Solvent Extraction Research and Development, Japan最新文献_第7页

Ultrasonic Assisted Microchannel Extraction of Fe(III) from Wet-Process Phosphoric Acid 超声波辅助微通道萃取湿法磷酸中铁(III)的研究

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.51

Shuai Zhang, Xingbin Lv, Qi Xia, Jiangpo Zhang, Jianjun Chen, Daijun Liu

引用次数: 0

Extraction Behavior of Precious Metals in Hydrochloric-acid Media Using a Novel Amine Extractant Bearing a Furan Group 含呋喃基新型胺萃取剂在盐酸介质中萃取贵金属的行为

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.69

T. Oshima, Seishiro Iwao, Naoki Matsuo, K. Ohe

引用次数: 3

Extraction of Cephalosporin Antibiotics with Aqueous Two-phase Systems Composed of Water-miscible Organic Solvents and Salts 水溶有机溶剂和盐组成的双水相萃取头孢菌素类抗生素

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.63

M. Matsumoto, T. Ueda

{"title":"Extraction of Cephalosporin Antibiotics with Aqueous Two-phase Systems Composed of Water-miscible Organic Solvents and Salts","authors":"M. Matsumoto, T. Ueda","doi":"10.15261/SERDJ.26.63","DOIUrl":"https://doi.org/10.15261/SERDJ.26.63","url":null,"abstract":"The -lactam antibiotics such as penicillin and cephalosporin account for over 65% of the market. Development of a more effective separation technique is desired to extract and purify the biologically active cephalosporin antibiotics. In this study, to recover cephalosporin antibiotics, cephalosporin C and cephalexin, an aqueous two-phase system (ATPS) composed of a water-miscible organic solvent and salts was used. For cephalosporin C extraction with the ATPS, the extent of extraction of cephalosporin C was small because of its high hydrophilicity. For cephalexin, which is more hydrophobic, it was successfully extracted with ATPS. From binodal experiments, tetrahydrofuran (THF), 1-propanol and acetone were selected as the candidates for the extraction solvent. In the extraction experiments, THF was found to be suitable because it gave the highest extractability of cephalexin and the lowest water content in the top (solvent) phase among the candidates. When the initial volume ratio of water to solvent was unity, the maximum distribution ratio was 3.13. The value of the distribution ratio increased up to 9.87 with increasing initial volume ratio. The ATPS composed of a water-miscible organic solvent and salt was found to be promising for purification of antibiotics under such mild conditions.","PeriodicalId":21805,"journal":{"name":"Solvent Extraction Research and Development, Japan","volume":null,"pages":null},"PeriodicalIF":0.7,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.15261/SERDJ.26.63","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67093685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

Multifunctional Effect of the Polymer Extractant Thiomethylbenzoxazoyl-α-Methylstyrene on the Extraction of Au(III) 聚合物萃取剂硫甲基苯并恶唑-α-甲基苯乙烯萃取金(III)的多功能效应

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.91

Takafumi Hanada, Minako Iwakuma, M. Goto

引用次数: 1

Mechanism of Palladium(II) Adsorption from Nitric Acid Solutions by a Styrene-Divinylbenzene Copolymer Functionalized with N,N,N-Trimethylglycine N,N,N-三甲基甘氨酸功能化苯乙烯-二乙烯基苯共聚物对硝酸溶液中钯的吸附机理

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.11

Tomoya Suzuki, H. Narita, Takeshi Ogata, Hideya Suzuki, T. Matsumura, Tohru Kobayashi, H. Shiwaku, T. Yaita

