Inorganic Chemistry最新文献_第5页

Dimensionally Tunable Rod-Shaped Zirconia Particles via Bottom-Up Assembly. 通过自下而上组装的尺寸可调棒状氧化锆颗粒。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-29 DOI: 10.1021/acs.inorgchem.5c02410

Zhenhong Xue,Chenmin Yao,Junhui Zhang,Matthias Quintelier,Joke Hadermann,Jozef Vleugels,Bart Van Meerbeek,Fei Zhang

{"title":"Dimensionally Tunable Rod-Shaped Zirconia Particles via Bottom-Up Assembly.","authors":"Zhenhong Xue,Chenmin Yao,Junhui Zhang,Matthias Quintelier,Joke Hadermann,Jozef Vleugels,Bart Van Meerbeek,Fei Zhang","doi":"10.1021/acs.inorgchem.5c02410","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c02410","url":null,"abstract":"The synthesis of anisotropic particles is highly desirable due to their broad potential applications. However, achieving well-controlled anisotropic morphologies without templates remains a significant challenge. In this work, we present a solvothermal approach utilizing cosolvent systems to synthesize uniform, monodispersed rod-like zirconia particles with precisely controlled dimensions. Comparative studies between single-solvent systems (water and ethanol) and water/alcohol cosolvent systems (water/methanol, water/ethanol, and water/isopropanol) reveal that the use of cosolvents significantly promotes the formation of anisotropic (rod-like) zirconia particles. Furthermore, the dimensions of these rod-like particles can be finely tuned by adjusting the cosolvent (water/ethanol) volume ratio. The formation of rod-like structures without template is attributed to a bottom-up assembly process, comediated by cosolvent systems and key solvothermal kinetic parameters, including synthesis temperature, reaction time, and precursor pH. Building on this strategy, rod-like monoclinic zirconia particles synthesized from ZrOCl2·8H2O in water/ethanol cosolvent systems exhibits tunable lengths ranging from 82 ± 0.6 to 929 ± 13.8 nm and aspect ratios from 1.3 to 3.8. Additionally, the developed method enables scalable synthesis with a high production yield of 98.8%, producing well-crystallized rod-like monoclinic zirconia particles with an aspect ratio of approximately 2.5.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"6 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145188815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Aromaticity in Ancient Zeise’s Salt 古泽泽盐的芳香

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-29 DOI: 10.1021/acs.inorgchem.5c03091

Ankur K. Guha, Amlan J. Kalita, Mesías Orozco-Ic, María A. Fernández-Herrera, Gabriel Merino

引用次数: 0

Constructing an 8-Connected Hydrogen-Bonded Organic Framework with Hafnium-Oxo Clusters. 含铪氧簇的8连接氢键有机骨架的构建。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-29 DOI: 10.1021/acs.inorgchem.5c03602

Jie Zhao,Yu-Long Zhang,Jun-Rui Liu,Zi-Ang Nan,Lin-Xia Tang,Zuo-Bei Wang,Yun-Zhe Zhou,Zhu Zhuo,You-Gui Huang,Wei Wang

{"title":"Constructing an 8-Connected Hydrogen-Bonded Organic Framework with Hafnium-Oxo Clusters.","authors":"Jie Zhao,Yu-Long Zhang,Jun-Rui Liu,Zi-Ang Nan,Lin-Xia Tang,Zuo-Bei Wang,Yun-Zhe Zhou,Zhu Zhuo,You-Gui Huang,Wei Wang","doi":"10.1021/acs.inorgchem.5c03602","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c03602","url":null,"abstract":"Hydrogen-bonded organic frameworks (HOFs) exhibit intriguing structural features with potential applications in various fields. However, constructing HOFs based on high-connectivity nodes is a challenging task. In this study, we report the synthesis of three new metal-hydrogen-bonded organic frameworks (M-HOFs), Hf4-P4/n, Hf4-Fddd-1, and Hf4-Fddd-2, based on a charge-neutral tetranuclear hafnium-oxo cluster [Hf4(μ2-OH)8L8] (L = 1H-benzimidazole-2-carboxylate) as the building unit. The rigid benzimidazole-carboxylate ligand maintains the cluster's symmetry while providing hydrogen-bonding sites. By modulating crystallization conditions, three distinct supramolecular packing modes are achieved: Hf4-P4/n forms an sql net via four pairs of hydrogen bonds and four groups of DMF-mediated van der Waals interactions between [Hf4(μ2-OH)8L8] units; Hf4-Fddd-1 adopts a rarely seen 8-connected tsi net through eight pairs of intercluster hydrogen bonds; Hf4-Fddd-2 exhibits a dia net with only four pairs of hydrogen bonds per cluster. Framework stability correlates with interaction strength and number. Notably, Hf4-P4/n and Hf4-Fddd-1 show superior solvent stability compared to Hf4-Fddd-2. Porosity analysis reveals that Hf4-Fddd-1 possesses interconnected channels, with a void fraction of 31.1% and a surface area of 277.7 m2/g. This work highlights metal-oxo clusters as potential building units for synthesizing complex HOFs with high-connectivity nodes.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"2 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145188814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Bonding Effect of Partial Valence Band Depletion in Metallic [ZnSi] Layers of Li2[ZnSi] and a Comparison to "White Graphene" h-BN. Li2[ZnSi]金属[ZnSi]层中部分价带损耗的成键效应及与“白色石墨烯”h-BN的比较。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-29 DOI: 10.1021/acs.inorgchem.5c03292

