{"title":"The isothermal section (500 °C) of the phase diagram of the ternary system Cu-Sn-Y","authors":"Zhuang Yinghong, Qin Can, Li Junqin","doi":"10.1016/0022-5088(91)90353-6","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90353-6","url":null,"abstract":"<div><p>The isothermal section (500 °C) of the phase diagram of the ternary system Cu-Sn-Y (40 at.% Y or less) was investigated by X-ray diffraction, differential thermal microanalysis, optical microanalysis and electron probe microanalysis techniques. The isothermal section consists of 12 single-phase regions, 25 two-phase regions and 14 three-phase regions. Three new ternary compounds were found in this isothermal section: the θ phase (Y<sub>8</sub>Cu<sub>7</sub>Sn<sub>5</sub>), the β phase (Y<sub>3</sub>Cu<sub>4</sub>Sn<sub>3</sub>) and the γ phase (Y<sub>19</sub>Cu<sub>66</sub>Sn<sub>15</sub>). They are all non-variable compounds. The θ phase is an orthorhombic system with <span><math><mtext>a = 9.702 </mtext><mtext>A</mtext><mtext>̊</mtext></math></span>, <span><math><mtext>b = 7.285 </mtext><mtext>A</mtext><mtext>̊</mtext></math></span> and <span><math><mtext>c = 6.545 </mtext><mtext>A</mtext><mtext>̊</mtext></math></span>.</p><p>The maximum solid solubility of tin in α-Cu at 500 °C is about 9.0 at.% and that of yttrium in α-Cu at 500 °C (with 4.3 at.% Sn) is about 1.5 at.%.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 1","pages":"Pages 97-101"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90353-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71731605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ion beam deposition of silver on YBCO powder and the superconductivity of Ag-YBCO composites","authors":"H.R. Khan , H. Frey","doi":"10.1016/0022-5088(91)90363-9","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90363-9","url":null,"abstract":"<div><p>YBa<sub>2</sub>Cu<sub>3</sub>O<sub>∼7</sub> (YBCO) powder of particle size distribution smaller than 80 μm has been coated with silver by a secondary ion beam deposition technique. Sintered Ag-YBCO composites prepared from this powder consist of homogeneously distributed orthorhombic phase, Ag<sub>2</sub>O, silver and a small amount of other phases. The composites are superconducting at about 92 K, with a sharp superconducting transition.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 1","pages":"Pages 177-182"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90363-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71712289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Crystal structure of the compound CeRh1 − xGe2 + x (x = 0.325)","authors":"B.I. Shapiev, O.L. Sologub, Ju.D. Seropegin, O.I. Bodak, P.S. Salamakha","doi":"10.1016/0022-5088(91)90343-3","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90343-3","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 1","pages":"Pages L1-L4"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90343-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71731371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rolf Berger , Auke Meetsma, Sander van Smaalen, Margareta Sundberg
{"title":"The structure of LiCu2O2 with mixed-valence copper from twin-crystal data","authors":"Rolf Berger , Auke Meetsma, Sander van Smaalen, Margareta Sundberg","doi":"10.1016/0022-5088(91)90356-9","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90356-9","url":null,"abstract":"<div><p>The structure of LiCu<sub>2</sub>O<sub>2</sub> was solved using two sets of X-ray diffraction twin-crystal data. Extended twinning creates virtual tetragonal symmetry. The compound crystallizes in <em>Pnma</em> (62) with unit-cell parameters <span><math><mtext>a = 5.72 </mtext><mtext>A</mtext><mtext>̊</mtext><mtext>, b = 2.86 </mtext><mtext>A</mtext><mtext>̊</mtext></math></span> and <span><math><mtext>c = 12.4 </mtext><mtext>A</mtext><mtext>̊</mtext></math></span> with a certain homogeneity range. The structure consists of LiCu<sup>II</sup>O<sub>2</sub> layers interleaved by layers of Cu<sup>I</sup> connected to oxygen in an almost linear coordination. Lithium and copper(II) have five oxygen neighbours in pyramidal arrangements that run as parallel bands through edge connections. Electron diffraction was used for characterizing the twinning.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 1","pages":"Pages 119-129"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90356-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71731604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Constitutional studies of molybdenum-palladium alloys using ultra-rapidly solidified samples","authors":"R. Gürler, J. N. Pratt","doi":"10.1016/0022-5088(91)90350-D","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90350-D","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"71 1","pages":"71-78"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89077424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mössbauer and magnetic properties study of Nd2Fe14C-type compounds","authors":"F. Xing, W.W. Ho, C.L. Yang, F.S. Li","doi":"10.1016/0022-5088(91)90352-5","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90352-5","url":null,"abstract":"<div><p>The dependence of the Curie temperature <em>T</em><sub><em>c</em></sub> and saturation magnetization <em>σ</em><sub><em>s</em></sub> on composition was studied in the alloys Nd<sub>14</sub>Fe<sub>78 − <em>x</em></sub>T<sub><em>x</em></sub>C<sub>8</sub> (<em>T</em> ≡ <em>Co</em>, <em>Ni</em>, <em>Mn</em>, <em>Cr</em>). The effects on <em>T</em><sub><em>c</em></sub> and <em>σ</em><sub><em>s</em></sub> of the substitution of these 3d elements for iron were found to be similar to the effects on <em>T</em><sub><em>c</em></sub> and <em>σ</em><sub><em>s</em></sub> of the corresponding borides. Mössbauer spectra of the tetragonal Nd<sub>2</sub>Fe<sub>14</sub>C compound were taken at various temperatures and fitted with a set of six subspectra owing to six non-equivalent iron sites. It was found that the average hyperfine fields at 295 K and 4.2 K are 28.04 T and 32.36 T, the corresponding average iron moments being about 1.89 <em>μ</em><sub><em>B</em></sub> and 2.19 <em>μ</em><sub><em>B</em></sub>, respectively.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 1","pages":"Pages 91-96"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90352-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71731613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Über die Möglichkeit einer Mischungslücke in dem Na-Ga binären System","authors":"P. Feschotte","doi":"10.1016/0022-5088(91)90344-4","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90344-4","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"91 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89760565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Shamraǐ, A. Pimenov, Y. Efimov, A. A. Babaréko, F. R. Karelin, V. F. Choporov, T. Frolova, E. Myasnikova, A. Postnikov
{"title":"The effect of cold deformation on the structure, texture and properties of yttrium high temperature superconducting powders and strips","authors":"V. Shamraǐ, A. Pimenov, Y. Efimov, A. A. Babaréko, F. R. Karelin, V. F. Choporov, T. Frolova, E. Myasnikova, A. Postnikov","doi":"10.1016/0022-5088(91)90347-7","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90347-7","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"1 1","pages":"29-36"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88760262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B.Chafik El Idrissi, G. Venturini, B. Malaman, D. Fruchart
{"title":"Magnetic structures of TbMn6Sn6 and HoMn6Sn6 compounds from neutron diffraction study","authors":"B.Chafik El Idrissi, G. Venturini, B. Malaman, D. Fruchart","doi":"10.1016/0022-5088(91)90359-C","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90359-C","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"8 1","pages":"143-154"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79200844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The crystal structure of the low temperature form of Co2As","authors":"Ingrid Lindeberg, Y. Andersson","doi":"10.1016/0022-5088(91)90361-7","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90361-7","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"109 1","pages":"163-169"},"PeriodicalIF":0.0,"publicationDate":"1991-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82500733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}