Journal of Earth Science最新文献

{"title":"Effect of Reclamation on the Groundwater-Lake Water Interaction in Chen Lake","authors":"Kun Lei, Teng Ma, Liuzhu Chen, Zhenxing Li, Yu Chen","doi":"10.1007/s12583-022-1652-y","DOIUrl":"https://doi.org/10.1007/s12583-022-1652-y","url":null,"abstract":"<p>Lake reclamation cut off the direct seepage from the lake to groundwater in reclaimed farmland, the aquifer showed a connection with lake water by horizontal groundwater flow. The chemical analysis demonstrated that after reclamation, groundwater hydrodynamic conditions are gradually weakening. The lake-groundwater interaction interface is gradually varied and moves into the lake during this period. This change is easily ignored because the modification may take years to be observed. However, the lake ecology may be threatened seriously during this process. Lake reclamation project exerts anthropogenic pressures on the groundwater environment and lake ecosystem function, would affect the natural resilience of the lake systems and increases their vulnerability.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"240 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Late Mesoproterozoic to Early Neoproterozoic Tectonic Evolution of the SW Yangtze Block, South China: Evidence from U-Pb Geochronology and Lu-Hf Isotopes of Detrital Zircons from Sedimentary Rocks","authors":"Peiwen Liu, Xiaozhong Ding, Yanxue Liu, Jibiao Zhang","doi":"10.1007/s12583-021-1563-3","DOIUrl":"https://doi.org/10.1007/s12583-021-1563-3","url":null,"abstract":"<p><i>In situ</i> zircon U-Pb geochronological and Lu-Hf isotope studies of detrital zircons from Late Mesoproterozoic to Early Neoproterozoic sedimentary units on the southwestern margin of the Yangtze Block have important implications for the tectonic evolution of the Yangtze Block. The Huili Group contains zircons whose ages are mainly Late Archean to Mesoproterozoic (2 650–2 450, 2 100–1 800, and 1 350–1 150 Ma). The Dengxiangying Group has one major age population of 1 900–1 600 Ma, and two subordinate age populations of 1 350–1 100 and 2 300–2 000 Ma. Yanbian Group sedimentary rocks have a zircon age population mainly in the range of 970–850 Ma, contemporaneous with the ages of widespread arc-related magmatism in the western Yangtze Block. Combining these results with previous work, the Huili and Dengxiangying groups were most likely deposited during ca. 1 160 to 1 000 Ma in an intra-continental rift basin setting, while the Yanbian Group accumulated during &gt;920 to 782 Ma in a back-arc basin setting at the southwestern margin of the Yangtze Block. In addition, all these results further suggest a tectonic transition from a continental rift basin to a convergent environment at the southwestern margin of the Yangtze Block at 1 000–970 Ma.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"14 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Petrogenesis and Economic Potential of the Sangong Mafic-Ultramafic Intrusion in the Eastern Tianshan, Central Asian Orogenic Belt: Constraints from Mineral, Whole-Rock, and PGE Geochemistry","authors":"Guochao Zhou, Yuwang Wang, Jingbin Wang, Yu Shi, Hongjing Xie, Dedong Li, Yong Fu, Pan Wu","doi":"10.1007/s12583-022-1777-z","DOIUrl":"https://doi.org/10.1007/s12583-022-1777-z","url":null,"abstract":"<p>The Sangong Cu-Ni sulfide mineralized mafic-ultramafic intrusion is located on the southern margin of the Bogeda-Harlik belt, eastern Tianshan, China. The intrusion is a well-differentiated complex and is comprised of leucogabbro, gabbro, olivine gabbro, Pl-bearing peridotite, and Pl-bearing pyroxenite. The Pl-bearing pyroxenite hosts both irregularly disseminated sulfide and round droplet sulfide. The intrusive rocks have a wide range of SiO₂ (42.1 wt.%–50.48 wt.%) and MgO (6.21 wt.%–22.11 wt.%), and are enriched in light rare earth elements (LREE), large-ion lithophile elements (LILE; e.g., Rb, Ba, Sr, and Pb), and palladium platinum group elements (PPGE) but depleted in high-field-strength elements (HFSE; e.g., Nb, Ta, and Ti) and iridium PGEs (IPGE). These geochemical characteristics indicate that the Sangong mafic-ultramafic intrusion was derived from high degree of partial melting of depleted mantle and interacted with subduction-related material. The low Pd/Ir (3.21–27.44) but high Ni/Cu (1.64–24.16) ratios, combined with the olivine crystals with low Fo (60.88–78.65) and Ni (54.99 ppm–1 688.87 ppm) concentrations suggest that the parental magma of the Sangong intrusion were likely high MgO basaltic in composition that experienced extensive evolution prior emplacement. The Ce/Pb ratios (5.8–13.6) and Nb/U