Radiochimica Acta最新文献

Study on separation of ReO4 −, a substitute for TcO4 −, using functional ionic liquid impregnated extraction chromatography resins 利用功能离子液体浸渍萃取色谱树脂分离锝氧化还原剂 ReO4 - 的研究

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-09-12 DOI: 10.1515/ract-2024-0290

Meiying Liu, Xupeng Zhi, Peng Liu, Xiaomin Li, Xinlong Chen, Bin Liu, Yinglin Shen

{"title":"Study on separation of ReO4 −, a substitute for TcO4 −, using functional ionic liquid impregnated extraction chromatography resins","authors":"Meiying Liu, Xupeng Zhi, Peng Liu, Xiaomin Li, Xinlong Chen, Bin Liu, Yinglin Shen","doi":"10.1515/ract-2024-0290","DOIUrl":"https://doi.org/10.1515/ract-2024-0290","url":null,"abstract":"99Tc has a long half-life, high fission yield, and good environmental mobility, posing a significant threat to the environment and human health. Therefore, removing technetium from radioactive wastewater is a very important and urgent task. For laboratory safety reasons, ReO4 − is often used as a non-isotopic substitute for 99TcO4 −. From this point of view, the study of the separation behavior of Re in the aqueous phase can provide a reference value for the removal of 99Tc. Here, a new type of extraction chromatography resin was prepared by impregnating the functionalized ionic liquid into the macroporous resin, whose imidazolium cations modified by amide functional groups which can effectively capture ReO4 −/TcO4 − from simulated radioactive wastewater. The results show the resin has good adsorption performance and fast adsorption kinetics (the adsorption equilibrium is about 20 min). The adsorption mechanism was investigated using Fourier transform infrared (FT-IR) spectra and X-ray photoelectron spectroscopy (XPS). It shows that the adsorption process is an anion exchange between Cl− in the resin and ReO4 − in the solution.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"11 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

In vivo evaluation of Cerenkov luminescence and SPECT imaging for nanoscale 177Lu-labeled metal-organic framework 纳米级 177Lu 标记金属有机框架的塞伦科夫发光和 SPECT 成像的体内评估

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-09-12 DOI: 10.1515/ract-2024-0306

Wenbing Ding, Jie Lyu, Yuying Yu, Fuyuan Tan, Ai Yang, Tu Lan, Jiali Liao, Yuanyou Yang, Ning Liu, Feize Li

引用次数: 0

[113mIn]In-PSMA: high potential agent for SPECT imaging of prostate cancer [113mIn]In-PSMA：用于前列腺癌 SPECT 成像的高潜力制剂

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-09-03 DOI: 10.1515/ract-2024-0298

Leyla Akbari, Sedigheh Sina, Samaneh Zolghadri, Ali Moghaddasi, Kamal Hadad, Hassan Yousefnia

{"title":"[113mIn]In-PSMA: high potential agent for SPECT imaging of prostate cancer","authors":"Leyla Akbari, Sedigheh Sina, Samaneh Zolghadri, Ali Moghaddasi, Kamal Hadad, Hassan Yousefnia","doi":"10.1515/ract-2024-0298","DOIUrl":"https://doi.org/10.1515/ract-2024-0298","url":null,"abstract":"The prevalence rate of prostate cancer is very high and unfortunately causes many deaths worldwide. This study aimed to prepare [113mIn]In-PSMA as a novel agent for single photon emission computed tomography (SPECT) imaging of prostate cancer. 113mIn was eluted from an in-house made 113Sn/113mIn generator in chloride form, and its radionuclide, chemical and radiochemical purities was studied. [113mIn]In-PSMA was prepared with radiochemical purity (RCP) > 99 % under optimal labeling conditions. The biodistribution of the labeled compound was studied in normal rats, showed the major activity in the urine and kidneys as the main excretion route from the body. Considerable uptake was observed in the prostate and salivary glands as the PSMA-expressing organs. These data are in complete agreement with the other published data on PSMA-labeled compounds both in animals and humans. The results demonstrated [113mIn]In-PSMA can be considered as a good option for SPECT imaging of prostate cancer.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"47 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Development of gelatin nanoparticles for positron emission tomography diagnosis in pancreatic cancer 开发用于胰腺癌正电子发射断层扫描诊断的明胶纳米粒子

