Industrial & Engineering Chemistry Research最新文献

{"title":"Reaction, Interaction, and Product Regulation of Thermolysis Section of Cu–Cl Thermochemical Cycle System for Hydrogen Production","authors":"Wenbin Tang,&nbsp;, ,&nbsp;Jin Shen,&nbsp;, ,&nbsp;Zhongjie Shen*,&nbsp;, ,&nbsp;Jiawei Wang,&nbsp;, and ,&nbsp;Haifeng Liu*,&nbsp;","doi":"10.1021/acs.iecr.5c02582","DOIUrl":"10.1021/acs.iecr.5c02582","url":null,"abstract":"<p >The four-step Cu–Cl thermochemical hydrogen production cycle can effectively convert heat energy into hydrogen energy, and the thermolysis reaction is the key stage for connecting the upstream and downstream reactions. This study focused on the influence of different upstream hydrolysates (Cu₂OCl₂ or CuO) on thermolysis and the different reaction mechanisms. The micromorphological changes during the reaction process, the specific information on the precipitated gases, and the effect of temperature and reaction time on the main and byproducts were analyzed. The results showed that the maximum CuCl yields of 84.58 and 82.26% were obtained from the thermolysis of Cu₂OCl₂ and CuCl₂–CuO equimolar mixtures. During the reaction, both reaction feedstocks shrink and then melt and start to precipitate O₂ at 430 and 415 °C, respectively. For the thermolysis of CuCl₂–CuO mixtures, an excess of CuCl₂ contributes to the main reaction. Finally, the complex reaction mechanism of thermolysis and product regulation was revealed.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18761–18771"},"PeriodicalIF":3.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pillared and Reduced Graphene Oxide Membranes for Organic Solvent Nanofiltration","authors":"Natechanok Yutthasaksunthorn,&nbsp;, ,&nbsp;Kaung Su Khin Zaw,&nbsp;, ,&nbsp;Scott A. Sinquefield,&nbsp;, and ,&nbsp;Sankar Nair*,&nbsp;","doi":"10.1021/acs.iecr.5c01758","DOIUrl":"10.1021/acs.iecr.5c01758","url":null,"abstract":"<p >This work demonstrates the capability of pillared and reduced graphene oxide (GO) membranes to perform organic solvent nanofiltration (OSN) in diverse nonpolar and polar solvents. The effects of pillaring by polyconjugated aromatic compounds (PACs) on solvent flux and molecular weight cutoffs (MWCOs) are investigated. Pyranine/solvent green 7 (SG) and toluidine blue O (TBO) were used as pillaring agents, followed by chemical reduction with hydriodic acid. This fabrication process yielded membranes with a stable cross-flow operation in both polar and nonpolar solvents. Pillared and reduced membranes (rSG-GO and rTBO-GO) exhibited 2-fold higher permeances in nonpolar solvents (C₆–C₁₀ alkanes and aromatics) compared to nonpillared membranes, while maintaining MWCOs of 500–600 Da in toluene. The membranes broadly followed a trend of higher permeance with decreasing solvent viscosity but with nuanced deviations based on membrane–solvent interactions. Reducing the thickness to ∼70 nm further enhanced permeance while maintaining rejection of larger solutes.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18817–18825"},"PeriodicalIF":3.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.iecr.5c01758","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Automated Machine Learning-Based Models for Predicting Effluent Total Nitrogen Concentration of Reclaimed Water in Constructed Wetlands and Precise Regulation of Manganese Ion Dosing Methods","authors":"Shuoyang Wang,&nbsp;, ,&nbsp;Yunze Bi,&nbsp;, ,&nbsp;Xiangyu Song,&nbsp;, ,&nbsp;Jia Liu,&nbsp;, ,&nbsp;Dangdang Gao,&nbsp;, ,&nbsp;Fei Zhao,&nbsp;, ,&nbsp;Fangchao Zhao,&nbsp;, ,&nbsp;Siyi Luo,&nbsp;, ,&nbsp;Wei Wei,&nbsp;, ,&nbsp;Cai Yanan*,&nbsp;, and ,&nbsp;Dong Chen*,&nbsp;","doi":"10.1021/acs.iecr.5c01469","DOIUrl":"10.1021/acs.iecr.5c01469","url":null,"abstract":"<p >Reclaimed water reuse is a vital strategy for addressing water scarcity, yet elevated total nitrogen (TN) concentrations in reclaimed water remain a major obstacle to its broader implementation. In this experiment, manganese ions (Mn²⁺) at concentrations of 0–8 mg/L were used to enhance the removal efficiency of ammonia nitrogen (NH₄–N), nitrite nitrogen (NO₂–N), nitrate nitrogen (NO₃–N), TN, total phosphorus (TP), and COD in constructed wetlands (CWs). The results showed that Mn²⁺ only improved the removal rates of NO₂–N, NO₃–N, and TN, with the TN removal rate increasing from 11 to 43%. Three different automated machine learning frameworks (Flaml, H₂O AutoML, and AutoGluon) were then applied to predict the effluent TN concentration, with the Flaml model demonstrating the best performance. Under a data set split ratio of 0.8 and a training time