MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic)最新文献

Optimization of Titanium Dioxide Wetting in Alkyd Paint and Varnish Materials in the Presence of Surfactants 表面活性剂存在下醇酸漆和清漆材料中二氧化钛润湿性能的优化

MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic) Pub Date : 2021-08-31 DOI: 10.15587/1729-4061.2021.237879

Kirill Ostrovnoy, A. Dyuryagina, A. Demyanenko, V. Tyukanko

{"title":"Optimization of Titanium Dioxide Wetting in Alkyd Paint and Varnish Materials in the Presence of Surfactants","authors":"Kirill Ostrovnoy, A. Dyuryagina, A. Demyanenko, V. Tyukanko","doi":"10.15587/1729-4061.2021.237879","DOIUrl":"https://doi.org/10.15587/1729-4061.2021.237879","url":null,"abstract":"This paper reports the results of studying the influence of surfactants (SAS) on the wetting of titanium dioxide in alkyd paint and varnish materials (PVM), based on pentaphthalic (PPh) and alkyd-urethane (AU) film-forming substances. Edge wetting angle (θ°) and adhesion work (Wa) were used as the criteria for assessing the wettability of titanium dioxide. Three additives were used as SAS: the original product AS-1, obtained from waste of oil refining (with low cost), and industrial additives: \"Telaz\" and polyethylene polyamine (PEPA). All the studied additives in PPh and AU PVM improve the wetting of titanium dioxide. At the 30 % content of AS film-forming substance in the composition, the maximum decrease in θ° for AS-1 is 4.5°, for PEPA and Telaz it is 4°. For pentaphthalic composition under similar conditions, a decrease in edge wetting angle for AS-1 is 10 °, for Telaz 8.6°, and for PEPA 5.9°. According to the relative change in edge wetting angle for both systems, the maximum decrease in θ° is about 10 %. The introduction of SAS into the composition of AU ambiguously affects the adhesion work, for PPh, the introduction of SAS causes a decrease in adhesion work (Wa). AS-1 is the SAS that minimally reduces adhesion work. The compositions of the PVM by the method of probabilistic-deterministic planning, which ensures maximum wetting of titanium dioxide with film-forming solutions, were analyzed. The equations for calculating the edge angle of wetting of titanium dioxide depending on the content of solvent and the SAS in the PVM were derived. The effectiveness of the AS-1 product as a wetting additive for alkyd paints and varnishes was proven. The wetting ability of the original SAS – AS-1 is close to industrial additives PEPA and Telaz.","PeriodicalId":18248,"journal":{"name":"MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic)","volume":"43 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73788600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 6

Novel Coating Technologies to Reduce Rate of Moisture Absorption of Phosphate and Phosphate/Urea Substrates 降低磷酸盐和磷酸盐/尿素基材吸湿率的新型涂层技术

MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic) Pub Date : 2020-05-28 DOI: 10.2139/ssrn.3612740

Lucas R. Moore, J. Fernández, Christina Konecki, Zachary Burrell

引用次数: 1

Wetting and Photocatalytic Behavior of Two-Dimensional Tin Oxides 二维锡氧化物的润湿和光催化行为

MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic) Pub Date : 2020-01-01 DOI: 10.2139/ssrn.3558244