Frank R Wagner,Alim Ormeci,Ulrich Schwarz

引用次数: 0

SrZnGeSe4: An Infrared Nonlinear Optical Crystal Material with Wide Transmission Range and Large SHG Response. SrZnGeSe4：具有宽透射范围和大SHG响应的红外非线性光学晶体材料。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-29 DOI: 10.1021/acs.inorgchem.5c03409

Xia Wu,Mengjie Ma,Huilin Yin,Shuchang Wu,Hang Zhang,Kuixian Cai,Xiaoming Jiang,Dajiang Mei

引用次数: 0

Silaiminyl-Silylene-Derived Unsymmetrical Diradicaloid Silacycles Isolated in Three Different Charge and Spin States. 在三种不同电荷和自旋状态下分离的硅胺基-硅基非对称双根类硅环。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-29 DOI: 10.1021/acs.inorgchem.5c01839

Chenfeng Wang,Yan Li,Sai Manoj N V T Gorantla,Ming-Der Su,Subuhan Ahamed,Zhifang Li,Liviu Ungur,Kartik Chandra Mondal

{"title":"Silaiminyl-Silylene-Derived Unsymmetrical Diradicaloid Silacycles Isolated in Three Different Charge and Spin States.","authors":"Chenfeng Wang,Yan Li,Sai Manoj N V T Gorantla,Ming-Der Su,Subuhan Ahamed,Zhifang Li,Liviu Ungur,Kartik Chandra Mondal","doi":"10.1021/acs.inorgchem.5c01839","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c01839","url":null,"abstract":"Organosilicon diradicals with singlet or triplet spin states of the two unpaired electrons are one of the foci in main group chemistry. However, to date, the reported isolable ones are still scarce owing to their high reactivity and lack of suitable synthetic methods. In this article, a series of diradical silacycles and their corresponding isomers 1,3-disila-pyrroles were facilely obtained via the reactions of a silaiminyl-silylene (1) serving as a precursor of \"masked\" bis-silylene, with various diarylacetylenes. The computed reaction mechanisms indicated a concomitant and energetically favored formation of both isomers through distinct paths. Theoretical studies demonstrated that the singlet diradicaloid silacycles (2) bear two unpaired electrons asymmetrically distributed in the molecular backbone and have a remarkably small singlet-triplet energy gap that results in the observable NMR and electron paramagnetic resonance signals. Moreover, the reactivity studies of the diradical silacycle were also conducted, giving rise to multiple hydrochlorinated products under the treatment of HCl and a monoradical cation (6) and a dication (7) via stepwise oxidation of AgOTf. Compounds 6 and 7 were isolated, characterized, and studied by density functional theory calculations. Interestingly, the heterocyclic compound 4 containing a CNPSi2 ring isolated from the reaction of 1 and Ad-C≡P showed Möbius-type aromaticity with the NICS(0) value of -6.8.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"95 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145182675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sr2CdGe3O9: A Potential Zero-Order Waveplate Crystal Featuring an Enlarged Bandgap and Extended Mid-Infrared Transparency. Sr2CdGe3O9：一种具有扩大带隙和扩展中红外透明度的潜在零阶波片晶体。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-26 DOI: 10.1021/acs.inorgchem.5c03571