{"title":"Mechanism of Palladium(II) Adsorption from Nitric Acid Solutions by a Styrene-Divinylbenzene Copolymer Functionalized with N,N,N-Trimethylglycine","authors":"Tomoya Suzuki, H. Narita, Takeshi Ogata, Hideya Suzuki, T. Matsumura, Tohru Kobayashi, H. Shiwaku, T. Yaita","doi":"10.15261/SERDJ.26.11","DOIUrl":"https://doi.org/10.15261/SERDJ.26.11","url":null,"abstract":"The ability of AMP03, a styrene–divinylbenzene copolymer functionalized with N,N,N -trimethylglycine moieties, to adsorb Pd(II) from HNO 3 solutions was investigated to elucidate the affinity of N,N,N -trimethylglycine for Pd(II). AMP03 effectively adsorbed Pd(II) from 0.10–0.50 M solutions in HNO 3 , and the adsorption ability decreased with increasing HNO 3 concentration owing to competitive adsorption of the acid. In contrast, the presence of added NO 3− increased the Pd(II) adsorption ability of the copolymer. On the basis of slope analysis of data for Pd(II) and HNO 3 at adsorption equilibrium, the Pd(II)/NO 3− /ligand stoichiometry of the adsorbed Pd(II) species was determined to be 1 : 2 : 1. Structural studies performed by means of Fourier transform infrared spectroscopy and extended X-ray absorption fine structure spectroscopy revealed that the N,N,N -trimethylglycine moieties on AMP03 and NO 3− coordinated to Pd(II) via their oxygen atoms. The adsorption selectivity of AMP03 for Pd(II), Ni(II), Cu(II), and Fe(III) was compared with the selectivities of commercially available carboxylic acid and iminodiacetic acid resins. AMP03 selectively adsorbed Pd(II) over Ni(II), Cu(II), and Fe(III) compared with that of the other resins. Our results suggest that AMP03 can be used for selective recovery of Pd(II) from HNO 3 solution.","PeriodicalId":21805,"journal":{"name":"Solvent Extraction Research and Development, Japan","volume":null,"pages":null},"PeriodicalIF":0.7,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.15261/SERDJ.26.11","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67093277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

Separation of Model Petroleum Heavy Fraction by Equilibrium Extraction 平衡萃取法分离模拟石油重馏分

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.35

H. Habaki, Tomonori Masuda, R. Egashira

引用次数: 0

Separation of Scandium from Yttrium in Aqueous Chloride Media by Solvent Extraction with an Acidic Phosphinate Extractant 酸性膦酸盐萃取剂溶剂萃取在氯水介质中分离钪和钇

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.99

J. Moon, Emi Yamada, S. Nishihama, K. Yoshizuka

引用次数: 2

Extraction Behavior of Metal Cations Using 8-Quinolinol as an Extractant in Cyclopentyl Methyl Ether 8-喹啉醇萃取环戊基甲基醚中金属阳离子的萃取行为

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2019-01-01 DOI: 10.15261/SERDJ.26.1

T. Oshima, Takao Koyama, K. Ohe, Noriyasu Otsuki

{"title":"Extraction Behavior of Metal Cations Using 8-Quinolinol as an Extractant in Cyclopentyl Methyl Ether","authors":"T. Oshima, Takao Koyama, K. Ohe, Noriyasu Otsuki","doi":"10.15261/SERDJ.26.1","DOIUrl":"https://doi.org/10.15261/SERDJ.26.1","url":null,"abstract":"To date, many kinds of chelating extractants have been developed, however, many of the good extractants are insoluble in aliphatic solvents. In the present study, cyclopentyl methyl ether (CPME) was assessed as a solvent for extractants to develop new solvent extraction systems. Many of the extractants (100 mM) were soluble in CPME. The extraction behavior of metal ions using a typical chelating extractant, 8-quinolinol (HQ) in CPME, was studied. The extraction profiles of metal ions using HQ in CPME were similar to those in toluene, whereas metal ions were extracted using HQ in 1-octanol and chloroform under lower pH conditions. The extraction reaction of In(III) using HQ in CPME was confirmed by slope analysis. A 3 : 1 complex between HQ and In(III) was formed in CPME by a proton exchange reaction, and the extraction equilibrium constant was determined. In(III), extracted using HQ in CPME, was quantitatively recovered using mineral acids. From the results, CPME was found to be a potential alternative solvent to other toxic organic solvents for the development of a solvent extraction system.","PeriodicalId":21805,"journal":{"name":"Solvent Extraction Research and Development, Japan","volume":null,"pages":null},"PeriodicalIF":0.7,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.15261/SERDJ.26.1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67093194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Silver Extraction with Sulfide Type Trident Compounds 硫化物型三叉戟化合物萃取银

