Gedefaw Mebratie
{"title":"Interplay of superconductivity and magnetism in the Fe1+yTe1‐xSex iron‐based superconductor: A theoretical study","authors":"Kefale Ayalew, Dagne Atnafu Shiferaw, Gedefaw Mebratie","doi":"10.1002/nano.202400038","DOIUrl":"https://doi.org/10.1002/nano.202400038","url":null,"abstract":"The competition between superconductivity and magnetism has been studied for the ongoing investigation of mechanisms in unconventional superconductors. Fe1+yTe1−xSex is distinct among iron‐based superconductors due to its structural simplicity, comprising solely FeTe/Se layers that are favorable for probing the superconductivity mechanism. The main goal of this article is to focus on the computational investigation of the interplay of magnetism and superconductivity in the Fe1+yTe1−xSex multiband superconductor. From the electronic structure of the Fe1+yTe1−xSex superconductor, a two‐band Hamiltonian model was considered to examine the interplay of magnetism and superconductivity in the Fe1+yTe1‐xSex superconductor. Using Green's function formalism with the Hamiltonian model, the mathematical statements for the superconducting (Sc) gap parameter, spin density wave (SDW) ordering parameter, Sc and magnetic transitional temperatures have been obtained. Using these mathematical expressions, the phase diagram of transition temperatures versus the gap parameters for the Fe1+yTe1‐xSex superconductor has been plotted. The intersection region in the phase diagram of transition temperatures as a function of the SDW order parameter has been plotted to show the possible interplay of superconductivity and magnetism in a Fe1+yTe1‐xSex iron‐based superconductor.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"52 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141339639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design and investigation of celastrol‐peptide nanoassemblies and their binding interactions with superoxide dismutase 1 and its mutants 设计和研究西司替醇-肽纳米组合及其与超氧化物歧化酶 1 及其突变体的结合相互作用
Nano Select Pub Date : 2024-06-11 DOI: 10.1002/nano.202400042
Beatriz G. Goncalves, Chau Anh N. Phan, Mary A. Biggs, Hannah L. Hunt, I. Banerjee
{"title":"Design and investigation of celastrol‐peptide nanoassemblies and their binding interactions with superoxide dismutase 1 and its mutants","authors":"Beatriz G. Goncalves, Chau Anh N. Phan, Mary A. Biggs, Hannah L. Hunt, I. Banerjee","doi":"10.1002/nano.202400042","DOIUrl":"https://doi.org/10.1002/nano.202400042","url":null,"abstract":"The misfolding and aggregation of superoxide dismutase 1 (SOD1) and its mutants has been implicated in amyotrophic lateral sclerosis (ALS). In this study, we have created three peptide conjugates with the antioxidant pentacyclic terpene celastrol and examined their interactions with SOD1 and its mutants A4V and G93A. The peptides YYIVS, MPDAHL, and GSGGL are derived from natural sources and are known for their inherent antioxidant properties. Docking studies revealed that most conjugates showed strong binding with the metal binding and electrostatic loops as well as the β1, β5, and β6 hydrophobic core of SOD1. The conjugates were synthesized and self‐assembled into nanoassemblies. Surface plasmon resonance studies further confirmed the binding interactions of the nanoassemblies with the SOD1 proteins. The nanoassemblies were found to internalize into HEK293T cells. The HEK 293T cells were then transfected with GFP fused WT (Wild Type), A4V and G93A SOD1 mutants. Flow cytometry revealed that treatment with celastrol‐peptide nanoassemblies, affected the fluorescence of the SOD1 protein, implying their role in modulating SOD1, particularly for the mutants. N–Acetyl–Leu–Leu–Norleucinal (ALLN) induced SOD1 aggregation was also affected upon treatment with the nanoassemblies. These results suggest that the nanoassemblies may potentially modulate the activity and structure of SOD1.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"54 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141360238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rhabdomyosarcoma targeting with tuned porous silicon nanoparticles 利用调谐多孔硅纳米粒子靶向横纹肌肉瘤
Nano Select Pub Date : 2024-06-08 DOI: 10.1002/nano.202400004
Sofia Dominguez‐Gil, Rita Sala, V. J. Morel, Christophe Nguyen, K. Cheikh, A. Morère, Jean‐Olivier Durand, Jochen Rössler, Michele Bernasconi, Frédérique Cunin, M. Gary‐Bobo
{"title":"Rhabdomyosarcoma targeting with tuned porous silicon nanoparticles","authors":"Sofia Dominguez‐Gil, Rita Sala, V. J. Morel, Christophe Nguyen, K. Cheikh, A. Morère, Jean‐Olivier Durand, Jochen Rössler, Michele Bernasconi, Frédérique Cunin, M. Gary‐Bobo","doi":"10.1002/nano.202400004","DOIUrl":"https://doi.org/10.1002/nano.202400004","url":null,"abstract":"We describe porous silicon nanoparticles (pSiNP) chemically functionalized with an analog of mannose 6‐phosphate (AMFA) and a porphyrin derivative to target aggressive pediatric Rhabdomyosarcoma (RMS) tumor cells. Our findings demonstrate that the pSiNP@AMFA@porphyrin nanosystems are efficiently internalized by RMS cells, which overexpress mannose 6‐phosphate receptors, and induce cytotoxicity and phototoxicity when exposed to two‐photon excitation light. These results provide an interesting potential for targeting and treating RMS pediatric tumors.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":" 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141368549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical simulation of a highly efficient perovskite solar cell based on FeSi2 photoactive layer 基于 FeSi2 光活性层的高效过氧化物太阳能电池的数值模拟
