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Synthesis, Characterization, and Photophysical Studies of Some Novel Ruthenium(II) Polypyridine Complexes Derived from Benzothiazolyl hydrazones 苯并噻唑腙衍生钌(II)多吡啶配合物的合成、表征及光物理研究
International Journal of Inorganic Chemistry Pub Date : 2013-10-02 DOI: 10.1155/2013/212435
S. Khaled, Mohammed Zamir Ahmed, F. Khan, Shaikh Ahmed
{"title":"Synthesis, Characterization, and Photophysical Studies of Some Novel Ruthenium(II) Polypyridine Complexes Derived from Benzothiazolyl hydrazones","authors":"S. Khaled, Mohammed Zamir Ahmed, F. Khan, Shaikh Ahmed","doi":"10.1155/2013/212435","DOIUrl":"https://doi.org/10.1155/2013/212435","url":null,"abstract":"A series of five benzothiazolylhydrazone ligands 3a–3e and their seven novel Ru(II) polypyridine complexes 4a–4d, 5a, 5d, 5e of the type [Ru(N–N)2(L)]Cl2, where (N–N)2 is 2,2′-bipyridine (bpy)2 or 1,10-phenanthroline (phen)2 and (L) is ligands 3a–3e, have been synthesized and characterized by elemental analysis, IR, 1H NMR, electronic absorption, and emission spectral studies. The interpretation of the analytical data revealed that the ligands coordinate with the metal ion in a bidentate fashion through azomethine nitrogen and phenolic oxygen to form complexes. These ligands and complexes also exhibit absorption and luminescence properties.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"220 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2013-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79849924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Effect of Ni Doping on the Growth and Properties of Mn-L-Histidine Hydrochloride Monohydrate Crystals Ni掺杂对mn - l -组氨酸盐酸盐一水晶体生长和性质的影响
International Journal of Inorganic Chemistry Pub Date : 2013-09-08 DOI: 10.1155/2013/716819
J. Chandra, P. Rani, V. Parvathi, Y. Sunandamma
{"title":"Effect of Ni Doping on the Growth and Properties of Mn-L-Histidine Hydrochloride Monohydrate Crystals","authors":"J. Chandra, P. Rani, V. Parvathi, Y. Sunandamma","doi":"10.1155/2013/716819","DOIUrl":"https://doi.org/10.1155/2013/716819","url":null,"abstract":"The main focus of this work had been to grow good quality crystals from amino acids and amino acid-based materials for nonlinear optics (NLO) applications. For the first time, a series of amino acid complexes doped with transition metal ions were grown in our laboratory from aqueous solutions by slow evaporation technique. Ni(II) ion doped Manganese L-Histidine hydrochloride monohydrate (Ni(II)-MnLHICl) crystals were grown on the same lines and were characterized by powder X-ray diffraction (XRD), optical absorption, electron paramagnetic resonance, and infrared absorption studies. From Powder XRD, the unit cell lattice parameters were calculated as  nm,  nm and  nm. From electron paramagnetic resonance (EPR) spectra, isotropic “g” factor and spin hamiltonian parameter A all were calculated as 2.0439 and , respectively. From optical absorption studies, crystal field splitting value () and the interelectron repulsion parameters B and C were calculated for Ni2","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"11 1","pages":"1-5"},"PeriodicalIF":0.0,"publicationDate":"2013-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88678822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Nickel (II) and Iron (II) Complexes with Azole Derivatives: Synthesis, Crystal Structures and Antifungal Activities 含唑衍生物的镍(II)和铁(II)配合物:合成、晶体结构和抗真菌活性
International Journal of Inorganic Chemistry Pub Date : 2013-08-26 DOI: 10.1155/2013/987574
E. Nfor, P. F. Asobo, J. Nenwa, O. N. Nfor, Julius N. Njapba, R. N. Njong, O. Offiong
