Reviews in Analytical Chemistry最新文献

Major biochemical constituents of Withania somnifera (ashwagandha) extract: A review of chemical analysis Withania somnifera (ashwagandha)提取物主要生化成分的化学分析综述

IF 4.3 3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2022-0055

Mahmoud Tareq Abdelwahed, Maha A. Hegazy, Ekram H Mohamed

引用次数: 3

A brief review of the application of microextraction by packed sorbent for antibiotics analysis from biological, food, and environmental samples 简要综述了包装吸附剂微萃取法在生物、食品和环境样品中抗生素分析中的应用

IF 4.3 3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2023-0057

G. Granados-Guzmán, Mónica Díaz-Hernández, R. Álvarez-Román, Norma Cavazos-Rocha, Omar J. Portillo-Castillo

{"title":"A brief review of the application of microextraction by packed sorbent for antibiotics analysis from biological, food, and environmental samples","authors":"G. Granados-Guzmán, Mónica Díaz-Hernández, R. Álvarez-Román, Norma Cavazos-Rocha, Omar J. Portillo-Castillo","doi":"10.1515/revac-2023-0057","DOIUrl":"https://doi.org/10.1515/revac-2023-0057","url":null,"abstract":"Abstract Currently, sample preparation is the most laborious part of the analytical process, requiring the most time and being susceptible to the most errors. In this context, numerous investigations have focused on the miniaturization of these techniques to reduce work time, costs, and errors. In this regard, microextraction by packed sorbent (MEPS) is a simple, fast, and robust sample preparation technique suitable for easy automation in several analytical systems and is applied to a wide variety of samples. Antibiotics are among the most commonly used drugs; however, their extensive and inappropriate use has garnered significant attention in the environment, human health, and food safety. This brief review is intended to provide an overview of recently reported antibiotic extraction methods based on MEPS, with a special interest in those applied to the analysis of biological, environmental, and food samples. In addition, the sample pretreatment step before extraction by the MEPS device was highlighted, as was the description of the sample-related steps within the MEPS procedure, such as extraction, washing, and elution.","PeriodicalId":21090,"journal":{"name":"Reviews in Analytical Chemistry","volume":"2 1","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85000995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Progress of sensitive materials in chemiresistive sensors for detecting chemical warfare agent simulants: A review 用于化学战剂模拟物探测的化学传感器敏感材料研究进展

IF 4.3 3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2022-0052

Liu Yang, Molin Qin, Genwei Zhang, Jie Yang, Junchao Yang, Jiang Zhao

{"title":"Progress of sensitive materials in chemiresistive sensors for detecting chemical warfare agent simulants: A review","authors":"Liu Yang, Molin Qin, Genwei Zhang, Jie Yang, Junchao Yang, Jiang Zhao","doi":"10.1515/revac-2022-0052","DOIUrl":"https://doi.org/10.1515/revac-2022-0052","url":null,"abstract":"Abstract Chemical warfare agents (CWAs) are chemical substances intended for use in military operations to kill, injure, or incapacitate an enemy. It is very important to detect toxic CWAs at trace levels on site. Compared with traditional CWA analysis instrument methods, chemiresistive gas sensors present advantages of being small, fast, and inexpensive. Chemiresistive gas sensors are still an important research topic with the development of nanofabrication technology and new kinds of sensing materials, including carbon nanotubes, graphene, and black phosphorus (BP). Chemiresistive gas sensors are divided into three categories according to the type of sensitive materials: carbon- and BP-based materials, conductive polymers, and metal oxide semiconductors. A brief analysis was carried out on fabrication strategies using sensitive materials, including hydrogen bonding strategies, nanostructures, morphology, doping effects, composite materials, and other material application methods, and the sensitive materials and detection effects are summarized in this study. This review aims to provide guidance in the development of chemiresistive sensors for the detection of CWAs. Graphical abstract","PeriodicalId":21090,"journal":{"name":"Reviews in Analytical Chemistry","volume":"196 1","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78979649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Detection of exosomes in various biological fluids utilizing specific epitopes and directed multiple antigenic peptide antibodies 利用特异性表位和定向多种抗原肽抗体检测各种生物体液中的外泌体

