Izmeritel`naya Tekhnika最新文献

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Accuracy of coordinate measurements at phase modulation by digital raster 数字光栅相位调制的坐标测量精度
Izmeritel`naya Tekhnika Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-35-41
V. A. Solomatin, Dmitriy G. Otkupman
{"title":"Accuracy of coordinate measurements at phase modulation by digital raster","authors":"V. A. Solomatin, Dmitriy G. Otkupman","doi":"10.32446/0368-1025it.2024-2-35-41","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-2-35-41","url":null,"abstract":"The development of optical-electronic instruments for measuring linear and angular quantities based on focal-plane array (photomatrices) using a digital phase analyzer (digital raster) is considered. It is shown that, unlike a phase raster with a mechanical drive, a digital raster provides the possibility of automation and increased measurement accuracy, reducing the weight and size characteristics of the measuring instrument. A method for constructing a digital raster is proposed, based on the use of photomatrices in combination with computer technologies. To ensure the required accuracy of the developed opto-electronic devices, the sources and components of the measurement error were investigated. The influence of the discrete structure of a digital raster on the error in measuring image coordinates has been studied. Mathematical expressions are obtained for calculating the limiting values of coordinate measurement errors caused by parasitic phase modulation that occurs when using a digital raster (sampling error). The dependence of these errors on image parameters and pixel size has been determined. It is shown that, based on the permissible maximum sampling error, it is possible to calculate the required dimensions of a photomatrix pixel, while the size of the sampling pixel can be larger than the size of the photomatrix pixel, which is very signifi cant from the point of view of energy relations. The results obtained will be useful in the development of optical-electronic means of angular and linear measurements with digital rasters.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"216 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140740293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Estimation of traditional numerical characteristics of lognormal distribution laws of a one-dimensional random variable in conditions of large volume statistical data 在大量统计数据条件下估计一维随机变量对数正态分布规律的传统数字特征
Izmeritel`naya Tekhnika Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-23-29
A. V. Lapko, V. A. Lapko
{"title":"Estimation of traditional numerical characteristics of lognormal distribution laws of a one-dimensional random variable in conditions of large volume statistical data","authors":"A. V. Lapko, V. A. Lapko","doi":"10.32446/0368-1025it.2024-2-23-29","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-2-23-29","url":null,"abstract":"The efficiency of estimating the numerical characteristics of a family of the lognormal distribution law of a onedimensional random variable under conditions of large volumes of statistical data is considered. To circumvent the problem of large samples, methods of discretization the range of values of a random variable based on the formulas of Sturges, Brooks-Carruthers, Heinhold-Gaede and the formula proposed by the authors of this article are used. Data arrays have been generated that make it possible to evaluate the numerical characteristics of the laws of distribution of random variables, taking into account their discrete values. Based on the transformed data arrays, estimates of the mathematical expectation, standard deviation, skewness and kurtosis coefficients were calculated. Estimates of the numerical characteristics of the considered distribution laws under the conditions of a continuous and discrete random variable are compared for different volumes of initial statistical data. The effectiveness of methods for estimating the numerical characteristics of the family of the lognormal distribution law based on the initial statistical data and on the results of transformations of these data using known discretization formulas has been established. The reliability of the comparison of the effectiveness indicators of the studied methods was confirmed by using the Kolmogorov-Smirnov criterion. It is shown that the discretization formula proposed by the authors of this article is better and more effective compared to traditional methods.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"26 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140738168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Method for asynchronous analysis of a glottal source based on a two-level autoregressive model of the speech signal 基于语音信号两级自回归模型的声源异步分析方法
Izmeritel`naya Tekhnika Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-55-62
V. V. Savchenko, L. V. Savchenko
