{"title":"Monitoring of volatile organic compounds using a single tin dioxide sensor.","authors":"Florin Caldararu, Cosmin Vatra, Mira Caldararu","doi":"10.1039/c2em30224a","DOIUrl":"https://doi.org/10.1039/c2em30224a","url":null,"abstract":"<p><p>The paper describes a new and simple method for monitoring volatile organic compounds resulting from a specific industrial indoor process. The method is based on the characteristics of tin dioxide sensors to be sensitive and non-selective to a large variety of gases. We use these characteristics to determine an equivalent concentration of the volatile organic compound mixture, a method which has not been used in other studies or experiments. The value of the equivalent concentration shows the accuracy of the process and the air purity of an industrial environment. A system including a tin dioxide sensor with its conditioning circuits and a temperature compensation circuit, a microcontroller and a graphical interface, was built in order to obtain a versatile, online and user friendly monitoring tool. The system was used for monitoring the volatile organic compound concentrations resulting from leather finishing processes in the Romanian industry.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 10","pages":"2616-23"},"PeriodicalIF":0.0,"publicationDate":"2012-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30224a","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30855426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"2-Butoxyethanol from cleaning products responsible for complaints in workplaces: a case study.","authors":"R Rella, A Sturaro, A Vianello","doi":"10.1039/c2em30499f","DOIUrl":"https://doi.org/10.1039/c2em30499f","url":null,"abstract":"<p><p>Indoor air quality is important because people are spending an increasing amount of time in the workplace. They are exposed to outdoor pollutants as well as pollutants emitted from products used indoors. Some chemicals, belonging to the category of volatile organic compounds (VOCs), easily release vapors at room temperature by evaporation. These accumulated vapors are often toxic and irritating. They may be alcohols, glycols, ketones, esters, etc., frequently present in the composition of many products for personal care or household purposes. This study suggests that the exposure levels of 2-butoxyethanol play an important role in the level of complaints of people at work. This study has emphasized the necessity of using different active and passive sampling methods for indoor air to avoid evaluation errors.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 10","pages":"2659-62"},"PeriodicalIF":0.0,"publicationDate":"2012-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30499f","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30839128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anne Karine Halse, Martin Schlabach, Andy Sweetman, Kevin C Jones, Knut Breivik
{"title":"Using passive air samplers to assess local sources versus long range atmospheric transport of POPs.","authors":"Anne Karine Halse, Martin Schlabach, Andy Sweetman, Kevin C Jones, Knut Breivik","doi":"10.1039/c2em30378g","DOIUrl":"https://doi.org/10.1039/c2em30378g","url":null,"abstract":"<p><p>Passive air samplers (PAS) are cost-efficient tools suitable for spatial mapping of atmospheric concentrations of persistent organic pollutants (POPs). The objective of this study was to use PAS to (i) determine atmospheric concentrations of selected POPs in Norwegian coastal zones with consumption advisories on seafood (N = 22), and (ii) evaluate a simple nested monitoring approach to assess the relative influence of local vs. long-range atmospheric transport (LRAT) at coastal sites. The latter was facilitated by comparison with data from a coordinated European-wide campaign in which an identical sampling and analytical approach was followed. Air concentrations were calculated based on the loss of performance reference compounds (PRCs), and results are presented for selected polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB), dichlorodiphenyltrichloroethanes (DDTs) and chlordanes. Air concentrations of PCBs were generally highest at sites within larger cities and up to about an order of magnitude higher than anticipated on the basis of LRAT alone. The distribution of PAHs and HCB occasionally showed elevated concentrations at coastal sites with ongoing or former industrial activity, while an urban site was significantly influenced by banned insecticides (technical DDT and lindane). Coastal sites were also elevated in α-HCH beyond the anticipated LRAT contribution, which we attribute to volatilization from the sea. We conclude that a simple nested PAS monitoring approach provides useful information for screening efforts aiming to assess both atmospheric burdens as well as the relative significance of local sources in controlling these burdens at sites in contaminated areas.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 10","pages":"2580-90"},"PeriodicalIF":0.0,"publicationDate":"2012-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30378g","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30901256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"An economic appraisal of using source separation of human urine to contain and treat endocrine disrupters in the USA.","authors":"Krishna Lamichhane, Roger Babcock","doi":"10.1039/c2em30254c","DOIUrl":"https://doi.org/10.1039/c2em30254c","url":null,"abstract":"<p><p>Elevated concentrations of estrogens in natural waters pose a significant threat to public health and aquatic ecosystems. Both natural (estrone, 17β-estradiol and estriol) and synthetic (17α ethynylestradiol) estrogens, ubiquitous in wastewater effluents and receiving waters, have been shown to affect the endocrine system of human and aquatic life. The effects vary from cancer to sex reversals at levels as low as parts per trillion in