Journal of The European Ceramic Society最新文献_第2页

Efficient protection of metal interconnect in fuel electrode atmosphere for direct methanol solid oxide fuel cells via La0.2Sr0.8TiO3-δ coating La0.2Sr0.8TiO3-δ涂层对直接甲醇固体氧化物燃料电池燃料电极气氛中金属互连的有效保护

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-27 DOI: 10.1016/j.jeurceramsoc.2025.117853

Xiangchen Wu , Jun Yang , Wu Liu , Liangzhu Zhu , Yang Zhang , Beibei Han , Maorong Chai , Wanbing Guan , Junkang Sang

{"title":"Efficient protection of metal interconnect in fuel electrode atmosphere for direct methanol solid oxide fuel cells via La0.2Sr0.8TiO3-δ coating","authors":"Xiangchen Wu , Jun Yang , Wu Liu , Liangzhu Zhu , Yang Zhang , Beibei Han , Maorong Chai , Wanbing Guan , Junkang Sang","doi":"10.1016/j.jeurceramsoc.2025.117853","DOIUrl":"10.1016/j.jeurceramsoc.2025.117853","url":null,"abstract":"<div><div>Metallic interconnects in direct methanol solid oxide fuel cells (SOFCs) are prone to being oxidized during operation, leading to electrical degradation and compromising the overall performance of the stack. The oxidation behavior of SUS441 stainless steel and the protective effect of a La<sub>0.2</sub>Sr<sub>0.8</sub>TiO<sub>3-δ</sub> (LST) coating were investigated under a methanol-steam atmosphere at 750°C, relevant to anode atmosphere. LST coatings, synthesized via solid-state reaction and was applied by screen printing. After 1000 h oxidation, coated SUS441 formed only a ≈ 4.8 μm thick oxide scale, compared to ≈ 11.6 μm on uncoated steel. The area-specific resistance increased moderately (9.67–16.36 mΩ·cm²), significantly lower than uncoated samples (216.46 mΩ·cm²). The oxidation rate constant decreased by an order of magnitude. These results highlight the efficiency of LST coating in enhancing oxidation resistance and electrical stability. Furthermore, the details about protective mechanisms of LST coating are illustrated.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 3","pages":"Article 117853"},"PeriodicalIF":6.2,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Perspectives on oxynitride glasses: Transparency, compositions, redox, composites, crystallization, and applications 氮化氧玻璃的展望：透明度、成分、氧化还原、复合材料、结晶和应用

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-25 DOI: 10.1016/j.jeurceramsoc.2025.117848

Alexis Duval , Patrick Houizot , Tanguy Rouxel

引用次数: 0

Synergistic multi-ion doping in BaTiO₃-based ceramics: Achieving high electrocaloric efficiency and wide temperature span for miniaturized cooling application BaTiO₃基陶瓷中的协同多离子掺杂：实现高热效率和宽温度范围，用于小型化冷却应用

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-24 DOI: 10.1016/j.jeurceramsoc.2025.117852

Ying Zheng , Yifei Liang , Huanhuan Li , Quan Li , Yan Yan , Hua Tan , Haibo Zhang , Shenglin Jiang , Gang Liu

