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Journal of Synthetic Organic Chemistry Japan最新文献

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Reductive Cleavage of C-O and C-N Bonds by Homogeneous Transition-Metal Catalysis 均相过渡金属催化C-O和C-N键的还原裂解
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2025-11-01 DOI: 10.5059/yukigoseikyokaishi.83.1006
Yumeng Liao, Kohei Takahashi, Kyoko Nozaki
{"title":"Reductive Cleavage of C-O and C-N Bonds by Homogeneous Transition-Metal Catalysis","authors":"Yumeng Liao, Kohei Takahashi, Kyoko Nozaki","doi":"10.5059/yukigoseikyokaishi.83.1006","DOIUrl":"https://doi.org/10.5059/yukigoseikyokaishi.83.1006","url":null,"abstract":"The selective cleavage of carbon-oxygen (C-O) and carbon-nitrogen (C-N) bonds remains a fundamental transformation in organic synthesis, offering a versatile platform for constructing new chemical bonds. In particular, homogeneous transition metal catalysis has enabled highly selective reductive cleavage of ethereal C-O bonds under mild conditions, providing new strategies for both small molecule functionalisation and polymer degradation. Meanwhile, recent advances have extended this approach to more challenging C-N bonds. This review highlights recent advances in the development of homogeneous catalysis for the reductive cleavage of C-O and C-N bonds alongside their mechanistic insights. Additionally, emerging applications in the valorisation of polymers such as lignin and epoxy resins highlight the broader impact of reductive cleavage of C-O bonds.","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"83 11","pages":"1006-1013"},"PeriodicalIF":0.0,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.jstage.jst.go.jp/article/yukigoseikyokaishi/83/11/83_1006/_pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147894427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Easy Access to Phenanthrenes Through Photoinduced Difunctionalization of Alkynes 通过光诱导炔烃双官能化制备菲
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2025-01-01 DOI: 10.6023/cjoc202407009
Mengqian Li, Zhe Lv, Shaojun Wang, Yuxuan Han, Xiuling Cui
{"title":"Easy Access to Phenanthrenes Through Photoinduced Difunctionalization of Alkynes","authors":"Mengqian Li, Zhe Lv, Shaojun Wang, Yuxuan Han, Xiuling Cui","doi":"10.6023/cjoc202407009","DOIUrl":"https://doi.org/10.6023/cjoc202407009","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"45 2","pages":"686-686"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147890969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Synthesis of the Reducing End Fuc-Agl Fragment of Saccharomicins 糖酵素还原端Fuc-Agl片段的合成
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2025-01-01 DOI: 10.6023/cjoc202409041
Dengxian Fu, Shiwei Xu, Lingkui Meng, Qian Wan, Jing Zeng
{"title":"Synthesis of the Reducing End Fuc-Agl Fragment of Saccharomicins","authors":"Dengxian Fu, Shiwei Xu, Lingkui Meng, Qian Wan, Jing Zeng","doi":"10.6023/cjoc202409041","DOIUrl":"https://doi.org/10.6023/cjoc202409041","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"45 3","pages":"945-945"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147915982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
One-Pot Transition-Metal-Free Synthesis of Carboline Derivatives via Dual C—N Bond Formation 通过双C-N键形成一锅无过渡金属合成羰基衍生物
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2025-01-01 DOI: 10.6023/cjoc202505007
Guiling Xie, Sudhakar Reddy Mopuri, Jie Jack Li, Yuanyong Yang, Tie-Gen Chen
{"title":"One-Pot Transition-Metal-Free Synthesis of Carboline Derivatives via Dual C—N Bond Formation","authors":"Guiling Xie, Sudhakar Reddy Mopuri, Jie Jack Li, Yuanyong Yang, Tie-Gen Chen","doi":"10.6023/cjoc202505007","DOIUrl":"https://doi.org/10.6023/cjoc202505007","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"45 10","pages":"3824-3824"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147919114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaporation-Processed X-Ray Imaging Scintillation Screen Based on Copper Clusters 基于铜簇的蒸发处理x射线成像闪烁屏
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2025-01-01 DOI: 10.6023/cjoc202503007
Gaozhan Xie, Cheng Chen, Jingru Zhang, Dongjie Xiao, Minyue Cai, Qiya Gao, Zhisheng Gao, Chengxi Sun, Hui Li, Huanhuan Li, Runfeng Chen, Tao Ye
{"title":"Evaporation-Processed X-Ray Imaging Scintillation Screen Based on Copper Clusters","authors":"Gaozhan Xie, Cheng Chen, Jingru Zhang, Dongjie Xiao, Minyue Cai, Qiya Gao, Zhisheng Gao, Chengxi Sun, Hui Li, Huanhuan Li, Runfeng Chen, Tao Ye","doi":"10.6023/cjoc202503007","DOIUrl":"https://doi.org/10.6023/cjoc202503007","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"45 11","pages":"4219-4219"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147904698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Cerium Doped Zirconium-Based Metal-Organic Framework Nanoparticles and Their Photocatalytic Performance for Carbon Dioxide Cycloaddition 铈掺杂锆基金属-有机骨架纳米颗粒的合成及其对二氧化碳环加成的光催化性能
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2024-01-01 DOI: 10.6023/cjoc202405044
Yingzhe Zhao, Zixuan Zhang, Jianling Zhang, Renjie Zhang, Meiling Li, Yunan Teng, Haoxiang Wang