ratios (11.6–30.3) of the intrusive rocks all range between MORB and crustal values, the Nb/Yb and Th/Yb values are close to the lower crust values, together with the low Se/S ratios [(17–100) × 10⁻⁶)] suggest that the magma experienced assimilation not only in mantle source but also in conduit, but the degree of crustal contamination is limited. The Cu/Pd ratios of the rocks range from 3.9 × 10⁴ to 10.8 × 10⁴, and the Cu/Zr ratios of Pl-bearing pyroxenite in the Sangong intrusion are &gt;1, combined with the presence of sulfide droplets in the Pl-bearing pyroxenite, indicating the parental magma experienced sulfide saturation and the economical ore bodies may present in the depth of the intrusion. Furthermore, given the discovery of the Baixintan and Yueyawan deposits, we propose the Dananhu-Harlik belt as an essential prospecting target for Cu-Ni mineralization in North Xinjiang.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"40 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Insight into the Permeability and Microstructure Evolution Mechanism of the Sliding Zone Soil: A Case Study from the Huangtupo Landslide, Three Gorges Reservoir, China","authors":"Qianyun Wang, Huiming Tang, Pengju An, Kun Fang, Junrong Zhang, Minghao Miao, Qingwen Tan, Lei Huang, Shengming Hu","doi":"10.1007/s12583-023-1828-0","DOIUrl":"https://doi.org/10.1007/s12583-023-1828-0","url":null,"abstract":"<p>A large number of laboratory investigations related to the permeability have been conducted on the sliding zones. Yet little attention has been paid to the particular sliding zones of the slide-prone Badong Formation. Here, we experimentally investigate the permeability nature and the mechanism of seepage in the viscous sliding zone of the Huangtupo Landslide. Saturated seepage tests have been performed first with consideration of six dry densities and thirteen hydraulic gradients, in conjunction with the mercury intrusion porosimetry test and scanning electron microscopy test for the microstructure analysis after seepage. The results show that seepage in the sliding zone soil does not follow Darcy’s Law, since there is a threshold hydraulic gradient (<i>i</i>₀) below which no flow is observed and a critical hydraulic gradient (<i>i</i>_<i>cr</i>) over which the hydraulic conductivity (<i>K</i>) tends to be stable. The percentage of bound water could be responsible for the occurrence of <i>i</i>₀ and <i>i</i>_<i>cr</i>. Furthermore, pore size distributions (PSD) less than 0.6 µm and between 10 and 90 µm exhibit positive and negative correlations with the <i>i</i>₀, respectively, indicating that the <i>i</i>₀ is related to the PSD. The mechanism accounting for this result is that pore water pressure forces fine clay particles into the surrounding large pores and converts arranged particles to discretely distributed ones, thereby weakening the connectivity of pores. The seepages in the sliding zones behave differently from that in the sliding mass and sliding bed in response to the permeability.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"16 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3-D Tunnel Seismic Advance Prediction Method with Wide Illumination and High-Precision","authors":"Peng Guan, Cuifa Shao, Yuyong Jiao, Guohua Zhang, Junpeng Zou, Fei Tan","doi":"10.1007/s12583-021-1503-2","DOIUrl":"https://doi.org/10.1007/s12583-021-1503-2","url":null,"abstract":"<p>Tunnel seismic advance prediction can effectively reduce the construction risk during tunnel excavation. Compared with the 2-D method, the 3-D method is more conducive to describing the spatial characteristics of the geological body by adding the seismic data in the vertical direction. However, some drawbacks still need improvement in the current 3-D tunnel seismic prediction method. (1) The geometry is complex, which is destructiveness, high cost, and time-consuming, and will delay the tunnel construction schedule. (2) Illumination of the anomalous body is insufficient, and the precision of migration imaging is low. (3) Shot points are far away from the tunnel face, the energy loss at the shot points is more serious. (4) The received signals at the tunnel wall have the surface wave with strong energy when the shot points are placed on the tunnel wall. (5) The geometry is not linear, so the directional filtering method cannot be used to extract the reflection wave. To overcome the drawbacks of the current prediction method, a new 3-D symmetrical tunnel seismic prediction method is proposed. Six geophones are installed on the tunnel wall, two on the left side, two on the right side, and two on the top side. Twenty-four shot