{"title":"Synergistic multi-ion doping in BaTiO₃-based ceramics: Achieving high electrocaloric efficiency and wide temperature span for miniaturized cooling application","authors":"Ying Zheng , Yifei Liang , Huanhuan Li , Quan Li , Yan Yan , Hua Tan , Haibo Zhang , Shenglin Jiang , Gang Liu","doi":"10.1016/j.jeurceramsoc.2025.117852","DOIUrl":"10.1016/j.jeurceramsoc.2025.117852","url":null,"abstract":"<div><div>Electrocaloric cooling, a solid-state refrigeration technology utilizing the electrocaloric effect (ECE), enables miniaturized cooling systems. However, its practical application is constrained by limited adiabatic temperature change (Δ<em>T</em>), restricted operating temperature span (<em>T</em><sub>span</sub>), and the fact that peak performance typically occurs at elevated temperatures. To overcome this, (1-x)Ba₀.₇₆Sr₀.₂₄TiO₃-xCa(Ti₀.₉Sn₀.₁)O₃ (BST-CS) lead-free ferroelectric ceramics were synthesized via solid-state reaction, enhancing Δ<em>T</em> and <em>T</em><sub>span</sub> through multi-ion doping. XRD and Raman spectroscopy confirmed tetragonal (T) and pseudo-cubic (PC) phase coexistence, with the PC phase increasing with doping. Temperature-dependent Raman and dielectric spectra revealed a tetragonal-cubic transition near the Curie temperature, contributing to the ECE. The optimized composition (<em>x</em> = 0.14) achieved Δ<em>T</em> = 1.74 K and <em>T</em><sub>span</sub>= 52 K (40–90°C, Δ<em>T</em> ≥ 80 % of Δ<em>T</em><sub>max</sub>) under 50 kV·cm<sup>−1</sup>. Phase coexistence lowers polarization barriers, while grain refinement improves breakdown strength. This work advances eco-friendly microelectronics cooling by balancing performance and practicality.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117852"},"PeriodicalIF":6.2,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Achieving ultrahigh piezoelectric performance and superior temperature stability in 0.35Pb(Ni1/3Nb2/3)O3-x(Pb0.92Ba0.04Sr0.04)ZrO3-(0.65-x)(Pb0.92Ba0.04Sr0.04)TiO3 ceramics through high-temperature poling 通过高温极化，获得了0.35Pb(Ni1/3Nb2/3)O3-x(Pb0.92Ba0.04Sr0.04)ZrO3-(0.65-x)(Pb0.92Ba0.04Sr0.04)TiO3陶瓷的超高压电性能和优异的温度稳定性

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-24 DOI: 10.1016/j.jeurceramsoc.2025.117849

Mingze Sun , Weiye Nie , Lang Bian , Wenwu Cao

{"title":"Achieving ultrahigh piezoelectric performance and superior temperature stability in 0.35Pb(Ni1/3Nb2/3)O3-x(Pb0.92Ba0.04Sr0.04)ZrO3-(0.65-x)(Pb0.92Ba0.04Sr0.04)TiO3 ceramics through high-temperature poling","authors":"Mingze Sun , Weiye Nie , Lang Bian , Wenwu Cao","doi":"10.1016/j.jeurceramsoc.2025.117849","DOIUrl":"10.1016/j.jeurceramsoc.2025.117849","url":null,"abstract":"<div><div>The attainable piezoelectric properties of ferroelectric ceramics depend on the degree of poling, in which domain reorientation occurred to align all polarizations. Conventional poling cannot fully pole the ceramic due to the strain generated during the non-180° domain reorientation. The 0.35Pb(Ni<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>-<em>x</em>(Pb<sub>0.92</sub>Ba<sub>0.04</sub>Sr<sub>0.04</sub>)ZrO<sub>3</sub>-(0.65-<em>x</em>)(Pb<sub>0.92</sub>Ba<sub>0.04</sub>Sr<sub>0.04</sub>)TiO<sub>3</sub> piezoceramic with <em>x</em> = 0.26 demonstrates remarkable piezoelectric performance when subjected to high-temperature poling at 150°C under 1 kV/mm, achieving an ultra-high piezoelectric coefficient <em>d</em><sub>33</sub> of 1280 pC/N, along with remnant polarization <em>P</em><sub>r</sub> of 25.4 μC/cm<sup>2</sup>. Notably, the obtained <em>d</em><sub>33</sub> value exhibits a 31.4 % enhancement compared to traditional poled samples (<em>d</em><sub>33</sub> = 974 pC/N, <em>P</em><sub>r</sub> = 24.2 μC/cm<sup>2</sup>, <em>ε</em><sub>r</sub> = 5641). For the <em>x</em> = 0.24 sample, high-temperature poling can simultaneously achieve very large piezoelectric coefficient (<em>d</em><sub>33</sub> = 983 pC/N) and high temperature stability (Δ<em>d</em><sub>33</sub>/<em>d</em><sub>33-RT</sub> = 4.88 % up to 65 °C). The enhancement mechanism of high-temperature poling is due to the formation of much smaller domains.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117849"},"PeriodicalIF":6.2,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

UV-activated seed strategy for promoting textured colossal grain growth in templated ceramic processing 紫外光激活种子策略促进陶瓷模板加工中有织构的巨粒生长

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-24 DOI: 10.1016/j.jeurceramsoc.2025.117851

