{"title":"Biosynthesis and In Vitro Cytotoxic Performance of Bimetallic ZnO/CeO2 Nanoparticles","authors":"Khadijeh Hamidian, Mina Sarani","doi":"10.1007/s13538-024-01685-7","DOIUrl":"10.1007/s13538-024-01685-7","url":null,"abstract":"<div><p>Our research explored an environmentally friendly approach for the synthesis of bimetallic zinc oxide-cerium oxide nanoparticles (ZC NP) through the utilization of <i>Salvadora persica</i> extract. We characterized the physicochemical properties of the synthesized nanoparticles using PXRD, Raman spectroscopy, FESEM, and EDX analyses. As a result, both main peaks of zinc oxide and cerium oxide NP appeared in the PXRD graph, which indicated the formation of bimetallic NP. Spherical morphology showed in the FESEM image which particles have a size of about 30–40 nm. The analysis of hemocompatibility indicated that the NP does not appreciably affect the integrity of erythrocytes at concentrations nearing 2000 µg mL<sup>−1</sup>. The toxicity function of synthesized sample on human colon cancer (HT-29) and fibroblast (NIH/3T3) cells was considered through the results of MTT trial. The outcomes of synthesized NP displayed significant cytotoxic effects against HT-29 cells at 20.73 μg mL<sup>−1</sup> concentration as its IC50, while it was non-toxic on NIH-3T3 cells. Therefore, we suggest the applicability of our product in therapeutic applications such as drug delivery as well as industrial implementations.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142890474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Coherent Manipulation of Covalent Interaction of Atoms Using Surface Plasmon Polariton Dispersion Relation and Kerr Nonlinearity","authors":"Hussain Ahmad, Ghulam Saddiq","doi":"10.1007/s13538-024-01684-8","DOIUrl":"10.1007/s13538-024-01684-8","url":null,"abstract":"<div><p>The characterization of covalent interactions between atoms is controlled and modified by the analysis of the dispersion relation of surface plasmon polariton (SPP) waves. The analysis was conducted at the interface of gold and dielectric cesium medium for the generation of SPPs and to extract information on covalent bonding among the atoms. Crucial information regarding atom localization and electron sharing among atoms is reported by damping and dispersion spectrums of SPPs. The real and imaginary components of the dispersion relation of SPP waves serve as indicators for the arrangement of atoms in elongated chains of covalent interactions. It is investigated that each atom contributes two electrons to the formation of double covalent bonds with neighboring atoms. The localization of atoms and the precise sharing of electrons is governed by the higher-order Kerr nonlinearity and the superposition of standing waves of control fields. Furthermore, the investigation extends to the identification of crystal defects within the optical lattice structure, which is achieved through an examination of the dispersion relation of surface SPP waves. Quantitatively eight atoms and twenty-four double covalent bonds are reported in the position ranges of <span>(2lambda )</span> in xy-plane. Our results provide useful information about material structure and nanotechnology.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142890445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Particle Current in Double-Path Josephson Junction under Rashba Interaction Connected to Bose-Einstein Condensate Reservoirs","authors":"Satoshi Kawaguchi","doi":"10.1007/s13538-024-01641-5","DOIUrl":"10.1007/s13538-024-01641-5","url":null,"abstract":"<div><p>We investigate the properties of a double-path Josephson junction connected to Bose-Einstein condensate reservoirs. By comparing the current in the proposed setup with that in a similar system connected to superconductors, we elucidate the key differences between the two systems. The systems are influenced by the Aharonov-Bohm effect, Rashba spin-orbit interaction, and phase difference of order parameters between left and right leads. Utilizing the Keldysh formalism, it turns out that, in the system connected to Bose-Einstein condensate reservoirs, the Josephson current includes higher frequency components of the phase difference between left and right reservoirs. Additionally, the dependence of critical current on energy level does not show the complete symmetric resonance but the Fano-type resonance with single or double peaks. These differences result from the bosonic statistics of reservoirs.