of 90 s, the Flaml model achieved an <i>R</i>² of 0.9833, with MAE and RMSE values of 0.145 and 0.182, respectively. Furthermore, the 3D partial dependence plot generated by the optimal model indicated that, while maintaining the effluent Mn²⁺ concentration below 0.1 mg/L, when the influent TN concentration reached its maximum value of 14.84 mg/L, the optimal Mn²⁺ dosing concentration was 6.3 mg/L, resulting in an effluent TN concentration of 4.9 mg/L. This study provides a novel modeling approach for understanding the complex biochemical processes in constructed wetlands for reclaimed water treatment, revealing the dependence between influent and effluent manganese ion concentrations and TN concentrations, and offering a new pathway for the application of artificial intelligence in the field of constructed wetlands.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18563–18575"},"PeriodicalIF":3.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mass Transfer Characteristics and Scale-Up of Cumene Oxidation in Continuous-Flow Reactors","authors":"Yuheng Lu,&nbsp;, ,&nbsp;Jinyu Sun,&nbsp;, ,&nbsp;Haitao Guo,&nbsp;, ,&nbsp;Jieyu Ran,&nbsp;, ,&nbsp;Jiqin Zhu,&nbsp;, and ,&nbsp;Le Du*,&nbsp;","doi":"10.1021/acs.iecr.5c02535","DOIUrl":"10.1021/acs.iecr.5c02535","url":null,"abstract":"<p >Technological upgrades and safe production are critical for cumene oxidation to produce phenol. Despite advancements in continuous-flow synthesis using microfluidics, scalability and productivity remain uncertain. Herein, we propose a strategy to maintain a consistent mass transfer coefficient in scaled-up coiled-tube and pipes-in-series reactors through flow pattern control. The relationship between flow characteristics and mass transfer coefficients under scaled-up conditions were explored, thereby validating the accuracy of mass transfer predictions based on flow pattern, flow velocities, and slug lengths. Reaction conversion and selectivity were confirmed to remain unaffected by a mass transfer coefficient greater than 0.001 m/s. Even in a scaled-up reactor with alternating 4 and 16.05 mm i.d. sections, mass transfer was also effectively accomplished within smaller tubes (4 mm i.d.) by controlling the flow pattern, ensuring sufficient liquid residence time and efficient gas dissolution. A conversion of approximately 64.0%, a yield of 57.3%, and a selectivity of 89.5% were maintained, while productivity increased 132-fold compared to the 0.6 mm i.d. reactor, reaching 88.4 t/a. The operational stability of the high-throughput pipes-in-series reactor was also verified.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18739–18749"},"PeriodicalIF":3.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145032255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Continuous-Flow Glycerolysis of Urea to Glycerol Carbonate: The Critical Role of Operating Pressure","authors":"Andrea Severini,&nbsp;, ,&nbsp;Biagio Anderlini,&nbsp;, ,&nbsp;Antonio Lezza,&nbsp;, ,&nbsp;Marianna Burello,&nbsp;, ,&nbsp;Nicola Porcelli,&nbsp;, ,&nbsp;Marco Mazzali,&nbsp;, ,&nbsp;Veronica D’Eusanio,&nbsp;, ,&nbsp;Mirco Rivi,&nbsp;, ,&nbsp;Claudio Fontanesi*,&nbsp;, and ,&nbsp;Fabrizio Roncaglia*,&nbsp;","doi":"10.1021/acs.iecr.5c02554","DOIUrl":"10.1021/acs.iecr.5c02554","url":null,"abstract":"<p >A combined theoretical and experimental study on the carbonylation of glycerol with urea has identified low operating pressure as a key parameter for process optimization. Based on these insights, an improved multiple-pass continuous-flow system was developed, enabling the solvent-free synthesis of glycerol carbonate (GC) with enhanced efficiency. The optimized process achieved a productivity of ∼130 g/day, delivering high purity (&gt;95%), and an isolated yield of 80%, thereby demonstrating the viability of this approach for sustainable GC production.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18630–18639"},"PeriodicalIF":3.9,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.iecr.5c02554","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigation of the Solubility Parameter of a Supercritical Carbon Dioxide–Cosolvent System by Molecular Dynamics Simulation","authors":"Junying Wang,&nbsp;, ,&nbsp;Yi Li,&nbsp;, ,&nbsp;Xuantong Li,&nbsp;, ,&nbsp;Bowei Zhang,&nbsp;, and ,&nbsp;Hui Jin*,&nbsp;","doi":"10.1021/acs.iecr.5c00701","DOIUrl":"10.1021/acs.iecr.5c00701","url":null,"abstract":"<p >The solubility parameter is a significant constant that could predict whether two substances are miscible. By applying molecular dynamics simulations, the solubility parameters of the SC-CO₂ and SC-CO₂–cosolvent were calculated in this work. The solubility parameter was studied concerning temperature, pressure, and density change; 11 various cosolvents were selected to examine the impact of cosolvent concentration and the interaction mechanism between cosolvents and SC-CO₂ molecules. The results showed that after adding the cosolvent, the system’s solubility parameter was greatly improved. As the cosolvent concentration increased, the solubility parameter grew. Furthermore, an equation was proposed to accurately predict the SC-CO₂–cosolvent mixed system’s solubility parameter, with a coefficient of determination <i>R</i>² of 0.996. There exists the hydrogen bonding interaction, the van der Waals interaction, and the electrostatic interaction between SC-CO₂ and cosolvent. Among them, the hydrogen bonding interaction energy was the most significant factor that helped increase the solubility parameter.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18964–18975"},"PeriodicalIF":3.9,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Modeling Chemical Looping Gasification with Agroforestry Residues: Validation against Results in a 20 kWth CLG Unit","authors":"Alberto Abad*,&nbsp;, ,&nbsp;Luis F. de Diego,&nbsp;, ,&nbsp;María T. Izquierdo,&nbsp;, ,&nbsp;Teresa Mendiara,&nbsp;, and ,&nbsp;Francisco García-Labiano,&nbsp;","doi":"10.1021/acs.iecr.5c01725","DOIUrl":"10.1021/acs.iecr.5c01725","url":null,"abstract":"<p >Biomass chemical looping gasification (BCLG) represents an innovative process that allows the generation of non-nitrogen-diluted synthesis gas with low tar content and the potential to avoid CO₂ emissions. In this work, a 1.5D macroscopic model for the fuel reactor of a BCLG unit was developed and validated to simulate the performance of the system under different operating conditions. The model was developed as simple as possible in order to have a powerful tool to simulate a large number of conditions in a relatively short period of time with low computing effort. However, it has the required complexity to consider the main processes affecting the reaction of the biomass and the oxygen carrier, such as reactor fluid dynamics and the reaction pathway of biomass in the fuel reactor. The main outputs of the model are presented and validated against results from a 20 kW_th BCLG unit with two biomasses, namely, pine forest residue and wheat straw pellets. The effects of several operating conditions (temperature, solid circulation rate, solid inventory, and gas flow) on the syngas yield and composition were successfully predicted by the model.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18576–18589"},"PeriodicalIF":3.9,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.iecr.5c01725","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Intensified Tricaprin Synthesis Using Multifrequency Ultrasound and Its Application as a Topical Drug Delivery System for Fungal Infections","authors":"Viraj N. Khasgiwale,&nbsp;, ,&nbsp;Jyotsna T. Waghmare,&nbsp;, and ,&nbsp;Parag R. Gogate*,&nbsp;","doi":"10.1021/acs.iecr.5c02112","DOIUrl":"10.1021/acs.iecr.5c02112","url":null,"abstract":"<p >The study presents the ultrasound-assisted synthesis of tricaprin using a triple frequency hexagonal ultrasonic reactor. The esterification of capric acid and glycerol was catalyzed by para-toluene sulfonic acid (<i>p</i>-TSA) at a 500 g scale. A one-factor-at-a-time approach was used to optimize reaction parameters under both conventional and ultrasonic conditions. Under optimized ultrasonic conditions of a 4:1 molar ratio, 150 W ultrasound power, 70% duty cycle, 1.5% <i>p</i>-TSA loading, and combined frequencies of 22–33–48 kHz, the tricaprin yield reached the maximum of 95.7% as determined by gas chromatography–flame ionization detector (GC–FID) analysis. The pseudo-first-order rate constant significantly increased to 0.0167 min^–1 in the ultrasound-assisted approach compared to 0.0035 min^–1 in the conventional method, while energy consumption was reduced by 19.2%, requiring only 1554.8 kJ against 1924.5 kJ. Among the catalysts evaluated, <i>p</i>-TSA and Amberlyst-15 showed the best catalytic performance among the homogeneous and heterogeneous categories, respectively. The synthesized tricaprin was formulated into a topical antifungal Bigel. Ex-vivo skin permeation studies demonstrated superior performance compared to a marketed formulation (Lulimac gel), with only 3.57% of the drug remaining unpenetrated in the Bigel, compared to 50% in the marketed product. Additionally, the bigel achieved significantly higher skin retention of 18%, while the marketed formulation showed only 0.45%. Overall, the study demonstrates the advantage of ultrasound technology for efficient tricaprin synthesis and its successful application in enhanced topical drug delivery.