{"title":"Parameters influencing electrospun nanofiber diameter of polylactide incorporated with cellulose nanofibrils and nanocrystals","authors":"Burcu Sari, Cevdet Kaynak","doi":"10.1177/08927057241235650","DOIUrl":"https://doi.org/10.1177/08927057241235650","url":null,"abstract":"The main purpose of this study was to investigate effects of various electrospinning parameters on the morphology and diameter of cellulose nanofibril (CNF) filled polylactide (PLA) nanofibers. For this purpose, first of all effects of three important electrospinning parameters; polymer solution concentration, solution feeding rate and collector distance to feeding tip were studied. Then, effects of using higher amount of CNF, effects of using cellulose nanocrystal (CNC) particles, and effects of adding potassium chloride salt were also investigated. It was observed that when optimum electrospinning parameters were determined, then it was possible to obtain almost “bead-free” morphology and “finest” average diameter of 232 nm for PLA/CNF electrospun fibers. Increasing values of feeding rate and collector distance parameters resulted in bead formation and thicker diameters. On the other hand, increasing CNF amount, using CNC particles and adding KCl salt, all resulted in further decreases in the diameter down to 152 nm; mainly due to increased charge density of the polymer solution. Moreover, in vitro degradation analysis of all types of electrospun nanofiber mats in a simulated body fluid revealed that increasing the immersion period increased their degradation rate in terms of “% weight loss”. It was also observed that, mats with fine diameter fibers had higher degradation rate.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"24 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140008282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Eshetie Kassegn, Belete Sirhabizu, Temesgen Berhanu, Bart Buffel, Frederik Desplentere
{"title":"A study of the mechanical, thermal and rheological properties of sisal fiber-reinforced polylactic acid bio-composites with tributyl 2-acetylcitrate as a plasticizer","authors":"Eshetie Kassegn, Belete Sirhabizu, Temesgen Berhanu, Bart Buffel, Frederik Desplentere","doi":"10.1177/08927057241235649","DOIUrl":"https://doi.org/10.1177/08927057241235649","url":null,"abstract":"In this study, bio-composites were developed using polylactic acid (PLA) as the matrix and sisal fibers (SFs) derived from agave sisalana leaves as the reinforcement. The bio-composites were prepared through injection molding with the addition of tributyl 2-acetylcitrate (ATBC) plasticizer. The mechanical, thermal, and rheological properties of these bio-composites were investigated to understand the effects of fiber and plasticizer contents. The results showed that the addition of SFs improved the tensile and flexural moduli of the bio-composites but led to a decrease in tensile strength compared to neat PLA. The flexural strength initially decreased with low fiber content but recovered to the level of neat PLA as the fiber content increased. The impact strength increased with the incorporation of SFs and ATBC. However, the presence of ATBC had a negative impact on the tensile and flexural properties of the bio-composites. The thermal conductivity of the materials was influenced by the fiber content and processing temperature, increasing with SFs inclusion but decreasing with temperature. Differential scanning calorimetry analysis revealed increased crystallinity of PLA with the presence of SFs and ATBC. The specific heat capacity increased with ATBC but decreased with increasing SFs. Dynamic mechanical property testing showed variations in storage and loss moduli of the bio-composites at different temperatures. The storage modulus increased with higher fiber content and abruptly dropped around glass transition temperature. Rheological characterization demonstrated effective interactions between the fibers and matrix with good fiber dispersion, resulting in uniform shear viscosity versus shear rate for different capillary dimensions. The shear viscosity of the SFs/PLA mixture increased with increasing fiber content but decreased with the addition of plasticizer. Furthermore, the compounding and molding processes had a notable impact on the microstructure of the fibers, specifically resulting in fiber breakage and fiber separation during processing.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"36 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139977807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A study on the formation and failure mechanisms of CF/PPS-metal induction welding joints strengthened by micro-pins","authors":"Xuda Qin, Tian Yu, Shipeng Li, Guoyu Fu, Xianming Meng, Hao Li","doi":"10.1177/08927057241236140","DOIUrl":"https://doi.org/10.1177/08927057241236140","url":null,"abstract":"This study proposed a novel hybrid joining technique that combines through-thickness reinforcement (TTR) and induction welding methods to address the challenges of composite-metal joining. The effects of geometrical parameters of micro-pins on the formation and bearing performance of hybrid joints were investigated by