points are placed on the tunnel face and near both sides of the tunnel wall, twelve shot points on the left side and twelve shot points on the right side. The shot points will move along with the forward excavation of the tunnel. The wavefield analysis, illumination statistics, and 3-D reverse time migration imaging are used to evaluate the proposed method. The result of modeled data indicates that the proposed 3-D geometry has some advantages: (1) the geometry is simple and the geophone installation time is short; (2) it has high illumination energy, wide illumination range, and can improve the prediction distance and imaging accuracy; (3) the proposed 3-D method can better estimate the velocity of surrounding rock and is more conducive to extracting the reflection wave with high resolution.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"14 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Low Resource Chinese Geological Text Named Entity Recognition Based on Prompt Learning","authors":"Hang He, Chao Ma, Shan Ye, Wenqiang Tang, Yuxuan Zhou, Zhen Yu, Jiaxin Yi, Li Hou, Mingcai Hou","doi":"10.1007/s12583-023-1944-8","DOIUrl":"https://doi.org/10.1007/s12583-023-1944-8","url":null,"abstract":"<p>Geological reports are a significant accomplishment for geologists involved in geological investigations and scientific research as they contain rich data and textual information. With the rapid development of science and technology, a large number of textual reports have accumulated in the field of geology. However, many non-hot topics and non-English speaking regions are neglected in mainstream geoscience databases for geological information mining, making it more challenging for some researchers to extract necessary information from these texts. Natural Language Processing (NLP) has obvious advantages in processing large amounts of textual data. The objective of this paper is to identify geological named entities from Chinese geological texts using NLP techniques. We propose the Ro-BERTa-Prompt-Tuning-NER method, which leverages the concept of Prompt Learning and requires only a small amount of annotated data to train superior models for recognizing geological named entities in low-resource dataset configurations. The RoBERTa layer captures context-based information and longer-distance dependencies through dynamic word vectors. Finally, we conducted experiments on the constructed Geological Named Entity Recognition (GNER) dataset. Our experimental results show that the proposed model achieves the highest F1 score of 80.64% among the four baseline algorithms, demonstrating the reliability and robustness of using the model for Named Entity Recognition of geological texts.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"76 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141531605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microstructures, Fabrics, and Seismic Properties of Mylonitic Amphibolites: Implications for Strain Localization in a Thickening Anisotropic Middle Crust of the North China Craton","authors":"Siqi Liu, Bo Zhang, Jinjiang Zhang, Jian Zhang, Lei Guo, Tao Wang, Baoyou Hang, Xiaorong Li","doi":"10.1007/s12583-021-1480-5","DOIUrl":"https://doi.org/10.1007/s12583-021-1480-5","url":null,"abstract":"&lt;p&gt;Strain localization processes in the continental crust generate faults and ductile shear zones over a broad range of scales affecting the long-term lithosphere deformation and the mechanical response of faults during the seismic cycle. Seismic anisotropy originated within the continental crust can be applied to deduce the kinematics and structures within orogens and is widely attributed to regionally aligned minerals, e. g., hornblende. However, naturally deformed rocks commonly show various structural layers (e.g., strain localization layers). It is necessary to reveal how both varying amphibole contents and fabrics in the structural layers of strain localization impact seismic property and its interpretations in terms of deformation. We present microstructures, petrofabrics, and calculate seismic properties of deformed amphibolite with the microstructures ranging from mylonite to ultramylonite. The transition from mylonite to ultramylonite is accompanied by a slight decrease of amphibole grain size, a disintegration of amphibole and plagioclase aggregates, and amphibole aspect ratio increase (from 1.68 to 2.23), concomitant with the precipitation of feldspar and/or quartz between amphibole grains. The intensities of amphibole crystallographic preferred orientations (CPOs) show a progressively increasing trend from mylonitic layers to homogeneous