{"title":"Method for asynchronous analysis of a glottal source based on a two-level autoregressive model of the speech signal","authors":"V. V. Savchenko, L. V. Savchenko","doi":"10.32446/0368-1025it.2024-2-55-62","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-2-55-62","url":null,"abstract":"The task of analyzing a glottal source over a short observation interval is considered. The acute problem of insufficient performance of known methods for analyzing a glottal source is pointed out, regardless of the mode of data preparation: synchronous with the main tone of speech sounds or asynchronous. A method for analyzing the glottal source based on a two-level autoregressive model of the speech signal is proposed. Its software implementation based on the high-speed Burg-Levinson computational procedure is described. It does not require synchronization of the sequence of observations used with the main tone of the speech signal and is characterized by a relatively small amount of computational costs. Using the described software implementation, a full-scale experiment was set up and conducted, where the vowel sounds of the control speaker’s speech were used as the object of study. Based on the results of the experiment, the increased performance of the proposed method was confirmed and its requirements for the duration of the speech signal during voice analysis in real time were formulated. It is shown that the optimal duration is in the range from 32 to 128 ms. The results obtained can be used in the development and research of digital speech communication systems, voice control, biometrics, biomedicine and other speech systems where the voice characteristics of the speaker’s speech are of paramount importance.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"195 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140740471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative analysis and classification of measurement procedures and procedures for transferring of unit of quantity as elements of metrological traceability chain of measurement results 作为测量结果计量溯源链要素的测量程序和量值单位传递程序的比较分析和分类
Izmeritel`naya Tekhnika Pub Date : 2024-04-05 DOI: 10.32446/0368-1025it.2024-2-63-72
A. Tumilovich
{"title":"Comparative analysis and classification of measurement procedures and procedures for transferring of unit of quantity as elements of metrological traceability chain of measurement results","authors":"A. Tumilovich","doi":"10.32446/0368-1025it.2024-2-63-72","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-2-63-72","url":null,"abstract":"The article analyzes types of measurement procedures and procedures for transferring a unit of quantity, such as: primary reference measurement procedures, reference measurement procedures, calibration procedures, validation procedures, end-user measurement procedures and measurement procedures. The article discusses requirements for developing the presented procedures, their research and approval. The article presents a classification of procedures depending on their place in metrological traceability chain, type of determined metrological characteristics and their application in the field of regulation. Based on the results of the analysis of regulatory documents, a table that describes basic requirements for development and approval of measurement procedures and procedures for transferring a unit of quantity is presented. The article also discusses requirements established for conformity assessment procedures for measurement procedures and procedures for transferring а unit of quantity, such as certification, validation and verification of procedures. The article presents definitions and scope of application for conformity assessment of measurement procedures and procedures for transferring a unit of quantity. Based on the analysis of requirements for conformity assessment of procedures, a flowchart for selecting appropriate conformity assessment procedure is presented. Due to this scheme, laboratories will be able to unambiguously choose one or another conformity assessment procedure to approve the required measurement method or method of transferring a unit of value. In particular, in preparation for accreditation for compliance with the requirements of ISO/IEC 17025-2017 “General requirements for the competence of testing and calibration laboratories.” The proposed scheme of choosing a procedure for conformity assessment of a specific measurement procedure eliminates ambiguity of the requirements of regulatory documents.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"62 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140739395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Method of instantaneous signal synchronization of measuring pulse generators 测量脉冲发生器的瞬时信号同步方法
Izmeritel`naya Tekhnika Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-48-55
O. G. Bondar, E. O. Brezhneva, M. D. Pushkarev
{"title":"Method of instantaneous signal synchronization of measuring pulse generators","authors":"O. G. Bondar, E. O. Brezhneva, M. D. Pushkarev","doi":"10.32446/0368-1025it.2024-1-48-55","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-1-48-55","url":null,"abstract":"The synchronization methods used in the pulse generators of the G5 measuring group in the external trigger mode are analyzed. The factors determining the error in the formation of time intervals in this mode have been studied. It is shown that the main source of errors in the formation of time intervals during external triggering of measuring pulse generators is the variation in the position of the clock generator reference pulses relative to the external trigger pulses. An analytical review of synchronization methods based on the sampling of time intervals by a multi-tap delay line as a pulse signal propagates along it is carried out. The method of instantaneous synchronization of output pulses is proposed, using