European Journal of Inorganic Chemistry最新文献_第6页

Selective Recognition of G-Quadruplex DNAs by Protoporphyrin IX: NMR Insights into 3′-Terminal G-Quartet Binding 原卟啉IX选择性识别g -四重体dna：核磁共振对3 '端g -四重体结合的洞察

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-14 DOI: 10.1002/ejic.202500262

China Okamoto, Yasuhiko Yamamoto, Atsuya Momotake

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Variable Coordination of Peroxide in a Dinuclear Copper Mono-Oxygenase Model Complex Supported by a Pyridazine-Bridged Ligand 由吡嗪桥接配体支持的双核铜单加氧酶模型配合物中过氧化物的可变配位

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-13 DOI: 10.1002/ejic.202500286

Alexander Stüber, Ramona Jurgeleit, Kira Berger, Benjamin Grimm-Lebsanft, Sören Buchenau, Laura Senft, Christian Näther, Ivana Ivanović-Burmazović, Michael Rübhausen, Maria A. Naumova, Felix Tuczek

{"title":"Variable Coordination of Peroxide in a Dinuclear Copper Mono-Oxygenase Model Complex Supported by a Pyridazine-Bridged Ligand","authors":"Alexander Stüber, Ramona Jurgeleit, Kira Berger, Benjamin Grimm-Lebsanft, Sören Buchenau, Laura Senft, Christian Näther, Ivana Ivanović-Burmazović, Michael Rübhausen, Maria A. Naumova, Felix Tuczek","doi":"10.1002/ejic.202500286","DOIUrl":"https://doi.org/10.1002/ejic.202500286","url":null,"abstract":"Copper-oxygen intermediates play an important role in nature as active species of many copper-containing enzymes. However, copper-oxygen intermediates have a key function not only in nature, but also in industry, for example as catalysts. Herein a study on a dinuclear copper complex is presented based on the literature known ligand BPMPD. This ligand combines features of the previously investigated systems (octadentate N-donor, like the MO8 system and pyridine donors, like the bdpdz system). Oxygenation of the Cu(I)-complex with O2 at low temperature leads to the formation of a μ-1,2-peroxo intermediate (Cu2O2), which is characterized with UV/Vis-, rRaman- and X-ray absorption spectroscopy (XAS), as well as by cryo-UHR-electrospray ionization mass spectrometry. The Cu2O2 species can be reversibly converted into a μ-1,1-hydroperoxo intermediate (Cu2OOH) by a reaction with lutidinium triflate and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), which can be monitored by UV/Vis and XAS. Furthermore, the reactivity of the Cu2O2 species toward dihydroanthracene is investigated.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 28","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202500286","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145272637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Precursor Development for Aerosol-Assisted Chemical Vapor Deposition of α-Fe2O3 and BiFeO3 as Effective Photoanodes for Photoelectrochemical Water Splitting 气溶胶辅助化学气相沉积α-Fe2O3和BiFeO3作为光电化学水分解有效光阳极的前驱体研制

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-13 DOI: 10.1002/ejic.202500333

Charles Brown, Thom R. Harris-Lee, Quan Yee Tey, Joe C. Goodall, Matthew Surman, Meng Nan Chong, Andrew L. Johnson

{"title":"Precursor Development for Aerosol-Assisted Chemical Vapor Deposition of α-Fe2O3 and BiFeO3 as Effective Photoanodes for Photoelectrochemical Water Splitting","authors":"Charles Brown, Thom R. Harris-Lee, Quan Yee Tey, Joe C. Goodall, Matthew Surman, Meng Nan Chong, Andrew L. Johnson","doi":"10.1002/ejic.202500333","DOIUrl":"10.1002/ejic.202500333","url":null,"abstract":"Photoelectrochemical (PEC) water splitting holds great potential to convert solar energy into hydrogen fuel, establishing an effective method for long-term renewable energy storage. Herein, a simple and effective approach is presented for fabricating thin films of α-Fe2O3 and BiFeO3 for use as PEC photoanodes via aerosol-assisted chemical vapor deposition (AACVD). A new Fe(III) precursor bearing an amino-tris-tert-butoxide ligand is designed and coupled with a Bi-based precursor bearing the same ligand framework to deposit nanostructured films of α-Fe2O3 and BiFeO3 with high phase purity. Under 1 sun solar irradiation α-Fe2O3 and BiFeO3 yielded a photocurrent density of 0.38 and 0.42 mA cm−1 at 1.23 VRHE, respectively. A study reveals that the bespoke precursors exhibit remarkable compatibility with one another, producing films of significantly higher quality compared to those produced with more conventional precursors not optimized for AACVD.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 25","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202500333","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145058097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Photocatalytic Hydrogen Production Enhanced by Copper(I) Pyridinium–Selenolate Complexes Supported on Mesoporous Titania 介孔二氧化钛负载的铜(I)吡啶-硒酸盐配合物增强光催化制氢

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-11 DOI: 10.1002/ejic.202500295

