The Open Chemical Engineering Journal最新文献

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Solubility of Mixtures Containing Soybean Oil, Ionic Liquid and Methanol 含大豆油、离子液体和甲醇混合物的溶解度
The Open Chemical Engineering Journal Pub Date : 2016-04-08 DOI: 10.2174/1874123101610010041
M. Manic, Vesna Najdanovic-Visak
{"title":"Solubility of Mixtures Containing Soybean Oil, Ionic Liquid and Methanol","authors":"M. Manic, Vesna Najdanovic-Visak","doi":"10.2174/1874123101610010041","DOIUrl":"https://doi.org/10.2174/1874123101610010041","url":null,"abstract":"This paper presents data on mutual solubility of the binary (soybean oil + ionic liquid) and ternary (soybean oil + methanol + ionic liquid) systems, where ionic liquid stands for 1-butyl-3-methylimidazolium thiocyanate [C4MIM][SCN] or 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide [C4MIM][NTf2] or 1-butyl-3-methylimidazolium dicyanamide [C4MIM][DCA] or 1-butyl-3-methylimidazolium hexafluorophosphate [C4MIM][PF6] or 1-butyl-3-methyl imida zolium hydrogensulfate [C4MIM] [HSO4] or 1-decyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C10MIM][NTf2] or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide [ALIQUAT][NTf2] or methyltrioctylammonium chloride [ALIQUAT][Cl]. Solubilities were determined by the cloud point titration method in the temperature range of 298 K to 343 K. Obtained results suggest that imidazolium based ionic liquids exhibit lower solubility in soybean oil than ionic liquids with the aliquat cation. Thus, aliquat based ionic liquids are good candidate to be used as co-solvents for biphasic (methanol + soybean oil) mixture.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"64 1","pages":"41-49"},"PeriodicalIF":0.0,"publicationDate":"2016-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78704896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Semi-Empirical Models and Cubic Equations of State for Correlation of Solids Solubility in scCO2: From Simple to Complex Substances scCO2中固体溶解度相关的半经验模型和三次状态方程:从简单到复杂物质
The Open Chemical Engineering Journal Pub Date : 2016-04-08 DOI: 10.2174/1874123101610010029
J. Coelho, R. Filipe, A. Palavra, G. Naydenova, D. Yankov, R. Stateva
{"title":"Semi-Empirical Models and Cubic Equations of State for Correlation of Solids Solubility in scCO2: From Simple to Complex Substances","authors":"J. Coelho, R. Filipe, A. Palavra, G. Naydenova, D. Yankov, R. Stateva","doi":"10.2174/1874123101610010029","DOIUrl":"https://doi.org/10.2174/1874123101610010029","url":null,"abstract":"The present paper examines the performance of cubic equations of state (CEoSs) and semi-empirical density-based models in correlating the solubility in supercritical carbon dioxide (scCO2) of several solid compounds of interest to the food industry, namely 2-propenamide, bixin, β-carotene and C-tetramethylcalix[4]resorcinarene. The four target solutes are with increasing structural complexity and, are typically pure solids, at ambient or slightly elevated temperatures. The Soave-Kwong-Redlich (SRK) CEoS with the one-fluid van der Waals mixing rule was chosen as representative of the class of CEoSs, while the group of the density-based models includes Chrastil model, Kumar and Johnston model, Bartle et al. model, Méndez–Santiago and Teja model, Garlapati and Madras model, Nejad et al. model and Khansary et al. model. The results obtained reveal that the more recently advocated density-based models (Garlapati and Madras, Nejad et al. and Khansary et al. models) perform better than the other models with overall average absolute deviations, AARD %, of 6.3, 7.8 and 7.2 %, respectively. The 9.1% overall AARD for the SRK CEoS was considered satisfactory since it can be used as a reliable thermodynamic model to predict the solubility of any compound for which there are no sufficient experimental data available.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"10 1","pages":"29-40"},"PeriodicalIF":0.0,"publicationDate":"2016-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89600829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Solubility of Bioactive Substances in Ethyl Lactate + Water Mixtures: Ferulic Acid and Caffeine 生物活性物质在乳酸乙酯+水混合物中的溶解度:阿魏酸和咖啡因