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2018-01-01 DOI: 10.15261/SERDJ.25.71

K. Ohto, Takuyou Yoshinaga, Hiroaki Furugou, Shintaro Morisada, H. Kawakita, K. Inoue

{"title":"Silver Extraction with Sulfide Type Trident Compounds","authors":"K. Ohto, Takuyou Yoshinaga, Hiroaki Furugou, Shintaro Morisada, H. Kawakita, K. Inoue","doi":"10.15261/SERDJ.25.71","DOIUrl":"https://doi.org/10.15261/SERDJ.25.71","url":null,"abstract":"A sulfide type trident molecule together with a monopodal compound has been prepared to investigate the extraction behavior of silver. The present trident molecule has a weaker extraction ability than thiol and dithioether derivatives of previously reported tripodal extraction reagents. On the contrary, it exhibited a higher extraction ability than the corresponding monopodal molecule due to the structural effect of the trident framework. Both sulfide molecules did not exhibit any pH dependency for silver extraction. The trident molecule showed a 1 : 1 stoichiometry (trident molecule : silver), while the monopodal molecule gave a 2 : 1 stoichiometry (monopodal molecule : silver). The coordination site of the trident molecule was confirmed by 1 H-NMR spectra before and after silver loading. The signal shifts for the protons of the methylene groups bounded to the sulfur atoms for the trident and monopodal compounds before and after silver loading were correlated with the formation of complexes. From the comparison of both molecules, the peak shift for the trident molecule included contributions not only from the functional groups but also from the structure of the trident framework.","PeriodicalId":21805,"journal":{"name":"Solvent Extraction Research and Development, Japan","volume":null,"pages":null},"PeriodicalIF":0.7,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89310438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Extraction and Esterification of Succinic Acid Using Aqueous Two-phase Systems Composed of Ethanol and Salts 乙醇-盐双水相体系萃取及酯化琥珀酸的研究

IF 0.7 4区工程技术

Solvent Extraction Research and Development, Japan Pub Date : 2018-01-01 DOI: 10.15261/SERDJ.25.101

M. Matsumoto, M. Tatsumi

{"title":"Extraction and Esterification of Succinic Acid Using Aqueous Two-phase Systems Composed of Ethanol and Salts","authors":"M. Matsumoto, M. Tatsumi","doi":"10.15261/SERDJ.25.101","DOIUrl":"https://doi.org/10.15261/SERDJ.25.101","url":null,"abstract":"Succinic acid and its ester have been considered as a renewable feedstock for chemical derivatives. A biotechnological production route for succinic acid has become of interest as a sustainable alternative to the chemical route. However, its hydrophilicity makes the separation of succinic acid from the fermentation broth difficult. In this study, to recover succinic acid from the fermentation broth, an aqueous two-phase system (ATPS) composed of ethanol and salts was used, and then the extracted succinic acid was esterified with ethanol because its ester had different physico-chemical properties that helped in its purification. In the ATPS, ammonium sulfate gave the highest extractability. Succinic acid was found to be co-extracted with water to the ethanol-rich phase. In a model experiment in the absence of water, succinic acid was successfully esterified with ethanol and the kinetics obeyed a pseudo-first-order consecutive reaction. Then the esterification of succinic acid using the ethanol-rich phase after the aqueous two phase extraction was carried out. In the case of the ATPS having a high extractability, the conversion of succinic acid and the yield of the di-ester were relatively low due to the large amount of co-extracted water. It was found that the water content was a key parameter in the esterification reaction.","PeriodicalId":21805,"journal":{"name":"Solvent Extraction Research and Development, Japan","volume":null,"pages":null},"PeriodicalIF":0.7,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78922844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3