发布求助
文献互助 智能选刊 最新文献

Inorganic Chemistry最新文献

筛选
英文 中文
IF 4.3 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30
Marcos Tapia, Shyam K. Pahari, Sandip Das, Firoz Shah Tuglak Khan and Shabnam Hematian*, 
{"title":"","authors":"Marcos Tapia, Shyam K. Pahari, Sandip Das, Firoz Shah Tuglak Khan and Shabnam Hematian*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 25","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c01099","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144513456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.3 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30
Dan Zhang, Taifang Zhang, Mekhrdod Kurboniyon, Peng Wang* and Chonggeng Ma*, 
{"title":"","authors":"Dan Zhang, Taifang Zhang, Mekhrdod Kurboniyon, Peng Wang* and Chonggeng Ma*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 25","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c01718","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144513457","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.3 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30
Ashish Kumar Dhara, Song-Song Bao, Ye-Hui Qin and Li-Min Zheng*, 
{"title":"","authors":"Ashish Kumar Dhara, Song-Song Bao, Ye-Hui Qin and Li-Min Zheng*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 25","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c00763","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144513462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.3 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30
Haoduo Yu, Yueliang Liu, Dandan Han, Xicheng Wang* and Yuhua Wang*, 
{"title":"","authors":"Haoduo Yu, Yueliang Liu, Dandan Han, Xicheng Wang* and Yuhua Wang*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 25","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c00929","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144513463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nickel Pyrrolide Complexes as Precursors for the Chemical Vapor Deposition of Metallic Thin Films of Nickel. 镍吡啶配合物作为化学气相沉积镍金属薄膜的前驱体。
IF 4.6 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30 DOI: 10.1021/acs.inorgchem.5c01934
Thomas Pugh,Joe C Goodall,Kieran C Molloy,Andrew L Johnson
{"title":"Nickel Pyrrolide Complexes as Precursors for the Chemical Vapor Deposition of Metallic Thin Films of Nickel.","authors":"Thomas Pugh,Joe C Goodall,Kieran C Molloy,Andrew L Johnson","doi":"10.1021/acs.inorgchem.5c01934","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c01934","url":null,"abstract":"We report here the synthesis of a novel class of precursors for the chemical vapor deposition (CVD) of thin films of metallic, face-centered cubic (fcc) nickel. The complexes are simple and inexpensive to synthesize, possess high volatility (vapor pressure = 0.1 Torr at 40 °C), and enable rapid deposition rates of nickel under CVD conditions (up to 6.5 nm/min at 250 °C). We show that the deposited nickel films have high elemental purity (>99 at%), resistivity comparable to bulk nickel (7-23 μΩ·cm cf. 6.93 μΩ·cm), exhibit shallow surface features (ca. ± 10 nm), and very low surface roughness (RMS = 2.72 nm). These data compare favorably with those of the current state-of-the-art metallic nickel CVD precursors.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"69 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144521439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direction and Temperature-Dependent Properties of an Antimony-Based Two-Dimensional Halide Double Perovskite. 锑基二维卤化物双钙钛矿的方向和温度依赖性质。
IF 4.6 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30 DOI: 10.1021/acs.inorgchem.5c02365
Shubham Ajaykumar Rajput,Sudhadevi Antharjanam,Aravind Kumar Chandiran
{"title":"Direction and Temperature-Dependent Properties of an Antimony-Based Two-Dimensional Halide Double Perovskite.","authors":"Shubham Ajaykumar Rajput,Sudhadevi Antharjanam,Aravind Kumar Chandiran","doi":"10.1021/acs.inorgchem.5c02365","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c02365","url":null,"abstract":"Two-dimensional (2D) organic-inorganic halide double perovskites have attracted wide attention due to their structural diversity and chemical tunability. Herein, we report a new 2D layered halide double perovskite material, (BrPA)4AgSbBr8 (BPAS), and its properties are compared with (BrPA)4AgInBr8 (BPAIn, PA─propylammonium) and previously reported noncentrosymmetric Cl0.26Br3.74PA4AgSbBr8 (CPAS, CPA─chloropropylammonium). BPAS and BPAIn crystallize in the P2/c monoclinic space group with 2D layers of inorganic octahedra formed by monovalent and trivalent cations separated by two layers of organic linkers. Unlike their 3D counterparts, Cs2Ag(In/Sb)X6 (X-halide), the octahedra are distorted, reducing their symmetry. This led to the broadening of the optical gap in the present materials and also affected the photoluminescence (PL) and conduction properties. The BPAS shows a slight indirect band gap but shows PL emission with contributions from band-to-band, free/bound excitonic, and self-trapped excitonic states. The STEs enabled broader emission in these two materials. The 2D nature of the material shows anisotropic conduction properties where the in-plane conduction is found to be different from out-of-plane conduction. The value of charge transfer resistance decreases from GΩ (at -73 °C) to kΩ (at 202 °C) due to the presence of thermally activated carrier mobility through a correlated barrier hopping mechanism.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"27 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144521505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.3 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30
