Halyna Medvid, O. Сheban, M. Kost, O. Teleguz, Vasyl Harasymchuk, I. Sakhnyuk, Orysia Maykut, Solomia Kalmuk
{"title":"Ecological and geochemical characteristic of natural waters within the influence limits of the Dobrivlyany gas condensate field (Precarpathia)","authors":"Halyna Medvid, O. Сheban, M. Kost, O. Teleguz, Vasyl Harasymchuk, I. Sakhnyuk, Orysia Maykut, Solomia Kalmuk","doi":"10.15407/ggcm2022.01-02.115","DOIUrl":"https://doi.org/10.15407/ggcm2022.01-02.115","url":null,"abstract":"A study of natural waters within the influence of the Dobrivlyany gas condensate field, located in the Dobryany and Dobrivlyany area village councils of the Stryi district of the Lviv Region of Ukraine, was conducted. The purpose of the work is to evaluate the geochemical indicators of natural waters based on our own research, to find out the role of natural and man-made factors in the formation of the chemical composition of waters. The objects of the research are surface waters and groundwaters within the influence of the Dobrivlyany gas condensate field. Research results. In the research area, as well as in the Bilche-Volytsia zone in general, there are unfavorable conditions for active water exchange and the formation of fresh infiltration waters, since the upper part of the geological section is characterized by clayey Neogene deposits. The depth of penetration of fresh hydrocarbonate-calcium waters here does not exceed 70 m. The small thickness of the zone of active water exchange is one of the indicators of difficult water exchange in the subsoil, therefore, favourable conditions for the preservation of hydrocarbon deposits. As a result of exploratory work, the Dobrivlyany gas condensate field was opened in 2016. During 2016–2019, 7 boreholes were drilled, and industrial gas inflows were received from horizons LD-9, LD-12, and N1kr+K2. In tectonic terms, the deposit is confined to the northwestern part of the Kosiv-Ugersko subzone of the Bilche-Volytsia zone of the Carpathian Foredeep. Observation of the macro component composition of groundwater from the wells of the Dobrivlyany gas condensate field indicates the stability of the hydrodynamic conditions of the deposit and, accordingly, the low variability of their geochemical characteristics. Direct hydrogeochemical zonation is clearly manifested in the increase in water mineralization with depth: for the LD-9 horizon at depths of 800–840 m, it varies within the range of 34.74–48.55 g/dm3, for LD-12 at depths of 995–1010 m – 33.82–73.70 g/dm3 and for N1kr+K2 at 1131–1158 m – 67.49–100.31 g/dm3. The content of Br and J doubles with depth. All waters are of the chloride-calcium type (according to Sulin), and genetic indicators vary within narrow limits (rNa/rCl – 0.82–0.91; Cl/Br – 216–315; rSO4 ∙ 100/rCl – 0.003–0.5) and indicate their thalassogenic sedimentogenic origin. The analysis of research results showed that underground waters belong to a single hydrodynamic system, and are characterized by the same type of water according to their chemical composition. According to the qualitative characteristics of groundwater from an ecological borehole and a well in the Dobrivlyany village remain clean and meets regulatory requirements for drinking water. At the same time, water from a well in Vivnya village is characterized by a high content of nitrates (2.28 maximum permissible concentration), which is caused by the location of the pig complex “Halychyna-Zakhid” LLC on the outskirts. Increase","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"195 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121280833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. Hnylko, S. Hnylko, M. Kulyanda, Romana Marchenko
{"title":"Tectonic-sedimentary evolution of the frontal part of the Ukrainian Carpathian nappe structure","authors":"O. Hnylko, S. Hnylko, M. Kulyanda, Romana Marchenko","doi":"10.15407/ggcm2021.01-02.045","DOIUrl":"https://doi.org/10.15407/ggcm2021.01-02.045","url":null,"abstract":"For the first time in the Ukrainian Carpathians, the depths and tectono-sedimentation processes in the north-eastern part of the Outer Carpathian Basin (Skyba and Boryslav-Pokuttya units) have been restored on the base of sedimentological and microfaunistic studies. It was established that in the Cretaceous-Eocene time, the deep-water (near Calcite Compensation Depth) turbidite and similar sedimentation (turbidites with Bouma textures, grainites, debris-flow deposits), which periodically alternated with (hemi)pelagic sedimentation (red, green and black shales) was dominant here. Sedimentation took place on the continental margin of the the Carpathian branch of the Tethys, where deep-water fans were formed. Cretaceous-Eocene background red and green shales are enriched in buried in situ benthic foraminifera which are similar in taxonomic composition and morphological features to the microfauna of the Carpathian-Alpine and Atlantic regions (deep-water agglutinated foraminifera), which indicate lower bathyal – abyssal depths of flysch sedimentation. Latest Eocene Globigerina Marl horizon contains the foraminiferal assemblage with plankton dominance, which indicates a general shallowing of the Outer Carpathian Basin (middle-upper bathyal conditions above a calcite compensation depth). Oligocene – lowermost Miocene Menilite-Krosno and Polyanytsia formations were accumulated in the Skyba and Boryslav-Pokuttya sub-basins. In the Miocene, shallow-water molasses were accumulated here. Probably, the tectonic uproot of flysch deposits from its substrate and their synsedymentary thrusting towards the platform caused a significant shallowing of the Skyba and Boryslav-Pokuttya sub-basins starting from the latest Eocene. These processes reflected the growth of the Carpathian frontal nappes at the final orogen formation stage.