Geochemical Perspectives最新文献

{"title":"Carbon Capture and Storage: From Global Cycles to Global Solutions","authors":"Eric Oelkers, Sigurdur Gislason","doi":"10.7185/geochempersp.12.2","DOIUrl":"https://doi.org/10.7185/geochempersp.12.2","url":null,"abstract":"Anthropogenic carbon emissions have overwhelmed the natural carbon cycle, leading to a dramatic increase in atmospheric CO2 concentration. The rate of this increase may be unprecedented in Earth’s history and is leading to a substantial increase in global temperatures, ocean acidification, sea level rise and potentially human health challenges. In this Geochemical Perspectives we review the natural carbon cycle and its link to global climate. Notably, as directly observed by field observations summarised in this volume, there is a natural negative feedback loop between increasing global temperature, continental weathering rates, and CO2 that has tended to limit Earth climate changes over geological time scales. Due to the rapid increase in atmospheric carbon concentrations, global average temperatures have increased by more than 1.2 °C since the start of the industrial revolution. One way to slow or even arrest this increasing global average temperature is through Carbon Capture and Storage (CCS). Carbon dioxide can be captured either from large industrial point sources or directly from the atmosphere. Taking account of the natural carbon cycle, the most secure approach to storing captured CO2 is by reacting it with mafic or ultramafic rocks to form stable carbonate minerals, a process referred to as “mineral carbonation”. Although mineral carbonation can occur and be accelerated at the Earth’s surface, due to the required scale and required time frames it is most effective in the subsurface. This subsurface mineralisation approach was developed into an industrial scale process through an academic-industrial collaboration called CarbFix. The history of CarbFix, from its beginnings as a concept through its installation as an industrial process is presented in detail. This Geochemical Perspectives concludes with an assessment of the future of subsurface mineralisation as a means to help address the global warming challenge, as well as a detailed list of potential research directions that need to be addressed to further upscale and optimise this carbon storage approach.","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"83 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135850260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A journey in Noble Gas Cosmochemistry and Geochemistry","authors":"R. Wieler","doi":"10.7185/geochempersp.12.1","DOIUrl":"https://doi.org/10.7185/geochempersp.12.1","url":null,"abstract":"I started my journey in science by studying noble gases implanted by the solar wind in dust grains on the surface of the Moon, and with many colleagues I have studied solar wind implanted noble gases in natural and artificial samples throughout my career, the latter exposed primarily by the Genesis space mission. Major questions are what noble gases in the solar wind can tell us about the present and the past Sun, and how they can contribute to understanding the formation and history of the planets and their building blocks, represented, for example, by meteorites. Since my early years as a postdoc, I have also been interested in noble gases (and radioactive nuclides) produced in meteorites and other extraterrestrial samples by interactions with energetic elementary particles from galactic cosmic radiation (and the Sun). These so called “cosmogenic” nuclides allow us to study the transport of meteorites to Earth, and the dynamics of the top surface layers (“regoliths”) on the Moon, asteroids, and comets. Cosmogenic noble gases are also crucial for studying even more exotic topics such as the history of tiny presolar grains that formed in the cooling envelopes of earlier generations of stars towards the end of their lives and were eventually incorporated into the meteoritic matter where they are found today. Cosmogenic noble gases in some tiny phases in meteorites are also likely tracers of our highly active Sun at a very early stage in its history. A few years later, I started my third major research topic in cosmochemistry, the study of primordial noble gases in meteorites and other extraterrestrial samples. These noble gases were incorporated into meteorites or their precursors in the early solar system or even in a presolar environment. I also participated in studies by colleagues of isotopic anomalies of other elements important in cosmochemistry, my expertise being mainly in aspects of the influence of cosmic rays on these elements. Although working in an Earth Science institution, it took quite a while before I started to also study noble gases (and radionuclides) in terrestrial samples. This is described in the second part of this contribution. A major focus was on cosmogenic noble gases and radionuclides produced in samples near the Earth’s surface. Although production rates of cosmogenic nuclides on Earth are several orders of magnitude lower than in space, making their analysis more challenging, they have become an important tool in geomorphology. Because stable noble gas nuclides are particularly well suited to the study of ancient landscapes, much of our work focused on areas with arid climates, such as Antarctica and the Andes in Chile, in collaboration with geoscience colleagues. We also participated in the large multinational CRONUS collaboration, funded by the European Union, a community effort to improve our knowledge of nuclide production rates at the Earth’s surface. In another major collaboration with external colleagues we ar","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"1 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2023-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48718228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anoxia-Related Biogeochemistry of North Indian Ocean","authors":"S. Naqvi","doi":"10.7185/geochempersp.11.2","DOIUrl":"https://doi.org/10.7185/geochempersp.11.2","url":null,"abstract":"Complex