Javzmaa Namshir, A. Shatar, Oyukhan Khandaa, Rentsenkhand Tserennadmid, V. G. Shiretorova, Manh Cuong Nguyen
{"title":"Antimicrobial, antioxidant and cytotoxic activity on human breast cancer cells of essential oil from Pinus sylvestris. var mongolica needle","authors":"Javzmaa Namshir, A. Shatar, Oyukhan Khandaa, Rentsenkhand Tserennadmid, V. G. Shiretorova, Manh Cuong Nguyen","doi":"10.5564/mjc.v21i47.1428","DOIUrl":"https://doi.org/10.5564/mjc.v21i47.1428","url":null,"abstract":"Pinus sylvestris. var mongolica is a major source of timber in Mongolia. The logging process makes many kinds of valuable biomass including bark, cones, and needles, which can be used for obtaining essential oil. The essential oil from the needles of wild growing Pinus sylvestris. var mongolica growing in Mongolia was chemically analyzed and its antibacterial, antifungal and cytotoxic activities were evaluated. The chemical analyses identified 101 compounds in the essential oil with the major compounds of α-pinene (29.87 %), limonene + β-phellandrene (16.15 %), camphene (4.95 %), bornylacetate (4.34 %), and β-pinene (3.88 %). This oil possessed the inhibitory activity against B. subtilis, S. cerevisiae, S. aureus and E. coli, successively with minimum inhibition concentration of 0.125, 0.1, 3.0, and 10.0 µg/mL. Importantly, the oil at 50 µg/mL and 100 µg/mL inhibited the growth of MCF-7 cells by 45.3 % and 99.7 %. The half of inhibition concentration of DPPH (2,2-Diphenyl-1-picrylhydrazyl) radical scavenging was 14.36 ± 0.28 mg/mL. The results, therefore, suggested that the essential oil of a Mongolian Scotch pine could potentially be used as a preservative material in cosmetic and food products, as a bioactive agent in anti-inflammatory and wound healing products in view of its antibacterial activity. Given our findings that this essential oil has such profound activity against MCF-7 cancer cells, a further investigation concerning the full extent of this essential oil’s anticancer activities seems warranted. Furthermore, given the promising antimicrobial effects of this essential oil against various bacterial species, an investigation concerning its effect against drug-resistant bacteria would be of immense interest.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43905530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wulan Gerile, Naranchimeg Dorjpalam, W. Gui, Liang Xu, Jinglin Liu
{"title":"The study on the antioxidant activity of polysaccharides isolated from Polygonatum odoratum (Mill.) Druce","authors":"Wulan Gerile, Naranchimeg Dorjpalam, W. Gui, Liang Xu, Jinglin Liu","doi":"10.5564/mjc.v21i47.1154","DOIUrl":"https://doi.org/10.5564/mjc.v21i47.1154","url":null,"abstract":"The polysaccharides isolated from Polygonatum odoratum (Mill.) Druce (POPs) by water extraction, after precipitation with ethanol were purified through deproteinization, decolorization, dialysis, and column chromatography leading to a purified polysaccharide (POPs-I) content of 90.7 %. The scavenging of oxygen free radicals and inhibition of lipid peroxidation (LPO) by POPs-I were analyzed using a colorimetric method. The results showed that the hydroxyl radical scavenging ability of the polysaccharides was weaker than that of benzoic acid, but stronger than those of ascorbic acid and mannitol, and that the superoxide anion radical scavenging ability was inferior to those of all three. When the concentration was higher than 1.0 mg/mL, the POPs-I could inhibit LPO by superoxide anion radicals to a certain degree. Therefore, this work suggests that POPs-I are potential antioxidant agents in medicine and functional food.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43149236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Batkhishig Damdin, B. Purevsuren, Yuanli Zhang, Haizhen Sun, Ariunaa Alyeksandr, Ankhtuya Ariunbold, Battsetseg Munkhtaivan, Namkhainorov Jargalsaikhan, B. Sanjaa
{"title":"Investigation on physical activation of some Mongolian coals","authors":"Batkhishig Damdin, B. Purevsuren, Yuanli Zhang, Haizhen Sun, Ariunaa Alyeksandr, Ankhtuya Ariunbold, Battsetseg Munkhtaivan, Namkhainorov Jargalsaikhan, B. Sanjaa","doi":"10.5564/mjc.v20i46.1238","DOIUrl":"https://doi.org/10.5564/mjc.v20i46.1238","url":null,"abstract":"Activation characteristics of four different Mongolian coals were investigated. The coals were carbonized at temperatures of 550 °C and the obtained samples were activated by preheated steam. The pore size, pore volume and surface areas of all activated carbons (AC) have been determined by adsorption of nitrogen (N2) gas. The BET surface areas of Aduunchuluun (ACAC), Shivee Ovoo (SCAC), Baganuur (BCAC) coal and Ulaan Ovoo coals (UCAC) are 283, 205, 251 and 460 m2/g respectively. Langmuir surface area is 283 m2/g of ACAC, 230 m2/g of SCAC, 537 m2/g in UCAC and 254 m2/g in BCAC.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42805192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B Narandalai, W. Shim, M. S. Balathanigaimani, H. Moon