Dong-Gyu Lee , Seung Hyeon Kong , Yi-Yeon Kim , Seung-Bum Kim , Iman M. Imani , Hyun Soo Kim , Jeong Min Baik , Heemin Kang , Sahn Nahm , Sunghoon Hur , Yongke Yan , Sangtae Kim , Kyung-Hoon Cho , Hyun-Cheol Song

{"title":"UV-activated seed strategy for promoting textured colossal grain growth in templated ceramic processing","authors":"Dong-Gyu Lee , Seung Hyeon Kong , Yi-Yeon Kim , Seung-Bum Kim , Iman M. Imani , Hyun Soo Kim , Jeong Min Baik , Heemin Kang , Sahn Nahm , Sunghoon Hur , Yongke Yan , Sangtae Kim , Kyung-Hoon Cho , Hyun-Cheol Song","doi":"10.1016/j.jeurceramsoc.2025.117851","DOIUrl":"10.1016/j.jeurceramsoc.2025.117851","url":null,"abstract":"<div><div>Templated Grain Growth (TGG) is a method of growing a matrix using crystallographically oriented seeds, allowing the manipulation of growth behavior by controlling their interfaces. We explore the surface treatment of seeds to enhance the piezoelectric properties of ceramics, focusing on 0.675Pb(Mg1/3Nb2/3)O<sub>3</sub>-0.325PbTiO<sub>3</sub> (PMN-32.5PT) and BaTiO<sub>3</sub> (BT) seeds. Employing Ultra-Violet (UV) light treatment on BT seeds promotes grain growth around them, a method termed UV-TGG. Notably, this technique leads to substantial grain enlargement and an increase in the piezoelectric constant, all achieved without altering the composition of the seed or matrix materials. When using UV-TGG, there was a 140 % improvement in the <em>d</em><sub>33</sub>×<em>g</em><sub>33</sub> value, which was 33.2 pm<sup>2</sup>/N compared to the conventional TGG's value of 23.7 pm<sup>2</sup>/N. The UV-TGG introduces an easy way to elevate ceramic performance and facilitate material design without altering composition.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 3","pages":"Article 117851"},"PeriodicalIF":6.2,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Eu2+ co-doped MgAl2O4: Mn2+ green phosphor ceramics: Anti-thermal quenching emission via trap engineering strategy Eu2+共掺杂MgAl2O4: Mn2+绿色荧光粉陶瓷：陷阱工程策略抗热猝灭发射

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-23 DOI: 10.1016/j.jeurceramsoc.2025.117838

Junwei Zhang, Hui Lin, Shuo Zhu, Yuetong Zhen, Ruijin Hong, Zhaoxia Han, Dawei Zhang

{"title":"Eu2+ co-doped MgAl2O4: Mn2+ green phosphor ceramics: Anti-thermal quenching emission via trap engineering strategy","authors":"Junwei Zhang, Hui Lin, Shuo Zhu, Yuetong Zhen, Ruijin Hong, Zhaoxia Han, Dawei Zhang","doi":"10.1016/j.jeurceramsoc.2025.117838","DOIUrl":"10.1016/j.jeurceramsoc.2025.117838","url":null,"abstract":"<div><div>The rapid advancement of high-power solid-state lighting highlights the importance of developing phosphor ceramics with high resistance to thermal quenching of its luminescence. Herein, a series of Eu<sup>2+</sup> co-doping MgAl<sub>2</sub>O<sub>4</sub>: Mn<sup>2+</sup> phosphor ceramics were synthesized by spark plasma sintering. The significant green light enhancement at 516 nm is attributed to Eu<sup>2+</sup>-Mn<sup>2+</sup> energy transfer. The introduction of Eu<sup>2+</sup> increases the concentration of electron trap levels and improve the luminescence intensity at 423 K from 80 % to 110 %, compared with the counterparts at room temperature. The strong correlation between trap levels and oxygen vacancies was demonstrated by the X-ray photoelectron spectroscopy and electron paramagnetic resonance analysis. Finally, the application demonstration of the optimized sample was explored through its integration with a 400 nm LED chip. This study proposes a strategy of leveraging trap levels to induce anti-thermal quenching behavior, providing some insights for the development of highly thermally stable phosphor ceramics.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 3","pages":"Article 117838"},"PeriodicalIF":6.2,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Molten CMAS resistance of PS-PVD (Gd0.2Y0.8)3Al5O12 /YSZ thermal barrier coating with high adherence PS-PVD (Gd0.2Y0.8)3Al5O12 /YSZ热障涂层耐熔融CMAS性能的研究