The Open Chemical Engineering Journal Pub Date : 2016-04-08 DOI: 10.2174/1874123101610010050
D. Villanueva-Bermejo, G. Reglero, R. Stateva, T. Fornari
{"title":"Solubility of Bioactive Substances in Ethyl Lactate + Water Mixtures: Ferulic Acid and Caffeine","authors":"D. Villanueva-Bermejo, G. Reglero, R. Stateva, T. Fornari","doi":"10.2174/1874123101610010050","DOIUrl":"https://doi.org/10.2174/1874123101610010050","url":null,"abstract":"D. Villanueva acknowledges the predoctoral contract (JAE) given by the Consejo Superior de Investigaciones Cientificas (CSIC) of Spain. This work was financed thanks ALIBIRD, S2013/ABI-2728 (Comunidad de Madrid) project.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"68 1","pages":"50-58"},"PeriodicalIF":0.0,"publicationDate":"2016-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73799451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Editorial: Current Topics in Phase Equilibria of Systems for Food Application 社论:食品应用系统相平衡的当前主题
The Open Chemical Engineering Journal Pub Date : 2016-04-08 DOI: 10.2174/1874123101610010001
T. Fornari, R. Stateva, A. Bonilla-Petriciolet
{"title":"Editorial: Current Topics in Phase Equilibria of Systems for Food Application","authors":"T. Fornari, R. Stateva, A. Bonilla-Petriciolet","doi":"10.2174/1874123101610010001","DOIUrl":"https://doi.org/10.2174/1874123101610010001","url":null,"abstract":"","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"77 1","pages":"1-3"},"PeriodicalIF":0.0,"publicationDate":"2016-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78275455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Liquid-liquid Equilibrium in Systems Containing Olive Oil, Free Fatty Acids, Ethanol and Water 含有橄榄油、游离脂肪酸、乙醇和水的液-液平衡
The Open Chemical Engineering Journal Pub Date : 2016-04-08 DOI: 10.2174/1874123101610010010
Daniel F. B. Lima, Luísa D. F. Santos, Daniel B. Pereira, M. Lenzi, M. Corazza, F. Voll
{"title":"Liquid-liquid Equilibrium in Systems Containing Olive Oil, Free Fatty Acids, Ethanol and Water","authors":"Daniel F. B. Lima, Luísa D. F. Santos, Daniel B. Pereira, M. Lenzi, M. Corazza, F. Voll","doi":"10.2174/1874123101610010010","DOIUrl":"https://doi.org/10.2174/1874123101610010010","url":null,"abstract":"This paper reports experimental data and the thermodynamic modeling of the liquid-liquid equilibrium systems with triacylglycerols, free fatty acids (obtained from olive oil), ethanol and water. The experimental data were fitted using the UNIQUAC model, in which absolute deviation of 1.28 % and root mean square deviation of 2.10 % between experimental and calculated mass fraction of the components in each phase were obtained. The results from this study can be complementary to investigations of more complex liquid-liquid equilibrium of systems containing diacylglycerols and monoacylglcerols of olive oil in hydroalcoholic solutions, once such systems will mostly also contain triacylglycerols and free fatty acids on its composition. Diacylglycerols are obtained from different reaction processes and can be purified by liquid-liquid extraction at mild conditions of temperature and pressure, what justifies the experimental and theoretical approach made in this work.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"8 1","pages":"10-17"},"PeriodicalIF":0.0,"publicationDate":"2016-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87368101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Useful Bioactive Substances from Wastes: Recovery of Trans-Resveratrol from Grapevine Stems 废物中有用的生物活性物质:从葡萄藤茎中回收反式白藜芦醇
The Open Chemical Engineering Journal Pub Date : 2016-04-08 DOI: 10.2174/1874123101610010004
G. Angelov, L. Boyadzhiev, S. Georgieva
