{"title":"Review on enzymatic synthesis of value added products of glycerol, a by-product derived from biodiesel production","authors":"J. Pradima, M. Rajeswari Kulkarni, Archna","doi":"10.1016/j.reffit.2017.02.009","DOIUrl":"10.1016/j.reffit.2017.02.009","url":null,"abstract":"<div><p>Crude glycerol is produced as a by-product from biodiesel production via trans-esterification with methanol and this process accounts for 10% (w/w) of the total biodiesel produced worldwide. The glycerol glut created can be utilized to increase biodiesel profitability since disposal can pose a threat to the environment. The need is to transform this surplus crude glycerol into added-value products. Biological based conversions are efficient in providing products that are drop-in replacements for petro-chemicals and offer functionality advantage, commanding higher price with the potential to increase bio-refinery revenue. Glycerol is a stable and multifunctional compound used as a building block in fine chemical synthesis like bio-polymers, polyunsaturated fatty acids, ethanol, hydrogen, <em>n</em>-butanol, glycerol carbonate, glycerol acetyl esters etc. Bio-catalysts add higher value to bio based products by catalyzing not only their selective modification, but also their synthesis under controlled and mild conditions. This article focuses on different bioconversion technologies of crude-glycerol to value added industrial products – obtained as waste from current bio-diesel production. We abridge the recent relevant approach for the production of various platform chemicals from bio-glycerol over enzyme and chemical catalysts.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 394-405"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.02.009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75900182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Performance investigation of vapour recompressed batch distillation for separating ternary wide boiling constituents","authors":"Rohith R Nair, Uday Bhaskar Babu G, Amol Raykar","doi":"10.1016/j.reffit.2017.04.007","DOIUrl":"10.1016/j.reffit.2017.04.007","url":null,"abstract":"<div><p>The vapour recompression scheme (VRC) has been very effective in continuous distillation for energy intensification. The applicability of this scheme for the separation of multicomponent wide boiling constituents in batch distillation is a major challenge, because of the unsteady nature of the batch. In this study, the vapour recompression scheme has been implemented for the separation of multicomponent wide boiling constituents in the batch distillation. For the optimal usage of energy from compressed vapours manipulation of top tray vapour or external energy is done. A comparative study of the vapour recompressed batch distillation having a variable speed single compressor (SVRBD) and double stage compressor (DVRBD) with conventional batch distillation in terms of energy savings and total annualized cost is done. The VRC schemes achieve an energy savings of 50% and 10.03% total annualized cost (TAC) for SVRBD and DVRBD achieve 52% energy savings and 12.21% TAC with a payback period of 10 years.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 452-458"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.04.007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86493100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review on biogenic synthesis of gold nanoparticles, characterization, and its applications","authors":"Soumya Menon, Rajeshkumar S., Venkat Kumar S.","doi":"10.1016/j.reffit.2017.08.002","DOIUrl":"10.1016/j.reffit.2017.08.002","url":null,"abstract":"<div><p>The nano-sized particles make an imprint on us in our daily lives and it has great importance in the numerous fields of biotechnology like the food industry, medical and industrial field. Gold nanoparticles are one of the widely used particles as it has many therapeutic applications, such as drug delivery system for many diseases like cancer, cardiovascular diseases, diabetes mellitus etc. biosensors, and environmental applications of dye degradation, bioremediation of toxic chemicals present in the environment (soil and atmosphere). Gold nanoparticles synthesis by the green route has become the latest development, because of the bioavailability of sources like plants or microorganisms, and it also reduces the utilization of toxic chemicals. This review explains the various microorganisms like bacteria, algae, fungi, actinomycetes and yeast involved in the synthesis of these nanoparticles also elucidate the size, shape and functional groups involved in the synthesis of nanoparticles and its applications.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 516-527"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.08.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87323994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amit Kumar Rohit, Amit Tomar, Anurag Kumar, Saroj Rangnekar