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-23 DOI: 10.1016/j.jeurceramsoc.2025.117846

Xingya Zhu , Wenting He , Yiqian Guo , Liangliang Wei , Dongrui Liu , Hongbo Guo , Hui Peng

{"title":"Molten CMAS resistance of PS-PVD (Gd0.2Y0.8)3Al5O12 /YSZ thermal barrier coating with high adherence","authors":"Xingya Zhu , Wenting He , Yiqian Guo , Liangliang Wei , Dongrui Liu , Hongbo Guo , Hui Peng","doi":"10.1016/j.jeurceramsoc.2025.117846","DOIUrl":"10.1016/j.jeurceramsoc.2025.117846","url":null,"abstract":"<div><div>Calcium-magnesium-alumina-silicate (CMAS) deposits significantly accelerate the degradation of thermal barrier coatings (TBCs) in advanced aeroengines, thereby posing a substantial threat to aviation safety. In this study, (Gd<sub>0.2</sub>Y<sub>0.8</sub>)<sub>3</sub>Al<sub>5</sub>O<sub>12</sub> (GYAG)/YSZ double-ceramic-layer thermal barrier coatings (TBCs), comprising dense GYAG on top and columnar YSZ beneath, were fabricated via plasma spray-physical vapor deposition (PS-PVD) in a single-step process to mitigate CMAS attack. High-temperature exposure tests at 1250 °C demonstrated the excellent phase stability of GYAG coating and interface stability of GYAG/YSZ coating. The interactions between CMAS and GYAG/YSZ coatings were investigated. Results showed that CMAS melt infiltration was suppressed. GYAG coating reacted rapidly with CMAS to crystallize apatite, garnet and anorthite phases with high-melting-point. These crystalline phases are alternatively distributed and collectively inhibit CMAS infiltration. The doping of Gd in GYAG coating facilitated precipitation of apatite, which is crucial for CMAS resistance enhancement.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117846"},"PeriodicalIF":6.2,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, microstructures, and aqueous chemical durability of high-entropy pyrochlore ceramic Eu2B2O7 (BTi, Zr, Sn, Hf, Nb, and Ce) for nuclear waste immobilization 用于核废料固定化的高熵焦绿陶瓷Eu2B2O7 （BTi, Zr, Sn, Hf， Nb和Ce）的合成、微观结构和水化学耐久性

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-23 DOI: 10.1016/j.jeurceramsoc.2025.117844

Zhuangzhuang Ma , Yunhao Wang , Tianhao Rui , Yulin Lan , Linyuan Lu , Yang Yu , Mingxuan Deng , Tianxing Lan , Zhekang Zhao , Zhen Teng , Haibin Zhang

{"title":"Synthesis, microstructures, and aqueous chemical durability of high-entropy pyrochlore ceramic Eu2B2O7 (BTi, Zr, Sn, Hf, Nb, and Ce) for nuclear waste immobilization","authors":"Zhuangzhuang Ma , Yunhao Wang , Tianhao Rui , Yulin Lan , Linyuan Lu , Yang Yu , Mingxuan Deng , Tianxing Lan , Zhekang Zhao , Zhen Teng , Haibin Zhang","doi":"10.1016/j.jeurceramsoc.2025.117844","DOIUrl":"10.1016/j.jeurceramsoc.2025.117844","url":null,"abstract":"<div><div>High-entropy pyrochlore ceramics with the nominal composition Eu<sub>2</sub>B<sub>2</sub>O<sub>7</sub>, incorporating up to five equiatomic B-site cations, were synthesized via a solid-state reaction method and evaluated their aqueous chemical durability for nuclear waste immobilization. Comprehensive characterization using XRD, Raman, and SEM analyses confirmed the formation of a single-phase pyrochlore structure with uniform and random elemental distribution. However, secondary phases were observed in the Ce- and Nb-doped samples, which is attributed to the larger ionic radius of Ce and the higher valence state of Nb. The 42 days leaching tests revealed normalized element release rates ranging from 10<sup>−5</sup> to 10<sup>−7</sup> g/(m<sup>2</sup>∙d), significantly lower than those of conventional pyrochlore materials. This enhanced durability is attributed to synergistic effects of electronegativity, ionic radius, and atomic number, which together hinder cation diffusion and strengthen chemical durability at the B site. These findings demonstrate the potential of Eu<sub>2</sub>B<sub>2</sub>O<sub>7</sub> high-entropy pyrochlore ceramics as long-term host materials for high-level radioactive waste. This study provides a valuable resource for enriching the thermophysical properties database of B-site high-entropy pyrochlore solidification, thereby supporting their engineering development.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117844"},"PeriodicalIF":6.2,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tunable nanostructures of SiHfBCN hierarchical porous ceramics with high strength and well-defined ductility 具有高强度和良好延展性的SiHfBCN分层多孔陶瓷的可调纳米结构

