Kolloid-Zeitschrift und Zeitschrift für Polymere最新文献

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Solutions of alkali soaps and water in fatty acids 碱性肥皂和脂肪酸中的水的溶液
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1969-08-01 DOI: 10.1007/BFB0109368
S. Friberg, L. Mandell, P. Ekwall
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引用次数: 52
Zur Ermittlung von Diffusionskoeffizienten in Festkörpern aus Sorptionsdaten 用于确定吸附性数据中的扩散系数
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1968-07-01 DOI: 10.1515/zpch-1974-25529
K. Pilchowski, F. Danes, F. Wolf
{"title":"Zur Ermittlung von Diffusionskoeffizienten in Festkörpern aus Sorptionsdaten","authors":"K. Pilchowski, F. Danes, F. Wolf","doi":"10.1515/zpch-1974-25529","DOIUrl":"https://doi.org/10.1515/zpch-1974-25529","url":null,"abstract":"ZusammenfassungZur Auswertung kinetischer Sorptionsdaten wurden die Bedingungen der Anwendbarkeit der Boydschen Lösung des 2. Fickschen Gesetzes untersucht. Es konnte gezeigt werden, daß bis auf einige Sonderfälle die Patersonsche Lösung des 2. Fickschen Gesetzes anzuwenden ist. Hierbei hängt der Umsetzungsgrad zusätzlich noch von einem w-Parameter ab, der das Verhältnis der Phasenvolumina und den Isothermenanstieg beinhaltet. Die Wahl der optimalen Anfangs- und Endbeladungen des Sorbens sowie das Verhältnis der Phasenvolumina wurden diskutiert.SummaryThe applicability conditions of the Boyd solution for the second Fick’s law of diffusion have been investigated for the evaluation of the kinetic sorption data. It could be pointed out, that the Paterson’s solution of the second Fick’s law must be applied with the exception of some special cases. In this expression the fractional attainment of equilibrium depends on a supplementary parameter which contains the ratio of the phase volumes and the isotherm slope. The choice of the optimum initial and final loadings of the sorbens and of the phase volumes ratio is discussed.","PeriodicalId":17849,"journal":{"name":"Kolloid-Zeitschrift und Zeitschrift für Polymere","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1968-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83796199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
14. Keramik, Ton, Zement, Glas, anorganische Farbstoffe 14. 陶瓷,陶土,水泥,玻璃,无有机染料
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1967-01-01 DOI: 10.1007/BF01525116
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引用次数: 0
7. Kunststoffe und Kautschuk 7. 塑料和橡胶
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1967-01-01 DOI: 10.1007/BF01525114
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引用次数: 0
6. Experimentelle Methodik
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1967-01-01 DOI: 10.1007/BF01525113
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引用次数: 0
4. Kolloide Systeme 4. Kolloide系统
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1967-01-01 DOI: 10.1007/BF01525111
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引用次数: 0
Studies on the preparation and characterisation of monodisperse polystyrene latices 单分散聚苯乙烯乳液的制备及表征研究
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1967-01-01 DOI: 10.1007/BFB0117065
R. Ottewill, J. Shaw
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引用次数: 151
5. Makromolekulare Systeme 5. Makromolekulare系统
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1967-01-01 DOI: 10.1007/BF01525112
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引用次数: 0
8. Textilien und Faserstoffe 8. 纺织品和纤维
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1967-01-01 DOI: 10.1007/BF01525115
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引用次数: 0
Crystallization under stress and non-gaussian behavior of macromolecular networks 应力结晶和大分子网络的非高斯行为
Kolloid-Zeitschrift und Zeitschrift für Polymere Pub Date : 1966-07-01 DOI: 10.5254/1.3544874
K. J. Smith, A. Greene, A. Ciferri
{"title":"Crystallization under stress and non-gaussian behavior of macromolecular networks","authors":"K. J. Smith, A. Greene, A. Ciferri","doi":"10.5254/1.3544874","DOIUrl":"https://doi.org/10.5254/1.3544874","url":null,"abstract":"Abstract (a) Shape of the isotherm.—The appearance of a “first” upturn in the conventional isotherm is associated with non-gaussian behavior. Crystallization takes place, under usual conditions, in a range of elongation where non-gaussian behavior prevails and tends, initially, to reduce the stress below the value expected for the amorphous non-gaussian network. On further stretching a “second”, steeper up turn may be observed which is associated with a substantial reduction of amorphous content and, therefore, with crystallization. This interpretation, which is coherent with most of the experimental observations (particularly the lack of correspondence between the first upturn and the downturn of the energy component, the swelling behavior and the independence of the first upturn upon the mode of obtaining the isotherm and upon temperature) is satisfactorly fitted in the present picture of behavior of the network under stress. (b) Energy component.—Extensive measurements and theoretical analysis indicate...","PeriodicalId":17849,"journal":{"name":"Kolloid-Zeitschrift und Zeitschrift für Polymere","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"1966-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78845851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 72
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