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Degradable polyurethanes with amino-acid phosphorodiamidates as breakage points 以氨基酸磷酸二甲酸酯为断裂点的可降解聚氨酯
Monatshefte für Chemie - Chemical Monthly Pub Date : 2025-10-03 DOI: 10.1007/s00706-025-03383-9
Nico Vennemann, Florian Hubner, Stephan Haudum, Ian Teasdale, Oliver Brüggemann
{"title":"Degradable polyurethanes with amino-acid phosphorodiamidates as breakage points","authors":"Nico Vennemann, Florian Hubner, Stephan Haudum, Ian Teasdale, Oliver Brüggemann","doi":"10.1007/s00706-025-03383-9","DOIUrl":"https://doi.org/10.1007/s00706-025-03383-9","url":null,"abstract":"Abstract The global polyurethane (PU) market in 2024 reached a volume of more than 80 billion dollars, or more than 25 million tons. PU are used in numerous applications and contributes to the global plastic waste crisis. For this reason, the customised degradability of polyurethanes, which has been little addressed to date, will become increasingly important. This paper describes our approach of introducing chemical breakage points based on amino-acid based phosphordiamidates (APdA) in the PUs' backbones. We demonstrate that with an increasing amount of APdA the PU disintegrates faster, already at neutral pH 7 and even more pronounced at acidic pH 3. In parallel, we observed that an increasing number of APdA based breakage points leads to decreasing parameters like tensile strength, which was also dependent on their environmental pH. Graphical abstract","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"157 3","pages":"423-430"},"PeriodicalIF":0.0,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00706-025-03383-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147902939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of tetrahydro-γ-carboline-based histone deacetylase inhibitors with antitumor activities 具有抗肿瘤活性的四氢-γ-羰基组蛋白去乙酰化酶抑制剂的研制
Monatshefte für Chemie - Chemical Monthly Pub Date : 2025-06-19 DOI: 10.1007/s00706-025-03336-2
Zeyi Wan, Xiangzhi Li, Yuhua Qu, Shule Fan, Wenxia Lu, Linlin Xu, Feifei Yang, Hua Zhang
{"title":"Development of tetrahydro-γ-carboline-based histone deacetylase inhibitors with antitumor activities","authors":"Zeyi Wan, Xiangzhi Li, Yuhua Qu, Shule Fan, Wenxia Lu, Linlin Xu, Feifei Yang, Hua Zhang","doi":"10.1007/s00706-025-03336-2","DOIUrl":"https://doi.org/10.1007/s00706-025-03336-2","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"156 7","pages":"791-810"},"PeriodicalIF":0.0,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147894160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Sensing of the COVID-19 antiviral molnupiravir in the presence of an anionic surfactant on the surface of a boron-doped diamond electrode in pharmaceutical formulation 在药物配方中掺杂硼的金刚石电极表面存在阴离子表面活性剂时检测COVID-19抗病毒药物莫诺比拉韦
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-12-17 DOI: 10.1007/s00706-024-03277-2
Yunus Bedir, Yavuz Yardım
{"title":"Sensing of the COVID-19 antiviral molnupiravir in the presence of an anionic surfactant on the surface of a boron-doped diamond electrode in pharmaceutical formulation","authors":"Yunus Bedir, Yavuz Yardım","doi":"10.1007/s00706-024-03277-2","DOIUrl":"https://doi.org/10.1007/s00706-024-03277-2","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"156 2","pages":"145-154"},"PeriodicalIF":0.0,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147887824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Copper on charcoal: copper nanoparticles catalyzed for highly efficient aerobic oxidative coupling of terminal alkynes 炭上铜：铜纳米颗粒催化末端炔的高效有氧氧化偶联
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-10-07 DOI: 10.1007/s00706-024-03260-x
Chao Fang, Kai Ma, Zixu Li, Fei Wang, Qiang Jia, Changhu Chu
{"title":"Copper on charcoal: copper nanoparticles catalyzed for highly efficient aerobic oxidative coupling of terminal alkynes","authors":"Chao Fang, Kai Ma, Zixu Li, Fei Wang, Qiang Jia, Changhu Chu","doi":"10.1007/s00706-024-03260-x","DOIUrl":"https://doi.org/10.1007/s00706-024-03260-x","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"155 11","pages":"1119-1124"},"PeriodicalIF":0.0,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147885114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances on the synthesis of pyrido[3,4-c]coumarin derivatives as the backbone of natural product schumanniophytin scaffolds 以吡啶[3,4-c]香豆素衍生物为骨架的天然产物舒曼藓素支架的合成研究进展
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-10-06 DOI: 10.1007/s00706-024-03252-x
Swarna Kamal Samanta, Susanta Patra, Biplab Biswas, Anupama Hatua Patra, P. Ghosh, Tarun Mistri, Dilip Rout, Prasanta Patra
