{"title":"M10S14O-type oxysulphides (M La, Ce, Pr, Nd, Sm) as an “oxygen trap” in oxidation reactions of reduced lanthanide chlorides with sulphur","authors":"T. Schleid, F. Lissner","doi":"10.1016/0022-5088(91)90017-X","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90017-X","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"28 1","pages":"309-319"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90041068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study of SiC-whisker-reinforced ZrO2 ceramics using the sol-gel method","authors":"G. Tu, Z. Sui, Changzhen Wang","doi":"10.1016/0022-5088(91)90005-O","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90005-O","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"49 4 1","pages":"205-208"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77327154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Kinetic study of the hafnium-hydrogen reaction","authors":"Y Levitin, J Bloch, M.H Mintz","doi":"10.1016/0022-5088(91)90007-Q","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90007-Q","url":null,"abstract":"<div><p>The kinetics of hafnium hydride formation were studied utilizing conventional rate measurements (Sieverts system) combined with metallographic examinations of partially hydrided samples. The rate measurements were performed at 700 TorrH<sub>2</sub> over a temperature range 200–550 °C. Two types of hafnium samples (polycrystalline and crystal bar) were compared. The progression of the massive stage of the reaction is characterized by a contracting-envelope morphology with a constant hydride front velocity. The anisotropy in the reaction front velocity regarding different crystalline orientations of the metal is small, resulting in similar results for the different types of hafnium. The temperature dependence of the front velocity obeys an Arrhenius-type relation over the temperature range 250–450 °C, with an apparent activation energy of 0.50 ± 0.05 eV. Considering a diffusion-controlled model, a diffusion activation barrier of about 0.4 eV is evaluated, which agrees with the average reported value for the diffusion of hydrogen in hafnium hydride. At temperatures above about 500 °C, deviations from the Arrhenius relation are displayed, possibly owing to a change of mechanism.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 219-234"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90007-Q","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ferromagnetic materials: A handbook on the properties of magnetically ordered substances, vol. 5","authors":"Ch.J. Raub","doi":"10.1016/0022-5088(91)90024-X","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90024-X","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 369-370"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90024-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"SrHgO2: Ein oxomercurat mit delafossitstruktur","authors":"M Soll, Hk Müller-Buschbaum","doi":"10.1016/0022-5088(91)90015-V","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90015-V","url":null,"abstract":"<div><p>For the first time, single crystals of SrHgO<sub>2</sub> have been prepared by a high pressure oxidation technique. X-ray investigations indicate that the crystals have trigonal symmetry, space group <em>D</em><sub>3</sub><sup>6</sup>-<em>P</em>3<sub>2</sub>21 (no. 154), with <span><math><mtext>a = 3.833(3) </mtext><mtext>a</mtext><mtext>̊</mtext><mtext>A</mtext></math></span>, <span><math><mtext>c = 18.990(15) </mtext><mtext>A</mtext><mtext>̊</mtext></math></span> and <em>Z</em> = 3. <em>Hg</em><sup>2+</sup> has a coordination number of two, while Sr<sup>2+</sup> is surrounded by six oxygen ions. Two-dimensional layers of edge-linked SrO<sub>6</sub> octahedra are connected by O-Hg-O dumb-bells. SrHgO<sub>2</sub> belongs to the delafossite-type structure.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 295-299"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90015-V","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiuguang Xu, Guangqiang Li, Hualong Yu, Changzhen Wang