sampling of the period of the reference pulses of the clock generator with a multi-tap delay line and fixing the position of the edge of the external trigger pulse within the period of the reference frequency by triggers that control the multiplexer, which connects the output of the multi-tap delay line to the output of the device, at which the edge of the next reference clock pulse generator lags by a minimum time from the front of the external trigger pulse. A device is presented that makes it possible to implement the proposed solution. The simulation of the device was carried out, illustrating the details of its functioning. Jitter was assessed on a prototype device using an integrated 5-tap delay line with a total delay of 20 ns. The method can be applied in measuring pulse generators and belongs to the field of pulse technology.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"129 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140257013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ensuring metrological traceability of reference materials of gas mixtures composition 确保气体混合物成分标准物质的计量可追溯性
Izmeritel`naya Tekhnika Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-61-66
A. V. Kolobova
{"title":"Ensuring metrological traceability of reference materials of gas mixtures composition","authors":"A. V. Kolobova","doi":"10.32446/0368-1025it.2024-1-61-66","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-1-61-66","url":null,"abstract":"The modern concept of metrological assurance for gas analytical measuring instruments with the use of reference materials of gas mixtures composition in cylinders under pressure is presented. The reference materials of gas mixtures composition of approved type in cylinders under pressure, which are the most often means of mole fraction and mass concentration units transfer in gas analytical measurements, are considered. The certified value in these reference materials is the content of the target component (or components) in the gas medium (analytical matrix). All the produced reference materials of gas mixtures composition, which are used for ensuring the uniformity of measurements are traceable to the State primary standard of units of mole fraction, mass fraction and mass concentration of components in gas and gas condensate media GET 154-2019, which characteristics are confirmed on the international level by the results of about 90 international comparisons. The paper presents a methodology for ensuring metrological traceability of reference materials of gas mixtures composition using GET 154-2019, taking into account the constantly increasing park of gas analytical instruments and the emergence of new measuring tasks in various fields of industry and environmental control. Currently, a park of secondary and working standards has been created at enterprises producing reference materials of gas mixtures composition, and their traceability to GET 154-2019 has been implemented according to the state verification scheme. The paper presents the results of international comparisons with participation of GET 154-2019, confirming the comparability of the obtained and reference value of the target component content in reference gas mixtures at the international level. The variety and large number of relevant gas analytical measurement tasks in various industries and the social sphere determines the need to choose priority areas for improving the existing reference base, including the structure of the GET 154 Standard and the nomenclature of reference gas mixtures. The strategic program of the Gas Analysis working group of the Consultative Committee of the Amount of Substance of the International Bureau of Weights and Measures developed for the period up to 2030 has been analysed and a review of the long-term tasks of gas analytical measurements is given. The currently existing GET 154-2019 Standard of the latest generation provides reproduction, storage and transfer of the components’ mole fraction units in gas and gas condensate media in the range from 1.5·10 –8 to 99.99999 %, and mass concentration units in the range from 1.0·10–6 to 2.0·105 mg/m3, what is confirmed by the results of participation in international comparisons and published CMC positions in the International database of calibration and measurement capabilities (about 400 CMCs positions).","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"31 13","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140257401","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
State primary special standard of the unit of length GET 199-2024: ensuring the uniformity of measurements of high-precision total stations and their analogues in the mode of three-dimensional measurements 长度单位国家主要特殊标准 GET 199-2024:确保高精度全站仪及其类似设备在三维测量模式下的测量一致性
Izmeritel`naya Tekhnika Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-12-18
S. I. Donchenko, O. V. Denisenko, I. S. Silvestrov, A. V. Mazurkevich, V. I. Lesnichenko