combing the experimental and numerical simulation approaches. Two simulation models which included the induction heating transfer and joint tensile failure process were established by COMSOL Multiphysics and Abaqus/Explicit. Subsequently, digital image correlation (DIC) was used to monitor the deformation process of different types of joints under tensile load, and a scanning electron microscope (SEM) was used to observe the welding interface of failed joints. By comparing the experimental and simulation results, it is found that adding pins can significantly improve the mechanical performance of welded joints, with maximum increases of 159% and 1758% in ultimate strength and energy absorption respectively compared to welded joints without interlock structures. This technique presents a potential solution for achieving high-quality metal-composite welded structures.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"12 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139979319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chao Zhang, Keyi Liu, Fernando Cepero-Mejias, Jose L Curiel-Sosa, Chunjian Mao
{"title":"Numerical investigation on orthogonal cutting and damage response of CFRP/Ti6Al4V stacks","authors":"Chao Zhang, Keyi Liu, Fernando Cepero-Mejias, Jose L Curiel-Sosa, Chunjian Mao","doi":"10.1177/08927057241234877","DOIUrl":"https://doi.org/10.1177/08927057241234877","url":null,"abstract":"CFRP/Ti6Al4V stacks are widely employed in aerospace, automotive and marine applications owing to their superior properties. However, machining these stacked structures pose challenges due to the intrinsic difference in the mechanical properties of CFRP and Ti6Al4V. Such difference can induce distinct failure mechanisms and chip formation processes compared to those observed in individual materials. This paper presents an explicit finite element (FE) modeling to predict the cutting forces and analyze the induced damage during the orthogonal cutting process. The proposed FE model is validated using available experimental data for separate CFRP and Ti6Al4V conditions before being applied to simulate the cutting behavior of CFRP/Ti6Al4V stacks. The effects of fiber angles, cutting sequences and cutting parameters on the cutting performance and damage mechanism of CFRP/Ti6Al4V stacks are investigated in detail. This work provides insights into the cutting behavior of CFRP/Ti6Al4V stacks and facilitates the optimization of machining process for such composite system.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"36 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139948531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Nonlinear dynamical characteristics of carbon nanotube-reinforced composite beams with piezoelectric actuators and elastically restrained ends under thermo-electro-mechanical loads","authors":"Nguyen Van Thinh, Hoang Van Tung","doi":"10.1177/08927057241233187","DOIUrl":"https://doi.org/10.1177/08927057241233187","url":null,"abstract":"Nonlinear free vibration and dynamical responses of carbon nanotube (CNT) reinforced composite beams with surface-bonded piezoelectric layers and tangentially restrained ends under thermo-electro-mechanical loads are investigated in this paper. The properties of constitutive materials are assumed to be temperature-dependent and effective properties of nanocomposite are estimated using an extended rule of mixture. Unlike previous studies, the present work considers the effects of tangentially elastic constraints of two ends on the nonlinear dynamic characteristics of hybrid beams. Motion equation is established within the framework of Euler-Bernoulli beam theory taking into account von Kármán nonlinearity. Analytical solution is assumed to satisfy simply supported boundary conditions and Galerkin procedure is employed to obtain a time ordinary differential equation including both quadratic and cubic nonlinear terms. This differential equation is numerically solved employing fourth-order Runge-Kutta scheme to determine the frequencies of nonlinear free vibration and nonlinear transient response. Parametric studies are executed to examine numerous influences on the nonlinear dynamical characteristics of hybrid nanocomposite beams. The study reveals that tangential constraints of ends substantially effect the frequencies and dynamic response of the beam, especially at elevated temperatures. The results also indicate that nonlinear dynamic responses can be controlled effectively by means of piezoelectric actuators and elasticity of tangential constraints of ends should be considered in design of piezo-CNTRC beams.