Indonesian Journal of Material Research最新文献

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Synthesis and Characterization of Ni/Al Layered Double Hydroxides Composite Based-Material with Chitosan, Cellulose, and Graphene Oxide 基于壳聚糖、纤维素和氧化石墨烯的镍/铝层状双氢氧化物复合材料的合成与表征
Indonesian Journal of Material Research Pub Date : 2024-03-26 DOI: 10.26554/ijmr.20242125
Amri Amri, Zaqiya Artha Zahara, P. M. S. B. Siregar, Zulkarnain Zulkarnain, A. Wijaya
{"title":"Synthesis and Characterization of Ni/Al Layered Double Hydroxides Composite Based-Material with Chitosan, Cellulose, and Graphene Oxide","authors":"Amri Amri, Zaqiya Artha Zahara, P. M. S. B. Siregar, Zulkarnain Zulkarnain, A. Wijaya","doi":"10.26554/ijmr.20242125","DOIUrl":"https://doi.org/10.26554/ijmr.20242125","url":null,"abstract":"In this study, the synthesis of composite materials produced from Ni/Al with three types of carbon-based materials namely chitosan (Ch), cellulose (Ce), and graphene oxide (GO) was successfully carried out supported by X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), and Brunauer-Emmett-Teller (BET) analysis. The combined characteristics of the two starting materials are present in the composite material based on XRD and FT-IR data. The surface area of Ni/Al-LDH increased after compositing with Ch, Ce, and GO, from 3.3 m2/g to 9.5 m2/g in Ni/Al-Ch, 5.1 m2/g in Ni/Al-Ce, and 78.4 m2/g in Ni/Al-GO. These findings indicate that the materials are suitable for various applications such as photocatalytic and adsorption as effective materials in further research.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"105 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140380706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Effect of Titanium Nanostructure on Corrosion Resistance as Dental Implants: A Review 钛纳米结构对牙科植入物耐腐蚀性的影响:综述
Indonesian Journal of Material Research Pub Date : 2024-03-26 DOI: 10.26554/ijmr.20242121
Fadhli Muhammad, Shintia Novia Sari, B. Dilasari
{"title":"The Effect of Titanium Nanostructure on Corrosion Resistance as Dental Implants: A Review","authors":"Fadhli Muhammad, Shintia Novia Sari, B. Dilasari","doi":"10.26554/ijmr.20242121","DOIUrl":"https://doi.org/10.26554/ijmr.20242121","url":null,"abstract":"Titanium is widely recognized as the most biocompatible metal due to the inert passive oxide layer that forms spontaneously on its surface. However, dental implants made of titanium and its alloys remain susceptible to corrosion when exposed to saliva for extended periods in the oral environment. Additionally, the presence of alloying elements in the alloy may raise concerns about potential toxicity concerns upon release into the human body. Consequently, there is an increasing need for research aimed at improving the mechanical properties and biocompatibility of dental implants made from both commercially pure titanium (CP Ti) and Ti alloys. This article provides a review of recent publications that investigate the impact of grain size reduction on ultrafine-grained and nanocrystalline CP Ti and Ti alloys. The article explores the modification of the oxide layer to nanotube TiO2 and its influence on corrosion resistance. The analysis of accumulated data provides a comprehensive understanding of the mechanisms underlying corrosion resistance improvement, offering valuable insights into the crucial directions for future research in this field.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"123 27","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140379711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selectivity Adsorption of Anionic Dyes by Macroalgae E. cottonii 大型藻类棉花藻对阴离子染料的选择性吸附
Indonesian Journal of Material Research Pub Date : 2024-03-26 DOI: 10.26554/ijmr.20242123
Bunga Indah Putri