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-09-02 DOI: 10.1515/ract-2024-0304

Yumi Sugo, Atsushi Kimura, Tomoya Koizumi, Kotaro Oyama, Mitsumasa Taguchi

引用次数: 0

Radiochemical separation of 161 Tb from neutron irradiated Gd target by liquid-liquid extraction technique 利用液液萃取技术从中子辐照钆靶中放射性化学分离 161 Tb

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-09-02 DOI: 10.1515/ract-2024-0286

Ahmed M. Shahr El-Din, Mohamed A. Gizawy, Emad H. Borai

{"title":"Radiochemical separation of 161 Tb from neutron irradiated Gd target by liquid-liquid extraction technique","authors":"Ahmed M. Shahr El-Din, Mohamed A. Gizawy, Emad H. Borai","doi":"10.1515/ract-2024-0286","DOIUrl":"https://doi.org/10.1515/ract-2024-0286","url":null,"abstract":"No-carrier-added (NCA) 161 Tb, which has advisable nuclear properties to be applied for cancer radiotherapy was produced at the Egyptian Second Research Reactor (ETRR-2) by neutron irradiation of natural gadolinium target via indirect nuclear reaction. The radiochemical separation of 161 Tb from irradiated gadolinium target was investigated based on solvent extraction technique using Cyanex 302. Several separation parameters were checked and optimized. According to the obtained results, the separation process of the investigated radioisotopes proceeds in two steps. The first step is an extraction of all of them into the organic phase in which the extraction % (98 %) was optimized at pH 4, 0.15 M of Cyanex 302 and 2.5 h extraction time. Moreover, the slope analysis method confirmed the participation of 2 mol of the organic extractant for the separation of 161 Tb from irradiated gadolinium. The second step is the separation of the 161 Tb isotope that was purified by the stripping of 159Gd with a citrate solution at pH 9, which is considered as a highly efficient and promising method for separation and purification of the two radioisotopes.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"75 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of ZnO particle size on the radiation shielding efficiency of B2O3–BaO–ZnO glass system 氧化锌粒度对 B2O3-BaO-ZnO 玻璃体系辐射屏蔽效率的影响

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-09-02 DOI: 10.1515/ract-2024-0312

Aljawhara H. Almuqrin, M. I. Sayyed, F.F. Alharbi, M. Elsafi

{"title":"Effect of ZnO particle size on the radiation shielding efficiency of B2O3–BaO–ZnO glass system","authors":"Aljawhara H. Almuqrin, M. I. Sayyed, F.F. Alharbi, M. Elsafi","doi":"10.1515/ract-2024-0312","DOIUrl":"https://doi.org/10.1515/ract-2024-0312","url":null,"abstract":"This study analyzes the ZnO particle size’s effect on glass samples’ radiation shielding ability. Four glass samples with differing micro and nanoparticle ZnO content were investigated at four energies, 0.060, 0.662, 1.173, and 1.333 MeV. The investigated glasses are a B2O3–BaO–ZnO glass system and are composed of 30 % micro ZnO (30 M), 20 % micro ZnO and 10 % nano ZnO (20 M−10 N), 10 % micro ZnO and 20 % nano ZnO (10 M−20 N), and lastly 30 % nano ZnO (30 N). The theoretical XCOM software was employed to validate the experimental LAC values of the glasses, revealing that for at all energies, the values obtained from the two methods agreed with each other well. The glasses’ HVL, MFP, and RSE were then compared. The HVL values at all energies decreased as more nano ZnO was introduced into the glass system, reaching a minimum of 1.947 cm at 0.662 MeV for the 30 N sample. This sample also had the lowest MFP at all energies, while the 30 M glass had the highest, such as 0.088 and 0.070 for 30 M and 30 N respectively at 0.060 MeV. The RSE of a 1 cm thick sample of each of the glasses was tested and found that the 30 N sample exhibited the greatest RSE. The relative percent deviation between the 30 N and 30 M glasses was also analyzed, which highlighted the difference between 30 N’s greater LAC values compared to 30 M at all energies.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"21 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The effect of rare earths (Nd3+, Er3+, Yb3+) additives on the radiation shielding properties of the tungsten oxide modified tellurite glasses 稀土（Nd3+、Er3+、Yb3+）添加剂对氧化钨改性碲玻璃辐射屏蔽性能的影响

