Syeda Hijab Zehra, Said Akbar Khan, Syeda Mahnoor Zehra, M. Asad
{"title":"Removal of Cr6+ from Synthetic Polluted Water using Fe Modified Sugarcane Bagasse & Peanut shell Powder","authors":"Syeda Hijab Zehra, Said Akbar Khan, Syeda Mahnoor Zehra, M. Asad","doi":"10.56946/jce.v2i2.146","DOIUrl":"https://doi.org/10.56946/jce.v2i2.146","url":null,"abstract":"Unprocessed waste is dumped in lakes and rivers which possess a severe environmental risk through heavy metal’s contamination within the food chain, especially chromium Cr6+. It applies for sustainable development goals by using green solid waste as a precursor. This research mainly focuses upon the analysis of time effect for Cr6+ removal by FeCl3 modified biochar using sugarcane bagasse and peanut shell powder as biomass. Adsorbent preparation was done using Bench-Scale Fixed Bed Reactor (B-SFBR) and Cr6+ was found using the calorimetric method. Characterization was done by BET, SEM-EDX, and FTIR. The highest Cr6+ percentage removal was achieved by Modified Peanut shell Powder with 99.97% removal upon pH 2, shaking time 180 mints, speed = 150 rpm, dosage 0.3 g, Cr6+ conc 20 mg/L. Percentage Removal by Modified SB was 98.96% with Cr6+ conc 20 mg/L, dosage 0.3 g, pH 2, shaking speed 150 rpm, time 180 mints. Hence, the present experimental research concludes that FeCl3 modified peanut shell powder shows greater Cr6+ removal efficiency up to 99.97 %.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"182 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87471235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization of Paper Mill Effluent and Its Impacts on the Environment","authors":"Md. Shakilur Zaman Shakil, M. Mostafa","doi":"10.56946/jce.v2i01.135","DOIUrl":"https://doi.org/10.56946/jce.v2i01.135","url":null,"abstract":"he study aimed to characterize paper mill effluents and determine the quality of surface water in the vicinity of the paper mills using a water quality index to understand the pollution level due to the discharge of untreated effluents. Physicochemical parameters and CCME (Canadian Council of Ministers of the Environment) Water Quality Index (WQI) were used to estimate the degree of pollution in the selected paper mills area in Bogura District of Bangladesh. Moreover, a public perception survey was conducted in the study area to illustrate the present scenario regarding paper mill effluent discharge. The analytical results revealed that the concentrations of TSS, EC, COD, BOD5, phenols, K, and NO3 – N were higher than the permissible limit, and the DO level was below the ECR 1997 standard. However, there was no concentrations of heavy metals exceeded the permissible level. The FTIR analysis showed the presence of several toxic pollutants, including lignin, phenol, and halo compound. The CCME WQI showed that sites S-1 and S-2 were ranked as marginal, while site S-3 was ranked as fair. The study observed that the discharge of untreated paper mill effluent has the potential to cause harm to aquatic life and the environment.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"84 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83901403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Elemental Mercury Removal from Natural Gas Using Nano-Tio2","authors":"M. Mandor","doi":"10.56946/jce.v2i01.147","DOIUrl":"https://doi.org/10.56946/jce.v2i01.147","url":null,"abstract":"The study focused on the utilization of titanium dioxide (TiO2) as a photo-catalyst for the treatment of natural gas contaminated with elemental mercury (Hg0). The catalyst was carefully characterized using various physical techniques, including transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDAX), UV-visible diffuse reflectance spectroscopy (DRS), Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS) , and X-ray diffraction analysis (XRD). The results clearly demonstrated that TiO2 exhibited outstanding efficacy in oxidizing Hg0 when exposed to UV light. This phenomenon was ascribed to the excitation of photoelectrons within the valence band, leading to their transfer to the conduction band, generating photo-induced electrons that acted as reactive agents responsible for converting Hg0 into HgO. Notably, the activity of TiO2 under UV-visible light was significantly lower compared to TiO2 under UV light. The overall findings indicated that TiO2 under UV light exhibited the highest removal capacity, measured at 31.74 µg/g, followed by TiO2 under UV-visible light at 25.91 µg/g, and TiO2 in the dark at 20.89 µg/g. The study underscores the promising potential of TiO2 photo-catalyst for effectively eliminating Hg0 contamination in natural gas.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"24 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78449742","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hira Zulfiqar, Iqbal Ahmed, Muhammad Furqan Farooq, Iqra Rani, Ijaz Hussain, Hunain Zulfiqar, Abid Jan
{"title":"Unraveling the Challenges of Oxidative Stability and Methods for Assessing Oxidation of Commercial Oils: A Review","authors":"Hira Zulfiqar, Iqbal Ahmed, Muhammad Furqan Farooq, Iqra Rani, Ijaz Hussain, Hunain Zulfiqar, Abid Jan","doi":"10.56946/jce.v2i01.131","DOIUrl":"https://doi.org/10.56946/jce.v2i01.131","url":null,"abstract":"Edible oils are among the most crucial nutritional constituents as these are utilized for frying or cuisine. Though, these oils are prone towards oxidative deterioration from manufacturing to transportation due to environmental exposure as well as storage conditions which result in generation of different types of oxidation products. The generation of primary and secondary products result in harmful impacts on human health and may also result in cardiovascular diseases in consumers. The mechanism of oxidative deterioration cannot