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13538-024-01641-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Spectroscopic Properties of Blue Light-Emitting Li2SiO3:xGd3+ Phosphors for Solid State Lighting Applications","authors":"Priya Barik, Ishwar Prasad Sahu","doi":"10.1007/s13538-024-01673-x","DOIUrl":"10.1007/s13538-024-01673-x","url":null,"abstract":"<div><p>A series of blue light-emitting Li<sub>2</sub>SiO<sub>3</sub>:<i>x</i>Gd<sup>3+</sup> phosphors were prepared via a solid-state reaction method at 950℃ for 3 h in an air atmosphere. According to the powder X-ray diffractometer (PXRD) and Rietveld refinment analysis, the crystalline structure of the Li<sub>2</sub>SiO<sub>3</sub>:<i>x</i>Gd<sup>3+</sup> phosphors matrix did not significantly change. The optical band gaps E<sub>g</sub> of the sintered Li<sub>2</sub>SiO<sub>3</sub>:0.03Gd<sup>3+</sup> material has been calculated by 5.62 eV by the Tauc plot. Photoluminescence (PL) investigation of Li<sub>2</sub>SiO<sub>3</sub>:<i>x</i>Gd<sup>3+</sup> phosphors displayed an intense blue emission peak of Gd<sup>3+</sup> ions <sup>8</sup>S<sub>7/2</sub> → <sup>6</sup>I<sub>7/2</sub> transition, under near utra-violet (NUV) excitation of 276 nm. After the concentration of Gd<sup>3+</sup> ions in the Li<sub>2</sub>SiO<sub>3</sub> host reached 0.03 mol, the concentration quenching occurred, indicating that it had reached an optimal concentration. Under the UV excitation (276 nm); theLi<sub>2</sub>SiO<sub>3</sub>: 0.03Gd<sup>3+</sup> materials exhibit good temperature stability. The emission intensity, Commission Internationale de lEclairage (CIE) chromaticity coordinates, correlated color temperature (CCT), color purity, and quantum efficiency of Li<sub>2</sub>SiO<sub>3</sub>:0.03Gd<sup>3+</sup> phosphor were comprehensively enhanced by Gd<sup>3+</sup> doping. The blue region's CIE coordinate value confirms that Li<sub>2</sub>SiO<sub>3</sub>:Gd<sup>3+</sup> can be utilized as a component in solid-state display applications and artificial blue light-emitting diode (LED) generation.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142875163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation of Modulational Instability Drift Wave Packet in Non-uniform Magneto-Rotating Plasma","authors":"M. Eghbali, M. Mokari","doi":"10.1007/s13538-024-01659-9","DOIUrl":"10.1007/s13538-024-01659-9","url":null,"abstract":"<div><p>This paper addresses the modulation instability of ion-acoustic waves in a rotating plasma subjected to a magnetic field, focusing on how inhomogeneities in equilibrium density, electron temperature, and magnetic field influence wave behavior. We employ a combined hydrodynamic approach and perturbation method to derive the nonlinear Schrödinger equation (NLSE), effectively balancing nonlinearity with dispersive effects. Our analysis reveals various localized ion-acoustic excitations, including bright and dark envelope solitons, which emerge from modulational instability. We also demonstrate that specific solutions of the NLSE, such as the Peregrine soliton, Akhmediev breather, and Kuznetsov-Ma breather, represent rogue wave phenomena within this context. Numerical simulations indicate that plasma structural parameters, including rotational frequency and scale lengths, significantly impact modulation instability conditions. Notably, while these parameters enhance instability, further increases can lead to a reduction in rogue wave amplitude. Our findings provide insights into the formation mechanisms of nonlinear electrostatic excitations in both ultra-dense astrophysical and experimental plasma environments.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. B. Peixoto, L. F. S. Andrade, M. H. Carvalho, J. D. T. Santos, L. S. Silva, J. G. S. Duque
{"title":"Synthesis and Magnetic Characterization of Dispersed Fe(_x)Ni(_{100-x}) (x = 10, 20, 30, 40, and 50) Nanoalloys Using the Thermal Decomposition Method","authors":"E. B. Peixoto, L. F. S. Andrade, M. H. Carvalho, J. D. T. Santos, L. S. Silva, J. G. S. Duque","doi":"10.1007/s13538-024-01679-5","DOIUrl":"10.1007/s13538-024-01679-5","url":null,"abstract":"<div><p>In this paper, we report on synthesis and magnetic properties of dispersed Fe<span>(_x)</span>Ni<span>(_{1-x})</span> (<i>x</i> = 10, 20, 30, 40, and 50) nanoalloys grown by thermal decomposition. X-ray diffraction patterns show that the majority crystalline phase is consistent with a <i>fcc</i> crystal structure (space group <i>Fm</i>3<i>m</i>) for all samples. Magnetization as a function of magnetic field and temperature shows that Fe<span>(_x)</span>Ni<span>(_{1-x})</span> are superparamagnetic with blocking temperatures around 10 K. However, for all samples, it is possible to observe a second very broad maximum, which can be ascribed to a bimodal nanoparticle size distribution and/or Ni nanoparticles for the case of samples grown with <i>x</i> = 10, 20, and 30. Finally, we argue that the nanoalloy size distribution and/or interaction effects should play a crucial role in determining the magnetic behavior of samples once we are not able to fit our <span>(H_C)</span>(<i>T</i>) data using the Néel relaxation and the Bean-Livingston approaches in a wide temperature range.