{"title":"Selectivity Adsorption of Anionic Dyes by Macroalgae E. cottonii","authors":"Bunga Indah Putri","doi":"10.26554/ijmr.20242123","DOIUrl":"https://doi.org/10.26554/ijmr.20242123","url":null,"abstract":"The selectivity analysis of anionic dye adsorption by E. cottonii macroalgae has been successfully conducted in this study. Selectivity analysis encompassed congo red, direct yellow, methyl orange, and direct green dyes with measurements taken at 0, 2, 4, 6, 8, and 10-minute intervals. The dye concentration was standardized at 50 g/mL, and 20 mL of each dye solution was utilized. Variations in absorbance were assessed using a UV-Vis Spectrophotometer, revealing that E. cottonii exhibited the highest selectivity for methyl orange. Characterization through FT-IR indicated the presence of O-H, C-H aliphatic, C=N, C=C, C-O, and N-H bonds in the dried E. cottonii macroalgae material. These results affirm the superior selectivity of E. cottonii in adsorbing methyl orange, as demonstrated by the selectivity test.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"103 44","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140380640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Comparative Analysis of Compressive and Flexural Strength in Concrete with Partial Cement Replacement using Waste Glass Powder 使用废玻璃粉替代部分水泥的混凝土抗压和抗折强度对比分析
Indonesian Journal of Material Research Pub Date : 2024-03-26 DOI: 10.26554/ijmr.20242120
Hedayat Ullah Safi, Mohammad Mukhlis Behsoodi, Mohammad Naseer Sharifi
{"title":"A Comparative Analysis of Compressive and Flexural Strength in Concrete with Partial Cement Replacement using Waste Glass Powder","authors":"Hedayat Ullah Safi, Mohammad Mukhlis Behsoodi, Mohammad Naseer Sharifi","doi":"10.26554/ijmr.20242120","DOIUrl":"https://doi.org/10.26554/ijmr.20242120","url":null,"abstract":"This experimental inquiry delves into the evaluation of compressive and flexural strengths in concrete through the utilization of waste glass powder as a partial substitute for cement. Compressive strength is a key metric, indicating the concrete’s ability to effectively support structural axial loads, while flexural strength signifies its capacity to withstand deformation under bending, specifically the maximum tensile stress it can endure without fracturing when subjected to a bending moment. Certain pozzolanic materials have demonstrated the ability to enhance the mechanical strength of concrete when used as a cement replacement, and waste glass powder is among them. To address this, the experimental investigation included the substitution of cement with glass powder at different proportions (0%, 10%, 15%, 17.5%, and 20%) in both cubic and prismatic samples. Compressive strength and flexural strength tests were made following the curing of the samples for 7, 14, and 28 days. The findings indicated that the 17.5% cement replacement level exhibited a 6.07% over-strength for compressive strength and a 6.85% over-strength for flexural strength on the 28th day. However, the 15% replacement showed superior strength compared to a 10% replacement, and the 10% replacement was stronger than a 0% cement replacement. Notably, the 20% cement replacement displayed negative over-strength percentages, specifically -2.42% in compressive strength and -1.42% in flexural strength on the 28th day. This deviation raises concerns about its suitability for use in concrete applications, signifying that a 20% replacement may not be recommended.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"108 23","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140380573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selective Adsorption of Cationic and Anionic Dyes using Ni/Al Layered DoubleHydroxide Modified withEucheuma cottonii 用桉树棉改性的 Ni/Al 层状双氢氧化物选择性吸附阳离子和阴离子染料
Indonesian Journal of Material Research Pub Date : 2024-03-26 DOI: 10.26554/ijmr.20242118
Sahrul Wibiyan, I. Royani, A. Lesbani
{"title":"Selective Adsorption of Cationic and Anionic Dyes using Ni/Al Layered DoubleHydroxide Modified withEucheuma cottonii","authors":"Sahrul Wibiyan, I. Royani, A. Lesbani","doi":"10.26554/ijmr.20242118","DOIUrl":"https://doi.org/10.26554/ijmr.20242118","url":null,"abstract":"This study investigates the selective adsorption capabilities of Ni/Al Layered Double Hydroxide (LDH) modified withEucheumacottoniifor the removal of cationic and anionic dyes from aqueous solutions. The primary objective was to evaluate the efficiencyand selectivity of these modified adsorbents towards different dyes, including rhodamine-b, malachite green, methylene blue(cationic dyes), and direct yellow, methyl orange, direct green (anionic dyes). The modification process aimed to enhancethe adsorption properties of LDHs, leveraging the natural adsorption capabilities ofEucheuma cottonii. Experimental resultsdemonstrated significant differences in adsorption percentages among the tested dyes, with malachite green showing thehighest adsorption efficiency among cationic dyes, indicating a strong affinity of the modified adsorbents towards cationic dyes.However, the ability to also adsorb anionic dyes suggests the dual-functionality of the modified LDHs, making them versatileagents for dye removal in water treatment applications.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"82 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140377878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reusable Heterogeneous Catalyst (M2+)Al-Layered Double Hydroxide used for Oxidative Desulfurization of 4,6-Dimethyldibenzothiophene 用于 4,6-二甲基二苯并噻吩氧化脱硫的可重复使用异质催化剂(M2+)铝层双氢氧化物
