Mineralogical Magazine最新文献_第7页

A brief comment on Hawthorne (2023): “On the definition of distinct mineral species: A critique of current IMA-CNMNC procedures” 对Hawthorne(2023)的简短评论:“关于独特矿物的定义:对当前IMA-CNMNC程序的批评”

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-05-24 DOI: 10.1180/mgm.2023.33

F. Bosi, F. Hatert, M. Pasero, S. Mills, R. Miyawaki, U. Hålenius

引用次数: 1

Discussion of the paper by Galuskin and Galuskina (2003), “Evidence of the anthropogenic origin of the ‘Carmel sapphire’ with enigmatic super-reduced minerals” 讨论Galuskin和Galuskina（2003）的论文“具有神秘超还原矿物的‘卡梅尔蓝宝石’的人为起源证据”

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-05-24 DOI: 10.1180/mgm.2023.36

W. Griffin, V. Toledo, S. O’Reilly

引用次数: 2

High-temperature behaviour of fedorite, Na2.5(Ca4.5Na2.5)[Si16O38]F2⋅2.8H2O, from the Murun Alkaline Complex, Russia 俄罗斯Murun碱性络合物中fedorite Na2.5(Ca4.5Na2.5)[Si16O38]F2⋅2.8H2O的高温行为

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-05-11 DOI: 10.1180/mgm.2023.31

M. Lacalamita, E. Mesto, E. Kaneva, R. Shendrik, T. Radomskaya, E. Schingaro

{"title":"High-temperature behaviour of fedorite, Na2.5(Ca4.5Na2.5)[Si16O38]F2⋅2.8H2O, from the Murun Alkaline Complex, Russia","authors":"M. Lacalamita, E. Mesto, E. Kaneva, R. Shendrik, T. Radomskaya, E. Schingaro","doi":"10.1180/mgm.2023.31","DOIUrl":"https://doi.org/10.1180/mgm.2023.31","url":null,"abstract":"Abstract The thermal behaviour of fedorite from the Murun massif, Russia, has been investigated by means of electron probe microanalysis (EPMA), differential thermal analysis (DTA), thermogravimetry (TG), in situ high-temperature single-crystal X-ray diffraction (HT-SCXRD), ex situ high-temperature Fourier-transform infrared spectroscopy (HT-FTIR). The empirical chemical formula of the sample of fedorite studied is: (Na1.56K0.72Sr0.12)Σ2.40(Ca4.42Na2.54Mn0.02Fe0.01Mg0.01)Σ7.00(Si15.98Al0.02)Σ16.00(F1.92Cl0.09)Σ2.01(O37.93OH0.07)Σ38.00⋅2.8H2O. The TG curve provides a total mass decrease of ~5.5%, associated with dehydration and defluorination processes from 25 to 1050°C. Fedorite crystallises in space group P$bar{1}$ and has: a = 9.6458(2), b = 9.6521(2), c = 12.6202(4) Å, α = 102.458(2), β = 96.2250(10), γ = 119.9020(10)° and cell volume, V = 961.69(5) Å3. The HT-SCXRD was carried out in air in the 25–600°C range. Overall, a continuous expansion of the unit-cell volume was observed although the c cell dimension slightly decreases in the explored temperature range. Structure refinements indicated that the mineral undergoes a dehydration process with the loss of most of the interlayer H2O from 25 to 300°C. The HT-FTIR spectra confirmed that fedorite progressively dehydrates until 700°C.","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":"87 1","pages":"542 - 553"},"PeriodicalIF":2.7,"publicationDate":"2023-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44728968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Holubite, Ag3Pb6(Sb8Bi3)Σ11S24, from Kutná Hora, Czech Republic, a new member of the andorite branch of the lillianite homologous series Holubite，Ag3Pb6（Sb8Bi3）∑11S24，来自捷克共和国KutnáHora，是绿柱石同源系列的一个新成员

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-05-11 DOI: 10.1180/mgm.2023.34