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-22 DOI: 10.1016/j.jeurceramsoc.2025.117843

Xiyue Zhu, Xingang Luan, Xinming Xu, Fang Ye, Laifei Cheng

{"title":"Tunable nanostructures of SiHfBCN hierarchical porous ceramics with high strength and well-defined ductility","authors":"Xiyue Zhu, Xingang Luan, Xinming Xu, Fang Ye, Laifei Cheng","doi":"10.1016/j.jeurceramsoc.2025.117843","DOIUrl":"10.1016/j.jeurceramsoc.2025.117843","url":null,"abstract":"<div><div>This paper presents a rapid and versatile fabrication process using the self-assembly of block copolymers to create both SiCN and SiHfBCN hierarchical porous ceramics. The multifarious three-dimensional micellar networks of gels, adjusted through regulating preceramic polymer content, can facilitate the production of nanotemplated preceramic polymers, and tunable nanostructure and porosity. The resulted ceramics feature interconnected nanoscale ceramic pillars. The synergistic effect of the nanostructures with low defect potential and the flexural mechanism of ceramic strut networks with high aspect ratio, endows the SiHfBCN hierarchical porous ceramics with exceptional mechanical properties. These include compressive strength of up to ∼262 MPa, ∼10 % recoverable strain, and high energy absorption (%<sub>P</sub>: ∼39 %). Moreover, they demonstrate excellent thermal stability and enhanced compressive strength (up to ∼363 MPa) following annealing at 1200 °C. These remarkable properties make the ceramics ideal for applications requiring high-temperature resistance, thermal insulation, energy absorption, and more, in extreme conditions.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117843"},"PeriodicalIF":6.2,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145155153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ag-toughened glass-ceramic coatings with excellent oxidation and spallation resistance under thermal shock at 700 °C ag增韧玻璃陶瓷涂层，在700°C的热冲击下具有优异的抗氧化和抗剥落性能

IF 6.2 2区材料科学

Journal of The European Ceramic Society Pub Date : 2025-09-20 DOI: 10.1016/j.jeurceramsoc.2025.117841

Kang Wang , Zhilin Zhang , Jiayong Jiang , Zehao Chen , Shasha Yang , Xingyao Wang , Hao Yin , Minghui Chen , Fuhui Wang

{"title":"Ag-toughened glass-ceramic coatings with excellent oxidation and spallation resistance under thermal shock at 700 °C","authors":"Kang Wang , Zhilin Zhang , Jiayong Jiang , Zehao Chen , Shasha Yang , Xingyao Wang , Hao Yin , Minghui Chen , Fuhui Wang","doi":"10.1016/j.jeurceramsoc.2025.117841","DOIUrl":"10.1016/j.jeurceramsoc.2025.117841","url":null,"abstract":"<div><div>Glass-ceramics, known for their thermal stability and strong adhesion to metal substrates, are widely used as protective coatings for high-temperature application. But they usually suffered from inherent brittleness and high susceptibility to cracking. Traditional approaches to improve fracture toughness <em>via</em> incorporation of metal particles have often failed due to the ongoing reactions between the particles and the corrosive media. In this study, thermal shock resistance was significantly enhanced by doping oxidation-resistant soft metal particles, specifically Ag. The interface crystallization increases bonding strength, ensures complete plastic deformation of Ag particles under thermal stress, thereby enhancing fracture toughness and preventing matrix cracking. After 100 thermal shock cycles at 700 °C, the Ag-doped glass-ceramic coating exhibited superior performance, with high oxidation resistance, no crack initiation and a minimal mass loss of 0.04 mg/cm². This approach addresses the brittleness challenge of glass-ceramics, while fully utilizing the advantage of oxidation resistance.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 3","pages":"Article 117841"},"PeriodicalIF":6.2,"publicationDate":"2025-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0