{"title":"Useful Bioactive Substances from Wastes: Recovery of Trans-Resveratrol from Grapevine Stems","authors":"G. Angelov, L. Boyadzhiev, S. Georgieva","doi":"10.2174/1874123101610010004","DOIUrl":"https://doi.org/10.2174/1874123101610010004","url":null,"abstract":"The methods for producing natural resveratrol are of big interest because of the many health benefits of this substance and its increasing use in functional foods, food supplements and para-pharmaceutical preparations. Generally, resveratrol is extracted from different natural sources, most of them usually produced for consumption purposes (grapes, nuts). This paper presents a method for recovery of resveratrol from a widely available raw material grapevine stems, a by-product of vine pruning. An efficient extraction-fractionation scheme is developed, based on shifting the phase equilibrium, by which more concentrated extracts of resveratrol are obtained. After a simple extraction, the initial extract is further separated into two fractions, containing either water or ethanol-soluble compounds. Using this approach, the resveratrol’s low water solubility helps isolate it from other water-soluble substances. The resulting product is almost ten times more concentrated in trans-resveratrol than the initial total extract. Additionally, a fraction containing water-soluble polyphenols is obtained, which could be used for water-based pharmaceutical and cosmetic preparations.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"28 1","pages":"4-9"},"PeriodicalIF":0.0,"publicationDate":"2016-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91438802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Retraction Note: Seasonal Variation of Tannin and Nutrient in Aegiceras corniculatum Leaves in Zhangjiang Mangrove Ecosystem 张江红树林生态系统山菖蒲叶片单宁和养分的季节变化
The Open Chemical Engineering Journal Pub Date : 2015-12-31 DOI: 10.2174/1874123101509010161
Minshen Huang, Li-hua Zhang, Shudong Wei, Qi Zeng, Haichao Zhou, Yi-ming Lin
{"title":"Retraction Note: Seasonal Variation of Tannin and Nutrient in Aegiceras corniculatum Leaves in Zhangjiang Mangrove Ecosystem","authors":"Minshen Huang, Li-hua Zhang, Shudong Wei, Qi Zeng, Haichao Zhou, Yi-ming Lin","doi":"10.2174/1874123101509010161","DOIUrl":"https://doi.org/10.2174/1874123101509010161","url":null,"abstract":"","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"103 1","pages":"161-161"},"PeriodicalIF":0.0,"publicationDate":"2015-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80758194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on Formation Mechanism of Jiyang Shallow Saline GroundWater 济阳浅层咸化地下水形成机理研究
The Open Chemical Engineering Journal Pub Date : 2015-11-10 DOI: 10.2174/1874123101509010155
Zhang Fengjuan, Xing Liting, Wang Song, Zhuang Huibo, Dou Tongwen, Yang Zengyuan
{"title":"Research on Formation Mechanism of Jiyang Shallow Saline GroundWater","authors":"Zhang Fengjuan, Xing Liting, Wang Song, Zhuang Huibo, Dou Tongwen, Yang Zengyuan","doi":"10.2174/1874123101509010155","DOIUrl":"https://doi.org/10.2174/1874123101509010155","url":null,"abstract":"Shallow salt water in the inland plain has huge development potential. Taking saline water area in Sungeng Town, Jiyang County as an example, based on field water quality and water table tests., tracing test, methods such as mathematical statistical, hydrochemistry diagram of piper and numerical simulation by PHREEQC are used to analyze synthetically. 6862 groups data were studied. Results showed: (1) The groundwater presents typically \"weather - evaporation\" type, chemistry type is Cl.SO4-Mg.Na. and Cl.SO4-Na.Mg type. (2) In area of inland saline water presents characteristics of lagging water flow with high clay content in aquifer medium. Groundwater mineralization is obvious. (3) Hydrogeochemistry actions such as evaporation, alternate adsorption and water-rock interaction are the primary cause of the forming complex hydrochemistry type. The unique groundwater circulation characteristics of inland plains salt- water area makes water dynamic being relatively stable.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"41 1","pages":"155-160"},"PeriodicalIF":0.0,"publicationDate":"2015-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77643298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Research of the Mineralogical and Element Geochemical Characteristics of Bauxite in Yunfeng, Qingzhen, in Central Guizhou Province, China 贵州中部清镇云峰铝土矿矿物学及元素地球化学特征研究