Nano Select Pub Date : 2024-05-05 DOI: 10.1002/nano.202400020
George G. Njema, J. Kibet, Nicholas Rono, Edson L. Meyer
{"title":"Numerical simulation of a highly efficient perovskite solar cell based on FeSi2 photoactive layer","authors":"George G. Njema, J. Kibet, Nicholas Rono, Edson L. Meyer","doi":"10.1002/nano.202400020","DOIUrl":"https://doi.org/10.1002/nano.202400020","url":null,"abstract":"The primary aim of this work is to investigate the use iron di‐silicide (FeSi2) as a photoactive layer in order to achieve superior performance in the solar cell architecture—ITO/TiO2/FeSi2/CuSCN/Ni. The optimum thickness of the absorber layer was found to be 1000 nm, which gave optimal properties of the proposed cell—a short‐circuit current density (Jsc) of 51.41 mAm−2, an open‐circuit voltage (Voc) of 0.93 V, a fill factor (FF) of 77.99%, and power conversion efficiency (PCE) of 37.17%. The introduction of an ultrathin interfacial layer between the electron transport layer (ETL), the perovskite interface, and the hole transport layer (HTL) enhanced the electrical output of the proposed solar cell. The Jsc increased to 51.86 mAcm−2, Voc rose to 0.97 V, while FF and PCE increased to 82.86% and 41.84%, respectively. Accordingly, the proposed cell architecture is promising and can be introduced into the manufacturing workflow for commercial applications. Moreover, because of its exceptional photon absorption capabilities, FeSi2 is a potentially excellent photoactive material for solar cell fabrication. The detailed findings of this study have therefore indicated that high‐performance FeSi2‐based solar can be achieved in future.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"271 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141012650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Role of vacancy defects and nanopumping on drug transport efficiency in boron nitride nanotubes 氮化硼纳米管中的空位缺陷和纳米泵浦对药物传输效率的作用
Nano Select Pub Date : 2024-05-02 DOI: 10.1002/nano.202300175
H. Jami, Roozbeh Sabetvand, Gurvinder Singh
{"title":"Role of vacancy defects and nanopumping on drug transport efficiency in boron nitride nanotubes","authors":"H. Jami, Roozbeh Sabetvand, Gurvinder Singh","doi":"10.1002/nano.202300175","DOIUrl":"https://doi.org/10.1002/nano.202300175","url":null,"abstract":"Boron nitride nanotubes (BNNTs) are promising nanomaterials for drug delivery due to their remarkable mechanical and electrical properties. BNNTs use nanopumping technique to transport drug molecules to target sites when subjected to an external force, such as an electric field or mechanical forces. Despite numerous efforts to investigate BNNTs/biomolecules interactions, the impact of atomic‐scale intrinsic characteristics of BNNT on drug delivery efficiency and delivery time is not well understood. To investigate this, we use molecular dynamics simulations (MD) to develop two simulation models: one with defective BNNT and another with a non‐defective (pristine) BNNT. Here, the fullerene molecule (C20) is introduced into BNNT and transported towards target cells. Our results show that vacancy defects can significantly impact the effectiveness of the nanopumping process. In pristine BNNTs, drug molecules move primarily by translation motion. However, the presence of vacancy defects and their concentration in BNNTs can affect the translation motion of drug molecules. We show that the judicious selection of oscillation frequency and amplitude of Cu tips is important to achieve efficient drug transport. This work provides new insights into the role of structural defects and oscillation on the drug transport efficiency of C20 molecules in BNNT using the nanopumping mechanism.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"34 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141018469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aqueous CuS nanocrystals via a flow synthesis approach 通过流动合成法获得水性 CuS 纳米晶体
Nano Select Pub Date : 2024-05-01 DOI: 10.1002/nano.202400025
Helena Decker, Andre Wolf, Moritz Kemmler, Vladimir Lesnyak
{"title":"Aqueous CuS nanocrystals via a flow synthesis approach","authors":"Helena Decker, Andre Wolf, Moritz Kemmler, Vladimir Lesnyak","doi":"10.1002/nano.202400025","DOIUrl":"https://doi.org/10.1002/nano.202400025","url":null,"abstract":"Aqueous synthesis of covellite CuS nanoparticles holds significant importance in the field of nanomaterials and environmental sustainability. Using water as a solvent and reactant in the synthesis process aligns with green chemistry principles. It enhances nanoparticle production's scalability and safety. CuS nanoparticles have gained attention for their diverse applications in catalysis, energy storage, and environmental remediation. Aqueous synthesis reduces the environmental footprint associated with hazardous organic solvents, making it an eco‐friendly approach. We report on synthesis routes toward covellite CuS nanocrystals (NCs), emphasizing easy and fast synthesis techniques. Additionally, we develop a flow synthesis of small near infrared active CuS NCs in a custom‐made flow reactor. Combining the advantages of aqueous synthesis and flow chemistry yields a robust and sustainable method for producing covellite CuS NCs readily dispersible in water medium, paving the way for their widespread application in diverse fields.","PeriodicalId":510500,"journal":{"name":"Nano Select","volume":"18 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141053747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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