Yujun Wang,Peng Zhao,Xianghao Kong,Tinghui Zhang,Ning Ye,Zhanggui Hu,Conggang Li

{"title":"Sr2CdGe3O9: A Potential Zero-Order Waveplate Crystal Featuring an Enlarged Bandgap and Extended Mid-Infrared Transparency.","authors":"Yujun Wang,Peng Zhao,Xianghao Kong,Tinghui Zhang,Ning Ye,Zhanggui Hu,Conggang Li","doi":"10.1021/acs.inorgchem.5c03571","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c03571","url":null,"abstract":"Zero-order waveplates play pivotal roles in polarization manipulation and laser technology, yet the fabrication of zero-order waveplate crystals that simultaneously exhibit small birefringence, a large bandgap, and a wide infrared (IR) transmission range remains a challenge. In this work, a novel germanate optical crystal, Sr2CdGe3O9 (SCGO), featuring isolated rigid [Ge3O9] clusters, was identified through spontaneous crystallization. SCGO demonstrates remarkable thermal stability, with an incongruent melting point of 1054 °C. Importantly, SCGO displays a favorable low birefringence of 0.006@1064 nm, superior to that of the commercially available waveplate crystal α-SiO2 (0.0092@532 nm). Additionally, this crystal exhibits an enlarged bandgap of 4.7 eV, a notably short UV cutoff edge at 225 nm, outperforming most germanates containing transition metals, along with an extended IR transmission window up to 6.0 μm. These exciting optical properties highlight the potential of SCGO as a zero-order waveplate crystal spanning from the UV to mid-IR wavelength range. The presence of isolated [Ge3O9] groups in the SCGO structure introduces a weak structural anisotropy, opening up new avenues for exploring zero-order waveplate materials in wide wavelength ranges.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"53 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145153351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Building Blocks Selected via a Rational Design Strategy for Developing POM-Based MOFs with Enhanced Proton Conductivity. 通过合理设计策略选择构建块以开发具有增强质子导电性的pom基mof。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-26 DOI: 10.1021/acs.inorgchem.5c03333

Bao-Yue Zhang,Ning-Hao Wang,Xue-Song Wu,Yu Tian,Xinlong Wang,Xingqi Han,Zhongmin Su

{"title":"Building Blocks Selected via a Rational Design Strategy for Developing POM-Based MOFs with Enhanced Proton Conductivity.","authors":"Bao-Yue Zhang,Ning-Hao Wang,Xue-Song Wu,Yu Tian,Xinlong Wang,Xingqi Han,Zhongmin Su","doi":"10.1021/acs.inorgchem.5c03333","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c03333","url":null,"abstract":"Designing and synthesizing polyoxometalate-based metal-organic frameworks (POMOFs) with high proton conductivity is highly significant yet challenging. An effective strategy for developing highly proton-conductive POMOFs involves using polyoxometalates (POMs) with specific acid dissociation constants (pKa), which reflect the ability of an acid to donate protons and serve as a key parameter for proton conduction. Herein, two Anderson-type POMs, (NH4)3[AlMo6O24H6]·7H2O (AlMo6) and (NH4)3[CrMo6O24H6]·7H2O (CrMo6), whose pKa values were determined via DFT calculation. The reliability of these calculated pKa values was confirmed by a strong correlation with experimentally measured proton conductivities under humidified conditions. Using these POMs, along with metal-organic frameworks under hydrothermal conditions, we synthesized two isostructural POMOFs, denoted as CUST-835 (AlMo6) and CUST-836 (CrMo6). Alternating current (AC) impedance studies reveal that CUST-835 achieves a proton conductivity of 2.06 × 10-4 S cm-1 at 90 °C and 98% RH, an order of magnitude higher than that of CUST-836 (1.11 × 10-5 S cm-1).","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"37 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145153347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Monomeric Sr Complexes Combined with Tetradentate Enaminolate Ligands for Containing Sr Thin-Film Deposition. 单体锶配合物与四齿漆包酸盐配体结合用于含锶薄膜沉积。

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-26 DOI: 10.1021/acs.inorgchem.5c02456

Yongmin Go,Sangmi Gu,Sunyoung Shin,Seung Uk Son,Taek-Mo Chung,Ji Yeon Ryu,Bo Keun Park