{"title":"Thermodynamic studies of La(FexAl1−x)13 alloys","authors":"Xiuguang Xu, Guangqiang Li, Hualong Yu, Changzhen Wang","doi":"10.1016/0022-5088(91)90012-S","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90012-S","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"1 1","pages":"271-278"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90215048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"On magnetic transitions in a novel compound, UPdGa","authors":"V. Tran, R. Troć","doi":"10.1016/0022-5088(91)90011-R","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90011-R","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"23 1","pages":"267-270"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85317454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and crystal structure of MTe2O6 (M≡Ce, Th)","authors":"M. López, M. Veiga, A. Jerez, C. Pico","doi":"10.1016/0022-5088(91)90008-R","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90008-R","url":null,"abstract":"","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"31 1","pages":"235-241"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88371802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shen Bao-gen, Yang Lin-yuan, Zhang Jun-xian, Zhao Jian-gao
{"title":"Influence of quenching rate and heat treatment on the magnetic properties and phase components of rapidly quenched Fe77.5Nd4B18.5 alloy","authors":"Shen Bao-gen, Yang Lin-yuan, Zhang Jun-xian, Zhao Jian-gao","doi":"10.1016/0022-5088(91)90004-N","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90004-N","url":null,"abstract":"<div><p>The magnetic properties and phase components of rapidly quenched Fe<sub>77.5</sub>Nd<sub>4</sub>B<sub>18.5</sub> alloy as a function of quenching rate and heat treatment were studied. X-ray diffraction and thermomagnetic measurements show that the Fe<sub>77.5</sub>Nd<sub>4</sub>B<sub>18.5</sub> ingot consists of Nd<sub>2</sub>Fe<sub>14</sub>B, Fe<sub>2</sub>B and α-Fe. The X-ray diffraction patterns of optimally annealed samples show only metastable Fe<sub>3</sub>B phase which decomposes into Fe<sub>2</sub>B and α-Fe at <em>T</em><sub><em>a</em></sub> > 850 °C, but the thermomagnetic curves show the presence of the Nd<sub>2</sub>Fe<sub>14</sub>B phase. In the sample annealed at 950 °C for 60 min, Nd<sub>1.1</sub>Fe<sub>4</sub>B<sub>4</sub> appears in coexistence with Nd<sub>2</sub>Fe<sub>14</sub>B, Fe<sub>2</sub>B and α-Fe. The Fe<sub>77.5</sub>Nd<sub>4</sub>B<sub>18.5</sub> alloy is found to have very good glass-forming ability. Samples prepared at quenching rates <em>v</em><sub><em>s</em></sub> ⩾ 6.6 m s<sup>−1</sup> are amorphous and magnetically soft. Annealing at about 650–670 °C gives the highest coercive field, which is nearly independent of quenching rate.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 199-204"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90004-N","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis, structure and properties of a new intermetallic compound, Ca7Ni4Sn13","authors":"Deborah A Vennos, Michael E Badding, F.J DiSalvo","doi":"10.1016/0022-5088(91)90020-5","DOIUrl":"https://doi.org/10.1016/0022-5088(91)90020-5","url":null,"abstract":"<div><p>Crystals of a new intermetallic compound, Ca<sub>7</sub>Ni<sub>4</sub>Sn<sub>13</sub>, have been prepared. The refined structure was solved in the <em>P</em>4/<em>m</em> space group, <em>Z</em> = 1 with lattice constants <span><math><mtext>a = 11.200(1) </mtext><mtext>A</mtext><mtext>̊</mtext></math></span> and <span><math><mtext>c = 4.594(1) </mtext><mtext>A</mtext><mtext>̊</mtext></math></span>, <em>R</em> = 2.8% and <em>R</em><sub><em>w</em></sub> = 2.4%. This new structure type consists of an Sn-Ni network forming channels parallel to the <em>c</em> axis which are filled with calcium atoms. Temperature-dependent magnetic and conductivity studies show Ca<sub>7</sub>Ni<sub>4</sub>Sn<sub>13</sub> to be Pauli paramagnetic with simple metallic behavior.</p></div>","PeriodicalId":17534,"journal":{"name":"Journal of The Less Common Metals","volume":"175 2","pages":"Pages 339-346"},"PeriodicalIF":0.0,"publicationDate":"1991-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-5088(91)90020-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"71754656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}