Indonesian Journal of Material Research Pub Date : 2023-11-29 DOI: 10.26554/ijmr.20231315
N. Ahmad, Sahrul Wibiyan, I. Royani, R. Mohadi, A. Lesbani
{"title":"Reusable Heterogeneous Catalyst (M2+)Al-Layered Double Hydroxide used for Oxidative Desulfurization of 4,6-Dimethyldibenzothiophene","authors":"N. Ahmad, Sahrul Wibiyan, I. Royani, R. Mohadi, A. Lesbani","doi":"10.26554/ijmr.20231315","DOIUrl":"https://doi.org/10.26554/ijmr.20231315","url":null,"abstract":"Catalyst material (M2+)Al-LDH was successfully prepared in this study. Characterisation analysis by XRD and FTIR. XRD analysis of Zn/Al-LDH, Mg/Al-LDH and Ni/Al-LDH showed agreement with pure LDH as seen from the JCPDS data and showed crystal forms similar to hydrotalcite, brucite and hydrotalcite respectively. FTIR analysis of the (M2+)Al-LDH material showed the presence of functional groups which explain the presence of O-H stretching, O-H bending, CO32- bonds and identified metal oxide (MO) groups from the synthesised LDH. (M2+)Al-LDH has the ability to act as a catalyst for excellent desulphurisation of 4,6-dimethyldibencothiophene with % conversion value above 90%. In addition, (M2+)Al-LDH is a heterogeneous and reusable catalyst.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"44 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139212919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Enhancement of The Surface Properties of 316, 304 Stainless Steel by Coating ZnO Films by PLD Method 利用 PLD 方法镀氧化锌薄膜提高 316、304 不锈钢的表面性能
Indonesian Journal of Material Research Pub Date : 2023-11-29 DOI: 10.26554/ijmr.20231314
Sarah A. Jasim, A. A. Habeeb, A. Kadhim
{"title":"The Enhancement of The Surface Properties of 316, 304 Stainless Steel by Coating ZnO Films by PLD Method","authors":"Sarah A. Jasim, A. A. Habeeb, A. Kadhim","doi":"10.26554/ijmr.20231314","DOIUrl":"https://doi.org/10.26554/ijmr.20231314","url":null,"abstract":"This study employed two alloys of AISI (316,304) Stainless steel to improve the mechanical characteristics. In addition, the corrosion rate achieved by pulse laser deposition (PLD) can be reduced by applying a ZnO coating. Zinc oxide has garnered significant interest. Biomaterials have long been well-acknowledged for their use in dentistry and medical applications. Using an optical microscope examined the coating morphology, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS). The corrosion protection has been examined by assessing the mechanical characteristics when submerged in saliva with a pH of 5.6. The surface alteration is assessed using roughness and microhardness measurements. The corrosion resistance of all samples is superior to that of bare AISI (316,304) stainless steel.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139211647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Structure, and Hirshfeld Surface Analysis of tetrakis(N,N’-diethylthiourea)bis(isothiocyanato)nickel 四(N,N'-二乙基硫脲)双(异硫氰基)镍的合成、结构和 Hirshfeld 表面分析
Indonesian Journal of Material Research Pub Date : 2023-11-29 DOI: 10.26554/ijmr.20231313
H. W. Wijaya, Danar Danar, Zainal Abiddin
{"title":"Synthesis, Structure, and Hirshfeld Surface Analysis of tetrakis(N,N’-diethylthiourea)bis(isothiocyanato)nickel","authors":"H. W. Wijaya, Danar Danar, Zainal Abiddin","doi":"10.26554/ijmr.20231313","DOIUrl":"https://doi.org/10.26554/ijmr.20231313","url":null,"abstract":"The complex compound tetrakis(N,N’-diethylthiourea)bis(isothiocyanato)nickel or [Ni(detu)4(NCS)2] (denoted as UMCC-1) has been synthesized by reflux method in two different solvents namely acetone and methanol. This study aims to synthesize, characterize, and analyze the Hirshfeld Surface complex UMCC-1, which was obtained using the reflux method with the mole ratio of NiCl2: detu: KSCN is 1:2:4. Single crystals UMCC-1 in acetone and methanol are dark green in color with melting points of 135-137°C and conductivity of 66.4-84.4 µS. The FTIR