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"9 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139948533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Tribological performance analysis of sustainable basalt micro-filler loaded bio-based polypropylene and high density polyethylene composites","authors":"Praveenkumara Jagadeesh, Sanjay Mavinkere Rangappa, Suchart Siengchin","doi":"10.1177/08927057231223478","DOIUrl":"https://doi.org/10.1177/08927057231223478","url":null,"abstract":"The current research work involves the fabrication and tribological properties analysis of constant basalt filler reinforced (30 wt %) bio-based polypropylene (PP) and high density polyethylene (HDPE) thermoplastic composites. Compression molding technique is used after an internal mixing process in order to produce composite samples. The physical and hardness properties have been evaluated for both neat polymers and composite samples. In order to study the coefficient of friction (COF) and specific wear rate (SWR) of PP and HDPE composite samples, the Taguchi and Analysis of Variance (ANOVA) methodologies were applied. For PP samples, the optimum parameters in response to COF are found to be 0 wt% basalt (rank 3), 9 N load (rank 1), 200 r/min speed (rank 4), and 100 m distance (rank 2); for the SWR output, the optimum parameters are 30 wt% basalt (rank 1), 6 N load (rank 4), 100 r/min speed (rank 2), and 200 m distance (rank 3). For HDPE samples, the optimum parameters in response to COF are 0 wt% basalt (rank 1), 6 N load (rank 3), 100 r/min speed (rank 4), and 100 m distance (rank 2); for the SWR output, the optimum parameters are 30 wt% basalt (rank 1), 6 N load (rank 3), 100 r/min speed (rank 4), and 150 m distance (rank 2). Consistently, it has been shown that incorporating basalt fillers to PP and HDPE composites has more dramatically decreased SWR than COF. The depth of wear constantly rises according to increasing load, irrespective of the processing variables, as shown in 2D depth profiles. It is discovered that the confirmation tests carried out for the optimum parameters are within statistically acceptable bounds. The depth profile plots revealed that the worn track edges are found with polymer bumps because of deep grooves and softened polymer debris, which commonly observed more with HDPE samples due to low softening temperature. Moreover, the worn surfaces of the composites have plowed lines and cracks that are brought about by the micro-cutting and micro-plowing activity of the erosive asperities counterface. In addition to surface characteristics, the transfer films created during sliding also significantly influenced the mode of sample wear.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"52 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139948416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Dynamic characterization and damage analysis for the thermoplastic fiber-reinforced epoxy composites exposed to repeated low velocity impact","authors":"Betul Sozen, T. Coskun, Omer Sinan Sahin","doi":"10.1177/08927057231223927","DOIUrl":"https://doi.org/10.1177/08927057231223927","url":null,"abstract":"In the current study, contrary to conventional fiber-reinforced composites, polyamide fiber was used as reinforcement material, and the effects of thermoplastic fiber reinforcement on repeated low velocity impact (LVI) responses of composites were examined. In this regard, polyamide fiber-reinforced composites were fabricated using the vacuum-assisted hand lay-up method (VAHLM) and then exposed to repeated LVI loadings. Experimental tests were performed on the specimens for 100 impacts with a constant velocity of 3 m/s, which is equivalent to 25.2 J, and the impacts of repeated LVI loadings on the dynamic responses such as peak force, energy absorbing/rebounding, total impulse, bending stiffness and contact stiffness were examined. Moreover, the damage mechanisms resulting from the relative damage accumulation depending on the impact numbers were examined. According to the findings, the thermoplastic polyamide fibers absorbed more than 60% of the applied energy, and the absorbed energy increased with ascending impact number. Furthermore, the thermoplastic fiber-reinforced epoxy composites gained stiffness with increasing impact, which was linked to the thermoplastic chain structure. Despite quite a number of impact loadings, no serious damage mechanisms such as fiber breakage, perforation, or penetration were observed, and the specimens maintained their structural integrity. Due to the higher energy absorption of thermoplastics, the utilization of polyamide fibers in composites has been found to be well suited for applications subjected to repeated impacts.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"46 2","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138946446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Revolutionizing transportation composite structures: Lightweight, sustainable, and multi-scale hybrid design through waste tire-driven graphene, hemp fiber, and bio-based overmoulding","authors":"Nargiz Aliyeva, Hatice S. Şaş, Burcu Saner Okan","doi":"10.1177/08927057231222821","DOIUrl":"https://doi.org/10.1177/08927057231222821","url":null,"abstract":"The pursuit of lightweight, environmentally friendly composite structures in transportation is crucial for minimizing ecological footprints and promoting energy-efficient manufacturing techniques. This study presents a novel approach by replacing traditional long glass fiber reinforced homopolymer polypropylene (homoPP) compounds with short hemp fiber reinforced homoPP, incorporating graphene nanoplatelets (GNP) derived from recovered carbon black via waste tire pyrolysis, resulting