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"21 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122467774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Facial features of the Paleocene-Eocene deposits of advanced units of the Skyba zone of Ukrainian Carpathians","authors":"H.Ya. Havryshkiv, Yu.P. Haievska","doi":"10.15407/ggcm2021.03-04.044","DOIUrl":"https://doi.org/10.15407/ggcm2021.03-04.044","url":null,"abstract":"There three main types of facies of Paleocene-Eocene complexes: sandy, siltstone and argillite distinguished within the study area by the nature of the distribution of the strata of the forming components were highlighted. Тhey accumulated avalanche at the foot of the continental slope and formed various facial parts of the foehn (Upper, Middle and Lower foehn). In the upper part of the Foehn was accumulated coarse-grained sediments (clusters of deep boulders and other psephyto-psammitic material containing edaphogenic rocks). Under the action of geostrophic and bottom currents, silt streams of pelitic and psammitic material moved in the direction to the south and south-east of the Carpathian sedimentation basin, forming sandy-clay and clay facies (Middle and Lower foehn). During the turbidite movement of a large amount of sediment from the first (shelf) to the second (foot of the continental slope) level of avalanche sedimentation, sorting and distribution of sediments on the continental slope took place. Based on the analysis of the material composition of Paleocene-Eocene sediments of the study area by such criteria as the size of the fragment, sedimentary textures and the ratio of different rocks, 7 facies were identified, which were deposited as gravitational flows down on the continental slope. Reconstructions of Paleocene-Eocene age flysch deposits showed that terrigene material in the studied sedimentation basin came from two sources – one of which was northwest of the study area and was characterized by a predominance of coarse-grained sandy sediments, while the source wear, which was in the central part of the studied basin was characterized by a predominance of clay silt and fine-grained psammitic material. This nature of the distribution of terrigenous material had a decisive influence on the further formation of Paleocene end Eocene sedimentary strata in the process of sedimentogenesis and post-sedimentary transformations of sediments, and on the formation of reservoir rocks and rocks with potential reservoir properties for hydrocarbon exploration. It has been established that the composition of the Psamitolites of the flysch formation of the Paleocene and Eocene ages of the Carpathians was formed on the passive continental margin or in the inland and boundary seas, and their genesis mostly corresponds only to the platform source of material wear.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"25 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125239465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Halyna Medvid, O. Teleguz, Vasyl Harasymchuk, M. Kost, Solomiya Kalmuk
{"title":"Prospects for oil and gas presence of Lower Sarmatian deposits in the north-western part of the Outer zone of the Carpathian foredeep (by hydrogeochemical and hydrodynamic indicators)","authors":"Halyna Medvid, O. Teleguz, Vasyl Harasymchuk, M. Kost, Solomiya Kalmuk","doi":"10.15407/ggcm2021.03-04.016","DOIUrl":"https://doi.org/10.15407/ggcm2021.03-04.016","url":null,"abstract":"The hydrogeochemical parameters of the Lower Sarmatian aquifer of the north-western part of the Outer Zone of the Carpathian Foredeep have been studied. The waters of the chloride-calcium type (according to the classification of V. O. Sulin) are dominated. Other types of water are distributed locally. On the basis of the calculated genetic coefficients, the conclusion on sedimentogenic conditions of their forming during a geological history of the region is made. It is established that the general tendency for the deposits of the Outer Zone is increasing of TDS of water with depth and stratigraphy. The waters of the north-western part of the Outer Zone are characterized by reduced values of sulfate content and sulfation coefficient rSO42– • 100/rCl–, indicating the conditions of hydrogeological closed structures. The genetic index of formation water metamorphism (rNa+/rCl–) is mainly inversely dependent on TDS. Its values greater than one are inherent in waters of hydrocarbonate-sodium and sulfate-sodium types, which are not typical for the hydrocarbon deposits. The nature of fluctuations in the values of the chlorine-bromine coefficient is fully consistent with other hydrochemical parameters and the results of paleohydrodynamic reconstructions. A detailed analysis of the current hydrodynamic situation of Lower Sarmatian aquifer in combination with geochemical features and paleohydrodynamic reconstructions allowed to identify the perspective structures of the studying region. Our forecasts for the gas potential of the Krukenychy depression are consistent with the forecasts of researchers of Ivano-Frankivsk National Technical University of Oil and Gas. The results of their research are based on gravitational field anomalies.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"83 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116986005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Deformations in the thrust zone between the Zelemianka and Parashka Skybas of the Ukrainian Carpathian Skyba Nappe (Hrebeniv quarry)","authors":"M. Bogdanova","doi":"10.15407/ggcm2022.01-02.048","DOIUrl":"https://doi.org/10.15407/ggcm2022.01-02.048","url":null,"abstract":"In the article, based on own field observations, the deformation structures into the thrust zone of the Zelemianka Skyba (=thrust-sheet) onto the Parashka Skyba (the Ukrainian Carpathian Skyba Nappe) are described. They are exposed in the Hrebeniv quarry located in the Opir River basin (Lviv Region, Skole district). The tectonically disintegrated Stryi Formation (Upper-Cretaceous–Paleocene flysch) characterized by the rigid sandstone blocks (formed mainly as a result of boudinage) placed in a ductile clay matrix is represented in the Hrebeniv quarry. This formation is proposed to be classified as a “broken formation”, which is strongly tectonized, but retain their lithological and stratigraphic identity. It is a transitional element between the weakly deformed strata and tectonic mélange. Their characteristic features are: linearity of the distribution zone; significant monomictic composition and absence of exotic formations; the presence of an intensively tectonized matrix with clastolites (blocks) of less tectonized rocks of the same lithostratum (formation, series); the presence of newly formed hydrothermal minerals in clastolite cracks; the upper and lower contacts limiting the broken formation have a tectonic nature. An intensely tectonized matrix and a weakly tectonized rigid blocks belong to the same stratigraphic unit in a broken formation. The structural features suggest a brittle deformations in the studied rocks. Tectonic processes occurred in the completely lithified deposits. Thrust processes were accompanied by the formation of the duplexes, including antiformal stack duplexes, which are well expressed in the quarry. Duplexes are observed in different parts of the quarry, and the most representative ones are developed in its central section. Horses in the duplexes are characterized by a size of 1 to 3 meters here. They are generally subparallel, which is consistent with monoclinal bedding, however, they sometimes acquire an antiform appearance as a result of tectonic thrusting.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114464697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V.Ye. Shlapinsky, M. Pavlyuk, Y. Lazaruk, O. Savchak, Myroslav Ternavsky
{"title":"Geological structure and prospects of oil-gas presence at the Pohar plot (Folded Carpathians)","authors":"V.Ye. Shlapinsky, M. Pavlyuk, Y. Lazaruk, O. Savchak, Myroslav Ternavsky","doi":"10.15407/ggcm2021.03-04.005","DOIUrl":"https://doi.org/10.15407/ggcm2021.03-04.005","url":null,"abstract":"The Pohar plot is situated in the Skole district of the Lviv Region, 30 km south-west of Skole town, between Pohar and Kryve villages. Tectonically it is located in of junction of the Skybian (Slavske Skyba) and the Krosno covers. At the end of XIX beginning of XX centuries in the region of the village the oil-extracting enterprise was existent. There deposits of Oligocen and Eocene of the Rozluch belt of the Krosno cover and Oligocene of the scale of the Slavske skyba of the Skybian cover were exploited. During two ten-years of exploitation by exploring shafts and shallow boreholes more than 3 thousand ton of oil was extracted. Prospects of the Pohar plot should be connected with sand horizons of the Holovets suite of Oligocen (Klivsky sandstones) that are characterized by satisfactory reservoir properties. They are localized in the immersed part of the Hrosivsky scale of the Krosno cover separated by the Rozluch fault (tectonically screened deposit) from its forkball part, drilled in 1973–1974 1-Pohar borehole (well bottom 1935 m), due to deflection of its hole to the south-east, didn’t expose the Klivsky sandstones and didn’t solve its task. For complete exposition of the Klivsky sandstones of the Holovets suite of Oligocene of the Hrosivsky scale it is necessary to design vertically oriented 2-Pohar borehole of 2300 m in depth. About probable commercial oil-gas saturation of the horizon of the Klivsky sandstones testifies not only to the existence of the oil-extracting enterprise in the past, but the intensive surface oil shows in the stretched area that is controlled by the Rozluch fault. Moreover, taking the prospect of the zone of junction of the given covers in consideration, the seismic survey should be conducted at the Pohar area for the estimation of the geological structure of the deeper horizons and parametric borehole of 4000–5000 m in depth should be designed.