IF 4.3 3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2023-0056

Dikshita Panwar, D. Shrivastava, Shalaka Bhawal, L. K. Gupta, N. S. S. Kumar, A. D. Chintagunta

{"title":"Detection of exosomes in various biological fluids utilizing specific epitopes and directed multiple antigenic peptide antibodies","authors":"Dikshita Panwar, D. Shrivastava, Shalaka Bhawal, L. K. Gupta, N. S. S. Kumar, A. D. Chintagunta","doi":"10.1515/revac-2023-0056","DOIUrl":"https://doi.org/10.1515/revac-2023-0056","url":null,"abstract":"Abstract Exosomes are nanosized cell-derived vesicles that have recently gained attention for their use as a biomarker since the biomolecules encountered in these vesicles are directly linked to specific diseases including immuno-inflammatory, cardiovascular, and hepatic disorders. Furthermore, due to their nano size and safe travel in extracellular fluids, exosomes have been investigated as natural drug delivery systems, delivering cargo to destined cells with excellent specificity and efficiency, and crossing the blood–brain barrier. This necessitates the isolation and detection of exosomes. However, numerous exosome isolation techniques are available, including ultracentrifugation, size-based chromatography, polymer precipitation, microfluidics, and immunoaffinity-based isolation, with the downfalls of non-specificity and lower cost-effectiveness. This article introduces an immunoaffinity-based detection of exosomes using targeted anti-exosome antibodies raised in chickens due to its economic and commercial viability. The current study is unique in that it identified a specific antigenic region on exosomal surface tetraspanins (CD9, CD63, CD81) and constructed a multiple antigenic peptide dendrimer for making a small peptide as an immunogen without the use of a carrier protein. The antigenic region selection is critical to the study because it determines the efficiency of antibodies for exosome capture. This technique was validated using enzyme-linked immunosorbent assay in various biological fluids such as serum, urine, milk, plasma, and blood due to its numerous advantages including high sensitivity, specificity, handling multiple samples at once, requiring a small sample amount, and no purification as an antigen. In light of this technique, it is a useful tool for clinical monitoring of the patient’s biological conditions. Graphical abstract","PeriodicalId":21090,"journal":{"name":"Reviews in Analytical Chemistry","volume":"73 1","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78062402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Enhancing methane sensing with NDIR technology: Current trends and future prospects 利用NDIR技术加强甲烷传感:当前趋势和未来前景

3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2023-0062

Li Fu, Shixi You, Guangjun Li, Zengchang Fan

{"title":"Enhancing methane sensing with NDIR technology: Current trends and future prospects","authors":"Li Fu, Shixi You, Guangjun Li, Zengchang Fan","doi":"10.1515/revac-2023-0062","DOIUrl":"https://doi.org/10.1515/revac-2023-0062","url":null,"abstract":"Abstract This study presents an in-depth review of non-dispersive infrared (NDIR) sensors for methane detection, focusing on their principles of operation, performance characteristics, advanced signal processing techniques, multi-gas detection capabilities, and applications in various industries. NDIR sensors offer significant advantages in methane sensing, including high sensitivity, selectivity, and long-term stability. The underlying principles of NDIR sensors involve measuring the absorption of infrared radiation by the target gas molecules, leading to precise and reliable methane concentration measurements. Advanced signal processing techniques, such as single-frequency filtering and wavelet filtering algorithms, have been explored to improve the performance of the sensor by reducing noise, enhancing the signal-to-noise ratio, and achieving more accurate results. In the context of multi-gas detection, NDIR sensors face challenges due to overlapping absorption spectra. However, various solutions, including narrow-band optical bandpass filters, gas filter correlation techniques, and machine learning algorithms, have been proposed to address these issues effectively. This study delves into specific applications of NDIR sensors in various industries, such as coal mines, wastewater treatment plants, and agriculture. In these settings, NDIR sensors have demonstrated their reliability, accuracy, and real-time monitoring capabilities, contributing to environmental protection, safety, and energy recovery. Furthermore, the anticipated future trends and developments in NDIR methane detection technology are explored, including increased miniaturization, integration with artificial intelligence, improvements in power efficiency, and the development of multi-gas NDIR sensors. These advancements are expected to further enhance the capabilities and widespread adoption of NDIR sensors in methane detection applications.","PeriodicalId":21090,"journal":{"name":"Reviews in Analytical Chemistry","volume":"25 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134980954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Eco-friendly HPLC method by using response surface design to measure a combination of three antidiabetic drugs 采用响应面设计环保型高效液相色谱法测定三种降糖药的联合用量

