Journal of Polymer Science最新文献_第8页

Current Trends and Future Prospects of Integrating Electrospinning With 3D Printing Techniques for Mimicking Bone Extracellular Matrix Scaffolds 结合静电纺丝与3D打印技术模拟骨细胞外基质支架的现状与展望

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-02-02 DOI: 10.1002/pol.20241010

Kardo Khalid Abdullah, Kolos Molnár

{"title":"Current Trends and Future Prospects of Integrating Electrospinning With 3D Printing Techniques for Mimicking Bone Extracellular Matrix Scaffolds","authors":"Kardo Khalid Abdullah, Kolos Molnár","doi":"10.1002/pol.20241010","DOIUrl":"https://doi.org/10.1002/pol.20241010","url":null,"abstract":"This article presents a review of the recent findings on the combination of electrospun nanofibers and three-dimensional (3D)-printed structures for extracellular matrix (ECM) scaffolds for bone tissue engineering. We explore the synergy between electrospinning (ES), which produces highly porous, fibrous structures from materials like collagen and gelatin, and 3D printing, which allow precise scaffold design using biopolymers. We discuss the selection of appropriate biopolymers based on their mechanical properties, biocompatibility, and biodegradability, as well as the key functions of ECM structures in cell attachment, migration, and differentiation. We analyze the strengths and limitations of each technique, noting that while ES enhances cellular adhesion and proliferation, it struggles with complex geometries and scalability. In contrast, 3D printing provides strong structural support but faces challenges with resolution and biomaterial compatibility. Our review focuses on the innovative integration of these methods, aiming to merge ES's microstructural precision with 3D printing's structural strength. We evaluate various hybrid combination methods, including sequential and coaxial techniques, and discuss potential solutions to challenges related to ECM scaffold quality, production time, and scalability. Furthermore, we highlight recent discoveries and propose future research directions to enhance further mimicking the ECM scaffold of bone.","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1481-1504"},"PeriodicalIF":3.9,"publicationDate":"2025-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pol.20241010","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of NiO Nanofiller on P(VdC-Co-AN) With PEG Polymer Blend Electrolyte for Energy Storage Applications 纳米填料NiO对聚乙二醇共混电解质P（VdC-Co-AN）储能性能的影响

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-02-02 DOI: 10.1002/pol.20241029

B. Vijaya, M. Usha Rani

{"title":"Effect of NiO Nanofiller on P(VdC-Co-AN) With PEG Polymer Blend Electrolyte for Energy Storage Applications","authors":"B. Vijaya, M. Usha Rani","doi":"10.1002/pol.20241029","DOIUrl":"https://doi.org/10.1002/pol.20241029","url":null,"abstract":"<div>\u0000 \u0000 Solid-state polymer electrolytes with safety and high energy density are promising novel options for energy storage devices. Nevertheless, the low ionic conductivity and limited mobility of lithium ions at room temperature have significantly impeded their practical application. A flexible composite polymer electrolyte was fabricated using a solution casting method. This electrolyte consisted of a polymer blend of poly (vinylidene chloride-co-acrylonitrile) (PVdC-co-AN) and polyethylene glycol (PEG), incorporated with lithium perchlorate (LiClO4) as salt, propylene carbonate (PC) as plasticizer, and nickel oxide (NiO) nanoparticles as filler. The electrolyte is prepared by the various concentrations of NiO nanoparticles (Nps) (0, 5, 10, 15, and 20 wt.%). The prepared NiO is confirmed by the XRD analysis, and the incorporation of NiO in the polymer blend also determined. The polymer salt plasticizer and filler interactions are confirmed by the FTIR analysis. At room temperature, the sample containing 15% of NiO has a high ionic conductivity value of up to 10−3 S cm−1. The electrochemical and also thermal stability of this electrolyte is achieved at 4.8 V and 312°C. The mechanical stability is enhanced up to 29 MPa. The remarkable performance enhancement is attributed to the incorporation of NiO, which facilitated improved ionic conductivity, mechanical properties, and compatibility for energy storage applications.\u0000 </div>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1466-1480"},"PeriodicalIF":3.9,"publicationDate":"2025-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advancing Green and Sustainable Approaches: Investigating the Impact of Carbohydrates on Silica-Filled Natural Rubber Composites 推进绿色和可持续的方法：研究碳水化合物对二氧化硅填充天然橡胶复合材料的影响