Xiong-Feng Ma, Zhuang Miao, Hongping Hou, Amei Zhang, Ying-Cong Wei, Rong Zhang, Yao-Du Zhang, Chaoqian Ai*, Zhihuan Zhou and Hongliang Du*, 
{"title":"","authors":"Xiong-Feng Ma, Zhuang Miao, Hongping Hou, Amei Zhang, Ying-Cong Wei, Rong Zhang, Yao-Du Zhang, Chaoqian Ai*, Zhihuan Zhou and Hongliang Du*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 25","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c01991","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144513442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 4.3 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30
Qingqing Feng, Chunliang Yang, Chenghui Wang, Qingmei Ge and Jiang Zhao*, 
{"title":"","authors":"Qingqing Feng, Chunliang Yang, Chenghui Wang, Qingmei Ge and Jiang Zhao*, ","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"64 25","pages":"XXX-XXX XXX-XXX"},"PeriodicalIF":4.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.5c00529","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144513470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficiency of Photodissociation of Carbonyl Ligand in Ruthenium Monocarbonyl Bipyridine Complexes: Effect of Isomeric Structures and Ligands. 钌单羰基联吡啶配合物中羰基配体的光解效率：异构体结构和配体的影响。
IF 4.6 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30 DOI: 10.1021/acs.inorgchem.5c00466
Yusuke Kuramochi,Jun Itabashi,Mari Toyama,Seiichi Tanaka,Noriharu Nagao,Ken Onda,Hitoshi Ishida
{"title":"Efficiency of Photodissociation of Carbonyl Ligand in Ruthenium Monocarbonyl Bipyridine Complexes: Effect of Isomeric Structures and Ligands.","authors":"Yusuke Kuramochi,Jun Itabashi,Mari Toyama,Seiichi Tanaka,Noriharu Nagao,Ken Onda,Hitoshi Ishida","doi":"10.1021/acs.inorgchem.5c00466","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c00466","url":null,"abstract":"Photoactivated CO-releasing molecules have potential medical applications. trans(Cl,Cl)-[Ru(bpy)(CO)2Cl2] (bpy = 2,2'-bipyridine) efficiently releases the first CO ligand (∼100% quantum yield), but the second CO dissociation is inefficient, and its precise quantum yield remains undetermined. Photodissociation of trans(Cl,Cl)-[Ru(bpy)(CO)2Cl2] yielded two monocarbonyl complexes, cis(Cl,Cl),trans(Cl,CH3CN)-[Ru(bpy)(CO)(CH3CN)Cl2] and trans(Cl,Cl)-[Ru(bpy)(CO)(CH3CN)Cl2], as the major and minor stereoisomeric products, respectively. The apparent quantum yields for the second CO dissociations were 0.56% and 0.78% for cis(Cl,Cl),trans(Cl,CH3CN)- and trans(Cl,Cl)-isomers, respectively. Considering the efficient photoisomerization of the trans(Cl,Cl)- to cis(Cl,Cl),trans(Cl,CH3CN)-isomer, the trans(Cl,Cl)-isomer would have a higher quantum yield. We also isolated the monocarbonyl complex after the first CO dissociation of trans(Cl,Cl)-[Ru(6Mes-bpy)(CO)2Cl2] (6Mes-bpy = 6,6'-dimesityl-2,2'-bipyridine), which contains bulky substituents at the 6,6'-positions of the bpy ligand. X-ray crystal structure analysis revealed the selective formation of trans(Cl,Cl)-[Ru(6Mes-bpy)(CO)(CH3CN)Cl2]. The quantum yield for the second CO dissociation from this structure was found to be 2.0%, nearly four times larger than that of cis(Cl,Cl),trans(Cl,CH3CN)-[Ru(bpy)(CO)(CH3CN)Cl2]. Time-resolved IR (TRIR) measurements demonstrated that photoirradiation of cis(Cl,Cl),trans(Cl,CH3CN)-[Ru(bpy)(CO)(CH3CN)Cl2] produced a five-coordinate pyramidal square intermediate with a stronger Ru-CO bond than in the ground state. In contrast, no such intermediate was observed for trans(Cl,Cl)-[Ru(6Mes-bpy)(CO)(CH3CN)Cl2]. The presence of this intermediate is thought to be a key factor in inhibiting further CO dissociation.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"19 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144521447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring Photophysical Properties and Sensitivity to Oxygen in Anisolyl-Picolinate Antenna Conjugated to Azamacrocycles. 偶氮大环共轭苯甲酸乙酯天线的光物理性质及其对氧的敏感性研究。
IF 4.3 2区 化学
Inorganic Chemistry Pub Date : 2025-06-30 DOI: 10.1021/acs.inorgchem.5c00436
Lucile Bridou, Loëza Collobert, Kyangwi P Malikidogo, Salauat R Kiraev, Maher Hojorat, Nadège Hamon, Anh Thy Bui, François Riobé, Akos Banyasz, Maryline Beyler, Raphaël Tripier, Olivier Sénèque, Olivier Maury
{"title":"Exploring Photophysical Properties and Sensitivity to Oxygen in Anisolyl-Picolinate Antenna Conjugated to Azamacrocycles.","authors":"Lucile Bridou, Loëza Collobert, Kyangwi P Malikidogo, Salauat R Kiraev, Maher Hojorat, Nadège Hamon, Anh Thy Bui, François Riobé, Akos Banyasz, Maryline Beyler, Raphaël Tripier, Olivier Sénèque, Olivier Maury","doi":"10.1021/acs.inorgchem.5c00436","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c00436","url":null,"abstract":"<p><p>An anisolyl-picolinate antenna grafted onto different macrocyclic ligands such as tacn, pyclen, or cyclen renders the resulting terbium(III) complexes highly sensitive to oxygen in aqueous solutions, enabling the design of ratiometric or lifetime-based molecular sensors. The underlying sensitization mechanism was investigated using analogous gadolinium(III) complexes, and the oxygen sensitivity was studied using transient absorption spectroscopy. The antenna-based triplet lifetime increased by up to 900-fold upon degassing, underscoring the role of the ligand excited states in designing highly sensitive oxygen probes.</p>","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":" ","pages":""},"PeriodicalIF":4.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144525423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
首页 上一页 下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：604180095
Book学术官方微信