R. Pažout, J. Plášil, M. Dušek, J. Sejkora, Z. Dolníček

{"title":"Holubite, Ag3Pb6(Sb8Bi3)Σ11S24, from Kutná Hora, Czech Republic, a new member of the andorite branch of the lillianite homologous series","authors":"R. Pažout, J. Plášil, M. Dušek, J. Sejkora, Z. Dolníček","doi":"10.1180/mgm.2023.34","DOIUrl":"https://doi.org/10.1180/mgm.2023.34","url":null,"abstract":"Abstract A new mineral species, holubite, ideally Ag3Pb6(Sb8Bi3)Σ11S24, has been found at Kutná Hora ore district, Czech Republic. The mineral is associated with other lillianite homologues (gustavite, terrywallaceite, vikingite and treasurite) most frequently as grain aggregates and replacement rims of earlier Ag–Pb–Bi minerals, growing together in aggregates up to 200 × 50 μm. It typically occurs in a close association with Ag,Bi-bearing galena and terrywallaceite. Holubite is opaque, steel-grey in colour and has a metallic lustre, the calculated density is 5.899 g/cm3. In reflected light holubite is greyish white and bireflectance and pleochroism are weak with grey tints. Anisotropy is weak to medium with grey to bluish-grey rotation tints. Internal reflections were not observed. Electron microprobe analyses yielded an empirical formula, based on 44 atoms per formula unit (apfu) of (Ag3.03Cu0.03)Σ3.06(Pb6.19Fe0.02Cd0.01)Σ6.22(Sb7.71Bi2.90)Σ10.61S24.12. Its unit-cell parameters are: a = 19.374(4), b = 13.201(3), c = 8.651(2) Å, β = 90.112(18)°, V = 2212.5(9) Å3, space group P21/n and Z = 2. Holubite is a new member of the andorite branch of the lillianite homologous series with N = 4. The structure of holubite contains two Pb sites with a trigonal prismatic coordination, eight distinct octahedral sites, of which one is a mixed (Bi,Ag) site and one is a mixed (Sb,Pb) site, and twelve anion sites. Holubite is defined as a lillianite homologue with the three following requirements: N = 4, L% [Ag+ + (Bi3+,Sb3+) ↔ 2 Pb2+ substitution] ≈ 70% and approximately one quarter to one third at.% of antimony is replaced by bismuth [Bi/(Bi+Sb) ≈ 0.26–34]. The new mineral has been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA2022-112) and named after Milan Holub, a key Czech geologist and specialist in the Kutná Hora ore district.","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":"87 1","pages":"582 - 590"},"PeriodicalIF":2.7,"publicationDate":"2023-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44848887","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

First occurrence of the M2a2b2c polytype of argentopolybasite, [Ag6Sb2S7][Ag10S4]: Structural adjustments in the Cu-free member of the pearceite–polybasite group 首次出现M2a2b2c多型银多碱矿[Ag6Sb2S7][Ag10S4]：磷铝石-多碱矿群无铜成员的结构调整

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-05-02 DOI: 10.1180/mgm.2023.30