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-29 DOI: 10.1002/pol.20241137

Abhijit Bera, Bharat Manna, Amit Ghosh, Samik Nanda, Santanu Chattopadhyay

{"title":"Advancing Green and Sustainable Approaches: Investigating the Impact of Carbohydrates on Silica-Filled Natural Rubber Composites","authors":"Abhijit Bera, Bharat Manna, Amit Ghosh, Samik Nanda, Santanu Chattopadhyay","doi":"10.1002/pol.20241137","DOIUrl":"https://doi.org/10.1002/pol.20241137","url":null,"abstract":"<div>\u0000 \u0000 Reducing rolling resistance in heavy-vehicle tyres, such as those used in trucks and buses, is crucial for lowering fuel consumption. Incorporating maximum silica filler into naturally derived elastomers, particularly cis-1,4-polyisoprene (CPI), presents a significant opportunity for the tyre industry to produce environmentally friendly and sustainable tyres with a reduced carbon footprint. However, achieving uniform dispersion of silica filler in CPI is challenging because of the disruption of silanization reactions by non-rubber substances, primarily proteins and phospholipids, present in CPI. This study explores the introduction of various cost-effective carbohydrates (i.e., Arabinose, Sucrose, Sorbitol, and Xylose) into the CPI matrix at different silica filler loadings to mitigate interference during silanization. Among these, the polyol group sugar alcohol, sorbitol, notably enhanced silica dispersion within the CPI matrix. The inclusion of sorbitol not only minimized rolling resistance but also improved processing behavior and significantly enhanced mechanical properties. The use of bio-based sugar alcohols in tyre production holds promise for advancing the development of eco-friendly and sustainable tyres. Molecular dynamics simulations of CPI with these carbohydrates and silica filler demonstrate minimal structural deviation in CPI and maximum network formation, particularly with sorbitol. The findings also confirm strong interactions between CPI's non-rubber components and the OH/CHO groups of the carbohydrates.\u0000 </div>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1453-1465"},"PeriodicalIF":3.9,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Multifunctional Waterproof Hydrogels Based on Copper Sulfide Nanoparticles for Burn Wound Healing 基于硫化铜纳米颗粒的多功能防水水凝胶用于烧伤创面愈合

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-28 DOI: 10.1002/pol.20241135

Jie Wu, Lei Dai, Limei Zhao, Shufan Wan, Yiyun Jiang, Bin Zou, Jiangtao Su, Hongmei Sun

{"title":"Multifunctional Waterproof Hydrogels Based on Copper Sulfide Nanoparticles for Burn Wound Healing","authors":"Jie Wu, Lei Dai, Limei Zhao, Shufan Wan, Yiyun Jiang, Bin Zou, Jiangtao Su, Hongmei Sun","doi":"10.1002/pol.20241135","DOIUrl":"https://doi.org/10.1002/pol.20241135","url":null,"abstract":"<div>\u0000 \u0000 Burn wounds care and healing are very difficult in clinic. Herein, a multifunctional waterproof hydrogel was fabricated with photothermal antimicrobial and NO anti-inflammatory properties. In the as-prepared hydrogel, polyethyleneimine (PEI) and thioctic acid (TA) were cross-linked by electrostatic interactions and hydrogen bonding while the aggregation of TA could be favor to the formation of hydrophobic caves. Benefit from the caves, CuS and BNN6 (N, N′-dibutyl-N, N′-dinitroso-1,4-phenylenediamine) could be incorporated in the PEI/TA-based hydrogel while the air permeability of the hydrogel could also be increased. Interestingly, the mild increased temperature from the photothermal conversion of CuS not only endowed the as-prepared hydrogel with photothermal antimicrobial ability but also promoted the release of NO from BNN6. The as-prepared PEI/TA/CuS/BNN6 hydrogel with good biocompatibility, self-healing ability and water resistance was suitable for promoting burn wounds healing. It provides a new platform for designing novel wound dressing for burn wounds.\u0000 </div>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1441-1452"},"PeriodicalIF":3.9,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Universal Phase Identification of Block Copolymers From Physics-Informed Machine Learning 基于物理信息的机器学习的嵌段共聚物的通用相识别

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-25 DOI: 10.1002/pol.20241063