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123467326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Myroslav Podolskyy, Dmytro Bryk, Lesia Kulchytska-Zhyhailo, Oleh Gvozdevych
{"title":"Consumption of combustible minerals in the context of the targets of sustainable development of Ukraine and global environment changes","authors":"Myroslav Podolskyy, Dmytro Bryk, Lesia Kulchytska-Zhyhailo, Oleh Gvozdevych","doi":"10.15407/ggcm2021.03-04.109","DOIUrl":"https://doi.org/10.15407/ggcm2021.03-04.109","url":null,"abstract":"An analysis of Ukraine’s sustainable development targets, in particular in the field of energy, resource management and environmental protection, are presented. It is shown that regional energetic is a determining factor for achieving the aims of sustainable development. Changes in the natural environment in Ukraine due to external (global) and internal (local) factors that are intertwined and overlapped can cause threats to socio-economic development. It is proved that in the areas of mining and industrial activity a multiple increase in emissions of pollutants into the environment are observed. The comparison confirmed the overall compliance of the structure of consumption of primary energy resources (solid fossil fuels, natural gas, nuclear fuel, oil and petroleum products, renewable energy sources) in Ukraine and in the European Union, shows a steaby trend to reduce the share of solid fuels and natural gas and increasing the shares of energy from renewable sources. For example, in Ukraine the shares in the production and cost of electricity in 2018 was: the nuclear power plants – 54.33 % and in the cost – 26.60 %, the thermal power – 35.95 and 59.52 %, the renewable energy sources – 9.6 and 13.88 %. The energy component must be given priority, as it is crucial for achieving of all other goals of sustainable development and harmonization of socio-economic progress. The paper systematizes the indicators of regional energy efficiency and proposes a dynamic model for the transition to sustainable energy development of the region.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"72 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115957737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Geochemical features of strontium accumulation and migration in the peats of the Lviv Region","authors":"M. Yakovenko","doi":"10.15407/ggcm2022.01-02.058","DOIUrl":"https://doi.org/10.15407/ggcm2022.01-02.058","url":null,"abstract":"The article is devoted to the study of geochemical characteristics of the distribution, accumulation and migration of Strontium in the lowland peats of the Lviv region, both laterally and vertically, and to identify the main factors influencing the formation of its concentrations. A significant uneven distribution of concentration, high dispersion and variability (coefficient of variation – 116.61, standard deviation – 564.11) of Sr in peats within deposits, districts and regions both with depth and area of distribution and high content indicators were established Sr relative to clarks of the lithosphere, soils, plant ash (CC relative to the lithosphere = 1.42; CC relative to soil clarks = 1.94; Сs relative to background values in the soils of Ukraine = 4.56; CK relative to clarks of terrestrial plants = 1.61). The content of Sr in the peat of the Lviv region ranges from 40–3190 mg/kg (average content 483.75 mg/kg, median content (background content) – 250 mg/kg), which is due to natural-climatic, geological, lithological, hydrogeochemical and anthropogenic factors. The features of the distribution and the degree of concentration of Sr in the peatlands of the Lvіv region are mainly influenced by the chemical-mineralogical-petrographic composition of the bedrocks of the wear area during their weathering; terrain, climatic, geomorphological, tectonic and hydrogeological conditions of the area, which determine the of the weathering processes of the rocks in the wear areas, the degree of transformation of terrigenous material in the weathering processes, the rate of accumulation of biomass and the rate of its decomposition; features of water and mineral nutrition of the peatland. High concentrations of Strontium in the peat of the Lviv region reflect the local regional processes of the concentration of the element in the mass of peat and may indicate the accumulation of Sr of both natural and anthropogenic origin in the upper layers of peat profiles.There is an enrichment of Sr in the upper intervals of deposits (0–1 m) of deposits in the northeastern part of the Lviv region (Malopoliska peat region) is observed.