{"title":"State primary special standard of the unit of length GET 199-2024: ensuring the uniformity of measurements of high-precision total stations and their analogues in the mode of three-dimensional measurements","authors":"S. I. Donchenko, O. V. Denisenko, I. S. Silvestrov, A. V. Mazurkevich, V. I. Lesnichenko","doi":"10.32446/0368-1025it.2024-1-12-18","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-1-12-18","url":null,"abstract":"The metrological support of optical-electronic means of measuring spatial coordinates is described. To meet modern consumer requirements for the accuracy of measurements of spatial coordinates with electronic tacheometers and their analogues (laser scanners, absolute trackers), the State primary special standard of the unit of length GET 199-2024 includes technical means for reproducing, storing and transmitting the unit of length in three-dimensional measurement mode. A reference complex of three-dimensional measurements (coordinate measurements, coordinate increments) has been developed and studied. The means and methods for transmitting a unit of length are presented, as well as the metrological characteristics of the GET 199-2024 in the mode of measuring coordinate increments (length). The sources of non-excluded systematic error and the standard deviation of the measurement result are determined.  As a result of the research performed, it became possible to reproduce a unit of length in the mode of measuring coordinate increments in the range of 0–60 m with a standard deviation of no more than 25 μm for 10 independent measurements and a non-excluded systematic error (with a confidence probability of 0.99) of 19 μm. The functionality of the GET 199-2024 will allow solving current problems of metrological support for high-precision electronic total stations and their analogues in three-dimensional measurement mode.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"32 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140257751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Methodology for determining the degree of magnetic induction of transformers with a sinusoidal magnetic flux 正弦磁通变压器磁感应强度的测定方法
Izmeritel`naya Tekhnika Pub Date : 2024-03-08 DOI: 10.32446/10.32446/0368-1025it.2024-1-35-39
S. Plotnikov
{"title":"Methodology for determining the degree of magnetic induction of transformers with a sinusoidal magnetic flux","authors":"S. Plotnikov","doi":"10.32446/10.32446/0368-1025it.2024-1-35-39","DOIUrl":"https://doi.org/10.32446/10.32446/0368-1025it.2024-1-35-39","url":null,"abstract":"The research presented in the article is aimed at reducing losses in the magnetic circuits of electrical machines. These losses amount to up to 5 % of the generated electricity, do not depend on the load and can increase over the life of the equipment. To effectively design and construct transformers with low no-load losses, total losses in steel are minimized by optimizing the crystal grain size and thickness of core sheets, improving the steel texture and magnetic circuit design, etc. However, the hysteresis, classical eddy current and anomalous eddy current components of losses in steel react in different directions to these measures, which does not effectively minimize total losses. To determine the three components of losses, a modernized method of three frequencies is proposed, which takes into account the dependence of the hysteresis loss coefficient on frequency. A formula for correcting this coefficient is derived. It is shown that the indicator of the degree of magnetic induction given in most modern scientific sources in the expression for eddy current anomalous losses has become irrelevant. A method for calculating this indicator for the core of a specific transformer is presented, which uses the loss components and total losses in steel found by the method of three frequencies and the total losses in steel at a reduced primary voltage. For the transformer under study, the degree of magnetic induction in anomalous losses was 1.88. The results obtained can be used in the design of dry and oil transformers of different powers operating with a sinusoidal magnetic flux.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"63 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140257110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
State primary special standard of acceleration unit in the field of gravimetry GET 190-2023: reproduction and transmission of the unit under the influence of geophysical factors 重力测量领域加速度单位国家初级特殊标准 GET 190-2023:地球物理因素影响下的单位再现和传输
Izmeritel`naya Tekhnika Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2024-1-4-11
L. F. Vitushkin, E. P. Krivtsov, P. P. Krolitsky, V. V. Nalivaev, O. A. Orlov, M. M. Haleev
{"title":"State primary special standard of acceleration unit in the field of gravimetry GET 190-2023: reproduction and transmission of the unit under the influence of geophysical factors","authors":"L. F. Vitushkin, E. P. Krivtsov, P. P. Krolitsky, V. V. Nalivaev, O. A. Orlov, M. M. Haleev","doi":"10.32446/0368-1025it.2024-1-4-11","DOIUrl":"https://doi.org/10.32446/0368-1025it.2024-1-4-11","url":null,"abstract":"The relevance of research on the reproduction and transmission of the acceleration unit in gravimetry is determined by the development of measuring instruments for the absolute value of the acceleration of free fall and its changes. Qualitative and quantitative changes in the instrument base are due to the requirements of applied tasks solved using gravimetric data in such fields as geodesy, navigation, geodynamics, as well as the expansion of the field of practical application of absolute gravimeters. At the same time, in order to solve applied problems, along with accuracy requirements at a level close to the maximum achievable at the current level of technology development, maximum