sensitive organisms. Separation of urine, which constitutes only about 1% of domestic sewage and contains nearly all of the excreted estrogens, potentially offers an energy-efficient way to contain and then treat these chemicals. With a capital expense of $2100 and operation and maintenance costs of $69 per year for a urine diverting toilet system, a family in the USA can realize estimated savings of $101 per year in energy, water, and nutrients and a decrease of 100 kg in greenhouse gas emissions. To remove 99% of estrogenicity in discharged waters would require approximately 12 kW h per year using continuous electrodialysis followed by ozonation (O(3)) of source separated urine. To achieve the same results by adding O(3) treatment after activated sludge at existing municipal wastewater treatment plants would require 23 kW h per year. From an energy standpoint it makes sense to practice source separation and treatment of urine to limit estrogen discharges into the environment.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 10","pages":"2557-65"},"PeriodicalIF":0.0,"publicationDate":"2012-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30254c","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30864172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Comprehensive environmental review following the pork PCB/dioxin contamination incident in Ireland.","authors":"Ian Marnane","doi":"10.1039/c2em30374d","DOIUrl":"https://doi.org/10.1039/c2em30374d","url":null,"abstract":"<p><p>In December 2008 the Irish Government made a decision to recall all Irish pork and bacon products from pigs slaughtered in Ireland since September 1 2008 as a result of polychlorinated biphenyl contamination identified during routine monitoring of Irish pork products. 30000 tonnes of returned product were subsequently destroyed, as well as 170000 pigs and 5700 cattle, with a cost to date to the Irish exchequer in excess of €120 million, as well as reputational damage to the Irish agriculture and food industries. The source of the contamination was traced to an animal feed production facility which was using the hot gases from the combustion of contaminated fuel oil to dry animal feed. This review examines the events which led to the contamination of the feed, the associated environmental monitoring investigations that followed, and also the lessons learned from this incident.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 10","pages":"2551-6"},"PeriodicalIF":0.0,"publicationDate":"2012-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30374d","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30843082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fecal coliform population dynamics associated with the thermophilic stabilization of treated sewage sludge.","authors":"Chris Ziemba, Jordan Peccia","doi":"10.1039/c2em30373f","DOIUrl":"https://doi.org/10.1039/c2em30373f","url":null,"abstract":"<p><p>The inactivation of fecal coliforms in anaerobic batch reactors has been investigated at the thermophilic temperatures of 50, 55 and 60 °C. Throughout inactivation experiments at each temperature, individual colonies were isolated and identified by 16S rDNA gene sequencing to illustrate how the diversity of fecal coliforms is affected by thermophilic treatment. Results indicate that even though fecal coliforms in raw sewage sludge are comprised of several different bacterial species, each with variable temperature induced decay rates, the overall inactivation of fecal coliforms in raw sewage sludge was found to follow a first-order relationship. No tailing was observed across the range of fecal coliform concentrations measured. Fecal coliforms in raw sludge contained six different genera of bacteria and were 62% enriched in E. coli. Within 1.5 log removal of fecal coliform concentration by thermophilic treatment, the populations had shifted to, and remained at 100% E. coli. Subsequent inactivation rates measured in isolated fecal coliform strains confirmed that E. coli cells isolated post-treatment were more thermotolerant than E. coli and non-E coli bacteria isolated prior to thermal treatment. Overall, this study describes the potential enrichment of thermotolerant E. coli in biosolids fecal coliforms and demonstrates that while thermotolerant species are present at the end of treatment, pure first-order approximations are appropriate for estimating residence times to reduce fecal coliforms to levels promulgated in U.S. Class A biosolids standards.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 10","pages":"2755-61"},"PeriodicalIF":0.0,"publicationDate":"2012-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30373f","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30886960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. Geer, M. Persad, C. D. Palmer, Amy J. Steuerwald, M. Dalloul, O. Abulafia, P. Parsons
{"title":"Response to comments on ‘Assessment of prenatal mercury exposure in a predominately Caribbean immigrant community in Brooklyn, NY’","authors":"L. Geer, M. Persad, C. D. Palmer, Amy J. Steuerwald, M. Dalloul, O. Abulafia, P. Parsons","doi":"10.1039/C2EM30666B","DOIUrl":"https://doi.org/10.1039/C2EM30666B","url":null,"abstract":"","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 1","pages":"2817-2818"},"PeriodicalIF":0.0,"publicationDate":"2012-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/C2EM30666B","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"58244221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M Fernandes, S Benger, S K Sharma, S Gaylard, T Kildea, S Hoare, M Braley, A D Irving
