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Bibliometric survey of the PVC production - Part I: the continuous polymerization challenge 聚氯乙烯生产的文献计量调查-第一部分:连续聚合的挑战
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-08-11 DOI: 10.1590/0104-1428.20220062
R. Lima, Jonildo Silva, M. Vasconcelos, Carlos Alberto Castor Junior, J. Pinto
{"title":"Bibliometric survey of the PVC production - Part I: the continuous polymerization challenge","authors":"R. Lima, Jonildo Silva, M. Vasconcelos, Carlos Alberto Castor Junior, J. Pinto","doi":"10.1590/0104-1428.20220062","DOIUrl":"https://doi.org/10.1590/0104-1428.20220062","url":null,"abstract":"Poly(vinyl chloride) (PVC) resins constitute the third most important plastic materials available commercially, in terms of worldwide volume production, and can be manufactured through several polymerization mechanisms, including free radical, ionic and redox polymerization processes. Approximately 80% of the worldwide commercial PVC production is performed through suspension polymerization processes in batch mode, due to intrinsic problems of continuous suspension polymerization processes, such as polymer incrustation in reaction vessels, transport equipment and pipes. For this reason, the present review provides an extensive bibliometric survey, including papers and patents, on attempts to develop continuous polymerization process technologies for PVC manufacture. Particularly, the present survey characterizes the degree of maturity and the main bottlenecks of continuous PVC processes that have been frequently overlooked in the technical literature.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of coupling agents on properties of vegetable fiber polymeric composites: review 偶联剂对植物纤维聚合物复合材料性能的影响
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-06-19 DOI: 10.1590/0104-1428.20220118
Dielen Marin, L. Chiarello, V. Wiggers, A. D. Oliveira, V. Botton
{"title":"Effect of coupling agents on properties of vegetable fiber polymeric composites: review","authors":"Dielen Marin, L. Chiarello, V. Wiggers, A. D. Oliveira, V. Botton","doi":"10.1590/0104-1428.20220118","DOIUrl":"https://doi.org/10.1590/0104-1428.20220118","url":null,"abstract":"Using natural fibers in composites presents a wide range of applications, from furniture to airplanes. In polymeric composite, the use of fiber is to boost strength and stiffness. However, this material presents low mechanical properties compared to virgin polymers due to hydrophilic nature of the fiber and hydrophobic nature of the polymer. It can result in weak bonding matrix/fiber which may cause incompatibility problem in bonding fibers with most of the polymer matrices. To achieve compatibility between surfaces there is a need to modify them, and one alternative is using coupling agents. Maleated coupling agents stand out as option, but their source is petroleum-derived polyolefin. Researchers have been seeking for more environmentally friendly alternatives to replace these materials. Therefore, this work aims to bring a comprehensive review of the mechanical behavior of maleated and ecological coupling agents. Based on the literature, resistance, flexural, and tensile strength were properties discussed.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"34 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Crystallization and fusion kinetics of Poly(butylene terephthalate)/Titanium Dioxide 聚对苯二甲酸丁二酯/二氧化钛的结晶和熔合动力学
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-06-02 DOI: 10.1590/0104-1428.20220087
J. V. M. Barreto, Antônio Anderson da Silva Gomes, A. M. Araújo, Andreas Ries, J. J. P. Barros, R. Wellen
{"title":"Crystallization and fusion kinetics of Poly(butylene terephthalate)/Titanium Dioxide","authors":"J. V. M. Barreto, Antônio Anderson da Silva Gomes, A. M. Araújo, Andreas Ries, J. J. P. Barros, R. Wellen","doi":"10.1590/0104-1428.20220087","DOIUrl":"https://doi.org/10.1590/0104-1428.20220087","url":null,"abstract":"In this paper, the crystallization, fusion, and activation energy (Ea) of PBT/TiO 2 were thoroughly evaluated using DSC. Increasing the rates shifted the peaks of melt crystallization to lower temperatures while the fusions were almost unaffected. TiO 2 hindered the melt crystallization of PBT and lower crystallization rates, i.e., CMAX and K’ were acquired, in general, the crystallinity degree (Xc) was 4% higher in PBT/TiO 2 which is in the marginal error. Pseudo-Avrami and Mo models were applied to evaluate the melt crystallization kinetics; both fitted the melt crystallization quite well; deviations were observed at the beginning and the crystallization end most due to the nucleation and spherulites impingement during the secondary crystallization. Ea was evaluated using the Friedman model, considering the values of Ea less energy has to be removed from PBT/TiO 2 when compared to PBT, specifically at 1% of TiO 2 .","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural characterization of polymeric nanofibers of polyvinylidene fluoride (PVDF) 聚偏氟乙烯(PVDF)纳米纤维的结构表征
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-05-29 DOI: 10.1590/0104-1428.20220117
José Carlos Osório Rodrigues da Silva, Walace Rodrigues da Silva Júnior, A. N. R. D. Silva, R. Künzel, J. Bortoleto, Emanuel Benedito de Melo, C. Ulsen, N. M. Trindade
