The Open Physical Chemistry Journal最新文献

Effect of Dioxane on N-(4-hydroxy-6-methyl-1,3,5-triazin-2-yl)-N’- phenylthiocarbamide 二氧六环对N-(4-羟基-6-甲基-1,3,5-三嗪-2-基)-N ' -苯硫脲的影响

The Open Physical Chemistry Journal Pub Date : 2014-01-23 DOI: 10.2174/1874067701406010001

D. Tayade, A. Kshirsagar, Y. Yang

引用次数: 3

Additional Experimental Confirmations of the New Chemical Species of Santilli Magnecules 新化学种Santilli磁分子的实验证实

The Open Physical Chemistry Journal Pub Date : 2013-09-06 DOI: 10.2174/1874067701305010001

Y. Yang, J. V. Kadeisvil, S. Marton

{"title":"Additional Experimental Confirmations of the New Chemical Species of Santilli Magnecules","authors":"Y. Yang, J. V. Kadeisvil, S. Marton","doi":"10.2174/1874067701305010001","DOIUrl":"https://doi.org/10.2174/1874067701305010001","url":null,"abstract":"In this paper, we present experimental confirmations of the new chemical species of magnecules identified by R. M. Santilli in 1998 [1], with particular reference to: stability of magnecules at ambient temperature; progressive reduction of magnecular species with the increase of the temperature; termination of magnecular species at a suitable Curie temperature; presence in the magnecular clusters of weakly bonded individual atoms, dimers, and conventional molecules; detection of magnecular clusters under suitable mass spectroscopy; transparency to infrared detectors at the a.m.u. of the clusters (and not at smaller a.m.u. characterizing constituents); dependence of the detected clusters from the elusion time; anomalous adhesion of magnecules to various substances; anomalous mutation of magnecular clusters; anomalous accretion of magnecules by one Hydrogen atom; and other features. It is stressed that conventional gas chromatographic equipment and procedures (that are so effective for the detection of molecules) are ineffective, if not misleading, for the detection of the new species of magnecules, thus explaining the protracted lack of general detection of mag-necules and the need for specialized equipment and procedures. The paper ends with the indication of the environmental advantages of fuels with Santillimagnecular structure due to the general lack of contaminants in the exhaust. The authors shall make available samples of magnecular gases at no cost to qualified chemists for independent analyses.","PeriodicalId":250297,"journal":{"name":"The Open Physical Chemistry Journal","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2013-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115424164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 17

IR Spectra and Vibrational Modes of the Hydrofluoroethers CF3OCH3, CF3OCF2H, and CF3OCF2CF2H and Corresponding Alkanes CF3CH3, CF3CF2H, and CF3CF2CF2H~!2010-03-11~!2010-05-19~!2010-08-06~! 氢氟醚CF3OCH3、CF3OCF2H和CF3OCF2CF2H及相应烷烃CF3CH3、CF3CF2H和CF3CF2CF2H的红外光谱和振动模式2010-03-11 2010-05-19 2010-08-06

The Open Physical Chemistry Journal Pub Date : 2010-08-19 DOI: 10.2174/1874067701004010017

J. Stevens, Lindsey D. Macomber, L. W. Davis

引用次数: 10

Molecular Dynamics Study of the Effect of Electrostatic Interactions on the Biphenyl Structure in the Active HNO3 Solvent~!2010-02-01~!2010-04-16~!2010-06-17~! 静电相互作用对活性HNO3溶剂中联苯结构影响的分子动力学研究2010-02-01 2010-04-16 2010-06-17

The Open Physical Chemistry Journal Pub Date : 2010-07-06 DOI: 10.2174/1874067701004010010

K. Kholmurodov, A. Chulkova, K. Yasuoka

引用次数: 0

Deactivation of Poly(o-Aminophenol) Film Electrodes After their Interaction with Ferric Cations. A Study Applying Interfacial Resistance Measurements~!2010-01-22~!2010-03-10~!2010-04-06~! 聚邻氨基酚膜电极与铁离子相互作用后的失活。应用界面电阻测量的研究2010-01-22 2010-03-10 2010-04-06

The Open Physical Chemistry Journal Pub Date : 2010-04-06 DOI: 10.2174/1874067701004010004

D. Scolari, R. Tucceri

{"title":"Deactivation of Poly(o-Aminophenol) Film Electrodes After their Interaction with Ferric Cations. A Study Applying Interfacial Resistance Measurements~!2010-01-22~!2010-03-10~!2010-04-06~!","authors":"D. Scolari, R. Tucceri","doi":"10.2174/1874067701004010004","DOIUrl":"https://doi.org/10.2174/1874067701004010004","url":null,"abstract":"The experimental arrangement in this investigation is one in which poly(o-aminophenol) (POAP) films were supported on thin gold films. Freshly prepared POAP film electrodes were firstly deactivated by interaction with a ferric cation solution and then, they were reactivated by treatment with an alkaline solution. Cyclic Voltammetry (CV) and Sur- face Resistance (SR) measurements were performed to analyze if after consecutive deactivation and reactivation proc- esses, the redox sites distribution (distance between adjacent redox sites) of POAP remained unaltered. By comparing with the resistance response of a freshly prepared POAP film, an attenuation of the gold film resistance within the poten- tial region of maximal electroactivity of POAP was observed after polymer deactivation. This attenuated resistance change was attributed to the creation of polymer inactive zones at the gold film-POAP film interface. Thus, deactivated POAP films exhibit a redox sites distribution with larger distances between active redox sites, as compared with that pre- sent at a gold film surface contacting a non-deactivated poly(o-aminophenol) film. Surface Resistance also showed that while the redox sites distribution of a POAP film with a low degree of deactivation (￻ c < 0.4), can be recovered without distortion, the redox sites distribution of a POAP film with a degree of deactivation higher than 0.4, suffers a irreversible distortion, which remains even after reactivation by alkaline treatment. This work can be interesting from the practical viewpoint, because conducting properties of POAP, which are associated to the electron hopping process between adja- cent redox sites, should remain substantially unchanged before and after the polymer has been used. In this regard, the re- sults of this work show the restrictive stability conditions of POAP.","PeriodicalId":250297,"journal":{"name":"The Open Physical Chemistry Journal","volume":"53 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133464291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