be assessed easily due to complexity of the reaction under which it may take place. Different types of approaches have been proposed to determine the products generated as a result of oxidation so that safety for their user can be assured. Different types of analytical techniques can be employed in addition to chemical methods so that analysis of oxidative deterioration can be done completely. The proposed study is aimed to assess the oxidative stability of oils in addition to the factors which can influence oxidation of these oils under different conditions. This review also summarize the classical and advanced state of the art analytical techniques which has recently been developed in different possible ways and effectively can be employed for analysis of oxidative deterioration of edible oils. This article possibly will oblige as a reference in the assortment, establishing, and enhancement of approaches for investigating the oxidative stability of edible oil.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"98 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85332772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"First Principles study of Silver Argyrodites-structured compounds A8BC6 (A=Ag; B=Si, Ge; C=Te) for Opto-electronic application","authors":"M. Munsif, M. Shah","doi":"10.56946/jce.v1i02.121","DOIUrl":"https://doi.org/10.56946/jce.v1i02.121","url":null,"abstract":"The structural and optical properties of a material are studied using Density Functional Theory. By the method of full potential linearized augmented plane wave (FP-LAPW) silver argyrodites Ag8SiTe6 and Ag8GeTe6 has been investigated. To obtain stable geometry of A8BC6 materials, the energy minimization approach is applied. The Generalized Gradient Approximation (GGA) approach is used to optimize the crystal structure of the Argyrodites materials. All these compounds crystalize in a cubic unit cell with lattice constant increasing from 12.13 Å (Si) to 12.28 Å (Ge). The mBJ-functional shows a semiconducting nature Ag8SiTe6 for and metallic nature for Ag8GeTe6 of these compounds with an indirect band gap lying at the L-X symmetry points with a band gap of 0.24 eV (Si) and 0.0068 eV (Ge) to obtain the optical properties such as refractive index, complex dielectric constant with real and imaginary part of dielectric function, and other optical properties are discussed. Effective mass of electrons is smaller than those of holes resulting in higher carrier mobility for electrons. Due their direct band gap, these Argyrodites materials could be particularly useful in optoelectronic devices.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75556024","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tahiru Saka, L. San-Pedro, A. Abubakar, Tome Sylvain, A. Budianto, Samia Rabet
{"title":"Evaluation of the Physical Properties of Various Biomass Materials for the Production of Activated Carbon","authors":"Tahiru Saka, L. San-Pedro, A. Abubakar, Tome Sylvain, A. Budianto, Samia Rabet","doi":"10.56946/jce.v1i02.132","DOIUrl":"https://doi.org/10.56946/jce.v1i02.132","url":null,"abstract":"This study aims to produce activated carbon (AC) from different biomass sources using chemical activation; characterize the AC using Fourier Transform Infrared (FTIR) Spectroscopy, Scanning Electron Microscopy (SEM), proximate and ultimate analysis; and compare the results from the AC produced. The biomass blends of rice husk & groundnut shell (RH-GS), cocoa nut shell & saw dust (CS-SD) and sugar cane bagasse & banana peel (SB-BP) were used for the preparation of AC. The samples were first characterized using proximate and ultimate analysis, SEM, and FTIR spectroscopy. The results of the BG-SD sample characterization showed that the blend produced the best results in terms of absorptive capacity. It is suggested that surface area difficulties with the ACs be investigated in order to improve their porosity and adsorption capacities.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"42 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78471350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Identification of Sources and Mobilization of Trace Elements in Shallow Groundwater of the Upper Ganges River Basin","authors":"Md. Shajedul Islam, M. Mostafa, M. Touseef","doi":"10.56946/jce.v1i02.94","DOIUrl":"https://doi.org/10.56946/jce.v1i02.94","url":null,"abstract":"The concentration of trace metals in groundwater is still not within the usual standards established by the national and international monitoring authorities. This study aims to evaluate the sources and distribution of trace metals in the shallow aquifer water of the Ganges River basin in the Bangladesh area. A total of 40 groundwater samples were collected and investigated for 11 trace elements and some selected water parameters followed by sophisticated methods. The results presented that three metals, viz. Fe, Mn, and Pb crossed the limit of WHO standard in most of the samples (70-100%), representing severe human health hazards. Besides, the samples are slightly acidic to basic and highly mineralized by divalent cations and bicarbonate because total hardness was found very high. To assess factors affecting the trace metal loads in groundwater samples and determine their possible sources and mobility, multivariate statistical techniques, including Pearson’s correlation coefficient, principal components analysis, and dendrogram cluster analysis are performed. Results revealed that sources of trace elements were identified to be geologic and little from human activities, i.e., application of agrochemicals, excess water mining, and industrial wastewater. It was recognized that the elevated concentration of trace elements in samples was caused by geogenic factors rather than manmade activities. Groundwater in this area poses a large threat due to high levels of trace metals, without any purification, it is essential to avoid this water for drinking. It advised that the groundwater quality should be constantly monitored for sustainable water quality management in the study zone.