Xinyi Fang, Elizabeth A. Murphy, Phillip A. Kohl, Youli Li, Craig J. Hawker, Christopher M. Bates, Mengyang Gu

{"title":"Universal Phase Identification of Block Copolymers From Physics-Informed Machine Learning","authors":"Xinyi Fang, Elizabeth A. Murphy, Phillip A. Kohl, Youli Li, Craig J. Hawker, Christopher M. Bates, Mengyang Gu","doi":"10.1002/pol.20241063","DOIUrl":"https://doi.org/10.1002/pol.20241063","url":null,"abstract":"Block copolymers play a vital role in materials science due to their diverse self-assembly behavior. Traditionally, exploring the block copolymer self-assembly and associated structure–property relationships involve iterative synthesis, characterization, and theory, which is labor-intensive both experimentally and computationally. Here, we introduce a versatile, high-throughput workflow toward materials discovery that integrates controlled polymerization and automated chromatographic separation with a novel physics-informed machine-learning algorithm for the rapid analysis of small-angle X-ray scattering data. Leveraging the expansive and high-quality experimental data sets generated by fractionating polymers using automated chromatography, this machine-learning method effectively reduces data dimensionality by extracting chemical-independent features from SAXS data. This new approach allows for the rapid and accurate prediction of morphologies without repetitive and time-consuming manual analysis, achieving out-of-sample predictive accuracy of around 95% for both novel and existing materials in the training data set. By focusing on a subset of samples with large predictive uncertainty, only a small fraction of the samples needs to be inspected to further improve accuracy. Collectively, the synergistic combination of controlled synthesis, automated chromatography, and data-driven analysis creates a powerful workflow that markedly expedites the discovery of structure–property relationships in advanced soft materials.","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1433-1440"},"PeriodicalIF":3.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pol.20241063","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

One-Step Synthesis of Multi-Block Copolymers of Isotactic Polypropylene (iPP) and Theoretical Studies on the Regioselectivity and Stereoselectivity of Polypropylene 一步法合成等规聚丙烯（iPP）多嵌段共聚物及其区域选择性和立体选择性的理论研究

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-25 DOI: 10.1002/pol.20240738

Xingyue Zhao, Han Li, Jingjiao Liu, Kefeng Wang, Shaomeng Zhang, Tongtong Dou, Jiayong Li, Jicheng Yu, Hongming Li, Jing Wang, Chaojie Gai, Shangtao Chen, Shuanhong Li, Qigu Huang

{"title":"One-Step Synthesis of Multi-Block Copolymers of Isotactic Polypropylene (iPP) and Theoretical Studies on the Regioselectivity and Stereoselectivity of Polypropylene","authors":"Xingyue Zhao, Han Li, Jingjiao Liu, Kefeng Wang, Shaomeng Zhang, Tongtong Dou, Jiayong Li, Jicheng Yu, Hongming Li, Jing Wang, Chaojie Gai, Shangtao Chen, Shuanhong Li, Qigu Huang","doi":"10.1002/pol.20240738","DOIUrl":"https://doi.org/10.1002/pol.20240738","url":null,"abstract":"<div>\u0000 \u0000 For multi-block copolymers, using a one-step synthesis route can avoid repeating addition of monomers during the reaction, thereby preventing the contamination of polymerization reaction and the accidental termination of the polymer chain. For this purpose, described herein is a simple and efficient approach for synthesizing topological structure multi-block copolymers of isotactic polypropylene by copolymerizing ethylene, propylene and higher α-olefins by [N, Si, N, P] multi-chelated complexes ({P(C6H5)2-N(C6H5)-(CH3)2Si-N-2,4,6-(F)3C6H2}ZrCl3). In this contribution, the complexes are found to exhibit high polymerization activity (up to 9.5 × 106gP (mol ∙ Zr)−1 ∙ h−1) and relatively high incorporation content of 1-octene (up to 15 mol%). Density functional theory (DFT) was used to study the mechanism of copolymerization reaction. The results showed that propylene monomer is more prone to 1,2-insertion in kinetics to obtain iPP. Different lengths of iPP segments in the copolymer (terpolymer) chain not only led to different melting points but also block the terpolymer of propylene, ethylene and higher α-olefins. Enhancing α-olefins and ethylene units within the copolymer chain will also destroy the layered polypropylene crystals. Furthermore, the crystallizable polyethylene segment was not observed, implying that ethylene only participates in forming the random segments in the copolymer chains. Most importantly, polypropylene thermoplastic elastomer with good elasticity can be produced by the copolymerization of propylene with ethylene and 1-octene.\u0000 </div>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1407-1418"},"PeriodicalIF":3.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cationic-Hydrophilic Di-Block Copolymers: Surface-Shielded Vectors for Gene Delivery 阳离子亲水性二嵌段共聚物：基因传递的表面屏蔽载体