3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2023-0063

Naser F. Al-Tannak, Ahmed Hemdan

{"title":"Eco-friendly HPLC method by using response surface design to measure a combination of three antidiabetic drugs","authors":"Naser F. Al-Tannak, Ahmed Hemdan","doi":"10.1515/revac-2023-0063","DOIUrl":"https://doi.org/10.1515/revac-2023-0063","url":null,"abstract":"Abstract In recent years, there has been a significant increase in the application of green chemistry principles in analytical chemistry. One of the key factors affecting the environmental sustainability of analytical methods is the choice of solvent. In this particular study, a two-factor, three-level response surface design was employed to develop an environmentally friendly chromatographic technique for a mixture of metformin, glimepiride, and pioglitazone. Ethanol, which is known to be harmless to the environment, was chosen as the organic modifier in the mobile phase. The separation of the mixture was achieved using a phosphate buffer solution (pH 3) mixed with ethanol (30:70 v/v). The linearity of the developed method covered a concentration of metformin of 10–120 µg·mL −1 with a correlation coefficient of 0.9998, glimepiride of 0.1–20 µg·mL −1 with a correlation coefficient of 0.9997, and pioglitazone of 1–50 µg·mL −1 with a correlation coefficient of 0.9999. To evaluate the environmental friendliness of the developed method, two assessment tools were employed: The Analytical GREEnness metric and Green Analytical Procedure Index. The results revealed that the developed method performed exceptionally well in terms of its eco-friendliness. Furthermore, the developed method was compared to other reported methods in terms of both accuracy and environmental sustainability. The results demonstrated that the developed method serves as an excellent alternative to well-established techniques for the separation and quantification of the analyzed mixture. Overall, this study highlights the importance of integrating green chemistry principles into analytical chemistry practices.","PeriodicalId":21090,"journal":{"name":"Reviews in Analytical Chemistry","volume":"273 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135508720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Real-time monitoring of recombinant GFP expression in single-cell Komagataella phaffii through filamentous pelletization technology 利用丝状球化技术实时监测重组GFP在法菲Komagataella phaffii单细胞中的表达

3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2023-0059

Xiao Zheng, Wenjie Cong, Hualan Zhou, Jianguo Zhang

引用次数: 0

A green HPLC method for the determination of apixaban in pharmaceutical products: Development and validation 绿色高效液相色谱法测定药品中阿哌沙班的含量:建立与验证