Sunny Kumar, S. Suresh

{"title":"Wetting and Photocatalytic Behavior of Two-Dimensional Tin Oxides","authors":"Sunny Kumar, S. Suresh","doi":"10.2139/ssrn.3558244","DOIUrl":"https://doi.org/10.2139/ssrn.3558244","url":null,"abstract":"Among the variety of two-dimensional oxides, tin oxides semiconducting are particularly interesting because of their promising in catalyst, energy harvesting, water purification, electronics device and space applications. In this study, three synthesized methods use adopted to explore the properties and application of oxides of tin sheets. The methods are air oxidation, aqueous and non-aqueous which characterized through techniques such as SEM-EDS, UV -spectroscopy, X ray diffraction, FTIR and photoluminescence. From SEM image showed the morphology of the tin oxide materials. The percentage of tin and oxygen from elemental analysis was ~ 55 % and 44 % respectively. FTIR spectra confirmed that Sn-O functional from the vibration peak. The X- ray diffraction pattern shows that prominent diffraction peak which indicates formation of tin oxide crystallinity. A photoabsorbtiy activity was tested in the tin oxide sample with methylene blue to explore how the tin oxide surface featured absorbs the integrity of a dye. Porosity and a surface alteration resulted in a increase in photoactivity. The tin oxide sheets emit green fluorescence in the UV light and emission might be dependent on the number of layers and concentration of it. The water droplet contact angle measure on the tin oxide sheets which is experimentally observed 69°. The theoretically molecular dynamics-based contact angle measurement was also studied on monolayer of stannous oxide, stannic oxide with effect of substrate. Based on above results, this material can be utilized as a photo-catalyst, drug delivery and thin film application of solar cell.","PeriodicalId":18248,"journal":{"name":"MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic)","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84557585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dynamics of Surface Morphology of Cu Film Under the Influence of Heat: An Experimental and Theoretical Study 热影响下Cu膜表面形貌动力学的实验与理论研究

MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic) Pub Date : 2019-01-08 DOI: 10.2139/ssrn.3311690

G. Kumar, Santanu Ghosh, R. P. Yadav, U. B. Singh, A. K. Mittal, P. Srivastava

{"title":"Dynamics of Surface Morphology of Cu Film Under the Influence of Heat: An Experimental and Theoretical Study","authors":"G. Kumar, Santanu Ghosh, R. P. Yadav, U. B. Singh, A. K. Mittal, P. Srivastava","doi":"10.2139/ssrn.3311690","DOIUrl":"https://doi.org/10.2139/ssrn.3311690","url":null,"abstract":"The evolution of surface morphology and formation of oxides is meticulously studied in annealed copper thin films in oxygen environment at various temperature using experimental results and Higuchi's algorithm. Initially, thin film of copper is deposited using thermal evaporation system having thickness of 27 nm and subsequently oxidized by annealing in temperatures range of 150 °C to 350 °C with a temperature interval of 50 °C in oxygen environment for one hour. The studies of morphological, structural and optical properties of samples are performed by atomic force microscopy (AFM), X-Ray diffraction (XRD) and UV-VIS spectroscopy respectively. XRD results reveal that Cu2O phase changes completely to CuO phase by rising in the temperature from 250 to 350 °C. The optical band gap of annealed copper films at different temperatures is calculated by Tauc's plot and it indicates the formation of Cupreous and Cupric oxide. A clear morphological variation is seen in AFM images of the surface of films. Additionally, Higuchi's algorithm for surface morphology is performed to observe the change in surface morphology under the effect of temperature variation in oxygen environment by various parameters e.g. interface width (w), Hurst exponent (H) and fractal dimension (Df).","PeriodicalId":18248,"journal":{"name":"MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic)","volume":"253 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82772401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Optical Analysis of Ag-NPs Containing Methyl Ammonium Lead Tri-Iodide Thin Films 含三碘化铅甲基铵Ag-NPs薄膜的光学分析

MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic) Pub Date : 2017-09-30 DOI: 10.22178/POS.26-10

C. Mosiori, W. Njoroge, L. Ochoo

引用次数: 3

Comparative Study on Azo Dye-Doped Polymer Films for Optical Phase Conjugation 偶氮染料掺杂聚合物光学相位共轭膜的比较研究

MatSciRN: Phase Stability & Interfacial Phenomena in Thin Films (Topic) Pub Date : 2015-04-10 DOI: 10.5281/ZENODO.61724

S. Aithal, Sreeramana Aithal, G. Bhat

引用次数: 10