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Benthic biogeochemical processes and fluxes in the hypoxic and acidified northern Gulf of Mexico, part II: Influence of Mississippi-Atchafalaya River system inputs on the differential cycling of Mn, Fe, and S in Louisiana continental shelf sediments 低氧酸化墨西哥湾北部底栖生物地球化学过程和通量,第二部分:密西西比-阿查法拉亚河系统输入对路易斯安那大陆架沉积物中锰、铁和S差异循环的影响
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-07-01 Epub Date: 2026-06-18 DOI: 10.1016/j.marchem.2026.104660
Anthony Boever, Evan Magette, Hanna Bridgham, Eva Ferreira, Owen Silvera, Mason Thackston, Christophe Rabouille, Jordon S. Beckler, Martial Taillefert
{"title":"Benthic biogeochemical processes and fluxes in the hypoxic and acidified northern Gulf of Mexico, part II: Influence of Mississippi-Atchafalaya River system inputs on the differential cycling of Mn, Fe, and S in Louisiana continental shelf sediments","authors":"Anthony Boever,&nbsp;Evan Magette,&nbsp;Hanna Bridgham,&nbsp;Eva Ferreira,&nbsp;Owen Silvera,&nbsp;Mason Thackston,&nbsp;Christophe Rabouille,&nbsp;Jordon S. Beckler,&nbsp;Martial Taillefert","doi":"10.1016/j.marchem.2026.104660","DOIUrl":"10.1016/j.marchem.2026.104660","url":null,"abstract":"<div><div>River-dominated ocean margins are carbon processing hot spots, but the spatiotemporal dynamics of the benthic biogeochemical cycling of Mn, Fe, and S under different discharge regimes and the impact of these variations on carbon cycling are not well characterized. Here, a comparative analysis of pore water profiles of redox-sensitive chemical species reveals the biogeochemical restructuring that occurred over a summer-spring-summer sequence on the Louisiana continental shelf in the northern Gulf of Mexico. Increases in depth-averaged pore water inventories, including exceptionally high Mn(II) concentrations, were associated with high river discharge and sediment inputs, suggesting that Mn reduction plays an important role in Louisiana continental shelf sediments, except during below-average discharge periods in summer when iron and sulfate reduction are promoted. The river effect was greatest and most consistent proximal to the Mississippi River and extended at least ∼60 km westward when high winds and discharge enhanced plume dispersal, whereas the area where seasonal bottom water hypoxia often develops remained largely isolated from any riverine influence. A river imprint on biogeochemical patterns was also observed south of Atchafalaya Bay, suggesting the area periodically receives inputs from the bay throughout the year. Results demonstrate that Mn(II) often traces these hydrodynamic processes and that river loads of Mn (oxyhydr)oxides buffer the redox state of shelf sediments and moderate the biogeochemical response to low discharge and hypoxia. Stores of river-derived Mn may therefore function as an environmental redox capacitor. Based on the patterns observed between the two summers, a period of Mn reduction may persist for ∼20 days after Mississippi River discharge subsides to below the threshold for net mobilization of sediment to the shelf.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"277 ","pages":"Article 104660"},"PeriodicalIF":2.5,"publicationDate":"2026-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148499590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Importance of atmospheric nitrogen deposition on primary productivity in the coastal bay of Bengal: Seasonality and source apportionment 大气氮沉降对孟加拉湾沿海初级生产力的重要性:季节性和来源分配
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-07-01 DOI: 10.1016/j.marchem.2026.104662
V. Rajani Kumari, V.V.S.S. Sarma
{"title":"Importance of atmospheric nitrogen deposition on primary productivity in the coastal bay of Bengal: Seasonality and source apportionment","authors":"V. Rajani Kumari,&nbsp;V.V.S.S. Sarma","doi":"10.1016/j.marchem.2026.104662","DOIUrl":"10.1016/j.marchem.2026.104662","url":null,"abstract":"<div><div>The anthropogenic aerosols transport inorganic and organic nutrients and deposit over the surface ocean. The highest levels and rate of increase in anthropogenic aerosols were reported over the Bay of Bengal, compared to the elsewhere in the globe, and it is hypothesised that their deposition may enhance nutrients and surface primary production in the Bay of Bengal. To examine this, aerosol samples were collected at a monthly interval, along with primary production incubation experiments in