interactions between microbial communities and geochemical processes drive the major element cycles and control the function of marine sediments as a dynamic reservoir of organic matter. Sulfate reduction is globally the dominant pathway of anaerobic mineralisation and is the main source of sulfide. The effective re-oxidation of this sulfide at the direct or indirect expense of oxygen is a prerequisite for aerobic life on our planet. Although largely hidden beneath the oxic sediment surface, the sulfur cycle is therefore critical for Earth’s redox state. This Geochemical Perspectives begins with a brief primer on the sulfur cycle of marine sediments and a description of my own scientific journey through nearly fifty years of studies of sulfur geochemistry and microbiology. Among the main objectives of these studies were to quantify the main processes of the sulfur cycle and to identify the microbial communities behind them. Radiotracers in combination with chemical analyses have thereby been used extensively for laboratory experiments, supported by diverse molecular microbiological methods. The following sections discuss the main processes of sulfate reduction, sulfide oxidation and disproportionation of the inorganic sulfur intermediates, especially of elemental sulfur and thiosulfate. The experimental approaches used enable the analysis of how environmental factors such as substrate concentration or temperature affect process rates and how concurrent processes of sulfate reduction and sulfide oxidation drive a cryptic sulfur cycle. The chemical energy of sulfide is used by chemolithotrophic bacteria, including fascinating communities of big sulfur bacteria and cable bacteria, and supports their dark CO2 fixation, which produces new microbial biomass. During the burial and aging of marine sediments, the predominant mineralisation processes change through a cascade of redox reactions, and the rate of organic matter degradation drops continuously over many orders of magnitude. The main pathways of anaerobic mineralisation and the age control of the organic matter turnover are discussed. In the deep methanic zone, only a few percent of the entire degradation process remains, which provides a small boost of substrate for sulfate reduction through the process of anaerobic methane oxidation. The stable isotopes of sulfur provide an additional tool to understand these diagenetic processes, whereby the combination of microbial isotope fractionation and open system diagenesis generate a differential diffusion flux of the isotopes. In relation to the organic carbon cycle of the seabed and the contribution of methane, the paper discusses the global sulfur budget and the role of sulfate reduction for organic matter mineralisation in different depth regions of the ocean - from coast to deep sea. The published estimates of these parameters are evaluated and compared. Finally, the paper looks at future perspectives with respect to gaps in our current u","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"1 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44733784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Academic Reminiscences and Thermodynamics-Kinetics of Thermo-Barometry-Chronology","authors":"J. Ganguly","doi":"10.7185/geochempersp.10.1","DOIUrl":"https://doi.org/10.7185/geochempersp.10.1","url":null,"abstract":"This article has three major components that include, in addition to the technical aspects, reminiscences of my academic upbringing, my move to the USA from India, and my professional career. I have recounted many stories that I hope convey some sense of time, especially in these two countries with vastly different cultures, my personal journey with its ups and downs and how I made the transition to an academic career path in USA even though that was not in my future plan as a young man. The development of the field of thermobarometry and its integration with diffusion and crystal kinetic modelling of compositional zoning (or lack thereof) and cation ordering in minerals have led to important quantitative constraints on the pressure-temperature-time evolution of terrestrial rocks and meteorites. I review the historical developments in these areas and a segment of my own research spanning the period of 1964-2021. The foundational works of the thermometry of metamorphic rocks and palaeothermometry were laid at the University of Chicago around 1950. Subsequently, the synergetic growth of thermodynamics and experimental studies in petrology in the 1960s and 1970s, along with the introduction of electron microprobe as a nondestructive analytical tool with micron scale resolution, gave a major boost to the field of thermobarometry. There were also significant new developments in the field of thermodynamics of solid solutions in the petrology community and demonstration from observational data, countering strong scepticism, that the principles of classical thermodynamics were applicable to “complex natural systems”. The section on thermodynamic basis of thermobarometry concludes with a discussion of the thermodynamics of trace element and single mineral thermometry. I further deal with the experimental protocols, along with selected examples, for phase equilibrium studies that provide the bedrock foundation for the field of thermobarometry based on elemental compositions of coexisting minerals in a rock. It is followed by an account of the controversies and international meetings relating to the aluminum silicate and peridotite phase diagrams that play crucial roles in the thermobarometry of metamorphic rocks and mantle xenoliths, respectively. The construction of quantitative petrogenetic grids to display stability relations of minerals in multicomponent–multiphase systems came into play in the field of metamorphic petrology in the mid-1960s and early 1970s. Augmented by experimental data, these petrogenetic grids led to important discoveries about the P-T-f(O2) and bulk compositional controls on the