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-25 DOI: 10.1002/pol.20240970

Eliška Hrdá, Ladislav Androvič, Marcela Filipová, Michal Pechar, Richard Laga

{"title":"Cationic-Hydrophilic Di-Block Copolymers: Surface-Shielded Vectors for Gene Delivery","authors":"Eliška Hrdá, Ladislav Androvič, Marcela Filipová, Michal Pechar, Richard Laga","doi":"10.1002/pol.20240970","DOIUrl":"https://doi.org/10.1002/pol.20240970","url":null,"abstract":"To tackle the main challenges in gene therapy, synthetic polycationic vectors are developed for nucleic acid (NA) delivery. In this work, vectors based on di-block copolymers consisting of a methacrylate-type cationic block and an electroneutral hydrophilic block are designed and synthesized to condense NA into compact particles shielded with a bioinert hydrophilic polymer layer. The results confirm that the cationic vector blocks, containing permanently charged trimethylammonium (TMA) or tributylphosphonium (TBP) groups and 0–20 mol% hydrophobic butyl groups, are able to efficiently complex DNA to form 100 to 200 nm spheroids, while the hydrophilic blocks based on 2-methacryloyloxyethylphosphorylcholine or N-(2-hydroxypropyl) methacrylamide coat the nanoparticle surfaces with an electroneutral polymer layer. Additionally, pH-responsive hydrazone bonds are incorporated between the TMA and TBP groups and the main polymer backbone of the polycationic block to ensure hydrolysis of the hydrazone bond. Theoretically, this should be accompanied by DNA release from the complex in a mildly acidic environment inside the cells while maintaining its stability under neutral blood conditions. In summary, this model study provides insight into the process of complexation/decomplexation of NA by pH-responsive di-block polycationic vectors. The results may contribute to the development of safe and efficient delivery systems for gene therapy applications.","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1419-1432"},"PeriodicalIF":3.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pol.20240970","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Luminescent Mesoporous Squaraine Copolymers: Probing the Structural, Optical, and Sensing Behaviors 发光介孔方胺共聚物：探测结构、光学和传感行为

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-21 DOI: 10.1002/pol.20240957

Saily Sriwastav, Sudip Malik

{"title":"Luminescent Mesoporous Squaraine Copolymers: Probing the Structural, Optical, and Sensing Behaviors","authors":"Saily Sriwastav, Sudip Malik","doi":"10.1002/pol.20240957","DOIUrl":"https://doi.org/10.1002/pol.20240957","url":null,"abstract":"<div>\u0000 \u0000 Herein, we have designed and developed four luminescent mesoporous squaraine copolymers (PSQ-X) based on substituted diaryl-1,4-diamine moiety with various heteroatom “X” such as CH2, O, S, and SO2 to demonstrate the effect of heteroatom on structural, thermal, electrochemical, and optical properties of copolymers. Synthesis has been achieved through a facile single step metal-free poly-condensation reaction using commercially available low-cost monomers. All polysquaraines (PSQs) possess good thermal stability, crystallinity and low bandgap energy (2–3 eV). Utilizing the fluorescent nature of the PSQs, we have explored them as a “turn-off” sensor for the selective and sensitive detection of picric acid among various nitro-aromatic explosives via photoinduced electron transfer (PET) and inner filter effect (IFE) mechanism. The Stern–Volmer constant (KSV) for PA has estimated as 1.93 × 104, 1.92 × 104, 0.68 × 104, and 3.57 × 104 M−1 for PSQ-CH2, PSQ-O, PSQ-S, and PSQ-SO2, respectively, indicating that PA can quench the emission intensity of PSQ-SO2 most efficiently with the detection limit in the nano-molar range (LOD = 5.96 nM). Contact mode detection of PA has been also accomplished using economical and transportable fluorescent paper test strip devices for on-site sensing, which can detect a minimum of 6.9 fg of PA.\u0000 </div>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1398-1406"},"PeriodicalIF":3.9,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Basic Composition and Synthesis Process and Representative Molecule of the Branched Polyethyleneimines With Low Molecular Weight 低分子量支化聚乙烯亚胺的基本组成、合成工艺及代表性分子