{"title":"Retraction notice: Influence of compressing pressure on macro void formation carbon monolith for methane adsorption","authors":"B Narandalai, W. Shim, M. S. Balathanigaimani, H. Moon","doi":"10.5564/MJC.V19I45.1089","DOIUrl":"https://doi.org/10.5564/MJC.V19I45.1089","url":null,"abstract":"RETRACTION NOTICEOn 21rd February 2019, the Editorial Board of the Mongolian Journal of Chemistry decided to retract this article entitled \"Influence of compressing pressure on macro void formation of carbon monolith for methane adsorption\" because of an authorship dispute. The article was originally published in Vol.18 No.44 2017 pp.24-35. doi: https://doi.org/10.5564/mjc.v18i44.934","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":"203 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41331558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization and thermogravimetric analysis of oil shale from Uvurjargalant deposit","authors":"Khulan Bayasgalan, Myagmargerel Bayanmunkh, Ulzii Baatar, Bolormaa Bayarkhuu, Tuya Murneren","doi":"10.5564/MJC.V19I45.1085","DOIUrl":"https://doi.org/10.5564/MJC.V19I45.1085","url":null,"abstract":"The yield, properties and composition of soluble and insoluble (kerogen) of organic matter of oil shale from Uvurjargalant deposit of Mongolia have been investigated in this study. The study result shows that oil shale contains low amount of moisture and volatile products, while the ash yield is high (71.86 %) - which implies that most of the oil shale are minerals. The total amount of bitumens in the oil shale was very low (1.27 wt %), whereas kerogen content was 22.84 wt %, which is relatively high compared to oil shale from other deposits in Mongolia. Under IR spectral analysis and the ratio of hydrogen and carbon, the Uvurjargalant oil shale belongs to I type of oil shale. The thermogravimetric analysis showed that organic matter of oil shale decomposed at a temperature 300-750 ºC to produce gas and liquid products.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46236260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B. Purevsuren, Otgonchuluun Dashzeveg, Ariunaa Alyeksandr, Narangerel Janchig, Jargalmaa Soninkhuu
{"title":"Pyrolysis of pine wood and characterisation of solid and liquid products","authors":"B. Purevsuren, Otgonchuluun Dashzeveg, Ariunaa Alyeksandr, Narangerel Janchig, Jargalmaa Soninkhuu","doi":"10.5564/MJC.V19I45.1086","DOIUrl":"https://doi.org/10.5564/MJC.V19I45.1086","url":null,"abstract":"Pyrolysis of pine wood was carried out at different temperatures and the yields of solid (biochar), liquid (tar and pyrolysed water) and gas products were determined. Temperature around 500 ºC was determined as an optimal heating temperature of pyrolysis and approximately 27.1% hard residue (biochar), 21.46% tar, 20.04% pyrolysed water and 31.30% gas were obtained by pyrolysis. The thermal stability indices of pine wood are relatively low, which are indications of its low thermal stability and high yield of volatile matter (Vdaf = 90.3%). The thermal stability indices of pyrolysis of solid residue show that it is characterised by a very high thermal stability than its initial sample, for example, there was an increase of Т5% 7.7 and Т15% 3.8 times. The chemical composition of pyrolysed tar of pine wood has also been determined. Were obtained 4 different fractions with varying boiling temperature ranges of pine wood pyrolysed tar and have determined the yields of each fraction. Neutral tar was analysed by GC/MS and 20 aliphatic compounds, 25 aromatic compounds and 18 polar compounds were determined.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42821068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhancing lithium leaching by mechanical activation","authors":"Nader Setoudeh, A. Nosrati, N. Welham","doi":"10.5564/MJC.V19I45.1090","DOIUrl":"https://doi.org/10.5564/MJC.V19I45.1090","url":null,"abstract":"The lithium (Li) bearing minerals lepidolite and spodumene were mixed with different mass ratios of Na2SO4 and mechanically activated by milling in a planetary ball mill for 5 h. The milled samples were studied using thermogravimetry under an air atmosphere up to 950 ºC. Isothermal heating of the milled samples was undertaken in a furnace at temperatures of 700 ºC and 800 ºC for 1 h. Hot water leaching of the calcines indicated that increasing the calcination temperature had a significant effect on the dissolution of lithium. The leaching of lithium from lepidolite was notably higher than that from spodumene.