in a remarkable 15% weight reduction. With new compound formulation by adjusting the amounts of compatibilizer and GNP, injection moulding process was integrated with overmoulding process by using bio-based UD prepregs to enhance the adhesion of injected part and interfacial interaction by decreasing the stress concentrations in the structure. This novel hybrid composite design having 40 wt% hemp fiber, 1.0 wt% GNP and 2.7 wt% compatibilizer provided to improve flexural modulus and strength by 169% and 67.9%, respectively, compared to neat homoPP. The overmolding process employed bio-based natural fibers reinforced UD tapes as inserts, leading to an impressive enhancement of 211% in tensile modulus and 93.6% in strength, further surpassing the performance of neat homoPP. This work not only achieves the conversion of conventional composite structures into recyclable, sustainable thermoplastic composites but also introduces multi-scale reinforcements with customizable functionality, demonstrating a significant step forward in the development of environmentally conscious materials and manufacturing methods by adopting Life-Cycle Assessment (LCA) methodology regarding the sustainability of the newly developed composites.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"124 12","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138958964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fracture morphology and strength characteristics of poly-lactic acid and poly-ethylene terephthalate glycol composites combined with taguchi method and response surface methodology","authors":"Akash Jain, Ankit Sahai, R. Sharma","doi":"10.1177/08927057231221749","DOIUrl":"https://doi.org/10.1177/08927057231221749","url":null,"abstract":"The emergence of additive manufacturing has enabled scientists to efficiently construct complex geometries, facilitating the development of novel, high-impact energy-absorbing structures suitable for a wide range of industrial applications. The present study conducted flexural and impact test to quantitatively assess the energy absorption capabilities of polymer composites fabricated through fused filament fabrication. Specifically, the polymer composites investigated were multi-walled carbon nanotubes reinforced poly-lactic acid, carbon fibre reinforced poly-ethylene terephthalate glycol, and carbon fibre reinforced poly-lactic acid. The investigation also examined the influence of different infill patterns and nozzle hole diameters on the polymer composites. The investigation depicts that by altering the process parameters, the flexural strength is improved from 21.079 MPa to 70.653 MPa by 235.18%. The experimental study of impact specimens utilising the Izod impact test demonstrates that the rectilinear infill pattern and a nozzle hole diameter of 0.6 mm result in the highest energy absorption of 37.76 kJ/m2 for carbon fibre reinforced poly-lactic acid. The study revealed that the energy absorption of the specimens was significantly influenced by both the independent and interaction effects of process variables. The application of the fused filament fabrication demonstrates an improved energy absorption, making it suitable for manufacturing of vehicle and aircraft components.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"35 5","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138997658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review on the influence of various metal oxide nanoparticles on structural, morphological, optical, thermal and electrical properties of PVA/PVP blends","authors":"K. Meera, M. T. Ramesan","doi":"10.1177/08927057231222833","DOIUrl":"https://doi.org/10.1177/08927057231222833","url":null,"abstract":"Biopolymer blend based nanocomposites have been interestingly investigated by researchers to achieve advanced composite functional materials that are environmentally amicable. Among the varieties of biopolymers, widespread attention has been given to polyvinyl alcohol (PVA) and polyvinyl pyrrolidone (PVP) owing to their interesting properties like water solubility, biodegradability, biocompatibility and non-toxicity. PVA and PVP form a completely miscible blend at all compositions as both the polymers are rich in a variety of functional groups that permit effective intermolecular interactions between the polymers as well as with filler. PVA/PVP blend exhibits excellent dopant sensitive properties also. Metal oxide nanoparticles (MONPs) have made a prominent place in the area of scientific and technological research due to their unique chemical and physical properties. Doping with MONPs enhances the properties of the PVA/PVP blend matrix and the resulting PVA/PVP/MONP polymer nanocomposites are suitable for multifunctional purposes. This review mainly focused on the influence of various MONPs such as ZnO, CuO, Al2O3, ZrO2, MnO, SnO, MgO, TiO2, etc. in the structural, morphological, thermal, optical and electrical properties of PVA/PVP blend as well as its applications in various fields.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"25 2","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138999803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}