{"title":"Structural characterization of polymeric nanofibers of polyvinylidene fluoride (PVDF)","authors":"José Carlos Osório Rodrigues da Silva, Walace Rodrigues da Silva Júnior, A. N. R. D. Silva, R. Künzel, J. Bortoleto, Emanuel Benedito de Melo, C. Ulsen, N. M. Trindade","doi":"10.1590/0104-1428.20220117","DOIUrl":"https://doi.org/10.1590/0104-1428.20220117","url":null,"abstract":"Polyvinylidene fluoride (PVDF) is a polymer material that exhibits piezoelectricity, which is the ability of certain materials to generate an electric charge in response to applied mechanical stress. Electrospun nanofibers were prepared from a solution with 1800 mg PVDF (18 wt.%) powder dissolved in 7.5 ml of dimethylformamide (DMF) and 2.5 ml acetone. The experimental setup used in the electrostatic deposition process was developed in our laboratory. Atomic Force Microscopy (AFM) showed that the fibers vary from 100 nm to 200 nm. Scanning Electron Microscopy (SEM) measurements showed distributed and well-formed nanofibers, but with few incidences of beads. The Energy Dispersive Spectroscopy (EDX) results showed that all points of the formed nanofibers have very similar chemical compositions, based on carbon and fluorine. Raman and Fourier Transform Infrared (FTIR) Spectroscopic analysis revealed the characteristic bands related to β-phase in the sample, which is responsible for the piezoelectricity of PVDF.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of hybridisation and nano reinforcement on repairing cracked pipeline 杂化与纳米补强对管道裂缝修复的影响
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-05-26 DOI: 10.1590/0104-1428.20220111
P. Ahmed
{"title":"Effect of hybridisation and nano reinforcement on repairing cracked pipeline","authors":"P. Ahmed","doi":"10.1590/0104-1428.20220111","DOIUrl":"https://doi.org/10.1590/0104-1428.20220111","url":null,"abstract":"Composite materials are used to repair cracks in pipelines that appear after a period of time. This study investigates the effect of hybridisation on the blister behaviour of composite repair by using the finite element method. The behaviour of the best hybridised stacking sequence is compared with the experimental results to validate the numerical outcomes. The effect of adding multiwall carbon nanotubes (MWCNTs) to the epoxy resin, used to stick the composite repair with the steel pipeline, is explored by combining the MWCNT and the epoxy through high shear mixing. The results showed that hybridisation has a great effect on improving the blistering behaviour of the composite repair. The preparation of nano-reinforced adhesive by shear mixing did not show noticeable improvement. Predicting the composite repair behaviour through blister test by using the finite element method can be used as a good indication of pipeline protection.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122732","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Phenoxazine and diketopyrrolopyrrole based donor-acceptor conjugated polymers: synthesis and optical properties 苯恶嗪和二酮吡咯基给受体共轭聚合物:合成和光学性质
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-05-22 DOI: 10.1590/0104-1428.20230002
T. T. Bui, T. H. Nguyen, B. Doan, L. Nguyen, C. Tran, H. T. Nguyen
{"title":"Phenoxazine and diketopyrrolopyrrole based donor-acceptor conjugated polymers: synthesis and optical properties","authors":"T. T. Bui, T. H. Nguyen, B. Doan, L. Nguyen, C. Tran, H. T. Nguyen","doi":"10.1590/0104-1428.20230002","DOIUrl":"https://doi.org/10.1590/0104-1428.20230002","url":null,"abstract":"While numerous phenoxazine-based small molecules developed for organic electronic devices, very limited attention has been received on synthesized conjugated polymers containing this phenoxazine. Herein, we designed and synthesized two new low-bandgap donor−acceptor conjugated copolymers based on phenoxazine with different side chains and diketopyrrolopyrrole by Pd-catalyzed direct (hetero)arylation polycondensation using a Pd(OAc) 2 catalyst and PCy 3 . HBF 4 ligand. The effects of side chain branched alkyl and benzoyl of phenoxazine on the thermal, and optical properties of the polymers have been investigated. Both the polymers have a good yield 85%, high molecular weight up to 41500 g/mol, low dispersity index 1.91, excellent solubility in common organic solvents, and a broad absorption spectrum in the range of 500-900 nm with optical bandgaps as low as 1.40 eV. All these polymers possess good thermal stability with decomposition temperatures over 350 o C and no obvious thermal transitions.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67123141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Influence of carbon fibre layers on the strength of thermally modified laminated veneer lumber 碳纤维层对热改性复合单板木材强度的影响
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-05-22 DOI: 10.1590/0104-1428.20220070
O. Perçin, Onur Ülker