The Open Chemical Engineering Journal Pub Date : 2015-10-22 DOI: 10.2174/1874123101509010134
Yang Wu, Dai Tagen, Long Yongzhen
{"title":"The Research of the Mineralogical and Element Geochemical Characteristics of Bauxite in Yunfeng, Qingzhen, in Central Guizhou Province, China","authors":"Yang Wu, Dai Tagen, Long Yongzhen","doi":"10.2174/1874123101509010134","DOIUrl":"https://doi.org/10.2174/1874123101509010134","url":null,"abstract":"The mineralogical and geochemical characteristics of the Yunfeng bauxite in Qingzhen were investigated through the handle specimen observation, thin section analysis, XRD、SEM and Element geochemistry. The mineral analyses reveal that diaspore, kaolinite and chlorite are the major minerals in the bauxite with small amounts of boehmite and pyrite. Geochemical investigations reveal that the main components in the bauxite are Al2O3, SiO2 and TFe2O3, the minorcomponents are TiO2, MgO and P2O5. In the process of weathering, some trace elements, such as Zr, Cr, Nb and Hf, are enriched. Zr vs Hf and Nb vs Ta display higher positive correlation. Trace elements show that Loushanguan For- mation is the main source of material for the bauxite formation and there may be exist other precursor rock provide few material for the bauxite formation. Ore deposit formed in a O-poor,reducing Marine sedimentary environment.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"94 1","pages":"134-142"},"PeriodicalIF":0.0,"publicationDate":"2015-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87502897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seasonal Variation of Tannin and Nutrient in Aegiceras corniculatum Leaves in Zhangjiang Mangrove Ecosystem 张江红树林生态系统山菖蒲叶片单宁和养分的季节变化
The Open Chemical Engineering Journal Pub Date : 2015-10-22 DOI: 10.2174/1874123101509010143
Minshen Huang, L. Zhang, Shudong Wei, Qi Zeng, Haichao Zhou, Yi-ming Lin
{"title":"Seasonal Variation of Tannin and Nutrient in Aegiceras corniculatum Leaves in Zhangjiang Mangrove Ecosystem","authors":"Minshen Huang, L. Zhang, Shudong Wei, Qi Zeng, Haichao Zhou, Yi-ming Lin","doi":"10.2174/1874123101509010143","DOIUrl":"https://doi.org/10.2174/1874123101509010143","url":null,"abstract":"Seasonal dynamics of total phenolics (TP), extractable condensed tannins (ECT), protein-bound condensed tannins (PBCT), fiber-bound condensed tannins (FBCT), total condensed tannins (TCT) and nitrogen contents in sun and shade leaves of Aegiceras corniculatum were studied in the Zhangjiang Estuary, Fujian Province, China. The contents of TP, ECT and TCT in the sun leaves were significantly higher than those in the shade leaves through the season. The N content in sun leaves was higher than that in shade leaves in the autumn, while it was lower in the summer, and there was no significant difference in the winter and spring. With the respect to the P through the year, P content in the sun leaves was different between seasons, with the highest in winter and the lowest in summer. In addition, the TP:N and ECT:N ratios in sun leaves were significantly higher than those in shade leaves except in autumn. High tannin levels and TP:N and ECT:N ratios in the sun leaves not only can reduce oxidative stress, but also improve the ability of resisting plant diseases and insect pests.","PeriodicalId":22933,"journal":{"name":"The Open Chemical Engineering Journal","volume":"7 1","pages":"143-148"},"PeriodicalIF":0.0,"publicationDate":"2015-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84382288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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