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-08-19 DOI: 10.1515/ract-2024-0297

Ömer Kaban, Gülçin Bilgici Cengiz, İlyas Çağlar, Gökhan Bilir

{"title":"The effect of rare earths (Nd3+, Er3+, Yb3+) additives on the radiation shielding properties of the tungsten oxide modified tellurite glasses","authors":"Ömer Kaban, Gülçin Bilgici Cengiz, İlyas Çağlar, Gökhan Bilir","doi":"10.1515/ract-2024-0297","DOIUrl":"https://doi.org/10.1515/ract-2024-0297","url":null,"abstract":"In this study, we have reported on the effect of the rare earth oxides on the radiation protection performance of the tellurite glasses. In order to determine the effect of rare earth oxides on the radiation shielding properties of tungsten oxide (WO3) modified tellurite glasses, three rare earth element oxides (Nd2O3, Yb2O3, and Er2O3) have been selected. The glass systems have been synthesized using the traditional melt quenching method and were doped with the different amount (1 %, 3 %, 5 %) of the oxides of rare earth elements (Nd2O3, Yb2O3, Er2O3). The linear attenuation coefficient, mass attenuation coefficient, half value layer, and effective atomic number of the synthesized samples were experimentally measured for 662, 1,173 and 1,332 keV gamma-ray energies which were emitted from 137Cs and 60Co radioactive sources. Measurements were conducted in narrow beam transmission geometry using a NaI(Tl) scintillation detector. In addition, all these parameters were calculated theoretically using the WinXCOM program in the energy region of 0.015–15 MeV. The addition of different types and amounts of rare earth oxides to the tellurite glass system was found to significantly enhance the radiation protection performance of the glasses. In particular, it was found that the radiation shielding characteristics of the glasses improved with increasing amount of rare earth doping, the TWYb5 glass system had the best radiation shielding properties, and there was a trend among the doped rare earth oxides in the form of Yb > Er > Nd according to their radiation shielding performance.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"11 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Influence of gamma irradiation on germination traits, growth and biochemical attributes of dragon fruit (Selenicereus monacanthus) 伽马辐照对火龙果（Selenicereus monacanthus）发芽特性、生长和生化属性的影响

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-08-17 DOI: 10.1515/ract-2024-0294

Kundan Kishore, Kuldeep K. Shukla, Manas R. Sahoo, Kedareswar Pradhan, Rajkumari Bhol, Subash C. Swain

{"title":"Influence of gamma irradiation on germination traits, growth and biochemical attributes of dragon fruit (Selenicereus monacanthus)","authors":"Kundan Kishore, Kuldeep K. Shukla, Manas R. Sahoo, Kedareswar Pradhan, Rajkumari Bhol, Subash C. Swain","doi":"10.1515/ract-2024-0294","DOIUrl":"https://doi.org/10.1515/ract-2024-0294","url":null,"abstract":"The aim of this research is to assess the effectiveness of gamma irradiation in developing genetic variability in dragon fruit by influencing biochemical attributes. Seeds of dragon fruit were exposed to 100, 200, 300, 400 and 500 Gy γ-radiation using Co-60 source. Highest germinability, mean germination time, mean daily germination, vigour index and growth rate were observed in untreated seeds, however these traits were relatively less affected at lower irradiation level (up to 200 Gy). An irradiation level of ≥ 400 Gy severely affected germination traits and seedling growth and consequently 441 Gy irradiation level was considered as the lethal dose (LD50) for dragon fruit. Photosynthetic pigments, protein content and nutrient content were highest in untreated seedlings and moderately high up to 200 Gy. Findings demonstrated that the concentration of biochemical markers for abiotic stress tolerance viz. proline, phenol, flavonoid and antioxidant enzymes (superoxide dismutase, catalase and ascorbate peroxidase), were significantly high at 200 Gy irradiation level. Hence an irradiation dose of 200 Gy may be considered as an optimal for induced mutagenesis for abiotic stress tolerance in dragon fruit with the least possible unintended damage to seedling growth traits. The findings provide valuable insights into the efficient utilization of γ-irradiation in expediting the development of abiotic stress-tolerant mutant lines of dragon fruit.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"162 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142192155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Significant influence of La2O3 content on radiation shielding characteristics properties of bismuth sodium borosilicate glasses La2O3 含量对硼硅酸铋钠玻璃辐射屏蔽特性的显著影响