ultramylonitic layers, as indicated by the &lt;i&gt;J&lt;/i&gt;&lt;sub&gt;Am&lt;/sub&gt; index increasing from 1.9–4.0 for the mylonitic layers and 4.0–4.8 for the transition layer, to 5.1–6.9 for the ultramylonitic layers. The CPO patterns are nearly random for plagioclase and quartz. Polycrystalline amphibole aggregates in the amphibolitic mylonite deform by diffusion, mechanical rotation, and weak dislocation creep, and develop CPOs collectively. The polymineralic matrix (such as quartz and plagioclase) of the mylonite and the ultramylonite deform dominantly by dissolution-precipitation, combined with weak dislocation creep. The mean P and S wave velocities are estimated to be 6.3 and 3.5 km/s, respectively, for three layers of the mylonitic amphibolite. The respective maximum P and S anisotropies are 1.5%–6.4% and 1.8%–4.5% for the mylonite layers of the mylonitic amphibolite, and 6.0%–6.9% and 4.5%–5.0% for the transition layers; but for the ultramylonite layers, these values increase significantly to 8.0%–9.1% and 5.1%–6.0%, respectively. Furthermore, increasing strain (strain localization) generates significant variations in the geometry of the seismic anisotropy. This effect, coupled with the geographical orientations of structures in the Hengshan-Wutai-Fuping complex terrains, can generate substantial variations in the orientation and magnitude of seismic anisotropy for the continental crust as measured by the existing North China Geoscience Transect. Thickened amphibolitic layers by extensively folding or thrusting in the middle crust can explain the strong shear wave splitting and the tectonic boundary parallel f","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"32 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141500823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Geochemistry and Zircon U-Pb and Hf Isotopes of Early Devonian Hardawu Granites in the Eastern Segment of the Ultrahigh-Pressure Metamorphic Belt, Northern Qaidam Basin","authors":"Hua Li, Ming Wang, Jiqing Li, Haikui Tong, Jiaxiang Dong, Minggang Tian, Xiaolin Chen, Leguang Li, Ting Xie, Xiong Li, Yuying Che","doi":"10.1007/s12583-022-1791-1","DOIUrl":"https://doi.org/10.1007/s12583-022-1791-1","url":null,"abstract":"<p>The Hardawu granites in the eastern segment of the ultrahigh-pressure metamorphic belt, the northern Qaidam Basin, were studied by whole-rock major and trace elements and <i>in-situ</i> zircon U-Pb geochronology and Hf isotopes to discuss the petrogenesis and tectonic evolution. Geochronological results show that the granites have a crystallization age of 401 ± 3 Ma, suggesting that they were formed in the Early Devonian. The granites have SiO₂ contents of 75.32 wt.%–76.05 wt.%, total alkali contents of 8.23 wt.%–8.36 wt.%, and K₂O/Na₂O ratios of 1.62–1.91. They were rich in K₂O, poor in TiO₂, MnO, MgO, and P₂O₅, and have A/CNK values of 1.05–1.07, Rittmann index <i>δ</i> values of 2.05–2.14, and differentiation index (DI) values of 92.85–94.18. They are high potassium calc-alkaline, weak-peraluminum, and highly differentiated I-type granites. The granites also show enrichment of large ion lithophile elements (LILE) such as Rb, Ba, and Th, and depletion of high field strength elements (HFSE) such as Nb, Ta, and Ti. The total REE concentrations range from 169 ppm to 232 ppm, with enrichments of light rare earth elements and negative Eu anomalies (δEu = 0.39–0.55). The zircon <i>ε</i>_Hf(<i>t</i>) values range from −0.65 to −2.29, and the two-stage model ages (<i>t</i>_DM2) changed within a small range of 1.44 to 1.54 Ga, indicating that the magma of the Hardawu granites was originated from the partial melting of Mesoproterozoic lower crustal materials. Combined with previous studies, we suggest that the Hardawu granites were formed in the extensional tectonic setting after the collision between the Qaidam Block and the central and southern Qilian Block in the Early Devonian.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"137 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141522401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Partitioning Anatolian Kinematics into Tectonic Escape and Slab Rollback Dominated Domains","authors":"Jiannan Meng, Timothy M. Kusky, Erdin Bozkurt, Hao Deng, Ozan Sinoplu","doi":"10.1007/s12583-023-1906-3","DOIUrl":"https://doi.org/10.1007/s12583-023-1906-3","url":null,"abstract":"<p>Anatolia is the global archetype of tectonic escape, as witnessed by the devastating 2023 Kahramanmaraş Earthquake sequence, and the 2020 Samos Earthquake, which show different kinematics related to the framework of the escape tectonics. Global Positioning