{"title":"The use of δ¹⁵N signatures of translocated macroalgae to map coastal nutrient plumes: improving species selection and spatial analysis of metropolitan datasets.","authors":"M Fernandes, S Benger, S K Sharma, S Gaylard, T Kildea, S Hoare, M Braley, A D Irving","doi":"10.1039/c2em10997b","DOIUrl":"https://doi.org/10.1039/c2em10997b","url":null,"abstract":"<p><p>The definition of the spatial footprint of land-derived nutrient plumes is a key element to the design of initiatives to combat eutrophication in urbanised coastal regions. These plumes, however, are difficult to monitor because of their inherent high-frequency temporal and spatial variability. Biomonitoring with macroalgae provides time-integration of bioavailable nitrogen inputs through the measurement of δ¹⁵N signatures in tissues, and adequate spatial coverage through translocation to desirable monitoring locations. In this study, we used laboratory incubations to compare three different species of macroalgae as bioindicators, and a field experiment to investigate the applicability of the technique for the large-scale mapping of nutrient plumes. Cladophora valonioides was selected for the field experiment as it showed rapid changes in δ¹⁵N values in the laboratory incubations, was abundant in shallow depths making collection cost-efficient, and had tough thalli capable of withstanding deployment in open water. Ecklonia radiata also performed well in the laboratory incubations, but field harvest from subtidal depths was comparatively more expensive. Ulva lactuca had fragile thalli, and large nitrogen reserves that acted to mask the isotopic signal of newly acquired nitrogen. Cladophora valonioides was translocated to 246 sites covering an area of ∼445 km² along the highly urbanized temperate coast of Adelaide, South Australia. The resulting isotopic signatures of nitrogen in tissues were spatially interpolated to produce maps of land-derived nutrient plumes, to model probability and standard error in the predictive surface, and to optimize sampling design.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 9","pages":"2399-410"},"PeriodicalIF":0.0,"publicationDate":"2012-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em10997b","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30776533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Isabela Araujo Fioravante, Bruna Albergaria, Taciane Silveira Teodoro, Sérgia Maria Starling Magalhães, Francisco Barbosa, Rodinei Augusti
{"title":"Removal of 17α-ethinylestradiol from a sterile WC medium by the cyanobacteria Microcystis novacekii.","authors":"Isabela Araujo Fioravante, Bruna Albergaria, Taciane Silveira Teodoro, Sérgia Maria Starling Magalhães, Francisco Barbosa, Rodinei Augusti","doi":"10.1039/c2em30320e","DOIUrl":"https://doi.org/10.1039/c2em30320e","url":null,"abstract":"<p><p>An unprecedented investigation dealing with the removal of 17α-ethinylestradiol (EE2, a contraceptive hormone) by the cyanobacteria Microcystis novacekii (a species that is abundant and easily accessible in Brazilian lakes) from a sterile WC medium is described herein. The results indicated that whereas EE2 experienced insignificant spontaneous degradation, Microcystis novacekii was capable of removing ca. 65% of the hormone from the culture medium. Furthermore, no metabolites were detected at the concentration levels evaluated (0.10 to 0.17 mg L(-1)) as verified by the use of GC-MS, a quite sensitive analytical technique, and adequate pre-concentration procedures (SPME and liquid extraction). Elucidative experiments, including an appropriate cell lyses procedure, indicated that EE2 was likely accumulated within the cells (bioaccumulation) rather than adsorbed on the cellular membrane (biosorption). Moreover, the intra- and extracellular contents of EE2 were shown to be roughly complementary. Finally, the species was found to be highly tolerant to the hormone as its growth rates were higher in the test than in the control experiments. All these findings, therefore, point to the use of Microcystis novacekii as a potential agent to treat effluents contaminated with EE2.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 9","pages":"2362-6"},"PeriodicalIF":0.0,"publicationDate":"2012-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30320e","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30762726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Quantifying the influence of EDTA on polymer nanoparticle deposition and retention in an iron-oxide-coated sand column.","authors":"Xinyao Yang, Dongxu Liang, Shihuai Deng","doi":"10.1039/c2em30145h","DOIUrl":"https://doi.org/10.1039/c2em30145h","url":null,"abstract":"<p><p>Ethylenediaminotetraacetic acid (EDTA) occurring in groundwater aquifers complicates the prediction of nanoparticle movement in the porous medium. This paper demonstrates an approach combining Triple Pulse Experiments (TPEs) and numerical modelling to quantify the influence of EDTA on the deposition and retention of polymer nanoparticles in a water-saturated column packed with iron-oxide-coated sand. TPEs injecting three successive pulses in the order of nanoparticle, EDTA, nanoparticle permit nanoparticle deposition in the absence and the presence of EDTA to be compared. Random Sequential Adsorption (RSA) modelling of the nanoparticle breakthrough curves combining mass balance calculation allows the influence of EDTA to be quantified. TPE results demonstrate that the injected EDTA eluted the oxide coatings (favorable deposition sites) from the sand surface and the resulting decline in sites led to enhanced nanoparticle mobility in the subsequent pulse. Quantification results suggest that at the experimental time-scale and under the controlled conditions, elution of one deposition site requires injection of 2.4 × 10(11) EDTA molecules. In total, 75 gram EDTA needs to be injected to remove all the column sites.</p>","PeriodicalId":50202,"journal":{"name":"Journal of Environmental Monitoring","volume":"14 9","pages":"2392-8"},"PeriodicalIF":0.0,"publicationDate":"2012-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/c2em30145h","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"30764063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}