IF 4.3 3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2023-0058

Erten Akbel, I. Bulduk, Süleyman Gökçe

{"title":"A green HPLC method for the determination of apixaban in pharmaceutical products: Development and validation","authors":"Erten Akbel, I. Bulduk, Süleyman Gökçe","doi":"10.1515/revac-2023-0058","DOIUrl":"https://doi.org/10.1515/revac-2023-0058","url":null,"abstract":"Abstract Apixaban (APX) is a novel anticoagulant drug used in the treatment of ischemic stroke and venous thromboembolism. In this study, two different chromatographic methods were developed for the determination of APX in pharmaceutical products. In the first method, an Agilent C18 column (250 mm × 4.6 mm, 5 μm) was used, and the temperature was kept constant at 30°C. The mobile phase was chosen to be 0.1% trifluoroacetic acid solution and acetonitrile (65:35, v/v), and isocratic elution was applied. The flow rate of the mobile phase was found to be 1.0 mL·min−1 and the injection volume was 20 µL. The detection was carried out at a wavelength of 276 nm using a UV detector. In the second method, ethanol was used as an organic modifier. The only difference between these methods was the organic modifier. All other conditions of the methods were the same. Both chromatographic methods were validated in accordance with ICH guidelines for various parameters such as selectivity, linearity, accuracy, precision, detection and quantification limit, and robustness. The determination coefficients of chromatographic methods were greater than 0.999 in the concentration range of 5–30 mg·mL−1 of APX. Later, these chromatographic methods were applied to tablet formulations. Comparison of the obtained results in terms of mean was made using Student’s (t) test, and comparisons in terms of standard deviations were made using the Fisher (F) test. It was observed that there was no significant difference between these methods. These two methods were then evaluated using AGREE-Analytical greenness metric software. The chromatographic method using ethanol as an organic modifier has been proposed as an excellent eco-friendly and analyst-friendly alternative for the determination of APX in pharmaceutical formulations. Graphical abstract","PeriodicalId":21090,"journal":{"name":"Reviews in Analytical Chemistry","volume":"43 1","pages":""},"PeriodicalIF":4.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90391980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green novel photometric and planar chromatographic assays of remdesivir: Comparative greenness assessment study using estimated GAPI tool versus ISO technical reported methods 瑞德西韦的绿色新型光度法和平面色谱法测定:使用估计的GAPI工具与ISO技术报告方法的绿色评估比较研究

3区化学

Reviews in Analytical Chemistry Pub Date : 2023-01-01 DOI: 10.1515/revac-2023-0060

Miranda F. Kamal, Mona M. Abdel Moneim, Mohamed M. A. Hamdy

{"title":"Green novel photometric and planar chromatographic assays of remdesivir: Comparative greenness assessment study using estimated GAPI tool versus ISO technical reported methods","authors":"Miranda F. Kamal, Mona M. Abdel Moneim, Mohamed M. A. Hamdy","doi":"10.1515/revac-2023-0060","DOIUrl":"https://doi.org/10.1515/revac-2023-0060","url":null,"abstract":"Abstract Green assessment of analytical procedures has become an environmental obligation in equivalence to their International Council of Harmonization analytical validation obligation. Worldwide awareness of our planet and ecological hazards have raised the shades of green and sustainable chemistry in pure or formulated API assays. The Green Analytical Procedure Index (GAPI) is instant five pentagrams for evaluating the greenness of each step in the developed analytical procedure, in discriminative colors: green, yellow, and red. In the present study, GAPI is applied to assess three novel direct analytical methods: spectrophotometric, fluorimetric, and high-performance thin-layer chromatography (HPTLC) for remdesivir (RDV) quantitation, both in bulk and pharmaceutical vials. Furthermore, a comparative green level calculated GAPI study has been assembled for the proposed methods versus the previously reported methods, for RDV assay, of similar techniques. Spectrophotometric direct A max method at 240 nm, fluorimetric emission at 404 nm upon excitation at 275 nm as well as the HPTLC densitometric measurement using ethanol and distilled water (7:3, v/v) as mobile phase, all three methodologies are developed, optimized, and fully validated for RDV quantitation. They have been applied to assay RDV pharmaceutical vials and results are compared together with a one-way ANOVA test. Satisfactory recoveries and nano-level sensitivities in addition to the least standard deviations encourage the use of developed methods for routine analysis in quality control laboratories. Their promising greenness profile satisfies the beliefs of ecological sustainability of Green Agenda 2030.","PeriodicalId":21090,"journal":{"name":"Reviews in Analytical Chemistry","volume":"28 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135311306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chemometrics and infrared spectroscopy – A winning team for the analysis of illicit drug products 化学计量学及红外线光谱学-分析违禁药物的优胜队伍

IF 4.3 3区化学

Reviews in Analytical Chemistry Pub Date : 2022-01-01 DOI: 10.1515/revac-2022-0046

E. Deconinck, Céline Duchateau, Margot Balcaen, L. Gremeaux, P. Courselle

引用次数: 3