territorial coverage of measurement sites within the entire territory of the Russian Federation is often necessary. The accuracy of the results obtained with the help of measuring instruments is determined by the level of their metrological support, the main stages of which are the reproduction of the corresponding unit by the standard and its transfer to the measuring instrument. An analysis of possible sources of errors in gravimetric equipment has shown that when reproducing and transmitting the acceleration unit in gravimetry, it is necessary to take into account the influence of geophysical factors that manifest themselves as additional accelerations of a gravitational or inertial nature. The distribution of the gravitational field within a gravimetric point can manifest itself as an additional constant acceleration. Seismic processes and lunar and solar tides manifest themselves as variable accelerations. For various stages of metrological support of gravimetric devices, the mechanisms of the effects of such accelerations have been studied, as well as methods for accounting and reducing their influence using additional equipment have been developed. An additional gravimetric point with a cryogenic relative gravimeter and a broadband seismometer, as well as transported absolute ballistic and relative quartz gravimeters, were introduced into the State primary special standard of acceleration units in the field of gravimetry GET 190-2023.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"23 26","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140258143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamics of changes in the temperature coefficient of electrical conductivity of distilled water in conductometric cells during heating and cooling 加热和冷却过程中电导测量池中蒸馏水电导率温度系数的动态变化
Izmeritel`naya Tekhnika Pub Date : 2024-03-08 DOI: 10.32446/0368-1025it.2023-12-56-60
I. Ageev, Yuri M. Rybin
{"title":"Dynamics of changes in the temperature coefficient of electrical conductivity of distilled water in conductometric cells during heating and cooling","authors":"I. Ageev, Yuri M. Rybin","doi":"10.32446/0368-1025it.2023-12-56-60","DOIUrl":"https://doi.org/10.32446/0368-1025it.2023-12-56-60","url":null,"abstract":"The problem of taking into account the influence of air on the properties of distilled water is considered, namely the lack of a single generally accepted method for calculating such an influence. The sensitivity of the structure of water to the influence of external factors is described and the possibility of recording and studying such factors by changes in the temperature coefficient of electrical conductivity of water is shown. The dependences of the temperature coefficient of electrical conductivity of distilled water on the rate of change in water temperature, the degree of filling of conductometric cells, as well as on the intensity of the exchange of carbon dioxide between water and air across their interface have been studied. It is noted that these metabolic processes are currently insufficiently studied. A hardware-software measuring complex has been developed and manufactured to study the temperature coefficient of electrical conductivity of water when its temperature changes within the range of 20–55 °C. The temperature coefficient of electrical conductivity of water in sealed conductometric cells was measured at different degrees of filling the cells with distilled water and the rate of heating and cooling of water. The degree of filling of the cells varied within the range of 10–100 %, the rate of change in water temperature varied within the range of 0.04–2.00 °C/min. With a constant heating and cooling time of 15 minutes in all experiments, the change in speed was achieved by changing the temperature of the heating element. The integral temperature coefficient of electrical conductivity is calculated based on the initial and final values of electrical conductivity and water temperature in each measurement cycle. The dependences of the temperature coefficient of electrical conductivity on the rate of change in water temperature at several constant degrees of cell filling were obtained. It has been shown that with a constant ratio of the volumes of water and air in the cell and an increase in the rate of heating of water, the temperature coefficient of electrical conductivity of water decreases by 19–22 %. It has been established that at a constant rate of water heating, with a decrease in the volume of water in the cell, the temperature coefficient of electrical conductivity of water decreases by 40–42 %. The results obtained can be used to quantify the dissociation coefficient of carbonic acid, the mobility of hydrogen ions, as well as the intensity of the gas exchange process under various external influences on water. Refinement of data on the electrical conductive properties of water and processes at the water/air interface is necessary for the development of models of atmospheric phenomena and climate change, as well as for the creation of sensors for weak changes in environmental parameters for the purposes of both environmental monitoring and medical diagnostics.","PeriodicalId":14651,"journal":{"name":"Izmeritel`naya Tekhnika","volume":"46 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140257477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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