Leonardo Carneiro Lanes, Rodrigo Cervo, Robert Alan Burrow, Bernardo Almeida Iglesias, Natália de Freitas Daudt, Ernesto Schulz Lang, Bárbara Tirloni, Roberta Cargnelutti

{"title":"Photocatalytic Hydrogen Production Enhanced by Copper(I) Pyridinium–Selenolate Complexes Supported on Mesoporous Titania","authors":"Leonardo Carneiro Lanes, Rodrigo Cervo, Robert Alan Burrow, Bernardo Almeida Iglesias, Natália de Freitas Daudt, Ernesto Schulz Lang, Bárbara Tirloni, Roberta Cargnelutti","doi":"10.1002/ejic.202500295","DOIUrl":"10.1002/ejic.202500295","url":null,"abstract":"The reaction of 1,2-bis(3-aminopyridin-2-yl)diselane (apySe)2 with [CuX(PPh3)3] (X = Cl, Br, I) yields monomers and the dimers coordination compounds. In both cases, the reduction of the diselane is observed, leading to the formation of 3-aminopyridinium-2-selenolate ligand. The complexes are characterized using spectroscopic and electrochemical methods, as well as single-crystal X-ray diffraction analysis. They are used as co-catalysts of mesoporous titania, for the preparation of photocatalysts. All photocatalysts synthesized are active for the hydrogen production by water photolysis. The m-TiO2-1 and m-TiO2-4 photocatalysts stood out, producing 2505 and 2423 μmol g−1 of hydrogen, respectively, after 6 h of irradiation with a 300 W Hg/Xe lamp. Their activities greatly exceed the amount observed for pure m-TiO2, being approximately eight times higher. Through recycling experiments, the stability of the most efficient m-TiO2-1 photocatalyst is verified, demonstrating the suitable impregnation of the co-catalyst over the m-TiO2 matrix and the importance of the complex to improve the ability of the photocatalyst to increase the absorption of visible radiation. These results highlight the potential of pyridinium–selenolate copper(I) complexes, to act as effective co-catalysts of m-TiO2, for hydrogen production via water photolysis, making them promising candidates for applications in heterogeneous photocatalysis processes.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 25","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202500295","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145057975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Hydroflux Synthesis and Crystal Structures of Na5[RE(OH)6][MO4] (RE = Y, Sc, Er–Lu; M = Cr, Mo, W) and Na8[Sc(OH)6]2[CrO4] Na5[RE(OH)6][MO4] （RE = Y, Sc, Er-Lu; M = Cr, Mo， W）和Na8[Sc(OH)6]2[CrO4]的磁流合成及晶体结构

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-08 DOI: 10.1002/ejic.202500317

Yuxi Li, Michael Ruck

{"title":"Hydroflux Synthesis and Crystal Structures of Na5[RE(OH)6][MO4] (RE = Y, Sc, Er–Lu; M = Cr, Mo, W) and Na8[Sc(OH)6]2[CrO4]","authors":"Yuxi Li, Michael Ruck","doi":"10.1002/ejic.202500317","DOIUrl":"https://doi.org/10.1002/ejic.202500317","url":null,"abstract":"Reacting rare-earth oxides RE2O3 (RE = Y, Sc, ErLu) with transition metal oxides MO3 (M = Cr, Mo, W) in ultra-alkaline NaOH hydroflux at 250 °C for 10 h results in transparent crystalline products with high yield and purity. Fifteen new compounds with the general formula Na5[RE(OH)6][MO4] are structurally characterized with single-crystal X-ray diffraction. The crystal structures consist of isolated [RE(OH)6]3− octahedra and [MO4]2− tetrahedra surrounded by Na+ cations. While the chromates crystallize in the monoclinic space group C2/c, the molybdates and tungstates adopt the space group I2/a, all with very similar lattice parameters. The two structure types are similar, but not identical. Both structure types can be derived from the same hypothetical structure, which exhibits higher translational symmetry in the k2 supergroup C2/m. Under similar hydroflux condition, the scandium compound Na8[Sc(OH)6]2[CrO4] is also obtained, which crystallizes in the noncentrosymmetric tetragonal space group I<math></math>2d. Three thulium compounds are investigated in more detail. Thermal analysis reveals that Na5[Tm(OH)6][WO4] decomposes at about 320 °C to Na2WO4 and Tm2O3. All thulium compounds are paramagnetic with moments close to the value expected for the free rare-earth cation, but show deviations from Curie–Weiss behavior below 25 K.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 27","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202500317","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145196649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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CC Insertion over NCO of Allyl Isocyanate into the GeSi Bond of a Germylene 异氰酸烯丙酯在N - <s:1> - C - O上的C - <s:1> - C插入到锗烯的Ge - Si键中

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-08 DOI: 10.1002/ejic.202500305

V. S. Ajithkumar, Nripen Khilari, Pratiksha B. Ghanwat, Debasis Koley, Sakya S. Sen

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Solid State Synthesis of BiVO4 and Its Use as a Photocatalyst for Solar Water Splitting BiVO4的固态合成及其在太阳能水分解光催化剂中的应用