L. Bindi, F. Keutsch, D. Topa, U. Kolitsch, M. Morana, K. Tait

{"title":"First occurrence of the M2a2b2c polytype of argentopolybasite, [Ag6Sb2S7][Ag10S4]: Structural adjustments in the Cu-free member of the pearceite–polybasite group","authors":"L. Bindi, F. Keutsch, D. Topa, U. Kolitsch, M. Morana, K. Tait","doi":"10.1180/mgm.2023.30","DOIUrl":"https://doi.org/10.1180/mgm.2023.30","url":null,"abstract":"Abstract The chemistry and the crystal structure of the recently described mineral argentopolybasite are critically discussed based on the study of two new occurrences of the mineral: Gowganda, Timiskaming District, Ontario, Canada and IXL Mine, Silver Mountain mining district, Alpine County, California. The crystal structure of argentopolybasite can be described as the sequence, along the c axis, of two alternating layers: a [Ag6Sb2S7]2– A layer and a [Ag10S4]2+ B layer. In the B layer there are linearly-coordinated metal positions (B sites), which are usually occupied by copper in all members of the pearceite–polybasite group, resulting in a B-layer composition [Ag9CuS4]2+. In argentopolybasite, however, Ag fills all the metal sites in both A and B layers. By means of a multi-regression analysis on 67 samples of the pearceite–polybasite group, which were studied by electron microprobe and single-crystal X-ray diffraction, the effect of Ag, Sb and Se on the B sites of the B layer was modelled. Although the nomenclature rules for these minerals are based on chemical data only, we think this approach is useful to evaluate the goodness of the refinement of the structure (Ag/Cu disorder) and thus fundamental to discriminate different members of the pearceite–polybasite group.","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":"87 1","pages":"561 - 567"},"PeriodicalIF":2.7,"publicationDate":"2023-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48385997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Crystallisation of Ca-bearing nepheline in basanites from Kajishiyama of Tsuyama Basin, Southwest Japan. 日本西南Tsuyama盆地Kajishiyama玄武岩中含钙霞石的结晶。

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-05-02 DOI: 10.1180/mgm.2023.32

Keiya Yoneoka, M. Hamada, S. Arai

{"title":"Crystallisation of Ca-bearing nepheline in basanites from Kajishiyama of Tsuyama Basin, Southwest Japan.","authors":"Keiya Yoneoka, M. Hamada, S. Arai","doi":"10.1180/mgm.2023.32","DOIUrl":"https://doi.org/10.1180/mgm.2023.32","url":null,"abstract":"Abstract Ca-bearing nepheline found in the Kajishiyama basanite, Tsuyama Basin, southwest Japan, was investigated to clarify its genesis in silica-undersaturated magmas. The basanite contains olivine and augite as phenocrysts and microphenocrysts, with Ca-bearing nepheline, olivine, augite, ulvöspinel, plagioclase, alkali feldspar, apatite and zeolites in the groundmass. Zeolites are more abundant in coarser-grained samples. The whole-rock composition of the basanite is characterised by low SiO2 and P2O5 contents and high total Fe, MgO, Na2O, K2O, Ba and Sr contents. The Ca-bearing nepheline, ~20 μm in size, occurs in the mesostasis of the Kajishiyama basanite and contains up to 2.31 wt.% CaO and 16.75 wt.% Na2O, in contrast to nepheline from the Hamada nephelinite, southwest Japan. The approximate compositional formula of the Kajishiyama nepheline with the highest Ca content is (Ca0.467Ba0.013Na5.286K0.919□Total1.385)Σ8.070(Si0.912Al6.980Cr3+0.003Fe3+0.067 Mg0.017)Σ7.979Si8.000O32; i.e. Ne65.50Ks11.39Qxs11.22CaNe11.89. Basanites are defined as being nepheline-normative, however they are high in normative plagioclase, the amount of which increases with fractionation of the magma. Nepheline crystallised after plagioclase, at the last stage of magmatic solidification is enriched in Ca. Such Ca-rich nepheline only forms from a magma which is high in normative plagioclase, as is the case in the Kajishiyama basanite. In contrast, Ca-poor nepheline is precipitated from nephelinitic magmas that crystallise melilite instead of plagioclase, even when Ca contents are high.","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":" ","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43748010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

New data on minerals with the GIS framework-type structure: gismondine-Sr from the Bellerberg volcano, Germany, and amicite and Ba-rich gismondine from the Hatrurim Complex, Israel 具有GIS框架型结构的矿物新资料:来自德国Bellerberg火山的gismondine- sr和来自以色列Hatrurim杂岩的amicite和富钡gismondine

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-04-21 DOI: 10.1180/mgm.2023.27