{"title":"Monomeric Sr Complexes Combined with Tetradentate Enaminolate Ligands for Containing Sr Thin-Film Deposition.","authors":"Yongmin Go,Sangmi Gu,Sunyoung Shin,Seung Uk Son,Taek-Mo Chung,Ji Yeon Ryu,Bo Keun Park","doi":"10.1021/acs.inorgchem.5c02456","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c02456","url":null,"abstract":"New strontium complexes, Sr(ONO1)2 (strontium-1-(bis(2-methoxyethyl)amino)-3,3-dimethylbut-1-en-2-olate) (1), Sr(ONO2)2 (strontium-1-(bis(2-ethoxyethyl)amino)-3,3-dimethylbut-1-en-2-olate) (2), and Sr(ONO3)2 (strontium-2-(bis(2-methoxyethyl)amino)-1-(dimethylamino)ethen-1-olate) (3), were successfully synthesized and characterized using tetradentate ligands. The molecular structures of 1-3 were elucidated by nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric analysis (TGA), elemental analysis (EA), and single-crystal X-ray crystallography (XRC). All three complexes exhibited mononuclear structures, featuring nearly identical bicapped trigonal prismatic geometries. TGA revealed that 1, 2, and 3 retained residues of approximately 9.9, 11.9, and 34.5% at 450 °C, respectively. Notably, 1 showed volatility at 70 °C under 0.75 Torr and exhibited a vapor pressure of 0.1 Torr at 150 °C. The enthalpy of evaporation (ΔHvap) for 1 was calculated to be 50.3 kJ/mol. Among the synthesized complexes, 1 demonstrated the highest thermal stability and is considered a promising precursor for atomic layer deposition (ALD) of strontium-containing oxide thin films.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"52 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tailoring the Luminescence Properties of Cs2TeCl6 Nanocrystals via High-Pressure and Low-Temperature Stimuli for Multiparameter Optical Manometry and Thermometry. 基于高压和低温刺激的Cs2TeCl6纳米晶体在多参数光学测压和测温中的发光特性

IF 4.6 2区化学

Inorganic Chemistry Pub Date : 2025-09-26 DOI: 10.1021/acs.inorgchem.5c03775

Zhiyu Pei,Marcin Runowski,Przemysław Woźny,Peng Du,Ning Chen

{"title":"Tailoring the Luminescence Properties of Cs2TeCl6 Nanocrystals via High-Pressure and Low-Temperature Stimuli for Multiparameter Optical Manometry and Thermometry.","authors":"Zhiyu Pei,Marcin Runowski,Przemysław Woźny,Peng Du,Ning Chen","doi":"10.1021/acs.inorgchem.5c03775","DOIUrl":"https://doi.org/10.1021/acs.inorgchem.5c03775","url":null,"abstract":"To search for a bifunctional luminescent platform for optical manometry and thermometry, Cs2TeCl6 nanocrystals were prepared. Excited at 456 nm, the designed nanocrystals emitted dazzling orange emission, whose fluorescence intensity, full width at half-maximum (fwhm), and decay time were sensitive to temperature. Through analyzing the temperature-dependent lifetime, the thermometric properties of the resulting nanocrystals were evaluated, resulting in a high relative sensitivity of 3.76% K-1. The pressure-related Raman spectra demonstrated the splendid structural stability and reversibility of the studied samples. By studying the pressure-dependent Raman modes, one knows that the maximum pressure sensitivity of the Cs2TeCl6 nanocrystals was 9.62 cm-1 GPa-1. Furthermore, as the pressure increases, a distinct spectral blue-shift was observed in the synthesized nanocrystals, contributing to the controllable luminescence at high-pressure. Through analyzing the pressure-dependent emission band centroid and fwhm, one knows that the maximum pressure sensitivities of the resultant nanocrystals were 3.54 and 4.82 nm GPa-1, respectively. Additionally, based on the pressure-dependent color coordinate, it was found that the maximum relative sensitivity of the designed nanocrystals was 4.62% GPa-1. Our findings imply that the utilization of high-pressure and low-temperature stimuli is an efficient route to regulate the luminescence properties of the Cs2TeCl6 nanocrystals.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"89 1","pages":""},"PeriodicalIF":4.6,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145140517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0