{"title":"Virtual lab based real-time data acquisition, measurement and monitoring platform for solar photovoltaic module","authors":"Amit Kumar Rohit, Amit Tomar, Anurag Kumar, Saroj Rangnekar","doi":"10.1016/j.reffit.2017.04.006","DOIUrl":"10.1016/j.reffit.2017.04.006","url":null,"abstract":"<div><p>The work presents real-time data acquisition and monitoring of solar photovoltaic modules using LabVIEW. A graphical program has been developed to obtain efficiency and fill factor of solar PV module. A front panel is designed, displaying all the acquired data such as; voltage, current, solar radiation, ambient temperature, humidity, Current vs. Voltage and Power vs. Voltage graphs which make it very useful to understand the performance behavior of the solar photovoltaic module in real time. Data acquisition and monitoring for solar panels of different ratings are carried out. This tool is an effective platform for experimental study in the laboratory of different solar photovoltaic modules with access to real-time data.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 446-451"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.04.006","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80078440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mathematical modeling of drying behavior of cashew in a solar biomass hybrid dryer","authors":"S. Dhanushkodi , Vincent H. Wilson , K. Sudhakar","doi":"10.1016/j.reffit.2016.12.002","DOIUrl":"10.1016/j.reffit.2016.12.002","url":null,"abstract":"<div><p>The main objective of this study is to analyze the drying behavior of cashew nut experimentally in a solar biomass hybrid dryer using mathematical models. Suitability of fifteen different mathematical drying models available in the literature is used to describe the drying characteristics of cashew. Experimental data of moisture ratio, temperature and relative humidity obtained from different dryer conditions were fitted to the various empirical drying models. The performance of the drying model was compared based on their correlation co-efficient (R<sup>2</sup>), Root Mean Square Error (RMSE) and Reduced Chi-Square (χ<sup>2</sup>) between the observed moisture ratios. The two terms and Midilli models showed the best fit under solar drying. Page model was found to be the best model for describing the thin layer drying behavior of cashew for biomass drying and hybrid drying.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 359-364"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2016.12.002","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84224835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Optimization studies on extraction of phytocomponents from betel leaves","authors":"Muruganandam L, Anantha Krishna, Jashwanth Reddy, G.S. Nirmala","doi":"10.1016/j.reffit.2017.02.007","DOIUrl":"10.1016/j.reffit.2017.02.007","url":null,"abstract":"<div><p>The present study aims at finding out the optimum parameters for the extraction of components from Betel leaves possessing medicinal applications using ethanol solvent by Soxhlet apparatus. The optimum conditions for the extract were calculated based on the extract yield by varying four parameters: material quantity (A: 2–4 g), solvent quantity (B: 250–300 ml), mantle temperature (C: 65–75 °C) and extraction time (D: 1–3 hours) and optimized using a four factor three level Box–Behnken response surface design (BBD) coupled with desirability function methodology. Results showed that temperature and extraction time had significant effect on yield of extract. Optimum conditions for highest yield of extract (10.94%) are as follows: material quantity (2 g), solvent quantity (281.4 ml), temperature (72 °C) and time (3 hours). The extract at the maximum yield condition was analyzed for phytocomponents by FTIR and GC–MS. The results indicated the presence of Hydroxy chavicol (69.46%), 4-Chromanol (24%) and Eugenol (4.86%), which possess wide application including as antioxidant, anti-inflammatory, anti-platelet and antithrombotic, antibacterial and antifungal agents.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 385-393"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.02.007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72674695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"An experimental analysis of quenching of continuously heated vertical rod with aqueous Al2O3 nanofluid","authors":"Nirupama Patra , Vivek Gupta , Ravi Singh , R.S. Singh , Pradyumna Ghosh , Arun Nayak","doi":"10.1016/j.reffit.2017.02.006","DOIUrl":"10.1016/j.reffit.2017.02.006","url":null,"abstract":"<div><p>Quenching characteristics of metallic vertical rod with an internal heater has been investigated in pure water and water-based nanofluid with alumina nanoparticles of 0.001% by volume. Initial temperature of the testing rod (12 mm diameter and 1000 mm length) ranges from 200 °C to 250 °C. The internal heater may be used to simulate the decay heat generated by the nuclear fuel rod after the power plant shutdown. Tests have been performed with varied range of experimental conditions of decay heat, constant water and nanofluid flow rates. The cooling curves follow a general trend of a rapid temperature drop up to almost 100 °C of the rod surface temperature irrespective of the operating parameters and the location of the thermocouple. The obtained results during quenching process indicated that HTC (heat transfer coefficient) for nanofluids are more than de-ionized water. It was also observed that in identical circumstances, the quenching time of the specimen in Al<sub>2</sub>O<sub>3</sub> nanofluid considerably decreased as compared to water. The results exhibit that nanofluids can enhance the reflood heat transfer performance in terms of quenching rate for a long vertical rod causing liquid-droplets-induced depositions of nanoparticles resulting in making a pre-coating effect characterized by higher wettability.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 378-384"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.02.006","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88282172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ragab A. El-Sehiemy , Shady H.E. Abdel Aleem , Almoataz Y. Abdelaziz , Murat E. Balci