Katarzyna Skrzyńska, G. Cametti, Rafał Juroszek, Christof Schӓfer, I. Galuskina

{"title":"New data on minerals with the GIS framework-type structure: gismondine-Sr from the Bellerberg volcano, Germany, and amicite and Ba-rich gismondine from the Hatrurim Complex, Israel","authors":"Katarzyna Skrzyńska, G. Cametti, Rafał Juroszek, Christof Schӓfer, I. Galuskina","doi":"10.1180/mgm.2023.27","DOIUrl":"https://doi.org/10.1180/mgm.2023.27","url":null,"abstract":"Abstract Gismondine-Sr, recently discovered in the Hatrurim Complex in Israel, has been recognised in a xenolith sample from the Bellerberg volcano in Germany. The empirical crystal-chemical formula indicates elevated K content: (Sr1.74Ca1.05Ba0.09K1.56Na0.49)Σ4.93[Al7.98Si8.06O32]⋅9.62H2O. Additionally, Ba-rich gismondine and amicite have been found in the low-temperature mineral association of the pyrometamorphic rock from the Hatrurim Complex. The Raman spectra of the studied zeolites and the crystal structure of gismondine-Sr from the second occurrence are presented. A review of zeolites with GIS framework-type structure leads to the following conclusions: (1) garronite-Na and gobbinsite are equivalent and constitute a solid solution with garronite-Ca; (2) gismondine-Ca, -Sr, and amicite belong to one mineral series; (3) two zeolites series with different R-factors (defined as Si/(Si+Al+Fe)) can be distinguished within GIS topology: the garronite series (R > 0.6) including garronite-Ca and gobbinsite, with general formula (MyD0.5(x–y))[AlxSi(16–x)O32]⋅nH2O, where M and D refer to monovalent and divalent cations, respectively; and the gismondine series, including amicite, gismondine-Sr and gismondine-Ca, with R ≈ 0.5, and the general formula (MyD0.5(8–y))[Al8Si8O32]⋅nH2O. The Raman band between 475 cm–1 and 485 cm–1 is distinctive for the garronite series, whereas the band around 460 cm–1 is characteristic of the gismondine series. On the basis of these findings, a revision of GIS zeolites nomenclature is suggested.","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":"87 1","pages":"443 - 454"},"PeriodicalIF":2.7,"publicationDate":"2023-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42660968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Classifying minerals and their related names in a relational database 在关系数据库中对矿物及其相关名称进行分类

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-04-20 DOI: 10.1180/mgm.2023.23

L. Gavryliv, V. Ponomar, M. Putiš

引用次数: 0

Mikenewite, the natural analogue of synthetic α-Mn2+(S4+O3)⋅3H2O, a new sulfite mineral from the Ojuela mine, Mapimí, Mexico Mikenewite，合成α-Mn2+(S4+O3)⋅3H2O的天然类似物，产自墨西哥Ojuela矿Mapimí

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-04-19 DOI: 10.1180/mgm.2023.24