absorption band analysis of the two crystals is very similar, ν(C S) detu 590 cm−1 and ν(C≡N) isothiocyanate 2119 cm−1. The refinement of the crystal structure from the single crystal XRD data shows that the two dark green crystals are a molecular type that has a distorted octahedral geometry with the same crystal lattice, monoclinic crystal lattice, P21/c1 space group (no.14), crystal lattice parameter a= 11.112(3) Å, b= 17.249(5) Å, c= 9.647(3) Å, and β= 100.785(10). However, the complex produced in acetone solvent has better refinement quality than methanol concerning %R= 3.27 and %R = 4.55, respectively. The UMCC-1 crystal shows intermolecular hydrogen bonds N-H---S(isothiocyanato) and intramolecular hydrogen bonds N-H---S(detu) with Hirshfeld Surface analysis showing a significant contribution of H---H (69.5%) on crystal packing.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139214428","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ca/Al and Mg/Al LDH Supported on Biochars As Effective Adsorbent and Highly Regeneration Ability for Phenol Removal from Aqueous Solution 以生物螯合剂为支撑的 Ca/Al 和 Mg/Al LDH 可作为有效的吸附剂,并具有很强的再生能力,用于从水溶液中去除苯酚
Indonesian Journal of Material Research Pub Date : 2023-11-29 DOI: 10.26554/ijmr.20231316
Erni Salasia Fitri, Try Nanda Yunita, R. Mohadi, A. Lesbani
{"title":"Ca/Al and Mg/Al LDH Supported on Biochars As Effective Adsorbent and Highly Regeneration Ability for Phenol Removal from Aqueous Solution","authors":"Erni Salasia Fitri, Try Nanda Yunita, R. Mohadi, A. Lesbani","doi":"10.26554/ijmr.20231316","DOIUrl":"https://doi.org/10.26554/ijmr.20231316","url":null,"abstract":"This research conducted a composite of Ca/Al and Mg/Al Layered double hydroxide with Biochar material using co-precipitation method. Characterization results were carried out with various analyses including XRD, FT-IR, and BET. The results of XRD analysis on Ca/Al-BC showed peaks at 10-11° and 22°, while the Mg/Al-BC material showed peaks at 11. 41° (003), 22. 95° (002), 34. 05° (012) and 60.2° (116). The FT-IR analysis showed that Ca/Al and Mg/Al LDH materials composited with Biochar have functional groups of -OH, nitrate ions, C=O, C-H, C-O, and M-O. BET analysis results show an increase in surface area in Ca/Al and Mg/Al LDH materials after composite with biochar from 29.333 m2/g to 158.291 m2/g in Mg/Al-BC, while in Mg/Al-BC there is an increase from 23.150 m2/g to 111.404 m2/g. The Ca/Al-BC and Mg/Al-BC composite materials have better stability than Ca/Al and Mg/Al LDH materials that can be used up to the fifth cycle. Hydrogen bonding and π-π interaction between the adsorbent and the aromatic ring on phenol can affect the adsorption process.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139210591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Layered Double Hydroxide Coated by Carbon-Based Material for Environmental Dye Pollutant 碳基材料包覆的层状双氢氧化物用于环境染料污染物的研究
Indonesian Journal of Material Research Pub Date : 2023-11-29 DOI: 10.26554/ijmr.20231311
N. Palapa, A. Wijaya
{"title":"Layered Double Hydroxide Coated by Carbon-Based Material for Environmental Dye Pollutant","authors":"N. Palapa, A. Wijaya","doi":"10.26554/ijmr.20231311","DOIUrl":"https://doi.org/10.26554/ijmr.20231311","url":null,"abstract":"We conducted this research to modify NiAl layered double hydroxide with several carbon-based materials, including cellulose, biochar and graphite. This material was successfully prepared by coprecipitation methods and was proven by XRD, SEM and FTIR characterization. Furthermore, we conducted the adsorption process and reusability to investigate their ability as water treatments. The dose effect on M.G. removal was investigated by the highest M.G. removal capacity using the CBC-NiAl LDHs composite, which was 100 mg. M.G. removal capacity was increased with an increase in contact time, and the saturation point was reached after 60 min for CC-NiAl and CGF-NiAl LDHs, which CBC-NiAl LDH increased and saturated after 100 min with high adsorption capacity. CC-NiAl, CBC-NiAl and CGF-NiAl LDHs composite have proved efficient, sustainable materials that maintain adsorption capability in each reusable cycle.","PeriodicalId":170983,"journal":{"name":"Indonesian Journal of Material Research","volume":"25 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139212154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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