Polymer Solar Cells with Polymer/Carbon Nanotube Composite Hole- Collecting Buffer Layers 聚合物/碳纳米管复合集孔缓冲层聚合物太阳能电池

The Open Physical Chemistry Journal Pub Date : 2010-01-09 DOI: 10.2174/1874067701004010001

Inhyuk Lee, S. S. Lee, Hwajeong Kim, Hyunjeong Lee, Youngkyoo Kim

引用次数: 13

Synthesis of Nanosized Ceria-Zirconia Solid Solutions by a Rapid Microwave- Assisted Combustion Method 微波辅助快速燃烧法制备纳米二氧化锆固溶体

The Open Physical Chemistry Journal Pub Date : 2009-06-19 DOI: 10.2174/1874067700903010024

B. M. Reddy, G. K. Reddy, L. H. Reddy, I. Ganesh

{"title":"Synthesis of Nanosized Ceria-Zirconia Solid Solutions by a Rapid Microwave- Assisted Combustion Method","authors":"B. M. Reddy, G. K. Reddy, L. H. Reddy, I. Ganesh","doi":"10.2174/1874067700903010024","DOIUrl":"https://doi.org/10.2174/1874067700903010024","url":null,"abstract":"By adopting a simple cost effective microwave-assisted synthesis methodology, nanosized ceria-zirconia solid solution (MW) has been prepared. For comparison purpose, ceria-zirconia solid solution with the same composition was also synthesized by a coprecipitation method (CP) and calcined at 773 K. Both the samples were examined by different characterization techniques namely, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, transmis- sion electron microscopy, BET surface area and other methods, and evaluated for CO oxidation activity. XRD studies re- vealed formation of monophasic Ce0.5Zr0.5O2 solid solution in the MW sample and Ce0.75Zr0.25O2 solid solution in the CP sample. TEM studies showed the presence of nanometre sized particles with broad particle size distribution in the sample prepared by microwave method. Raman spectroscopy and oxygen storage capacity measurements suggested the presence of more oxygen vacancies and lattice defects in the MW sample. XPS studies indicated a high reducibility and surface en- richment of Ce 3+ ions in the MW sample. Higher CO oxidation activity and lower light off temperature was observed for","PeriodicalId":250297,"journal":{"name":"The Open Physical Chemistry Journal","volume":"42 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2009-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126928557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 21

Spectrometric Studies and Semi-Empirical Calculations of Some Thiomorpholides 一些硫纯化物的光谱研究和半经验计算

The Open Physical Chemistry Journal Pub Date : 2009-04-07 DOI: 10.2174/1874067700903010018

P. Allegretti, D. Ruiz, E. Castro, J. Furlong

引用次数: 0

Response Equation Based Thermochemical Analysis of Singlet Bipolaron Structures in Oligo(3-Methyl-Thiophenes) 基于响应方程的低聚(3-甲基-噻吩)单线态双极化子结构热化学分析

The Open Physical Chemistry Journal Pub Date : 2009-03-06 DOI: 10.2174/1874067700903010008

E. Hoffmann, Z. Fekete, C. Visy, T. Körtvélyesi

{"title":"Response Equation Based Thermochemical Analysis of Singlet Bipolaron Structures in Oligo(3-Methyl-Thiophenes)","authors":"E. Hoffmann, Z. Fekete, C. Visy, T. Körtvélyesi","doi":"10.2174/1874067700903010008","DOIUrl":"https://doi.org/10.2174/1874067700903010008","url":null,"abstract":"A thermochemical investigation of singlet dication (bipolaron) structures in a set of 3-methyl-thiophene oligo- mers (up to the length of 24-mers) was carried out. Equlibrium structures and heats of formation were calculated with the semiempirical quantum chemical method RHF/PM3 for the doubly oxidized forms. All-cisoid planar structural variants of the form An1Qn2An3 were considered, where A and Q are thiophene monomer units in aromatic and quinoidal chain segments, respectively. The types of segments were determined from their bond-length pattern. At this level of theory, di- verse structures combining both types of segments were found stable. The so-called \"response equation based quantitative structure-property relationship\" (REQ-QSPR) method, recently pro- posed by Fishtik et al. was used to perform and interpret regression data analysis. The REQ-based approach rationalizes mathematical treatment of stoichiometric equations. It provides a simple concept for breaking down a dataset for heat of formation into linear combination of terms that are easy to interpret in the framework of chemical groups. REQ-QSPR in- cludes arbitrary structural descriptors rather than being restricted to using only the number of chemical constituents. Ap- plied to our system, it is demonstrated that modelling nonlinear effects becomes possible as well. Supra-linear dependence of the energy with respect to the bipolaron localization length is indicated by REQ-QSPR, and detailed analysis suggests specific further calculations to carry out for improving the model.","PeriodicalId":250297,"journal":{"name":"The Open Physical Chemistry Journal","volume":"117 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2009-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115376970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lux-Flood Basicity of Mixed La2O3-Alkali Molten Carbonates Determined by Analysis of their Oxygen Solubility Properties 用氧溶解度分析测定混合la2o3 -碱熔融碳酸盐的超淹碱度

The Open Physical Chemistry Journal Pub Date : 2009-01-16 DOI: 10.2174/1874067700903010001

S. Frangini

引用次数: 6