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Organocatalyzed Asymmetric Friedel‐Crafts Reactions: An Update 有机催化不对称Friedel - Crafts反应:最新进展
The Chemical Record Pub Date : 2019-03-14 DOI: 10.1002/TCR.201800190
M. Heravi, Vahideh Zadsirjan, Masumeh Heydari, B. Masoumi
{"title":"Organocatalyzed Asymmetric Friedel‐Crafts Reactions: An Update","authors":"M. Heravi, Vahideh Zadsirjan, Masumeh Heydari, B. Masoumi","doi":"10.1002/TCR.201800190","DOIUrl":"https://doi.org/10.1002/TCR.201800190","url":null,"abstract":"The Friedel ‐ Crafts alkylation (F ‐ CA) reaction is a special kind of carbon−carbon bond formations, which is frequently being used for the formation of such bond in some aromatic rings in organic synthesis. Its asymmetric variant gives enantiorich products. Commonly, an in situ organocatalyzed asymmetric Friedel ‐ Crafts alkylation (AF ‐ CA) proceeds via generation of an enamine as an intermediate. The organocatalyzed ‐ AF ‐ CA was discovered and established in the mid ‐ 1980s and reviewed comprehensively in 2010. In this report, we are trying to update the applications of novel organocatalysts in the AF ‐ CA as a versatile synthetic strategy, which is frequently used in the effective asymmetric synthesis of complex molecules, pharmaceutically important compounds and most importantly in the total synthesis of biologically active natural products .","PeriodicalId":22443,"journal":{"name":"The Chemical Record","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87239497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
Cover Picture: One‐Step Construction of the Shape Persistent, Chiral But Symmetrical Polyimine Macrocycles (Chem. Rec. 2‐3/2019) 封面图:形状持久、手性但对称的聚亚胺大环的一步构建(化学)。Rec。2量3/2019)
The Chemical Record Pub Date : 2019-02-01 DOI: 10.1002/TCR.201980201
M. Kwit, J. Grajewski, P. Skowronek, Mikołaj Zgorzelak, J. Gawroński
{"title":"Cover Picture: One‐Step Construction of the Shape Persistent, Chiral But Symmetrical Polyimine Macrocycles (Chem. Rec. 2‐3/2019)","authors":"M. Kwit, J. Grajewski, P. Skowronek, Mikołaj Zgorzelak, J. Gawroński","doi":"10.1002/TCR.201980201","DOIUrl":"https://doi.org/10.1002/TCR.201980201","url":null,"abstract":"","PeriodicalId":22443,"journal":{"name":"The Chemical Record","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91487412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cover Picture: Continuous‐Flow Suzuki‐Miyaura and Mizoroki‐Heck Reactions under Microwave Heating Conditions (Chem. Rec. 1/2019) 封面图片:微波加热条件下连续流动的Suzuki - Miyaura和Mizoroki - Heck反应(化学)。Rec。1/2019)
The Chemical Record Pub Date : 2019-01-01 DOI: 10.1002/TCR.201980101
Y. Monguchi, T. Ichikawa, Tsuyoshi Yamada, Y. Sawama, H. Sajiki
{"title":"Cover Picture: Continuous‐Flow Suzuki‐Miyaura and Mizoroki‐Heck Reactions under Microwave Heating Conditions (Chem. Rec. 1/2019)","authors":"Y. Monguchi, T. Ichikawa, Tsuyoshi Yamada, Y. Sawama, H. Sajiki","doi":"10.1002/TCR.201980101","DOIUrl":"https://doi.org/10.1002/TCR.201980101","url":null,"abstract":"","PeriodicalId":22443,"journal":{"name":"The Chemical Record","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79747078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 73
Data‐Driven Materials Exploration for Li‐Ion Conductive Ceramics by Exhaustive and Informatics‐Aided Computations 通过详尽和信息辅助计算的数据驱动材料探索Li -离子导电陶瓷
The Chemical Record Pub Date : 2018-11-30 DOI: 10.1002/TCR.201800129
M. Nakayama, Kenta Kanamori, Koki Nakano, R. Jalem, I. Takeuchi, H. Yamasaki
{"title":"Data‐Driven Materials Exploration for Li‐Ion Conductive Ceramics by Exhaustive and Informatics‐Aided Computations","authors":"M. Nakayama, Kenta Kanamori, Koki Nakano, R. Jalem, I. Takeuchi, H. Yamasaki","doi":"10.1002/TCR.201800129","DOIUrl":"https://doi.org/10.1002/TCR.201800129","url":null,"abstract":"","PeriodicalId":22443,"journal":{"name":"The Chemical Record","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79802640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 29
Cover Picture: The Catalytic Reduction of Carboxylic Acid Derivatives and CO 2 by Metal Nanoparticles on Lewis‐Acidic Supports (Chem. Rec. 10/2018) 封面图:金属纳米颗粒在Lewis -酸性载体上催化还原羧酸衍生物和二氧化碳(化学)。Rec。10/2018)
The Chemical Record Pub Date : 2018-10-01 DOI: 10.1002/TCR.201881001
Takashi Toyao, S. H. Siddiki, K. Kon, K. Shimizu
{"title":"Cover Picture: The Catalytic Reduction of Carboxylic Acid Derivatives and CO\u0000 2\u0000 by Metal Nanoparticles on Lewis‐Acidic Supports (Chem. Rec. 10/2018)","authors":"Takashi Toyao, S. H. Siddiki, K. Kon, K. Shimizu","doi":"10.1002/TCR.201881001","DOIUrl":"https://doi.org/10.1002/TCR.201881001","url":null,"abstract":"","PeriodicalId":22443,"journal":{"name":"The Chemical Record","volume":"83 7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89600989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover (Chem. Rec. 7-8/2018) 封面(化学)Rec 7-8/2018)。
The Chemical Record Pub Date : 2018-07-01 DOI: 10.1002/tcr.201880801
{"title":"Front Cover (Chem. Rec. 7-8/2018)","authors":"","doi":"10.1002/tcr.201880801","DOIUrl":"https://doi.org/10.1002/tcr.201880801","url":null,"abstract":"","PeriodicalId":22443,"journal":{"name":"The Chemical Record","volume":"87 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2018-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81228329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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