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Structure and Bonding of Group 14 Clusters: Wade’s Rules and Beyond 14组簇的结构和键合:韦德的规则及以后
4区 化学
Structure and Bonding Pub Date : 2021-01-01 DOI: 10.1007/430_2021_84
Jing-Xuan Zhang, F. Sheong, Zhenyang Lin
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引用次数: 0
Introduction to Tensor Surface Harmonic Theory 张量曲面调和理论导论
4区 化学
Structure and Bonding Pub Date : 2021-01-01 DOI: 10.1007/430_2021_89
D. Mingos
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引用次数: 0
Electron Counting Rules for Gold Clusters Which Are Stereochemically Non-rigid and Exhibit Skeletal Isomerism 具有立体非刚性和骨架异构的金簇的电子计数规则
4区 化学
Structure and Bonding Pub Date : 2021-01-01 DOI: 10.1007/430_2021_87
D. Mingos
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引用次数: 1
Personal Historical Perspective on the Development of Electron Counting Rules for Boranes and Clusters and Ken Wade’s Contribution 硼烷和团簇电子计数规则发展的个人历史观点及肯·韦德的贡献
4区 化学
Structure and Bonding Pub Date : 2021-01-01 DOI: 10.1007/430_2021_86
D. Mingos
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引用次数: 0
Binary Zintl Anions Involving Group 13–15 (Semi-)Metal Atoms, and the Relationship of Their Structures to Electron Count 含13-15族(半)金属原子的二元锌离子及其结构与电子数的关系
4区 化学
Structure and Bonding Pub Date : 2021-01-01 DOI: 10.1007/430_2021_88
Fuxing Pan, B. Weinert, S. Dehnen
{"title":"Binary Zintl Anions Involving Group 13–15 (Semi-)Metal Atoms, and the Relationship of Their Structures to Electron Count","authors":"Fuxing Pan, B. Weinert, S. Dehnen","doi":"10.1007/430_2021_88","DOIUrl":"https://doi.org/10.1007/430_2021_88","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":"14 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85912186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Thermoelectric Properties of Ternary and Quaternary Mo6 and Mo9 Cluster Selenides 三元和季系Mo6和Mo9簇硒化物的热电性质
4区 化学
Structure and Bonding Pub Date : 2019-04-28 DOI: 10.1007/430_2019_36
C. Candolfi, P. Gougeon, P. Gall, M. Potel, A. Dauscher, B. Lenoir
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引用次数: 3
The Periodic Table's Impact on Bioinorganic Chemistry and Biology's Selective Use of Metal Ions. 元素周期表对生物无机化学的影响及生物对金属离子的选择性利用。
4区 化学
Structure and Bonding Pub Date : 2019-01-01 DOI: 10.1007/430_2019_45
Ambika Bhagi-Damodaran, Yi Lu
{"title":"The Periodic Table's Impact on Bioinorganic Chemistry and Biology's Selective Use of Metal Ions.","authors":"Ambika Bhagi-Damodaran,&nbsp;Yi Lu","doi":"10.1007/430_2019_45","DOIUrl":"https://doi.org/10.1007/430_2019_45","url":null,"abstract":"<p><p>Despite the availability of a vast variety of metal ions in the periodic table, biology uses only a selective few metal ions. Most of the redox active metals used belong to the first row of transition metals in the periodic table and include Fe, Co, Ni, Mn and Cu. On the other hand, Ca, Zn and Mg are the most commonly used redox inactive metals in biology. In this chapter, we discuss the periodic table's impact on bio-inorganic chemistry, by exploring reasons behind this selective choice of metals biology. A special focus is placed on the chemical and functional reasons why one metal ion is preferred over another one. We discuss the implications of metal choice in various biological processes including catalysis, electron transfer, redox sensing and signaling. We find that bioavailability of metal ions along with their redox potentials, coordination flexibility, valency and ligand affinity determine the specificity of metals for biological processes. Understanding the implications underlying the selective choice of metals of the periodic table in these biological processes can help design more efficient catalysts, more precise biosensors and more effective drugs.</p>","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":"182 ","pages":"153-173"},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1007/430_2019_45","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9448612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
The Periodic Table as a Career Guide: A Journey to Rare Earths 元素周期表作为职业指南:稀土之旅
4区 化学
Structure and Bonding Pub Date : 2019-01-01 DOI: 10.1007/430_2019_43
A. J. Ryan, W. Evans
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引用次数: 1
Chemical Valency: Its Impact on the Proposal of the Periodic System and Some Thoughts About Its Current Significance 化学价:对周期制提出的影响及对其当前意义的思考
4区 化学
Structure and Bonding Pub Date : 2019-01-01 DOI: 10.1007/430_2019_40
L. Gade
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引用次数: 1
Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes 八面体硫系铼簇:从固体到分离簇配合物
4区 化学
Structure and Bonding Pub Date : 2019-01-01 DOI: 10.1007/430_2019_33
V. Fedorov, N. Naumov
{"title":"Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes","authors":"V. Fedorov, N. Naumov","doi":"10.1007/430_2019_33","DOIUrl":"https://doi.org/10.1007/430_2019_33","url":null,"abstract":"","PeriodicalId":49469,"journal":{"name":"Structure and Bonding","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74583192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
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