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-21 DOI: 10.1002/pol.20241015

Pandeng Li, Gen Lu, Tingting Liu, Tong Shu, Tianyi Yu, Chunhua Fu, Longjiang Yu

{"title":"Basic Composition and Synthesis Process and Representative Molecule of the Branched Polyethyleneimines With Low Molecular Weight","authors":"Pandeng Li, Gen Lu, Tingting Liu, Tong Shu, Tianyi Yu, Chunhua Fu, Longjiang Yu","doi":"10.1002/pol.20241015","DOIUrl":"https://doi.org/10.1002/pol.20241015","url":null,"abstract":"<div>\u0000 \u0000 Branched polyethyleneimines (B-PEIs) have been widely used in industries and researches, such as the papermaking, water treatment, and enzyme immobilization. However, they exhibit a complex composition, leading to ambiguity in understanding the B-PEIs' synthetic process and relevant influencing factors. Additionally, no representative molecule of B-PEIs has been identified, leading to subjective selections when studying structure–performance relationships. This study focused on three commercially low-molecular-weight B-PEIs: 300, 600, and 1800. It identified that they primarily consisted of C, H, and N elements in the form of methylene and primary, secondary, and tertiary amine groups. The ratios of amine groups were also revealed, offering guidance for application. Moreover, the types of polymerization degrees and their proportions were determined, with the free ends identified as primary amino groups. Based on these, this study proposed synthetic processes and potential influencing factors. This provided valuable insights into the synthesis of B-PEIs with varying compositions and properties. Furthermore, the stability of over 527 potential molecular structures was calculated. By weighing above features, the representative model molecules used to analyze B-PEIs' structure–performance relationships was identified. These results had significant implications for the synthesis, application, and functional analysis of B-PEIs.\u0000 </div>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1389-1397"},"PeriodicalIF":3.9,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622566","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Kinetically Controlled Seeded Living Supramolecular Polymerization of Tb(III) Complex Tb（III）配合物的动力学控制种子活性超分子聚合

IF 3.9 3区化学

Journal of Polymer Science Pub Date : 2025-01-21 DOI: 10.1002/pol.20240849

Minkyeong Hwang, Seol-A Lim, Yumi Park, Sung Ho Jung, Jong Hwa Jung

{"title":"Kinetically Controlled Seeded Living Supramolecular Polymerization of Tb(III) Complex","authors":"Minkyeong Hwang, Seol-A Lim, Yumi Park, Sung Ho Jung, Jong Hwa Jung","doi":"10.1002/pol.20240849","DOIUrl":"https://doi.org/10.1002/pol.20240849","url":null,"abstract":"<div>\u0000 \u0000 We describe the synthesis of metallosupramolecular polymers using a Tb3+ complex as a primary building block. This synthesis is facilitated through the strategic manipulation of non-equilibrium self-assemblies, employing a living supramolecular polymerization method. Our extensive investigation into the metallosupramolecular polymerizations, which are both thermodynamically and kinetically regulated and centered around the Tb3+ complex with bisterpyridine-modified ligand (R-L\u0000 \u0000 1\u0000 ) incorporating R-alanine units, revealed noteworthy properties. These complexes initially form kinetically metastable aggregates, characterized by a coordination number of nine. This structure involves one Tb3+ cation and three NO3− anions at one terpyridine moiety, while the opposite terpyridine moiety remains unoccupied. Intriguingly, these aggregates can transition into a thermodynamically more stable state, also characterized by a nine-coordination number. In this state, each of the two terpyridine units is coordinated with one Tb3+ cation and three NO3− anions, respectively. This transformative process is expedited by seed-induced living polymerization. Therefore, we have successfully executed the seeded living supramolecular polymerization of the monomeric building unit under kinetically controlled conditions. This process yielded a metallosupramolecular polymer with a precisely regulated length and minimal polydispersity, demonstrating the potential of this approach in the design of advanced functional materials.\u0000 </div>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1381-1388"},"PeriodicalIF":3.9,"publicationDate":"2025-01-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0