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Douglas Oliveira Novaes, José Helder Facundo Severo, Felipe Barbedo Rizzato, Gilson Ronchi, Tiago Fernandes, Mayara Yumi Ikeda, Vinícius Maia Neto, Fernando Albuquerque, Fellype do Nascimento, Juan Iraburu, Wanderley Pires de Sá, Leonardo Gimenes Sgubin, Jacques Levaton, Gustavo Paganini Canal, Zwinglio Guimarães Filho, Ricardo Magnus Osório Galvão, Michael Tendler
{"title":"Estimation of Effective Momentum Diffusivity and Its Correlation with Neutral Particle Density Based on Toroidal Rotation Profiles in the TCABR Tokamak","authors":"Douglas Oliveira Novaes, José Helder Facundo Severo, Felipe Barbedo Rizzato, Gilson Ronchi, Tiago Fernandes, Mayara Yumi Ikeda, Vinícius Maia Neto, Fernando Albuquerque, Fellype do Nascimento, Juan Iraburu, Wanderley Pires de Sá, Leonardo Gimenes Sgubin, Jacques Levaton, Gustavo Paganini Canal, Zwinglio Guimarães Filho, Ricardo Magnus Osório Galvão, Michael Tendler","doi":"10.1007/s13538-024-01681-x","DOIUrl":"10.1007/s13538-024-01681-x","url":null,"abstract":"<div><p>An equation for estimating the effective diffusivity <span>(chi _varphi ^textrm{eff})</span> based on the thermal and frictional forces arising from the interactions with neutral particles is provided. These interactions are primarily attributed to charge-exchange processes between ions and neutral particles. Our analysis indicates that the proposed forces are strong candidates to act as sources or sinks of momentum at the plasma edge. Furthermore, although we only have an estimated profile of neutral particles, the results demonstrate a strong dependence of the effective diffusivity on the ion-neutral collision frequency and a comparatively weaker dependence on ion temperature. We showed that the toroidal rotation profile in the TCABR tokamak is well described by the Helander model for toroidal rotation velocity in the Pfirsch-Schlüter regime, which depends on the ion temperature gradient in the presence of the neutral particles. The toroidal rotation profile has been reconstructed by a sum of Bessel functions, derived from the solution of a second-order differential equation for the toroidal velocity. In this initial study on momentum transport in TCABR, our findings indicate that <span>(chi _varphi ^textrm{eff})</span>—which accounts for both the diffusivity and pinch terms in the momentum equation—increases significantly in the outer plasma region. Additionally, it achieves a reasonable maximum value of approximately <span>(chi _varphi ^textrm{eff} approx 20)</span> m<span>(^2/)</span>s near the plasma edge at <span>(r/a simeq 0.87)</span>, in the same radial position of the maximum ion-neutral collision frequency, demonstrating that the applied method successfully captures the general behaviour of this component as reported in other works, and guiding future experimental validation.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Quantum Chemical Calculations, Spectroscopic Properties, Molecular Docking and ADMET Studies of 2-(4-Tert-Butyl-2,6-Dimethyl-3-Hydroxybenzyl)-2-Imidazoline","authors":"Taner Kalayci","doi":"10.1007/s13538-024-01674-w","DOIUrl":"10.1007/s13538-024-01674-w","url":null,"abstract":"<div><p>This study focuses on examining the molecular geometry, biological activities, as well as the electronic and vibrational properties of 2-(4-tert-butyl-2,6-dimethyl-3-hydroxybenzyl)-2-imidazoline (oxymetazoline). The investigation integrates quantum chemical calculations, molecular docking, and experimental methods. The ground state geometry and electronic structure of oxymetazoline are optimized using the DFT/B3LYP/6–311 + + G(d,p) basis set. To predict the chemical reactivity of the title molecule, MEPS, frontier orbital analysis, and electronic reactivity descriptors were used. Charge transfer within the molecule was presented using HOMO and LUMO energies. The energies of intra and intermolecular hydrogen bonds in molecules, as well as their electronic properties, were examined using natural bond orbitals (NBOs). To determine the efficiency of the title chemical, molecular docking tests were undertaken against α1A and α2A adrenergic receptors (α1A; PDB ID: 7YM8, 4MQT, and α2A; PDB ID: 3QAK, 7EJ8). According to the results, we found that the situation with the lowest binding score and therefore the best binding affinity is the OMZ-7YM8 interaction. The analysis of drug-likeness, physicochemical properties, and ADMET results indicates that the title molecule possesses a favorable pharmacokinetic profile and adheres to Lipinski’s Rule of Five, demonstrating efficient absorption and distribution. Consequently, the study supports the use of oxymetazoline as an inhibitor of α1A and α2A adrenergic receptors.