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-07 DOI: 10.1002/ejic.202500100

Trang T. Vu, Ly T. Le, Hoang V. Le, Duc N. Nguyen, Phong D. Tran

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Syntheses and Crystal Structures of the Novel Salts Sr[MoVI2O2F9]2·HF, Ba[MoVI2O2F9]2·2HF, and of Ba[MoVOF5] 新型盐Sr[MoVI2O2F9]2·HF、Ba[MoVI2O2F9]2·2HF和Ba[MoVOF5]的合成及晶体结构

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-07 DOI: 10.1002/ejic.202500316

Tobias B. Wassermann, Giuliana Hoß, Antti J. Karttunen, Florian Kraus

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Ethylenediamine-Derived PNNP Bisphosphine: Synthesis and Transition Metal Chemistry 乙二胺衍生的PNNP双膦：合成和过渡金属化学

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-06 DOI: 10.1002/ejic.202500296

Bhupinder Kaur, Ankit Pandey, Basvaraj S. Kote, Maravanji S. Balakrishna

{"title":"Ethylenediamine-Derived PNNP Bisphosphine: Synthesis and Transition Metal Chemistry","authors":"Bhupinder Kaur, Ankit Pandey, Basvaraj S. Kote, Maravanji S. Balakrishna","doi":"10.1002/ejic.202500296","DOIUrl":"https://doi.org/10.1002/ejic.202500296","url":null,"abstract":"The synthesis of the ethylenediamine-derived bisphosphine ligand, (o-PPh2 (C6H4)C(O)NH(CH2))2 (1) (hereafter referred to as PNHNHP), is described via two methods distinct from previously reported procedures. Treatment of ligand 1 with Pd(COD)Cl2 afforded the trans-dichloropalladium complex [PdCl2(PNHNHP)-κ2-P,P] (2). In contrast, the reaction of 1 with Pd(COD)Cl2 in the presence of a base led to the formation of the tetradentate cis-complex [Pd(PNNP)-κ4-P,N,N,P] (3). Similarly, ligand 1 reacted with Pt(COD)Cl2 to yield the corresponding cis-complex [Pt(PNNP)-κ4-P,N,N,P] (4). Reaction of 1 with NiCl2(DME) in the presence of a base resulted in the formation of [Ni(PNNP)-κ4-P,N,N,P] (5). Notably, exposure of the cis-palladium complex 3 to HCl gas led to its conversion to the trans-complex 2, while the cis-platinum complex 4 remained unaffected. Density functional theory (DFT) calculations confirm that the conversion of 3 to 2 is thermodynamically favorable, with a Gibbs free energy change (ΔG) of −29.7 kcal mol. Furthermore, treatment of ligand 1 with cuprous halides yield [CuX(PNHNHP)-κ2-P,P] (6: X = Cl; 7: X = Br; 8: X = I). Reaction with Cu(NCCH3)4BF4 produced the dinuclear complex [Cu2(PNHNHP)2-κ4-P,O,O,P]BF4 (9).","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 27","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145196563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Selective Oxidation of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Diformylfuran over the Oxygen-Vacancy-Rich Ru/MnO2 Catalyst 富氧空位Ru/MnO2催化剂选择性氧化生物质衍生的5-羟甲基糠醛为2,5-二甲酰呋喃

IF 2 4区化学

European Journal of Inorganic Chemistry Pub Date : 2025-08-06 DOI: 10.1002/ejic.202500181

Chuan Qin, Xusheng Guo, Yuxi Si, Yuanchao Huang, Youwei Cheng

{"title":"Selective Oxidation of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Diformylfuran over the Oxygen-Vacancy-Rich Ru/MnO2 Catalyst","authors":"Chuan Qin, Xusheng Guo, Yuxi Si, Yuanchao Huang, Youwei Cheng","doi":"10.1002/ejic.202500181","DOIUrl":"https://doi.org/10.1002/ejic.202500181","url":null,"abstract":"Due to the depletion of traditional fossil resources and the increasing environmental problems, the utilization of sustainable biomass resources has become imperative. The selective oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) has attracted much attention in recent years. However, the large-scale production of DFF remains a challenge given the low dosage of HMF in previous research. In this contribution, a desirable DFF yield of 90.5% is obtained from concentrated HMF (130 °C, 2.0 MPa oxygen, 8 h) over the prepared Ru/MnO2 catalyst with abundant oxygen vacancies (OV). The Ru/MnO2 catalyst with high OV exhibits a weak MnO bond intensity resulting in high lattice oxygen (OL) reactivity, which promotes a high catalytic activity of HMF oxidation. Reusability studies show that the Ru/MnO2 catalyst is stable and reusable. Furthermore, the direct production of DFF from fructose is also successfully realized via two consecutive steps, leading to a cost-efficient oxidation of HMF solution and facilitating the industrial production of DFF. This research provides profound insights into the selective oxidation of HMF to DFF, thereby fostering further investigations into the conversion of fructose into high-value chemicals.","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"28 27","pages":""},"PeriodicalIF":2.0,"publicationDate":"2025-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145196577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0