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46121346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Leaching of a Mongolian chalcopyrite concentrate","authors":"N. Welham, J. Temuujin, Nader Setoudeh","doi":"10.5564/MJC.V19I45.1082","DOIUrl":"https://doi.org/10.5564/MJC.V19I45.1082","url":null,"abstract":"A Mongolian chalcopyrite flotation concentrate was leached using sodium hypochlorite adjusted to different pH using hydrochloric acid. It was found that using a starting pH of below 5.0 resulted in more efficient leaching. The extent of chalcopyrite leaching was determined by the concentration of sodium hypochlorite with > 40% dissolution being achieved. The residue after leaching was found to consist primarily of unreacted chalcopyrite which would be suitable for further leaching or smelting.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47060387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B. Buyan-Ulzii, Odbayar Daariimaa, Chuluunsukh Munkhdelger, G. Oyunbileg, B. Enkhsaruul
{"title":"Effect of nickel precursor and catalyst activation temperature on methanation performance","authors":"B. Buyan-Ulzii, Odbayar Daariimaa, Chuluunsukh Munkhdelger, G. Oyunbileg, B. Enkhsaruul","doi":"10.5564/MJC.V19I45.1084","DOIUrl":"https://doi.org/10.5564/MJC.V19I45.1084","url":null,"abstract":"This work studied an effect of anionic precursor on the preparation of active and fine nickel metal catalysts for syngas methanation. Nickel catalysts were pr¬epared by impregnation-co-precipitation method. Nickel hydrate salts of Ni(NO3)2·6H2O, NiSO4·6H2O and NiCl2·6H2O were used as a metal catalyst precursor, and the obtained catalysts were named as Ni/Al (N), Ni/Al (S) and Ni/Al (Cl), respectively. Methanation synthesis of carbon monoxide was carried out in a fixed bed stainless reactor. Prior to experiment, the catalyst powder was pressed into tablets, then crushed and sieved to use 0.5-0.9 mm particles. Reactions were performed at the temperature of 350 °C in the pressure of 3 atm of H2:CO syngas (the molar ratio of 3:1) with the GHSV of 3000 h-1. In the present methanation conditions, the Ni/Al (N), Ni/Al (S) and Ni/Al (Cl) catalysts gave the CH4 selectivity of 93%, 18% and 91% (vol.), respectively. The XRD and ICP-OES analysis clarified that although the Ni/Al (S) catalyst contained a similar nickel amount of 17.4 wt % to other two catalysts, its metal distribution was poor. Also the low activity of the Ni/Al (S) catalyst was caused by the contamination of remained sulfur from sulfate precursor. This work also examined an influence of catalyst activation temperature pre-synthesis. The Ni/Al (N) catalyst was reduced by pure hydrogen gas at different temperatures of 350 ºС, 400 ºС or 450 ºС. The catalyst activated at 400 ºС produced the highest CH4 amount of 0.087 mmol·g-1cat for the duration of 1h methanation. An initial temperature of methane formation was the lowest for the Ni/Al (N) catalyst which was activated at 400 ºС among three catalysts.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41479191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Uugangerel Erdenetsogt, Choijamts Gotov, K. Voigt, S. Bartram, W. Boland, Enkhmaa Dagvadorj
{"title":"Chemical composition and antimicrobial activity of essential oil from Pyrethrum pulchrum Ledeb.","authors":"Uugangerel Erdenetsogt, Choijamts Gotov, K. Voigt, S. Bartram, W. Boland, Enkhmaa Dagvadorj","doi":"10.5564/MJC.V19I45.1088","DOIUrl":"https://doi.org/10.5564/MJC.V19I45.1088","url":null,"abstract":"The chemical composition and antimicrobial activity of the essential oil from the aerial parts of Pyrethrum pulchrum Ledeb. were investigated. Dried plant material was hydro-distillated yielding 0.1% of essential oil. The oil was analyzed by GC-MS techniques. Fifty-five compounds were identified representing 99.7% of the total oil composition. Camphor was the predominant compound (33.9%) followed by linalool (21.1%) and α-pinene (9.0%). The antimicrobial activity of the oil was determined using the disk diffusion method against Gram-positive bacteria (Bacillus subtilis, Staphylococcus aureus and Enterococcus faecalis), Gram-negative bacteria (Pseudomonas aeruginosa and Escherichia coli), Mycobacterium vaccae and fungi (Candida albicans, Sporidiobolus salmonicolor and Penicillum notatum). The essential oil of P. pulchrum displays an intermediate activity against selected bacteria.","PeriodicalId":36661,"journal":{"name":"Mongolian Journal of Chemistry","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44657578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}