{"title":"Influence of carbon fibre layers on the strength of thermally modified laminated veneer lumber","authors":"O. Perçin, Onur Ülker","doi":"10.1590/0104-1428.20220070","DOIUrl":"https://doi.org/10.1590/0104-1428.20220070","url":null,"abstract":"Obstract Thermally modification of wood is an environment-friendly alternative method for improving several properties of wood without the use of chemicals. The compressive strength (CS) parallel to the grain of reinforced laminated veneer lumber (LVL) manufactured from heat treated beech ( Fagus orientalis ) veneers and carbon fibre was determined. Thermally modification was performed at 140°C, 160°C, 180°C, and 200 °C according to thermal treatment process. Carbon fibre were added as a reinforcement layer between wood veneers bonded with phenol-formaldehyde (PF), polyvinyl acetate (PVAc) polyurethane adhesives (PU) to improve properties of LVL. Results showed that reinforcing LVL panels with carbon fibre increased both density and CS. The PF adhesive showed better results for reinforced LVL panels with carbon fibre. The anatomical structure and density of the wood material significantly affect its mechanical properties, including compressive strength parallel to the grains. Wood density had a strong significant linear relationship with CS.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chitosan: an overview of its multiple advantages for creating sustainable development poles 壳聚糖:概述其创造可持续发展极点的多重优势
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-05-19 DOI: 10.1590/0104-1428.20220103
Cristóbal Lárez-Velásquez
{"title":"Chitosan: an overview of its multiple advantages for creating sustainable development poles","authors":"Cristóbal Lárez-Velásquez","doi":"10.1590/0104-1428.20220103","DOIUrl":"https://doi.org/10.1590/0104-1428.20220103","url":null,"abstract":"An overview perspective of the potential of chitin and chitosan biopolymers to promote economically and environmentally sustainable development poles, which could be exploited especially in developing countries, is presented. Their following advantages have been considered and briefly outlined: (i) the natural sources of chitin have a wide distribution on the entire planet and are usually accessible as inexpensive waste materials; (ii) the great versatility of these materials, with applications in diverse fields such as agriculture, water treatments, food industry, environment, petroleum, healthcare, energy, technology, etc., with some trials conducted even off-planet; (iii) the production and use of these materials could promote advances in the endogenous capacity of some countries to create own technologies and generate products and applications, basic and advanced, in sensitive sectors, i","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ternary segmented polyurethanes: morphology and kinetics of the crystallization 三元分节聚氨酯:结晶的形态和动力学
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-05-19 DOI: 10.1590/0104-1428.20220123
André Sanches Bevilacqua, R. B. Trinca, M. I. Felisberti
{"title":"Ternary segmented polyurethanes: morphology and kinetics of the crystallization","authors":"André Sanches Bevilacqua, R. B. Trinca, M. I. Felisberti","doi":"10.1590/0104-1428.20220123","DOIUrl":"https://doi.org/10.1590/0104-1428.20220123","url":null,"abstract":"Segmented polyurethanes based on poly(l-lactide)diol – PLLA, poly(ethylene-glycol) – PEG, poly(trimethylene-carbonate)diol – PTMC and hexamethylene diisocyanate were synthesized by a two-step polyaddition. Polyurethanes with variable compositions and molar mass were semi-crystalline and presented PLLA or PLLA + PEG crystalline phases and a heterogeneous amorphous phase. Sequential crystallization of PLLA and PEG resulted in a confined PEG crystallization into the PLLA crystalline phase. The random distribution of the segments in the polymer chains and the partial miscibility of the segments in the amorphous phase strongly influenced the morphology of the crystalline phase, and the kinetics of the crystallization. Morphology changed from not well-defined spherulites with Maltese cross to ring banded spherulites and axialites as the PLLA mass fraction decreased. PLLA nucleation and crystal growth rates varied with crystallization temperature similarly to homopolymers, presenting a bell-shaped curve, and the temperature for the maximum growth rate dependent on the polyurethanes composition.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of the ultrasonic treatment for Tara gum using response surface methodology 响应面法优化塔拉胶超声处理工艺
IF 1.3 4区 化学
Polimeros-ciencia E Tecnologia Pub Date : 2023-04-17 DOI: 10.1590/0104-1428.20220090
B. S. Soares, C. W. P. D. Carvalho, E. Garcia-Rojas
{"title":"Optimization of the ultrasonic treatment for Tara gum using response surface methodology","authors":"B. S. Soares, C. W. P. D. Carvalho, E. Garcia-Rojas","doi":"10.1590/0104-1428.20220090","DOIUrl":"https://doi.org/10.1590/0104-1428.20220090","url":null,"abstract":"High-intensity ultrasound irradiation proved to be an effective method for modifying tara gum by generating low molecular weight products and better water solubility. The objectives of this research were to optimize the parameters for the high-intensity ultrasonic treatment with response surface methodology and improve the tara gum solubility. The results demonstrated that after the ultrasound treatment, the solubility of the tara gum had increased (17.7%) as a result of the reduced intrinsic viscosity (70%). The molecular weight of the untreated tara gum was 1.89 x 10 6 Da, and after ultrasound treatment, it was reduced to 0.47 x 10 6 Da. Rheological analyses confirmed the reduction in molecular weight for the modified and optimized tara gum and the resulting increase in solubility. This knowledge provides a better understanding of ultrasound treatment technology and increases the scope for use of tara gum in the food industry.","PeriodicalId":20282,"journal":{"name":"Polimeros-ciencia E Tecnologia","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"67122750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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