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130844709","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Lithogeochemistry of black shales of the Phanerozoic of the Western Ukraine ‒ unconventional hydrocarbon reservoirs","authors":"I. Popp, Petro Moroz, M. Shapovalov","doi":"10.15407/ggcm2022.01-02.082","DOIUrl":"https://doi.org/10.15407/ggcm2022.01-02.082","url":null,"abstract":"The purpose of this work is to compare the lithological, geochemical and mineralogical features of carbonaceous clayey and siliceous-clay rocks of Cretaceous-Paleogene flysch of the Ukrainian Carpathians and Lower Silurian of the Volyn-Podillya edge of the East European Platform and to determine the factors that contributed to the formation of zones of “unconventional reservoirs” in these sedimentary strata of cracked and mixed types. Data from the lithology, geochemistry and mineralogy of bituminous siliceous-clay rocks and siliceous rocks of Lower Cretaceous and Oligocene of the Carpathians and black argillites of Lower Silurian of the Volyn-Podillya edge of the East European Platform are presented. Sedimentogenesis of Lower Cretaceous and Oligocene bituminous deposits of the Carpathians and Lower Silurian deposits of Volyn-Podillya took place in anoxic conditions (phases of oceanic anoxic events: OAE-1 (Barrem–Albian), OAE-4 (Oligocene) and at the border of Ordovician and Silurian. Paleoceanographic conditions of their sedimentation differed significantly. The first are deep-sea formations at the foot of the continental slope of the Carpathian segment of the Tethys Ocean, the second were accumulated in the warm shallow sea on the eastern shelf of the West European Sea Basin. The layered texture of carbonaceous deposits, as well as the catagenetic transformation of rock-forming clay and siliceous minerals and their hydrophobization, played a significant role in the formation of the filtration capacity properties of “unconventional reservoirs”. In Cretaceous-Paleogene flysch deposits of the Carpathians, “unconventional reservoirs” are usually terrigenous-clay or siliceous-clay rocks with shale and layered texture or compacted sandstones localized in conventional oil, gas or condensate deposits. Lower Silurian clay deposits of Volyn-Podillya are promising for the search for “shale gas”.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129540645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Prospects of using peats in the Lviv Region for humates extraction","authors":"M. Yakovenko, Yu.V. Khokha, O. Lyubchak","doi":"10.15407/ggcm2021.01-02.076","DOIUrl":"https://doi.org/10.15407/ggcm2021.01-02.076","url":null,"abstract":"The paper briefly considers the problems of the Ukraine’s peat industry and identifies the reasons for its decline, including the low quality of peat as an energy source. We assume that the use of peat for briquetting will be stopped in the near future due to economic and political factors. On the other hand, peat can be a source of chemicals and their mixtures that have found application in agriculture and industry. It is known that the addition of sodium humates to the drilling mud improves its rheological properties and makes them environmentally safe, especially when passing through aquifers. We set a goal to determine the geological, technological and geochemical characteristics of peat in the Lviv Region, to establish its suitability for the humic acids extraction and to identify promising deposits for future processing. The study of the peats microelement composition of the Radekhiv district (Lviv Region) showed that the studied peats are not contaminated with heavy metals, as evidenced by the values of pollution indices. It is shown that the content of chemical elements in peats of Lviv Region is less than clarke in the lithosphere, soils and terrestrial plants. There is a tendency to scatter chalcophilic and most siderophilic elements, to a lesser extent lithophilic. Determining the yield of total and free humic acids testified to the possibility of using peat in the Lviv Region to extract humates. The studied samples were characterized by a high content of humic acids in terms of dry weight. Preliminary assessment of deposits suitability for peat extraction was performed according to the following parameters: field reserves, degree of decomposition, humus content and ash content. After constructing maps of these geochemical characteristic’s distribution, we have identified several of the most promising deposits in the Lviv Region: in the Kamyanka-Buzka district – Didylivske and Yarychivske deposits; in the Mykolayiv district – Verbizke, Saikivske, Demnyanske and Trostyanetske.","PeriodicalId":176324,"journal":{"name":"Geology and Geochemistry of Combustible Minerals","volume":"39 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127631944","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}