Journal of The Less Common Metals最新文献

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M10S14O-type oxysulphides (M La, Ce, Pr, Nd, Sm) as an “oxygen trap” in oxidation reactions of reduced lanthanide chlorides with sulphur m10s14o型氧硫化物(M、La、Ce、Pr、Nd、Sm)在还原性镧系氯化物与硫氧化反应中的“氧阱”作用
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90017-X
T. Schleid, F. Lissner
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引用次数: 55
Study of SiC-whisker-reinforced ZrO2 ceramics using the sol-gel method 溶胶-凝胶法制备sic晶须增强ZrO2陶瓷
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90005-O
G. Tu, Z. Sui, Changzhen Wang
{"title":"Study of SiC-whisker-reinforced ZrO2 ceramics using the sol-gel method","authors":"G. Tu, Z. Sui, Changzhen Wang","doi":"10.1016/0022-5088(91)90005-O","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90005-O","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"49 4 1","pages":"205-208"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77327154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Kinetic study of the hafnium-hydrogen reaction 铪-氢反应动力学研究
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90007-Q
Y Levitin, J Bloch, M.H Mintz
{"title":"Kinetic study of the hafnium-hydrogen reaction","authors":"Y Levitin,&nbsp;J Bloch,&nbsp;M.H Mintz","doi":"10.1016/0022-5088(91)90007-Q","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90007-Q","url":null,"abstract":"<div><p>The kinetics of hafnium hydride formation were studied utilizing conventional rate measurements (Sieverts system) combined with metallographic examinations of partially hydrided samples. The rate measurements were performed at 700 TorrH<sub>2</sub> over a temperature range 200–550 °C. Two types of hafnium samples (polycrystalline and crystal bar) were compared. The progression of the massive stage of the reaction is characterized by a contracting-envelope morphology with a constant hydride front velocity. The anisotropy in the reaction front velocity regarding different crystalline orientations of the metal is small, resulting in similar results for the different types of hafnium. The temperature dependence of the front velocity obeys an Arrhenius-type relation over the temperature range 250–450 °C, with an apparent activation energy of 0.50 ± 0.05 eV. Considering a diffusion-controlled model, a diffusion activation barrier of about 0.4 eV is evaluated, which agrees with the average reported value for the diffusion of hydrogen in hafnium hydride. At temperatures above about 500 °C, deviations from the Arrhenius relation are displayed, possibly owing to a change of mechanism.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 219-234"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90007-Q","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Ferromagnetic materials: A handbook on the properties of magnetically ordered substances, vol. 5 铁磁材料:磁性有序物质性质手册,第5卷
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90024-X
Ch.J. Raub
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引用次数: 8
SrHgO2: Ein oxomercurat mit delafossitstruktur 弓状x光片
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90015-V
M Soll, Hk Müller-Buschbaum
{"title":"SrHgO2: Ein oxomercurat mit delafossitstruktur","authors":"M Soll,&nbsp;Hk Müller-Buschbaum","doi":"10.1016/0022-5088(91)90015-V","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90015-V","url":null,"abstract":"<div><p>For the first time, single crystals of SrHgO<sub>2</sub> have been prepared by a high pressure oxidation technique. X-ray investigations indicate that the crystals have trigonal symmetry, space group <em>D</em><sub>3</sub><sup>6</sup>-<em>P</em>3<sub>2</sub>21 (no. 154), with <span><math><mtext>a = 3.833(3) </mtext><mtext>a</mtext><mtext>̊</mtext><mtext>A</mtext></math></span>, <span><math><mtext>c = 18.990(15) </mtext><mtext>A</mtext><mtext>̊</mtext></math></span> and <em>Z</em> = 3. <em>Hg</em><sup>2+</sup> has a coordination number of two, while Sr<sup>2+</sup> is surrounded by six oxygen ions. Two-dimensional layers of edge-linked SrO<sub>6</sub> octahedra are connected by O-Hg-O dumb-bells. SrHgO<sub>2</sub> belongs to the delafossite-type structure.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 295-299"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90015-V","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
Thermodynamic studies of La(FexAl1−x)13 alloys La(FexAl1−x)13合金的热力学研究
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90012-S
Xiuguang Xu, Guangqiang Li, Hualong Yu, Changzhen Wang
{"title":"Thermodynamic studies of La(FexAl1−x)13 alloys","authors":"Xiuguang Xu, Guangqiang Li, Hualong Yu, Changzhen Wang","doi":"10.1016/0022-5088(91)90012-S","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90012-S","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"1 1","pages":"271-278"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90215048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