the coastal Bay of Bengal, off Visakhapatnam. The concentrations of nitrate (0.02–0.35 μmol m<sup>−3</sup>), ammonium (0.01–1.31 μmol m<sup>−3</sup>), and dissolved organic nitrogen (DON; 0.02–0.32 μmol m<sup>−3</sup>) showed significant temporal variability in the aerosols. The atmospheric nitrogen mainly originated from biomass burning, vehicular and industrial emissions, with large seasonality associated with seasonal reversing winds. Dry depositional flux of inorganic nitrogen was higher in the coastal compared to the offshore Bay of Bengal, supporting 14–42% (mean of 30 ± 9%) of primary production in the surface ocean. This contribution is notably higher than global estimates in other marine regions, associated with the highest aerosol optical depth, highlighting the regional importance of atmospheric nutrient inputs. These results provide strong evidence that atmospheric deposition is a significant nutrient source influencing coastal productivity in the central east coast of India with large seasonality driven by different sources. Therefore, it is strongly recommend to incorporate the atmospheric sources of nitrogen in the numerical models for accurate simulation of nitrogen and carbon cycling in the north Indian Ocean.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"277 ","pages":"Article 104662"},"PeriodicalIF":2.5,"publicationDate":"2026-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148499592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-parameter imaging with planar optodes and 2D DET hydrogels: Application in the rhizosphere of seagrass (Z. marina) 平面光电器件和2D DET水凝胶的多参数成像:在海草根际的应用
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-07-01 Epub Date: 2026-06-24 DOI: 10.1016/j.marchem.2026.104661
Marie Duverger, Aurélia Mouret, Kasper Elgetti Brodersen, Michael Kühl, Florian Cesbron
{"title":"Multi-parameter imaging with planar optodes and 2D DET hydrogels: Application in the rhizosphere of seagrass (Z. marina)","authors":"Marie Duverger,&nbsp;Aurélia Mouret,&nbsp;Kasper Elgetti Brodersen,&nbsp;Michael Kühl,&nbsp;Florian Cesbron","doi":"10.1016/j.marchem.2026.104661","DOIUrl":"10.1016/j.marchem.2026.104661","url":null,"abstract":"<div><div>Multi-parameter analysis of chemical conditions in sediment microenvironments is of great importance to highlight key biogeochemical processes and conditions at interfaces. Yet, many imaging approaches only allow for determining one analyte at a time. Here we present a new planar optical sensor combination to investigate simultaneously the two-dimensional distribution and dynamics of sediment pore-water chemical conditions at a millimeter resolution using planar optodes (PO) of pH and O<sub>2</sub> in combination with Diffusive Equilibrium in Thin film gels (DET) for mapping dissolved iron (Fe<sup>2+</sup>/Fe<sup>3+</sup>) or nitrite-nitrate. We used the combined sensor imaging approach to simultaneously map pH/dissolved iron and O<sub>2</sub>/nitrite-nitrate distributions in the rhizosphere of the seagrass <em>Zostera marina.</em> This combination enabled the imaging of seagrass rhizosphere acidification via H<sup>+</sup> ions leakage or, indirectly, via enhancement of microbial processes upon O<sub>2</sub> leakage, and the remobilization of iron and nitrogen.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"277 ","pages":"Article 104661"},"PeriodicalIF":2.5,"publicationDate":"2026-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148499591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The isotopic composition of solid-phase extracted dissolved organic nitrogen in seawater 海水中固相萃取溶解有机氮的同位素组成
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-05-01 Epub Date: 2026-04-25 DOI: 10.1016/j.marchem.2026.104646
Yeongjun Ryu , Dario Marconi , Sandi M. Smart , Sarah E. Fawcett , Rodney Johnson , Run Zhang , Angela N. Knapp , Sergey Oleynik , Alfredo Martínez-García , Gerald H. Haug , Daniel M. Sigman