Hexiong Yang, R. Jenkins, J. McGlasson, R. Gibbs, R. Downs

{"title":"Mikenewite, the natural analogue of synthetic α-Mn2+(S4+O3)⋅3H2O, a new sulfite mineral from the Ojuela mine, Mapimí, Mexico","authors":"Hexiong Yang, R. Jenkins, J. McGlasson, R. Gibbs, R. Downs","doi":"10.1180/mgm.2023.24","DOIUrl":"https://doi.org/10.1180/mgm.2023.24","url":null,"abstract":"Abstract A new mineral species, mikenewite (IMA2022-102), ideally Mn2+(S4+O3)⋅3H2O, has been discovered from the San Judas Chimney, Ojuela mine, Mapimí, Durango, Mexico. It occurs as spheres of platy crystals. Associated minerals include goethite, cryptomelane, adamite and lotharmeyerite. Mikenewite is yellowish in transmitted light, transparent with a white streak and vitreous lustre. It is brittle and has a Mohs hardness of 2½–3. Cleavage is perfect on {101}. The measured and calculated densities are 2.48(5) and 2.467 g/cm3, respectively. Optically, mikenewite is biaxial (+), with α = 1.606(5), β = 1.614(5), γ = 1.627(1) (white light), 2V(meas.) = 69(3)° and 2V(calc.) = 77°. An electron microprobe analysis yielded an empirical formula (based on 6 O apfu) of (Mn0.86Zn0.12Fe0.04Ca0.02)Σ1.04(S0.98O3)⋅3H2O, which can be simplified to (Mn,Zn,Fe)(SO3)⋅3H2O. Mikenewite is the natural analogue of synthetic α-Mn2+(S4+O3)⋅3H2O, as well as the Mn-analogue of albertiniite, Fe2+(S4+O3)⋅3H2O. It is monoclinic, with space group P21/n and unit-cell parameters a = 6.6390(3), b = 8.8895(4), c = 8.7900(4) Å, β = 96.095(2)°, V = 515.83(4) Å3 and Z = 4. The crystal structure of mikenewite is characterised by each Mn atom coordinated octahedrally by six O atoms, three from different sulfite O atoms and three from H2O molecules. Each S4+O3 group is bonded to three Mn atoms, resulting in a sheet parallel to (101) with the sheet composition of Mn2+(S4+O3)⋅3H2O. Such sheets, stacked along [10$bar{1}$], are joined together by hydrogen bonds, accounting for the perfect cleavage of the mineral. Mikenewite is dimorphous with orthorhombic Pnma gravegliaite, as albertiniite is with fleisstalite. Its discovery from the Ojuela mine, which is particularly rich in Zn, implies the possibility of finding Zn-bearing sulfites there as well.","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":"2 3","pages":"534 - 541"},"PeriodicalIF":2.7,"publicationDate":"2023-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41243597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Evidence of the anthropogenic origin of the ‘Carmel sapphire’ with enigmatic super-reduced minerals 具有神秘的超还原矿物的“卡梅尔蓝宝石”的人为起源证据

IF 2.7 3区地球科学

Mineralogical Magazine Pub Date : 2023-04-19 DOI: 10.1180/mgm.2023.25

E. Galuskin, I. Galuskina

{"title":"Evidence of the anthropogenic origin of the ‘Carmel sapphire’ with enigmatic super-reduced minerals","authors":"E. Galuskin, I. Galuskina","doi":"10.1180/mgm.2023.25","DOIUrl":"https://doi.org/10.1180/mgm.2023.25","url":null,"abstract":"Abstract Corundum with inclusions of enigmatic super-reduced minerals was found in mineral separates received as a result of alluvial sediment exploration near Mt Carmel, Israel by the Shefa Yamim Company. This corundum, registered as ‘Carmel sapphireTM’, has been an object of numerous publications by W. Griffin's scientific team, in which they propose a questionable hypothesis of sapphire formation at the crust–mantle boundary with the participation of CH4+H2 fluids. Typically the Carmel sapphire is in small fragments of breccia with white cement, which in the opinion of Griffin et al. is a carbonate-cemented volcanic ash. Our investigation of the ‘white breccia’ showed that it consists of unsorted angular fragments of Carmel sapphire from ~1 μm to 7 mm in size cemented by aluminium hydroxides (bauxite) and is a waste product of the fused alumina process, i.e. it has an anthropogenic origin. Phases typical for slags of fused alumina production and metallurgical slags were identified in the ‘white breccia’. Carmel sapphire has numerous microscopic spherical inclusions of Si–Fe alloy indicating that the removal of Si and Fe from the corundum melt occurred at a temperature >2000°С. Osbornite, TiN, from Carmel sapphire has a chemical zonation characteristic of osbornite from fused alumina with enrichment of central zones in carbon. Comparison of the growth heterogeneity of Carmel sapphire and ‘electrocorundum’ indicates that the crystallisation of the corundum melt proceeded in a similar way. Unfortunately, in the case of Carmel sapphire from the Carmel locality, the contamination of geological samples with anthropogenic material has led to popularisation of biased views.","PeriodicalId":18618,"journal":{"name":"Mineralogical Magazine","volume":"87 1","pages":"619 - 630"},"PeriodicalIF":2.7,"publicationDate":"2023-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44994394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3