{"title":"Recent advances on the synthesis of pyrido[3,4-c]coumarin derivatives as the backbone of natural product schumanniophytin scaffolds","authors":"Swarna Kamal Samanta, Susanta Patra, Biplab Biswas, Anupama Hatua Patra, P. Ghosh, Tarun Mistri, Dilip Rout, Prasanta Patra","doi":"10.1007/s00706-024-03252-x","DOIUrl":"https://doi.org/10.1007/s00706-024-03252-x","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"155 11","pages":"997-1026"},"PeriodicalIF":0.0,"publicationDate":"2024-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147886065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Molecular docking, expounding the chemo-, regio-selectivity, and the mechanism of [3 + 2] cycloloaddition reaction between nitrile-imine and (thio)-chalcone 分子对接，阐述腈-亚胺与（硫）查尔酮的[3 + 2]环加成反应的化学性、区域选择性和机理
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-06-13 DOI: 10.1007/s00706-024-03221-4
K. Ryachi, Mohammed El Idrissi, Haydar A. Mohammad-Salim, A. Bahkali, J. D. de Julián-Ortiz, A. Zeroual, Shifa Wang, Ling Shing Wong, Asad Syed, A. Tounsi
{"title":"Molecular docking, expounding the chemo-, regio-selectivity, and the mechanism of [3 + 2] cycloloaddition reaction between nitrile-imine and (thio)-chalcone","authors":"K. Ryachi, Mohammed El Idrissi, Haydar A. Mohammad-Salim, A. Bahkali, J. D. de Julián-Ortiz, A. Zeroual, Shifa Wang, Ling Shing Wong, Asad Syed, A. Tounsi","doi":"10.1007/s00706-024-03221-4","DOIUrl":"https://doi.org/10.1007/s00706-024-03221-4","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141347674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrochemical visualization of latent fingerprints using polyphenazine dyes on brass cartridges 使用聚吩嗪染料在黄铜盒上电化学显现潜在指纹
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-06-13 DOI: 10.1007/s00706-024-03222-3
Sára Hermochová, Petr Hlavín, M. Novotný, Martin Vrňata, G. Broncová
{"title":"Electrochemical visualization of latent fingerprints using polyphenazine dyes on brass cartridges","authors":"Sára Hermochová, Petr Hlavín, M. Novotný, Martin Vrňata, G. Broncová","doi":"10.1007/s00706-024-03222-3","DOIUrl":"https://doi.org/10.1007/s00706-024-03222-3","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"37 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141345209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly regioselective synthesis of branched saturated aldehydes by tandem hydroformylation/isomerization/hydrogenation of 1-arylbutadienes 通过 1-芳基丁二烯的串联氢甲酰化/异构化/氢化高区域选择性合成支链饱和醛
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-06-13 DOI: 10.1007/s00706-024-03224-1
Huibing Shi, Peng Wang, Yaozong Yan, Guiai Yang, Haigang Wu
{"title":"Highly regioselective synthesis of branched saturated aldehydes by tandem hydroformylation/isomerization/hydrogenation of 1-arylbutadienes","authors":"Huibing Shi, Peng Wang, Yaozong Yan, Guiai Yang, Haigang Wu","doi":"10.1007/s00706-024-03224-1","DOIUrl":"https://doi.org/10.1007/s00706-024-03224-1","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"45 19","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141349689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pilot-scale foam and cast-coated nanocellulose filters for water treatment 用于水处理的中试规模泡沫和铸涂纳米纤维素过滤器
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-05-17 DOI: 10.1007/s00706-024-03211-6
Khatanbaatar Byambatsogt, Qixiang Jiang, A. Jaiswal, Vesa Kunnari, Alexander Bismarck, Andreas Mautner
{"title":"Pilot-scale foam and cast-coated nanocellulose filters for water treatment","authors":"Khatanbaatar Byambatsogt, Qixiang Jiang, A. Jaiswal, Vesa Kunnari, Alexander Bismarck, Andreas Mautner","doi":"10.1007/s00706-024-03211-6","DOIUrl":"https://doi.org/10.1007/s00706-024-03211-6","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"16 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140963296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
New insights into the photoassisted anodic reactions of n-type 4H SiC semiconductors n 型 4H SiC 半导体光助阳极反应的新见解
Monatshefte für Chemie - Chemical Monthly Pub Date : 2024-05-14 DOI: 10.1007/s00706-024-03212-5
Katharina Mairhofer, Silvia Larisegger, A. Foelske, Markus Sauer, Gernot Friedbacher, Günter Fafilek
{"title":"New insights into the photoassisted anodic reactions of n-type 4H SiC semiconductors","authors":"Katharina Mairhofer, Silvia Larisegger, A. Foelske, Markus Sauer, Gernot Friedbacher, Günter Fafilek","doi":"10.1007/s00706-024-03212-5","DOIUrl":"https://doi.org/10.1007/s00706-024-03212-5","url":null,"abstract":"","PeriodicalId":19044,"journal":{"name":"Monatshefte für Chemie - Chemical Monthly","volume":"54 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140980923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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