{"title":"The isotopic composition of solid-phase extracted dissolved organic nitrogen in seawater","authors":"Yeongjun Ryu ,&nbsp;Dario Marconi ,&nbsp;Sandi M. Smart ,&nbsp;Sarah E. Fawcett ,&nbsp;Rodney Johnson ,&nbsp;Run Zhang ,&nbsp;Angela N. Knapp ,&nbsp;Sergey Oleynik ,&nbsp;Alfredo Martínez-García ,&nbsp;Gerald H. Haug ,&nbsp;Daniel M. Sigman","doi":"10.1016/j.marchem.2026.104646","DOIUrl":"10.1016/j.marchem.2026.104646","url":null,"abstract":"<div><div>Dissolved organic nitrogen (DON) is likely comprised of multiple compound classes with varying reactivities and turnover times, resulting in numerous roles in ocean biogeochemistry. Here, we present measurements of total DON and solid-phase extracted DON (SPE-DON) concentrations and δ<sup>15</sup>N values from sampling sites across the global ocean. An optimized SPE protocol was developed to maximize total DON recovery, with a recovery of 41.0 ± 9.4% for surface DON across the global ocean and 56.6 ± 11.2% for deep water DON from the Sargasso Sea. SPE-DON concentrations were 1.8–1.9 μM across most sampling sites, in contrast to greater variation in total DON concentration (4.0–5.9 μM). However, in the equatorial upwelling zones, SPE-DON concentrations were slightly (0.3–0.4 μM) higher than in other regions. The δ<sup>15</sup>N of total DON in surface waters correlated well with the δ<sup>15</sup>N of nitrate supplied to the euphotic zone from the subsurface. SPE-DON δ<sup>15</sup>N was also correlated with nitrate δ<sup>15</sup>N, but SPE-DON δ<sup>15</sup>N values were confined to a narrower range compared to those of total DON. The combined concentration and δ<sup>15</sup>N data indicate that while SPE-DON is biased toward long-lived DON, it still retains some reactive components introduced through regional inputs in the upper ocean, and even some of its longer-lived components may be labile on the timescales of deep ocean circulation. The longer average turnover time of SPE-DON suggests that greater molecular polarity and/or charge directly increase or are otherwise correlated with the biogeochemical lability of different DON pools.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"276 ","pages":"Article 104646"},"PeriodicalIF":2.5,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147956555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Distribution and chemical composition of atmospheric aerosols over the Gulf of Thailand during the southwest monsoon 西南季候风期间泰国湾上空气溶胶的分布和化学成分
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-05-01 Epub Date: 2026-04-20 DOI: 10.1016/j.marchem.2026.104645
Jariya Kayee , Penjai Sompongchaiyakul , Reshmi Das , Xianfeng Wang , Narainrit Chinfak , Sukchai Arnupapboon , Sujaree Bureekul
{"title":"Distribution and chemical composition of atmospheric aerosols over the Gulf of Thailand during the southwest monsoon","authors":"Jariya Kayee ,&nbsp;Penjai Sompongchaiyakul ,&nbsp;Reshmi Das ,&nbsp;Xianfeng Wang ,&nbsp;Narainrit Chinfak ,&nbsp;Sukchai Arnupapboon ,&nbsp;Sujaree Bureekul","doi":"10.1016/j.marchem.2026.104645","DOIUrl":"10.1016/j.marchem.2026.104645","url":null,"abstract":"<div><div>Marine aerosols were collected over the Gulf of Thailand (GOT) during the 2018 southwest monsoon on board the M.V. SEAFDEC2 while sailing. Water-soluble inorganic ions (i.e., Na<sup>+</sup>, NH<sub>4</sub><sup>+</sup>, K<sup>+</sup>, Mg<sup>2+</sup>, Ca<sup>2+</sup>, Cl<sup>−</sup>, NO<sub>3</sub><sup>−</sup>, and SO<sub>4</sub><sup>2−</sup>) and elemental concentrations (i.e., Al, As, Ba, Ca, Cd, Cu, Cr, Fe, Mg, Mn, Na, Ni, Pb, Sr, V, and Zn) were determined to investigate their distribution patterns in order to evaluate the influence of particle sources on the chemical properties of atmospheric aerosols. During the southwest monsoon, the wind predominantly blows over the Indian Ocean to the GOT. Correspondingly, our results indicated that coarse particles are dominated by sea salts. Cl<sup>−</sup> and Na<sup>+</sup> are the major ions, accounting for ∼64.8% (range: 51.2–84.3%) of total ions in the coarse mode particles. The strong correlation between Cl<sup>−</sup> and Na<sup>+</sup> (<em>r</em> = 0.999) along with the Cl/Na ratio (1.5, range: 0.66–2.00) suggest sea salt origin. Enrichment factor (EF) values indicate that elements are originated from oceanic, crustal, and anthropogenic sources. The oceanic source (Sr, Ca, Mg and Na) explains 95% (range: 81–99%) of total elements in the aerosols. Elements such as Al, Fe, Mn and Ba explain 4.6% of the total elements. These elements associate with the crustal source. Only a minimal amount (0.63%, range: 0.02–4.5%) of the total elements is originated from anthropogenic activities over or nearby the GOT as shown by loading of As, Cd, Cu, Cr, Ni, Pb, V and Zn.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"276 ","pages":"Article 104645"},"PeriodicalIF":2.5,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147797852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioaccumulation of rare earth elements (REEs) and trace metals in corals of the South China Sea 南海珊瑚中稀土元素和微量金属的生物富集