stability of certain “index” minerals that are used to define metamorphic isograds and different types of regional metamorphism; one such grid also opened up a new field that came to be known as ultra-high temperature metamorphism. The construction of petrogenetic grids has now evolved to computer based calculations of complex equilibrium P-T phase diagram","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"1 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2021-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46366423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Origins and Early Evolution of the Atmosphere and the Oceans","authors":"B. Marty","doi":"10.7185/geochempersp.9.2","DOIUrl":"https://doi.org/10.7185/geochempersp.9.2","url":null,"abstract":"My journey in science began with the study of volcanic gases, sparking an interest in the origin, and ultimate fate, of the volatile elements in the interior of our planet. How did these elements, so crucial to life and our surface environment, come to be sequestered within the deepest regions of the Earth, and what can they tell us about the processes occurring there? My approach has been to establish geochemical links between the noble gases, physical tracers par excellence, with major volatile elements of environmental importance, such as water, carbon and nitrogen, in mantle-derived rocks and gases. From these analyses we have learned that the Earth is relatively depleted in volatile elements when compared to its potential cosmochemical ancestors (e.g., ~2 ppm nitrogen compared to several hundreds of ppm in primitive meteorites) and that natural fluxes of carbon are two orders of magnitude lower than those emitted by current anthropogenic activity. Further insights into the origin of terrestrial volatiles have come from space missions that documented the composition of the proto-solar nebula and the outer solar system. The consensus behind the origin of the atmosphere and the oceans is evolving constantly, although recently a general picture has started to emerge. At the dawn of the solar system, the volatile-forming elements (H, C, N, noble gases) that form the majority of our atmosphere and oceans were trapped in solid dusty phases (mostly in ice beyond the snowline and organics everywhere). These phases condensed from the proto-solar nebula gas, and/or were inherited from the interstellar medium. These accreted together within the next few million years to form the first planetesimals, some of which underwent differentiation very early on. The isotopic signatures of volatiles were also fixed very early and may even have preceded the first episodes of condensation and accretion. Throughout the accretion of the Earth, volatile elements were delivered by material from both the inner (dry, volatile-poor) and outer (volatile-rich) solar system. This delivery was concomitant with the metals and silicates that form the bulk of the planet. The contribution of bodies that formed in the far outer solar system, a region now populated by comets, is likely to have been very limited. In that sense, volatile elements were contributed continuously throughout Earth’s accretion from inner solar system reservoirs, which also provided the silicates and metal building blocks of the inner planets. Following accretion, it likely took a few hundred million years for the Earth’s atmosphere and oceans to stabilise. Luckily, we have been able to access a compositional record of the early atmosphere and oceans through the analysis of palaeo-atmospheric fluids trapped in Archean hydrothermal quartz. From these analyses, it appears that the surface reservoirs of the Earth evolved due to interactions between the early Sun and the top of the atmosphere, as well as the de","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"9 1","pages":"135-136"},"PeriodicalIF":3.8,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41836532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Geology, Policy and Wine – The Intersection of Science and Life","authors":"L. Meinert","doi":"10.7185/geochempersp.9.1","DOIUrl":"https://doi.org/10.7185/geochempersp.9.1","url":null,"abstract":"","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"9 1","pages":"1-133"},"PeriodicalIF":3.8,"publicationDate":"2020-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45804462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"My Stable Isotope Journey in Biogeochemistry, Geoecology, and Astrobiology","authors":"M. Fogel","doi":"10.7185/geochempersp.8.2","DOIUrl":"https://doi.org/10.7185/geochempersp.8.2","url":null,"abstract":"","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"1 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2019-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49415541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"CO2: Earth’s Climate Driver","authors":"W. Broecker","doi":"10.7185/GEOCHEMPERSP.7.2","DOIUrl":"https://doi.org/10.7185/GEOCHEMPERSP.7.2","url":null,"abstract":"","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"1 1","pages":""},"PeriodicalIF":3.8,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44430446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Big-Picture Geochemistry from Microanalyses – My Four-Decade Odyssey in Sims","authors":"N. Shimizu","doi":"10.7185/GEOCHEMPERSP.8.1","DOIUrl":"https://doi.org/10.7185/GEOCHEMPERSP.8.1","url":null,"abstract":"","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"8 1","pages":"1-2"},"PeriodicalIF":3.8,"publicationDate":"2018-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45994482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cosmochemistry Along The Rhine","authors":"H. Palme","doi":"10.7185/GEOCHEMPERSP.7.1","DOIUrl":"https://doi.org/10.7185/GEOCHEMPERSP.7.1","url":null,"abstract":"","PeriodicalId":48921,"journal":{"name":"Geochemical Perspectives","volume":"7 1","pages":"1-2"},"PeriodicalIF":3.8,"publicationDate":"2018-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45260233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}