{"title":"浅谈电解铝液直接铸造铝合金圆锭发展趋势","authors":"志强 应","doi":"10.33142/msra.v1i1.1285","DOIUrl":"https://doi.org/10.33142/msra.v1i1.1285","url":null,"abstract":"分析电解铝液特点以及生产中使用固体料的情形,结合相关实践经验,探讨了炉料添加顺序和电解铝液的转注方式、固液比的选择、熔体的预精炼和精炼方法、晶粒细化剂添加方法、在线除气及除渣方法等,就铝合金圆铸锭为例展开研究。","PeriodicalId":21005,"journal":{"name":"Research and Application of Materials Science","volume":"14 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87848705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Renbo Zhu, J. Zou, J. Mao, Xiaofeng Zhang, C. Deng, Min Liu, Wenlong Chen
{"title":"Fabrication and Growing Kinetics of Highly Dispersed Gadolinium Zirconate Nanoparticles","authors":"Renbo Zhu, J. Zou, J. Mao, Xiaofeng Zhang, C. Deng, Min Liu, Wenlong Chen","doi":"10.33142/msra.v1i1.670","DOIUrl":"https://doi.org/10.33142/msra.v1i1.670","url":null,"abstract":"Highly dispersed gadolinium zirconate (GZ) nanoparticles with fluorite structure were successfully synthesized by co-precipitation method, and their phase composition and microstructure, formation mechanism, and grain growth kinetics were investigated. The results suggest that the nanoparticles were obtained through hydroxide dehydration and solid phase reaction. High dispersion was accomplished by ethanol solvent to reduce the hydrogen bond and sodium dodecyl benzene sulfonate (SDBS) surfactant to increase the electrostatic repulsion between the nanoparticles. The grain growth activation energy of GZ powders calcined at lower temperature (< 1200 °C) is 86.5 kJ/mol (Ql ), and the grain growth activation energy of GZ powders calcined at higher temperature (> 1200 °C) is 148.4 kJ/mol (Qh ). The current study shows that the optimal process to synthesize dispersed GZ nanoparticles includes ethanol solvent, 3 wt.% SDBS surfactant, and 1100 °C as calcining temperature.","PeriodicalId":21005,"journal":{"name":"Research and Application of Materials Science","volume":"39 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76826120","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"One Novel Zn(II) Nitro-containing Metal Organic Framework for Dye- Adsorption and Photo Degradation","authors":"Weiqi Li, Xieao Du, Haiyan He","doi":"10.33142/MSRA.V1I1.672","DOIUrl":"https://doi.org/10.33142/MSRA.V1I1.672","url":null,"abstract":"A novel metal-organic framework [Zn0.5(L1)(4,4'-Bpy)0.5], (HU21, HU for Hohai University, L1 = 4-hydroxy-3-nitrobenzoic acid, 4,4'-bipyridine = 4,4'-Bpy), has been isolated through hydrothermal reaction. Single-crystal X-ray diffraction reveals the compound features a 1D fishbone-like chain. A fast adsorption rate of methylene blue with HU21 was observed in the dark, but under irritation the degradation rate of the dye was obviously increased. The degradation of methylene blue dye reached 248 mg/g under light irritation, and the photocatalytic activity reached 96.1%.","PeriodicalId":21005,"journal":{"name":"Research and Application of Materials Science","volume":"36 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77523968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wenbo Wang, Yanhong Shi, Yangfen Su, Yihai Wang, Haizhu Sun
{"title":"Construction of MnO2 Nanowire for a High-Performance Lithium Ion Supercapacitor","authors":"Wenbo Wang, Yanhong Shi, Yangfen Su, Yihai Wang, Haizhu Sun","doi":"10.33142/MSRA.V1I1.668","DOIUrl":"https://doi.org/10.33142/MSRA.V1I1.668","url":null,"abstract":"Developing lithium ion capacitors possessing both brilliant energy and power density is still significant for numerous re-searchers. In this paper, we synthesized MnO2 nanowires via a simple hydrothermal process. The nanostructure MnO2 can expose more electrochemical sites and thus optimize the kinetics of Li+. Moreover, we used MnO2 nanowires (MnO2 NWs) as anode and a N-doped porous carbon (NPC) as cathode to assemble lithium ion capacitors (MnO2 NWs//NPC LIC). Compared to the traditional supercapacitor with aqueous electrolyte, the MnO2 NWs//NPC LIC exhibits a wider voltage of 0-4.2 V, which is helpful to enhance its energy and power density. Furthermore, MnO2 NWs//NPC LIC can deliver an excellent capacity of 150 mAh g-1 with an excellent energy density of 82.7 Wh kg-1 and power density of 1.05 kW kg-1. Meanwhile, a good cyclic stability of LICs with a 20% retention after 1000 times charge and discharge process proves its practical potential, indicating a good promising for the application in storage devices.","PeriodicalId":21005,"journal":{"name":"Research and Application of Materials Science","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88460195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}