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86745329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of bimetallic iron ferrite and its applications in alcohol fuel cell","authors":"Qurat‐ul Ain, Suqqyana Fazal, F. Ahmad","doi":"10.56946/jce.v1i02.104","DOIUrl":"https://doi.org/10.56946/jce.v1i02.104","url":null,"abstract":"Fuel cell is a clean, safe, eco-friendly source of energy as an alternative to already existing energy resources like incineration of fossil fuel. Efficiency of fuel cell is high when platinum is used as an electrode material for both anode and cathode. However, it is very expensive metal. Bimetallic Iron Ferrite (BMIF) has shown better EOR activity considering onset potential, mass activity when compared with noble metal catalyst but it is economical as compared to Pt. XRD reveals the conformation of BMIF and its purity. FTIR before and after electrochemical analysis has confirmed the retainment of its structure. However, it hasn’t shown good activity for MOR in any parameter i-e Tafel slope value, mass activity and onset potential comparatively.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"69 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85904877","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Advancement and Future Perspectives of Prostate Cancer Treatment by Using Plant Bio-actives: A Review","authors":"Hira Zulfiqar, Hunain Zulfiqar, Muhammad Furqan Farooq, Iqbal Ahmed, Iqra Rani, Farman Ullah","doi":"10.56946/jce.v1i01.48","DOIUrl":"https://doi.org/10.56946/jce.v1i01.48","url":null,"abstract":"Prostate cancer (PCa) is the world's second most lethal and hateful disease in people. Even while chemotherapy medications have made considerable progress against cancer disease, the body still has to deal with their toxic side effects. In order to produce anticancer medicines with the lowest cost and treatment time, mostly people are using mechanistic techniques. In addition to chemotherapy advanced treatment techniques are also used in clinical practices, and they have an excellent healing results by enhancing patient survival rates. The social care net faces serious challenges because of the lack and high cost of modern therapeutic techniques. The side effects of chemotherapeutic drugs and expensive advance techniques triggered the patient interest towards phytochemicals drugs which indicate that nature always attracts human to fulfill their medical needs at very low cost.\u0000The pharmaceutical industries are showing strong interest in recent research, which has led to the addition of a quite large number of phyto-medicines in PCa therapeutic practices. Currently, several experimental epidemiological and clinical research reports confirmed that plant bio-actives play a significant role in PCa prevention by using different mechanistic ways such as suppressing adhesion, anti-angiogenesis, pro-apoptosis, anti-proliferation, invasion and migration. This review systematically highlighted various strategies to treat PCa and advances in research by using different bioactive plant extracts and isolated components that have been tested for PCa therapy along with corresponding clinical and epidemiological studies.","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"69 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86813617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Ullah, Suleman Muhammad, Fazal Hina, Zafar Ali Shah Shah, M. Ahmad, Y. Ahmed, Nawaz Naik, Niaz Aiman, Kashif Ahmed
{"title":"Evaluation of Heavy Metals in Drinking Water of Tribal Districts Ex-FATA Pakistan","authors":"R. Ullah, Suleman Muhammad, Fazal Hina, Zafar Ali Shah Shah, M. Ahmad, Y. Ahmed, Nawaz Naik, Niaz Aiman, Kashif Ahmed","doi":"10.56946/jce.v1i01.74","DOIUrl":"https://doi.org/10.56946/jce.v1i01.74","url":null,"abstract":"This study was conducted to evaluate the six heavy metals zinc (Zn), iron (Fe), copper (Cu), nickel (Ni), chromium (Cr), and cadmium (Cd) in seven water samples collected from seven tribal districts (Bajaur, Mohmand, Khyber, Orakzai, Kurram, South Waziristan and North Waziristan) from Ex-FATA Pakistan. All samples were digested using the wet digestion method and the digested samples were analyzed for heavy metals using an atomic absorption spectrophotometer. Results from water samples from seven districts were compared to the recommended standard value from the World Health Organization and the Environmental Protection Agency. The results obtained from the analysis for nickel (Ni) showed that the highest concentration (0.093 mg/l) was reported in the water of Khyber district, while the lowest concentration (0.011 mg/l) was found in the water of South Orakzai district. Iron (Fe) had the highest concentration (0.32 mg/l) in the water of Orakzai district. The highest concentration (0.19 mg/L) of chromium (Cr) was reported in the water of Orakzai district. In addition, the result showed that the highest concentration (0.87 mg/l) of zinc (Zn) was in Orakzai district, the highest concentration (1.92 mg/l) of copper (Cu) in Khyber and Mohmand districts ( 1.92 mg/l), while the highest concentration (0.0029 mg/l) of cadmium (Cd) was measured in the water of Orakzai district. Therefore, based on comparison to WHO and EPA standard values, this study shows that the water of all tribal districts is safe for drinking water purposes","PeriodicalId":29792,"journal":{"name":"Journal of Chemistry and Environment","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89556757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}