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18601–18617"},"PeriodicalIF":3.9,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Drastic Impact of Pressure on Energy Consumption in a Xylene-Splitter Distillation Column","authors":"William L. Luyben*,&nbsp;","doi":"10.1021/acs.iecr.5c02518","DOIUrl":"10.1021/acs.iecr.5c02518","url":null,"abstract":"<p >The use of distillation to separate close-boiling components requires columns that feature many stages, high reflux ratios, and large reboiler duties. Many of these types of columns that are widely used in the petroleum and chemical industries include “C2-Splitters” separating ethylene and ethane and “C3-Splitters” separating propylene and propane. Other important examples include separating several types of hydrocarbon isomers. The normal boiling points of the ortho, meta, and para isomers of xylene differ by only a few degrees (144, 139, and 138 °C), so a column that produces a bottoms rich in <i>ortho</i>-xylene has high energy consumption and large capital cost (many trays and large heat exchangers). A recent paper [Dai and co-workers, “Methanol Aromatization for the Co-Production of Para-Xylene and Light Olefins: Process Simulation and Evaluation”, <i>Ind. Eng. Chem. Res.</i> <b>2025</b>, <i>64</i>, 11428–11440] included this xylene separation using both conventional columns and advanced configurations. However, the authors appear to have arbitrarily set the operating pressure of the xylene-splitter column at 1.2 bar. The purpose of this work is to demonstrate that drastic reductions in energy and capital costs can be achieved by operating under vacuum conditions (0.1 bar).</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18976–18978"},"PeriodicalIF":3.9,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mesoporous K- and Ca-Promoted Ni/Al2O3 Catalysts Derived from MIL-53(Al) for Microwave Plasma-Assisted Dry Reforming of Methane into Syngas","authors":"Supaphorn Thammakan,&nbsp;, ,&nbsp;Dheerawan Boonyawan*,&nbsp;, ,&nbsp;Yothin Chimupala,&nbsp;, ,&nbsp;Saranphong Yimklan,&nbsp;, ,&nbsp;Arlee Tamman,&nbsp;, ,&nbsp;Pimchanok Tapangpan,&nbsp;, ,&nbsp;Takron Opassuwan,&nbsp;, ,&nbsp;Mudtorlep Nisoa,&nbsp;, and ,&nbsp;Choncharoen Sawangrat*,&nbsp;","doi":"10.1021/acs.iecr.5c02287","DOIUrl":"10.1021/acs.iecr.5c02287","url":null,"abstract":"<p >Microwave plasma-catalyzed dry reforming of methane (DRM) offers an innovative strategy for the conversion of CO₂ and CH₄ into syngas, highlighting the necessity for the development of novel catalysts. This study investigates the comparative efficacy of alkaline (e.g., K) and alkaline earth (e.g., Ca) promoters in enhancing the catalytic performance. The Ni₅M_2.5/Al_MIL (M = K, Ca) catalysts derived from MIL-53(Al) were synthesized and employed in the plasma-assisted DRM process. Among the catalysts evaluated, Ni₅Ca_2.5/AlMIL exhibited exceptional activity and synergy with plasma, achieving a fuel production efficiency (FPE) of about 36%. This catalyst demonstrated a CO₂ conversion of 53.5%, a CH₄ conversion of 43.4%, a CO selectivity of 56.5%, and a H₂ selectivity of 86.7%, resulting in CO and H₂ yields of 25.9 and 39.1%, respectively. The significant enhancement in catalytic efficiency can be attributed to several factors: improved reducibility, stronger metal–support interactions (MSI), increased basicity, facilitated the formation of oxygen vacancies, and diminished carbon deposition. These attributes collectively facilitate the enhanced adsorption and activation of reactive species, thereby optimizing the synergy between plasma and catalysts in the DRM process. Moreover, the mesoporous Al_MIL support contributes to a larger surface area and improved dispersion of active metals, effectively mitigating the limitations typically associated with conventional supports. Notably, the variation of the H₂/CO ratio from 4.0 to 1.9 can be linked to the modulation of CO selectivity influenced by the MSI and basicity of the catalysts. This study underscores the potential of tailored catalysts in enhancing the efficiency of the microwave plasma-catalyzed DRM process.</p>","PeriodicalId":39,"journal":{"name":"Industrial & Engineering Chemistry Research","volume":"64 38","pages":"18727–18738"},"PeriodicalIF":3.9,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acs.iecr.5c02287","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}