{"title":"A new fuzzy framework for the optimal placement of phasor measurement units under normal and abnormal conditions","authors":"Ragab A. El-Sehiemy , Shady H.E. Abdel Aleem , Almoataz Y. Abdelaziz , Murat E. Balci","doi":"10.1016/j.reffit.2017.08.005","DOIUrl":"10.1016/j.reffit.2017.08.005","url":null,"abstract":"<div><p>This paper presents a new procedure for finding the optimal placement of the phasor measurement units (PMUs) in modern power grids to achieve full network observability under normal operating conditions, and also abnormal operating conditions such as a single line or PMU outage, while considering the availability of PMU measuring channels. The proposed modeling framework is implemented using the fuzzy binary linear programming (FBLP) technique. Linear fuzzy models are proposed for the objective function and constraints alike. The proposed procedure is applied to five benchmark systems such as the IEEE 14-bus, 30-bus, 39-bus, 57-bus, and 118-bus. The numerical results demonstrate that the proposed framework is capable of finding a fine-tuned optimal solution with a simple model and acceptable solution characteristics compared with early works in the literature. Besides, four evaluation indices are introduced to assure the various criteria under study such as the observability depth, measurement redundancy, and robustness of the method under contingencies. The results show that full network observability can be met under normal conditions using 20% PMUs penetration; however, under contingencies, approximately 50% PMUs penetration is required. The novelty of the proposed procedure has proven the capability of the proposed linear fuzzy models to find better optimal number of PMUs with lower number of channels compared to other algorithms under various operating conditions. Hence, the proposed work represents a potential tool to monitor power systems, and it will help the operators in a smart grid environment.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 542-549"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.08.005","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74145828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biosynthesis of ZnO/SiO2 nanocatalyst with palash leaves’ powder for treatment of petroleum refinery effluent","authors":"Rajani Bharati, S. Suresh","doi":"10.1016/j.reffit.2017.08.004","DOIUrl":"10.1016/j.reffit.2017.08.004","url":null,"abstract":"<div><p>This work aims the synthesis and characterization of ZnO/SiO<sub>2</sub> nanocatalyst from plant waste material by green route and application of this ZnO/SiO<sub>2</sub> nanocatalyst for the treatment of petroleum refinery effluent. Butea monosperma (Palash) leaves’ powder was used as reducing and stabilizing agent for synthesis of ZnO/SiO<sub>2</sub> nanocatalyst. Palash leaves contain broad variability of biomolecules which work as reducing and capping agent. In this research work, COD and acenaphthylene which is Polycyclic Aromatic Hydrocarbons (PAH) were degraded by synthesizing ZnO/SiO<sub>2</sub> nanocatalyst under UV-light in an annular photocatalytic reactor. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), FIELD emission gun-Scanning electron microscopy (FEG-SEM), Energy dispersive X-ray (EDX) and Transmission electron microscopy (TEM) analysis confirmed the formation of ZnO/SiO<sub>2</sub> nanocatalyst. Characterization studies revealed that spherical and hexagonal nanoparticles with particle size ranging from 8 ± 5 nm to 40 ± 5 nm and mean particle with diameter of 20 ± 5 nm were synthesized using this method which is stable in the environment. Brunauer, Emmett and Teller (BET) surface area of ZnO/SiO<sub>2</sub> nanocatalyst is found to be 150.25 m<sup>2</sup>/g. Fractional Factorial design was applied to find optimum condition of process parameters and found that optimum percent. Removal of COD (mg/l), and acenaphthylene were achieved at reaction condition of 1 g/L of ZnO/SiO<sub>2</sub> nanocatalyst loading, 30<span></span>°C temperature and 4 h reaction time and found that optimum percent removal of COD (mg/l), and acenaphthylene is 75%, and 73% respectively. Various metals, naturally present in palash leaves’ powder, decrease band gap of energy and improve photocatalytic activity of nanocatalyst.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 528-541"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.08.004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81517602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Prem Kumar Chaurasiya, Siraj Ahmed, Vilas Warudkar
{"title":"Wind characteristics observation using Doppler-SODAR for wind energy applications","authors":"Prem Kumar Chaurasiya, Siraj Ahmed, Vilas Warudkar","doi":"10.1016/j.reffit.2017.07.001","DOIUrl":"10.1016/j.reffit.2017.07.001","url":null,"abstract":"<div><p>This paper presents an application of Doppler SODAR (Sound Detection and Ranging) system for the assessment of wind characteristics at an onshore site in Tamil Nadu, India. The wind speed is statistically analyzed by means of Weibull distribution function and results were used to compute several characteristics parameters related to wind energy applications and no significant discrepancies were observed. The characteristics of wind shear coefficient were evaluated for different altitudes. The vertical profile of wind speed measured from SODAR system was compared with existing models. Furthermore, the turbulence characteristics were analyzed and compared along with the turbulence intensity. From the economic point of view the SODAR system was found to be cost-effective at higher heights. The results of this study are expected to provide useful information for the deployment of remote sensing instruments for wind energy development in India.</p></div>","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"3 4","pages":"Pages 495-505"},"PeriodicalIF":0.0,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.reffit.2017.07.001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85241416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}