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ernesto Kemp, Willian Vieira dos Santos, João C. dos Anjos, Pietro Chimenti, Luis Fernando Gomez Gonzalez, Germano P. Guedes, Herman P. Lima Jr., Rafael Antunes Nóbrega, Iuri Muniz Pepe, Dion Barbosa dos Santos Ribeiro
{"title":"Results from ON-OFF Analysis of the Neutrinos-Angra Detector","authors":"Ernesto Kemp, Willian Vieira dos Santos, João C. dos Anjos, Pietro Chimenti, Luis Fernando Gomez Gonzalez, Germano P. Guedes, Herman P. Lima Jr., Rafael Antunes Nóbrega, Iuri Muniz Pepe, Dion Barbosa dos Santos Ribeiro","doi":"10.1007/s13538-024-01667-9","DOIUrl":"10.1007/s13538-024-01667-9","url":null,"abstract":"<div><p>The Neutrinos Angra Experiment, a water-based Cherenkov detector, is located at the Angra dos Reis nuclear power plant in Brazil. Designed to detect electron antineutrinos produced in the nuclear reactor, the primary objective of the experiment is to demonstrate the feasibility of monitoring reactor activity using an antineutrino detector. This effort aligns with the International Atomic Energy Agency (IAEA) program to identify potential and novel technologies applicable to nonproliferation safeguards. Operating on the surface presents challenges such as high noise rates, necessitating the development of very sensitive, yet small-scale detectors. These conditions make the Angra experiment an excellent platform for both developing the application and gaining expertise in new technologies and analysis methods. The detector employs a water-based target doped with gadolinium to enhance its sensitivity to antineutrinos. In this work, we describe the main features of the detector and the electronics chain, including front-end and data acquisition components. We detail the data acquisition strategies and the methodologies applied for signal processing and event selection. Preliminary physics results suggest that the detector can reliably monitor reactor operations by detecting the inverse beta decay induced by electron antineutrinos from the reactor.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electrochemical Deposition of Ag/C Films: Effects of Silver Concentration on Structural, Optical, and Electrical Properties","authors":"Onur Nur, Alper Çetinel","doi":"10.1007/s13538-024-01675-9","DOIUrl":"10.1007/s13538-024-01675-9","url":null,"abstract":"<div><p>Silver-carbon (Ag/C) composite films were successfully fabricated on PET/ITO substrates using a novel two-step electrochemical deposition method. The impact of silver concentration on the structural, optical, and electrical properties of the films was systematically investigated. Scanning electron microscopy (SEM) revealed a heterogeneous film structure, with carbon conforming to the underlying silver morphology, which varied with silver concentration. Higher silver concentrations resulted in larger and denser silver structures. Optical characterization demonstrated that the addition of carbon significantly enhanced transmittance, particularly at lower silver concentrations, making these films promising candidates for transparent conductive electrodes. Both Ag and Ag/C films exhibited ohmic behavior, as evidenced by linear current–voltage (I-V) characteristics. Ag/C films showed superior conductivity compared to pure Ag films, attributed to the contribution of the carbon layer to electron transport. Hall measurements further confirmed the enhanced electrical properties of Ag/C films, revealing lower sheet resistance and resistivity compared to Ag films. The improved homogeneity of Ag/C films, due to the incorporation of carbon, is beneficial for achieving uniform electrical properties. These findings highlight the potential of electrochemically deposited Ag/C composites for various technological applications, including flexible electronics, optoelectronics, sensors, and energy storage devices.</p></div>","PeriodicalId":499,"journal":{"name":"Brazilian Journal of Physics","volume":"55 1","pages":""},"PeriodicalIF":1.5,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142821485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}