On magnetic transitions in a novel compound, UPdGa 新型化合物UPdGa的磁跃迁
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90011-R
V. Tran, R. Troć
{"title":"On magnetic transitions in a novel compound, UPdGa","authors":"V. Tran, R. Troć","doi":"10.1016/0022-5088(91)90011-R","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90011-R","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"23 1","pages":"267-270"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85317454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Synthesis and crystal structure of MTe2O6 (M≡Ce, Th) MTe2O6 (M≡Ce, Th)的合成与晶体结构
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90008-R
M. López, M. Veiga, A. Jerez, C. Pico
{"title":"Synthesis and crystal structure of MTe2O6 (M≡Ce, Th)","authors":"M. López, M. Veiga, A. Jerez, C. Pico","doi":"10.1016/0022-5088(91)90008-R","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90008-R","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"31 1","pages":"235-241"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88371802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Influence of quenching rate and heat treatment on the magnetic properties and phase components of rapidly quenched Fe77.5Nd4B18.5 alloy 淬火速率和热处理对快速淬火Fe77.5Nd4B18.5合金磁性能和相成分的影响
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90004-N
Shen Bao-gen, Yang Lin-yuan, Zhang Jun-xian, Zhao Jian-gao
{"title":"Influence of quenching rate and heat treatment on the magnetic properties and phase components of rapidly quenched Fe77.5Nd4B18.5 alloy","authors":"Shen Bao-gen,&nbsp;Yang Lin-yuan,&nbsp;Zhang Jun-xian,&nbsp;Zhao Jian-gao","doi":"10.1016/0022-5088(91)90004-N","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90004-N","url":null,"abstract":"<div><p>The magnetic properties and phase components of rapidly quenched Fe<sub>77.5</sub>Nd<sub>4</sub>B<sub>18.5</sub> alloy as a function of quenching rate and heat treatment were studied. X-ray diffraction and thermomagnetic measurements show that the Fe<sub>77.5</sub>Nd<sub>4</sub>B<sub>18.5</sub> ingot consists of Nd<sub>2</sub>Fe<sub>14</sub>B, Fe<sub>2</sub>B and α-Fe. The X-ray diffraction patterns of optimally annealed samples show only metastable Fe<sub>3</sub>B phase which decomposes into Fe<sub>2</sub>B and α-Fe at <em>T</em><sub><em>a</em></sub> &gt; 850 °C, but the thermomagnetic curves show the presence of the Nd<sub>2</sub>Fe<sub>14</sub>B phase. In the sample annealed at 950 °C for 60 min, Nd<sub>1.1</sub>Fe<sub>4</sub>B<sub>4</sub> appears in coexistence with Nd<sub>2</sub>Fe<sub>14</sub>B, Fe<sub>2</sub>B and α-Fe. The Fe<sub>77.5</sub>Nd<sub>4</sub>B<sub>18.5</sub> alloy is found to have very good glass-forming ability. Samples prepared at quenching rates <em>v</em><sub><em>s</em></sub> ⩾ 6.6 m s<sup>−1</sup> are amorphous and magnetically soft. Annealing at about 650–670 °C gives the highest coercive field, which is nearly independent of quenching rate.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 199-204"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90004-N","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Synthesis, structure and properties of a new intermetallic compound, Ca7Ni4Sn13 新型金属间化合物Ca7Ni4Sn13的合成、结构与性质
Journal of The Less Common Metals Pub Date : 1991-10-01 DOI: 10.1016/0022-5088(91)90020-5
Deborah A Vennos, Michael E Badding, F.J DiSalvo
{"title":"Synthesis, structure and properties of a new intermetallic compound, Ca7Ni4Sn13","authors":"Deborah A Vennos,&nbsp;Michael E Badding,&nbsp;F.J DiSalvo","doi":"10.1016/0022-5088(91)90020-5","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90020-5","url":null,"abstract":"<div><p>Crystals of a new intermetallic compound, Ca<sub>7</sub>Ni<sub>4</sub>Sn<sub>13</sub>, have been prepared. The refined structure was solved in the <em>P</em>4/<em>m</em> space group, <em>Z</em> = 1 with lattice constants <span><math><mtext>a = 11.200(1) </mtext><mtext>A</mtext><mtext>̊</mtext></math></span> and <span><math><mtext>c = 4.594(1) </mtext><mtext>A</mtext><mtext>̊</mtext></math></span>, <em>R</em> = 2.8% and <em>R</em><sub><em>w</em></sub> = 2.4%. This new structure type consists of an Sn-Ni network forming channels parallel to the <em>c</em> axis which are filled with calcium atoms. Temperature-dependent magnetic and conductivity studies show Ca<sub>7</sub>Ni<sub>4</sub>Sn<sub>13</sub> to be Pauli paramagnetic with simple metallic behavior.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 339-346"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90020-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
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