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-05-01 Epub Date: 2026-04-20 DOI: 10.1016/j.marchem.2026.104644
Yao-Wen Qiu , Han-Lin Qiu
{"title":"Bioaccumulation of rare earth elements (REEs) and trace metals in corals of the South China Sea","authors":"Yao-Wen Qiu ,&nbsp;Han-Lin Qiu","doi":"10.1016/j.marchem.2026.104644","DOIUrl":"10.1016/j.marchem.2026.104644","url":null,"abstract":"<div><div>Global coral coverage has declined significantly, and environmental pollution is a factor that cannot be ignored. This study presents a comprehensive investigation into the bioaccumulation of rare earth elements (REEs) and other trace elements in corals from two distinct coral reef areas in the South China Sea (SCS). Results revealed that the concentrations of trace elements in coastal corals (tissues + skeleton) from Sanya were generally higher than those in offshore Xisha corals, with median REEs values of 1.35 μg g<sup>−1</sup> dw and 0.22 μg g<sup>−1</sup> dw, respectively. The predominant trace elements in corals from both regions were B, Ni, Zn, and Cu, while the dominant REEs plus yttrium (REY) were Ce, La, Y, and Nd. Trace metal (including REY) concentrations were significantly higher in massive, densely structured <em>Porites</em> than in branching <em>Pocillopora</em> and <em>Acropora</em>. The standardized coral REY patterns showed the depletion of heavy REEs and enrichment of light REEs bioaccumulation, as well as positive anomalies of La and Eu, weak negative anomaly of Ce and high Y/Ho ratio (&gt;50). The results demonstrated that REY accumulated more easily from seawater than from sediment. This study indicates that the geochemical characteristics of REY in corals can serve as a reliable alternative proxy to assess the environmental quality of local seawater and sediment, and may provide new insights into the coral bioaccumulation patterns of trace metals, including REEs.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"276 ","pages":"Article 104644"},"PeriodicalIF":2.5,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147797891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Distributions of particulate Al and Fe in the Bay of Bengal and south Indian subtropical gyre 孟加拉湾和南印度亚热带环流中颗粒Al和Fe的分布
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-03-01 Epub Date: 2026-01-23 DOI: 10.1016/j.marchem.2026.104611
Pamela M. Barrett , Joseph A. Resing , Maxime M. Grand , Christopher I. Measures , William M. Landing
{"title":"Distributions of particulate Al and Fe in the Bay of Bengal and south Indian subtropical gyre","authors":"Pamela M. Barrett ,&nbsp;Joseph A. Resing ,&nbsp;Maxime M. Grand ,&nbsp;Christopher I. Measures ,&nbsp;William M. Landing","doi":"10.1016/j.marchem.2026.104611","DOIUrl":"10.1016/j.marchem.2026.104611","url":null,"abstract":"<div><div>The trace element composition (Al, Si, P, Ca, and Fe) of suspended particulate matter is presented for the upper 1000 m of the water column along U.S. CLIVAR/CO<sub>2</sub> Repeat Hydrography zonal section I05 (2009) in the South Indian subtropical gyre and meridional section I09N/I08S (2007) in the eastern Indian Ocean from the Bay of Bengal to the subtropical front. Along I09N, high particulate Al and Fe concentrations are found throughout the Bay of Bengal and the northern Indian Ocean indicating significant lithogenic particle loads from river-borne sediment transport and smaller contributions from continental dust flux than current model estimates. Particles have elevated Fe:Al ratios compared to the composition of local shelf sediments, indicating that suspended particulate matter becomes enriched from scavenging of dissolved Fe that accumulates in the oxygen minimum zone in the Bay of Bengal. Along I05, retroflection of the Agulhas Return Current transports African shelf-derived lithogenic particles into the western South Indian basin, resulting in the elevated subsurface concentrations of particulate Al and Fe nearly 3000 km into the interior of the subtropical gyre. Another region of elevated dissolved Fe concentrations and Fe-enriched particulate matter was also observed along I05 in intermediate waters (&gt;600 m) in the subtropical gyre at 32°S between 70 and 74°E, suggesting inputs from a shallow sedimentary or possibly