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-08-07 DOI: 10.1515/ract-2024-0307

Eman M. Mahrous, Ateyyah M. Al-Baradi, Kh. S. Shaaban

{"title":"Significant influence of La2O3 content on radiation shielding characteristics properties of bismuth sodium borosilicate glasses","authors":"Eman M. Mahrous, Ateyyah M. Al-Baradi, Kh. S. Shaaban","doi":"10.1515/ract-2024-0307","DOIUrl":"https://doi.org/10.1515/ract-2024-0307","url":null,"abstract":"Melt-quenching was used to create high density glasses with a chemical composition of (15-x) Na2O–45B2O3–20Bi2O3–20SiO2–xLa2O3, where, x = (0 ≤ x ≥ 15) mol%. Through the use of (XRD) analysis, the amorphous status of these glasses was ascertained. We examined on the synthetic glasses physical attributes as well as their ability to shield against gamma radiation. The density increased from 4.913 g/cm3 for BBSNLa0 glass to 6.497 g/cm3 for BBSNLa15 glass. The study employed the Phy-X/PSD code to explore the radiation shielding properties of these glasses. As the mol% of La2O3 increases, the MFP decreases. This indicates that glass samples with a higher concentration of La2O3 have a greater ability to attenuate or absorb photons, resulting in a shorter average distance traveled before interaction. The BBSNLa-15 glass sample is the best choice for applications in radiation protection.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"103 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141939822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study on the adsorption performance of zeolite imidazole frameworks materials for Co(II) and Mn(II) in solution 沸石咪唑框架材料对溶液中 Co(II) 和 Mn(II) 的吸附性能研究

IF 1.8 3区化学

Radiochimica Acta Pub Date : 2024-07-24 DOI: 10.1515/ract-2024-0274

Ping Bao, Yipeng Zhou, Xiaowei Wang, Jinfeng Men, Chengqiang Liang, Hao Ding

{"title":"Study on the adsorption performance of zeolite imidazole frameworks materials for Co(II) and Mn(II) in solution","authors":"Ping Bao, Yipeng Zhou, Xiaowei Wang, Jinfeng Men, Chengqiang Liang, Hao Ding","doi":"10.1515/ract-2024-0274","DOIUrl":"https://doi.org/10.1515/ract-2024-0274","url":null,"abstract":"The radionuclides 60Co and 54Mn are the main activation products produced in the operation of nuclear power facilities. Wastewater with these radionuclides must be treated to meet standards before being discharged. A variety of zeolite imidazole frameworks (ZIFs) materials were synthesized at room temperature, and the adsorption effect of ZIF-67 was found to be the best through adsorption experiments on Co(II) and Mn(II). The thermal stability test and structural characterization of ZIF-67 were carried out. At the same time, the influence of the initial pH value, adsorption time, and initial concentration of the solution on the adsorption of Co(II) and Mn(II) by ZIF-67 was investigated. The results show that: ZIF-67 has a microporous structure with a BET surface area of 1,035.72 m2/g. In addition, ZIF-67 has good thermal stability, under the condition of pH = 6, a temperature of 303 K and the initial concentration of 500 mg/L. The saturated adsorption capacity for Co(II) and Mn(II) reached 230.25 mg/g and 338.75 mg/g, respectively. ZIF-67 exhibits good selective adsorption performance for Co(II) and Mn (II) in high concentration interfering ion solutions and multi-ion solutions. The adsorption process of ZIF-67 was analyzed by kinetics, thermodynamics, isotherms, and adsorption diffusion models. The analysis of thermodynamic parameters shows that the adsorption process of ZIF-67 to Co(II) and Mn(II) is spontaneous and endothermic. The pseudo-second-order kinetic model, Langmuir isotherm model, and Boyd model are more in line with the adsorption process of Co(II) and Mn(II) by ZIF-67. It shows that the active sites on the surface of ZIF-67 are evenly distributed, and the adsorption process is single-molecule chemical layer adsorption. In addition, the liquid film diffusion dominates the adsorption rate during the adsorption process of Co(II) and Mn(II) by ZIF-67.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":"34 2 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141785268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0