System (GPS) motions of the wedge-shaped plate differ regionally from northwestwards to southwestwards (from east to west). Anatolia was extruded westward from the Arabian-Eurasian collision along the North and East Anatolian fault systems, rotating counterclockwise into the oceanic free-faces of the Mediterranean and Aegean, with dramatic extension of western Anatolia in traditional interpretations. However, which is the dominant mechanism for this change in kinematics, extrusion related to the Arabia/Eurasia collision or rollback of the African slab beneath western Anatolia is still unclear. To assess the dominant driving mechanisms across Anatolia, we analyze recent GPS velocity datasets, and decomposed them into N-S and E-W components, revealing that westward motion is essentially constant across the whole plate and consistent with the slip rates of the North and East Anatolia fault zones, while southward components increase dramatically in the transition area between central and western Anatolia, where a slab tear is suggested. This phenomenon is related to different tectonic driving mechanisms. The Arabia-Eurasia collision drives the Anatolian Plate uniformly westwards while western Anatolia is progressively more affected by the southward retreating African subducting slab west of the Aegean/Cypriot slab tear, which significantly increases the southward component of the velocity field and causes the apparent curve of the whole modern velocity field. The 2020 and 2023 earthquake focal mechanisms also confirm that the northward colliding Arabian Plate forced Anatolia to the west, and the retreating African slab is pulling the upper plate of western Anatolian apart in extension. We propose that the Anatolian Plate is moving westwards as one plate with an additional component of extension in its west caused by the local driving mechanism, slab rollback (with the boundary above the slab tear around Isparta), rather than separate microplates or a near-pole spin of the entire Anatolian Plate, and the collision-related extrusion is the dominant mechanism of tectonic escape.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"10 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140568358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Kerogen Kinetic Distributions and Simulations Provide Insights into Petroleum Transformation Fraction (TF) Profiles of Organic-Rich Shales","authors":"David A. Wood","doi":"10.1007/s12583-024-1981-0","DOIUrl":"https://doi.org/10.1007/s12583-024-1981-0","url":null,"abstract":"<p>Two hundred and fifty single first-order Arrhenius reactions are simulated to generate S2 pyrograms at three heating rates 25, 15, and 5 °C·min⁻¹. The activation energy (<i>E</i>) and pre-exponential factor (<i>A</i>) of the reactions simulated follow a long-established trend of those variable values displayed by shales and kerogens. The characteristics of the transformation fraction (TF) profiles (product generation window temperatures) of the simulated single reactions are compared to the TF profiles of recorded shale pyrograms generated by multiple reactions with different <i>E-A</i> values lying near the defined <i>E-A</i> trend. Important similarities and differences are observed between the TF profile values of the two datasets. The similarities support the spread of <i>E-A</i> values involved in shale pyrogram best fits. The differences are most likely explained by the complexity of the multiple kerogen first-order and second-order reactions contributing to the recorded shale pyrograms versus the simplicity and crispness of the single first-order reactions simulated. The results also justify the validity of using the previously described “variable <i>E-A</i> pyrogram-fitting method” of multi-heating-rate shale pyrograms enabling optimizers to choose multiple reactions from an unlimited range of <i>E-A</i> values. In contrast, further doubt is cast on the validity of the constant-<i>A</i> pyrogram-fitting method used by the Easy%Ro technique, in that a distribution of reactions with a single <i>A</i> value is unlikely to represent the complex variety of kerogen macerals observed in shale formations. TF profiles generated by the variable <i>E-A</i> pyrogram-fitting method lie close to the established <i>E-A</i> trend and are likely to provide more realistic TF generation window temperatures than TF profiles generated by the constant-<i>A</i> pyrogram-fitting method.</p>","PeriodicalId":15607,"journal":{"name":"Journal of Earth Science","volume":"5 1","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140568362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}