{"title":"Claysphere Linking Geo-and Biospheres","authors":"T. Naganuma","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.129","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.129","url":null,"abstract":"","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"82 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2003-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125248018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Diagenesis and Clay Minerals","authors":"T. Yoshimura","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.167","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.167","url":null,"abstract":"","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2003-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124261322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Clay Minerals Occurred in Landslide Areas on Mikabu Green Rocks","authors":"M. Miyahara, Yohei Uno, R. Kitagawa","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.81","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.81","url":null,"abstract":"","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126466151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Clay Minerals in Marine Sediments","authors":"S. Aoki","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.97","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.97","url":null,"abstract":"","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"96 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127597080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"La feuille d'or et ses HAKU-UCHIGAMI","authors":"Takéo Wada, Noriyuki Takahashi, Mituru Demura, Tougo Kameyama","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.89","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.89","url":null,"abstract":"","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"62-63 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132468954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Adsorptions of Fe (II) and Mn (II) Ions on Two Oxides, Silica and Gibbsite","authors":"K. Saeki, K. Nakagawa, S. Wada","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.77","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.77","url":null,"abstract":"","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"104 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122668426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hidetoshi Hirahara, Y. Sawai, S. Aisawa, Satoshi Takahashi, Y. Umetsu, E. Narita
{"title":"Synthesis and Antacid Property of Mg-Fe Layered Double Hydroxide","authors":"Hidetoshi Hirahara, Y. Sawai, S. Aisawa, Satoshi Takahashi, Y. Umetsu, E. Narita","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.70","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.70","url":null,"abstract":"The synthesis of the CO3/Mg-Fe layered double hydroxide (LDH) by a standard coprecipitation method has been investigated together with its antacid property. The LDH crystallinity of the solid product was influenced by the synthesized pH, Fe/(Mg+ Fe) mixed molar ratio and aging time. The solid products have the carbonated LDH structure with the basal spacing, d003, of 7.8 A, in particular the well crystallized CO3/Mg -Fe LDH was obtained at pH 10, Fe/(Mg+ Fe)=0.25 and aging time 5 hours. From the results of XRD and TG-DTA, it was found that lattice constants a and c of the CO3/Mg-Fe LDH obtained at the Fe/(Mg+Fe) mixed molar ratio of 0.17-0.25 range ageered with the Vegard rule, and the temperatures of elimination of interlayer water, dehydration of hydroxide basal layer and decarboxylation of guest anion were shifted by the amount of substituted Fe3+ ion for the LDH basal layer. In the durability experiments of the CO3/Mg-Fe LDH as antacid, the time effecting antacid property for 65-95 min was observed in the CO3/Mg-Fe LDH obtained at the Fe/(Mg+Fe) mixed molar ratio of 0.17-0.25 range. This feature of the CO3/Mg-Fe LDH indicates that it can be used as for the substitute of the CO3/Mg-Al LDH as antacid.","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"102 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114971345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of Grinding on the Hydrothermal Transformation of Sepiolite","authors":"T. Mashiko, Takabumi Sakamoto","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.6","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.6","url":null,"abstract":"It is well known that grinding of crystalline material cause a structural degradation and finally produce an amorphous phase. The amorphous phase thus prepared is expected to have a high reactivity under hydrothermal conditions. In the previous study, one of the authors reported that grinding treatment significantly increase the hydrothermal reactivity of talc, and aluminum bearing layer silicates was easily formed from ground talc by the hydrothermal treatment with AlCl3 solution. In the present study, original and well ground sepiolite from Kuzu, which is non-crystalline on an XRD pattern, was treated hydrothermally with Al(NO3)3, NaA102, and NaOH solutions. As a result, in Al(NO3)3 solution, tri -octahedral smectite, di-octahedral smectite, and kaoline mineral are formed successively from both ground and original sepiolite with increasing Al (in solution)/Si (in sepiolite) ratio. In NaA102 and NaOH solution, both sample transformed into trioctahedral smectite and serpentine minerals with increasing the concentration of the solution. The kaolin mineral and the serpentine mineral formed from ground sepiolite are different from those from original sepiolite in the polytype and morphology. These results reveal that the crystallinity of sepiolite is not effective in the reactivity in hydrothermal condition, because the nano-scale nature of sepiolite may dominate the hydrothermal behavior. It is also concluded, however, that the crystallinity of sepiolite has influence on the selection of reaction process in the hydrothermal transformations.","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"84 7 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"117336861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Surface Microtopographies of Pyrophyllite and Kaolinite Occurred in the Uku Pyrophyllite Deposit","authors":"M. Jige, R. Kitagawa, Noriko Ikemi","doi":"10.11362/JCSSJNENDOKAGAKU1961.42.15","DOIUrl":"https://doi.org/10.11362/JCSSJNENDOKAGAKU1961.42.15","url":null,"abstract":"The Au-decoration technique of electron microscopy was applied to the crystal surfaces of pyrophyllite and kaolinite collected from the Uku pyrophyllite deposit in Abu-Susa district, Yamaguchi Prefecture. The specimens composed of pyrophyllite and kaolinite exclusively exhibited malformed step growth patterns and polygonal spiral growth patterns. Saw -tooth step patterns , which are formed by dissolution, were also observed. The crystals with malformed layer by layer step growth patterns are corresponded to pyrophyllite, they with polygonal spiral growth pattern and/or saw-tooth step patterns are indicated kaolinite crystals. It is considered from these observation that kaolinite was formed before pyrophyllite grew under the hydrothermal alteration.","PeriodicalId":164792,"journal":{"name":"Journal of the Clay Science Society of Japan","volume":"6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2002-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131410037","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}