{"title":"Synthesis of Cerium Doped Zirconium-Based Metal-Organic Framework Nanoparticles and Their Photocatalytic Performance for Carbon Dioxide Cycloaddition","authors":"Yingzhe Zhao, Zixuan Zhang, Jianling Zhang, Renjie Zhang, Meiling Li, Yunan Teng, Haoxiang Wang","doi":"10.6023/cjoc202405044","DOIUrl":"https://doi.org/10.6023/cjoc202405044","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"44 10","pages":"3169-3169"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147908049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Study on Synthesis, Pyrolysis and Antioxidation of Ethyl Maltol Succinate Diester 麦芽糖醇丁二酸乙酯的合成、热解及抗氧化研究
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2024-01-01 DOI: 10.6023/cjoc202311011
Zhaojin Yu, Zhan Zhang, Haiyang Wang, Bo Wang, Guangming Fu, Ying Zhang, Xiaopeng Yang, Aijun Dong, Xiaoming Ji
{"title":"Study on Synthesis, Pyrolysis and Antioxidation of Ethyl Maltol Succinate Diester","authors":"Zhaojin Yu, Zhan Zhang, Haiyang Wang, Bo Wang, Guangming Fu, Ying Zhang, Xiaopeng Yang, Aijun Dong, Xiaoming Ji","doi":"10.6023/cjoc202311011","DOIUrl":"https://doi.org/10.6023/cjoc202311011","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"44 5","pages":"1526-1526"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sioc-journal.cn/Jwk_yjhx/EN/article/downloadArticleFile.do?attachType=PDF&id=350626","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147890509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Synthesis and Anti-neuroinflammatory Activities of 25-Hydroxycholesterol and Its Analogues 25-羟基胆固醇及其类似物的合成及其抗神经炎活性
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2024-01-01 DOI: 10.6023/cjoc202312002
Liusong Lan, Qian Yang, Yongyi Li, Shu-Jun Fang, Yuxuan Huang, Jun‐Cheng Su, Cheng‐Xue Pan, Guifa Su
{"title":"Synthesis and Anti-neuroinflammatory Activities of 25-Hydroxycholesterol and Its Analogues","authors":"Liusong Lan, Qian Yang, Yongyi Li, Shu-Jun Fang, Yuxuan Huang, Jun‐Cheng Su, Cheng‐Xue Pan, Guifa Su","doi":"10.6023/cjoc202312002","DOIUrl":"https://doi.org/10.6023/cjoc202312002","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"44 7","pages":"2305-2305"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147908458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Design, Synthesis and Biological Activity Studies of 2-(1,3-Dioxoiso-indolin-2-yl)-N-phenethylacetamide and 2-(3,4-Dihydroisoquinolin-1-yl)isoindole-1,3-dione as Monoamine Oxidase (MAO) and Cholinesterase (ChE) Inhibitors 2-（1,3-二氧异喹啉-2-基）- n-苯乙酰胺和2-（3,4-二氢异喹啉-1-基）异吲哚-1,3-二酮作为单胺氧化酶（MAO）和胆碱酯酶（ChE）抑制剂的设计、合成及生物活性研究
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2024-01-01 DOI: 10.6023/cjoc202311027
Yi-Ming Hu, Jiayu Xu, Min Tang, Yawen Liu, Liping Guan, Qinghao Jin
{"title":"Design, Synthesis and Biological Activity Studies of 2-(1,3-Dioxoiso-indolin-2-yl)-N-phenethylacetamide and 2-(3,4-Dihydroisoquinolin-1-yl)isoindole-1,3-dione as Monoamine Oxidase (MAO) and Cholinesterase (ChE) Inhibitors","authors":"Yi-Ming Hu, Jiayu Xu, Min Tang, Yawen Liu, Liping Guan, Qinghao Jin","doi":"10.6023/cjoc202311027","DOIUrl":"https://doi.org/10.6023/cjoc202311027","url":null,"abstract":"","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"44 6","pages":"1907-1907"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147883138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Transition Metal-Free Selective Aerobic Olefination of Methyl N-Heteroarenes with Alcohols 甲基n -杂芳烃与醇的无过渡金属选择性好氧烯烃反应
4区 化学
Journal of Synthetic Organic Chemistry Japan Pub Date : 2024-01-01 DOI: 10.6023/cjoc202308011
Jie Liu, Feng Han, Shuangyan Li, Tianyu Chen, Jianhui Chen, Qing Xu
{"title":"Transition Metal-Free Selective Aerobic Olefination of Methyl <i>N</i>-Heteroarenes with Alcohols","authors":"Jie Liu, Feng Han, Shuangyan Li, Tianyu Chen, Jianhui Chen, Qing Xu","doi":"10.6023/cjoc202308011","DOIUrl":"https://doi.org/10.6023/cjoc202308011","url":null,"abstract":"By performing the reactions in the presence of adequate amount of air and a suitable base, selective olefination of methyl N-heteroarenes with alcohols can be effectively achieved without using any external catalyst. Control experiments revealed that, with adequate air, base can promote the aerobic oxidation of alcohols almost completely to carbonyl intermediates, which then condense with the methyl N-heteroarenes to afford the alkenyl N-heteroarene products. As the reaction is performed with adequate amount of air and a lower loading of the base at a lower temperature than that of the alkylation reaction, the generated alkenyl N-heteroarenes cannot be transfer hydrogenated to the alkylated products by the remained small amount of alcohol in the reaction mixture, which leads to a high selectivity of the olefination reaction. This method is thus a practical way for preparation of the alkenyl N-heteroarenes, being a complementary method to previous transition metal-free C-alkylation reaction of methyl N-heteroarenes with alcohols in the presence of small amount of air.","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"44 2","pages":"573-573"},"PeriodicalIF":0.0,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://sioc-journal.cn/Jwk_yjhx/EN/article/downloadArticleFile.do?attachType=PDF&id=350488","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147895618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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