volcanic Fe source to these stations. Comparison of data from the crossover between the I05 and I09N/I08S sections and from the 2007 and 2016 occupations of I09N allows investigation of the temporal variability of basin-scale distributions of particle-associated trace metals with relatively short residence times in the upper water column. The most pronounced differences in trace metal distributions are associated with interannual variability in productive near-coastal and upwelling regions where mixed-layer pFe concentrations vary by a factor of 2–7, whereas Fe and Al in deeper waters and dust-impacted surface waters in oligotrophic regions show significantly less variability.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"275 ","pages":"Article 104611"},"PeriodicalIF":2.5,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147399977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Surface macro- and micro-nutrients within the Copper River plume region respond to along-shore winds” [Marine Chemistry volume 270 (2025) Number 104508] “铜河羽流区域内的表层宏观和微量营养物质对沿岸风的反应”[海洋化学第270卷(2025)号104508]的勘误表
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-03-01 Epub Date: 2026-02-27 DOI: 10.1016/j.marchem.2026.104621
E.L.S. Ortega, I. Reister, S.L. Danielson, A.M. Aguilar-Islas
{"title":"Corrigendum to “Surface macro- and micro-nutrients within the Copper River plume region respond to along-shore winds” [Marine Chemistry volume 270 (2025) Number 104508]","authors":"E.L.S. Ortega,&nbsp;I. Reister,&nbsp;S.L. Danielson,&nbsp;A.M. Aguilar-Islas","doi":"10.1016/j.marchem.2026.104621","DOIUrl":"10.1016/j.marchem.2026.104621","url":null,"abstract":"","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"275 ","pages":"Article 104621"},"PeriodicalIF":2.5,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147399979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The distribution of chlorophyll-a degradation derivatives in the Holocene Black Sea and their marine ecological significance 全新世黑海叶绿素-a降解衍生物的分布及其海洋生态意义
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-03-01 Epub Date: 2026-01-22 DOI: 10.1016/j.marchem.2026.104606
Wenshuo Zhao , Junpeng Fu , Olawale O. Alo, Xiao-Lei Liu
{"title":"The distribution of chlorophyll-a degradation derivatives in the Holocene Black Sea and their marine ecological significance","authors":"Wenshuo Zhao ,&nbsp;Junpeng Fu ,&nbsp;Olawale O. Alo,&nbsp;Xiao-Lei Liu","doi":"10.1016/j.marchem.2026.104606","DOIUrl":"10.1016/j.marchem.2026.104606","url":null,"abstract":"<div><div>Chlorophyll-<em>a</em> degradation derivatives (Chl-<em>a</em>-DDs) provide valuable insights into past phytoplankton dynamics. Using a new LC-QToF-MS method, we identified eleven steryl chlorin esters (SCEs), eight oxidative chlorophyll transformation products (OxCs), four reductive chlorophyll transformation products (ReCs), and two cyclopheophorbide derivatives (CPBs) in the Holocene Black Sea sapropel. Total Chl-<em>a</em>-DDs reveal two productivity peaks: post-stratification (∼7.5 ka) and after surface freshening (∼3 ka). ReCs track progressive redox changes, and a peak in the 3<sup>1</sup>-meso-pyropheophytin-<em>a</em>/pyropheophytin-<em>a</em> ratio in upper Unit II implies intensified euxinia between ∼5 and 3 ka B.P. Elevated OxCs in Units II and I suggest intracellular oxidation as the dominant chlorophyll transformation pathway. SCEs dominance in Unit III indicates fecal pellet as the primary organic carbon delivery mechanism preceding stratification, while their decline in Units II and I reflects reduced grazing under euxinia. Increase in CPBs under euxinia likely reflects protists' physiological responses to oxidative stress associated with light stress.</div></div>","PeriodicalId":18219,"journal":{"name":"Marine Chemistry","volume":"275 ","pages":"Article 104606"},"PeriodicalIF":2.5,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146081235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seasonal variations in mercury species and selenium in plankton from Kagoshima Bay, southern Kyushu, Japan: Impact of active submarine volcanoes on ecosystems 日本九州南部鹿儿岛湾浮游生物中汞种类和硒的季节变化:海底活火山对生态系统的影响
IF 2.5 3区 地球科学
Marine Chemistry Pub Date : 2026-03-01 Epub Date: 2026-01-24 DOI: 10.1016/j.marchem.2026.104610
Takashi Tomiyasu , Hayato Uwashitomi , Taijyu Wakimaru , Hitoshi Kodamatani , Ryo Kanzaki , Toru Kobari
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