{"title":"Nickel (II) and Iron (II) Complexes with Azole Derivatives: Synthesis, Crystal Structures and Antifungal Activities","authors":"E. Nfor, P. F. Asobo, J. Nenwa, O. N. Nfor, Julius N. Njapba, R. N. Njong, O. Offiong","doi":"10.1155/2013/987574","DOIUrl":"https://doi.org/10.1155/2013/987574","url":null,"abstract":"Two new complexes of nickel (II) with 4-amino-3, 5-bis(pyridyl)-1, 2, 4-triazole (abpt) and iron (II) with 2-(3-phenyl-1H-pyrazole-5-yl) pyridine (phpzpy) have been synthesized and characterized by elemental analysis and IR spectroscopy. The crystal structures of the complexes have been determined by single crystal X-ray diffraction techniques. In the nickel and iron complexes, the ligands are coordinated through nitrogen atoms in bidentate manner. The ligands and their respective complexes have been tested for their antifungal activity against Aspergillus niger, Aspergillus flavus, and Candida albicans. From the study, the complexes showed enhanced activities against the tested organisms compared to the ligands.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"10 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74840950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Zn (II) and Cu (II) Halide Complexes of Poly(propylene amine) Dendrimer Analysed by Infrared and Raman Spectroscopies 用红外和拉曼光谱分析聚(丙烯胺)树状聚合物的Zn (II)和Cu (II)卤化物配合物
International Journal of Inorganic Chemistry Pub Date : 2013-07-22 DOI: 10.1155/2013/895956
I. Grabchev, I. Boyaci, U. Tamer, I. Petkov
{"title":"Zn (II) and Cu (II) Halide Complexes of Poly(propylene amine) Dendrimer Analysed by Infrared and Raman Spectroscopies","authors":"I. Grabchev, I. Boyaci, U. Tamer, I. Petkov","doi":"10.1155/2013/895956","DOIUrl":"https://doi.org/10.1155/2013/895956","url":null,"abstract":"Two nondestructive and complementary spectral methods as infrared and Raman spectroscopies have been used for characterizations of poly(propylene amine) dendrimers comprising 1,8-naphthalimide units in the dendrimer periphery and their metal complexes with Cu2","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"205 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77412132","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Characterization, and Biological Studies of Binuclear Copper(II) Complexes of (2E)-2-(2-Hydroxy-3-Methoxybenzylidene)-4N-Substituted Hydrazinecarbothioamides (2E)-2-(2-羟基-3-甲氧基苄基)- 4n取代肼碳硫酰胺双核铜配合物的合成、表征和生物学研究
International Journal of Inorganic Chemistry Pub Date : 2013-07-11 DOI: 10.1155/2013/741269
P. M. Krishna, B. Shankara, N. Reddy
{"title":"Synthesis, Characterization, and Biological Studies of Binuclear Copper(II) Complexes of (2E)-2-(2-Hydroxy-3-Methoxybenzylidene)-4N-Substituted Hydrazinecarbothioamides","authors":"P. M. Krishna, B. Shankara, N. Reddy","doi":"10.1155/2013/741269","DOIUrl":"https://doi.org/10.1155/2013/741269","url":null,"abstract":"Four novel binuclear copper(II) complexes [1–4] of (2E)-2-(2-hydroxy-3-methoxybenzylidene)-4N-substituted hydrazinecarbothioamides, (OH)(OCH3)C6H4CH=NNHC(S)NHR, where R = H (L1), Me (L2), Et (L3), or Ph (L4), have been synthesized and characterized. The FT-IR spectral data suggested the attachment of copper(II) ion to ligand moiety through the azomethine nitrogen, thioketonic sulphur, and phenolic-O. The spectroscopic characterization indicates the dissociation of dimeric complex into mononuclear [Cu(L)Cl] units in polar solvents like DMSO, where L is monoanionic thiosemicarbazone. The DNA binding properties of the complexes with calf thymus (CT) DNA were studied by spectroscopic titration. The complexes show binding affinity to CT DNA with binding constant ( <path id=\"x1D43E\" d=\"M764 650l-7 -26q-61 -10 -91.5 -22.5t-76.5 -48.5l-235 -184q104 -152 208 -276q31 -37 54.5 -48.5t68.5 -16.5l-7 -28h-156q-138 170 -213 284q-19 29 -33.5 35t-33.5 -7l-29 -173q-15 -75 -5.5 -90.5t74.5 -20.5l-5 -28h-260l7 28q58 5 74 21.5t30 89.5l70 378\u0000q12 68 2 83t-72 22l6 28h257l-7 -28q-62 -7 -76 -21.5t-27 -83.5l-32 -172q29 11 78 46q112 84 217 179q18 16 23.5 25.5t-1 14.5t-26.5 8l-30 4l5 28h249z\" /> <path id=\"x1D44F\" d=\"M452 333q0 -82 -46 -164t-116 -128q-81 -53 -158 -53q-26 0 -51 13t-37 32q-26 41 -6 134l91 431q7 40 2.5 47t-34.5 7h-33l2 25q36 4 72.5 13t58.5 15.5t28 6.5q10 0 4 -29l-91 -391h2q65 77 130 116.5t105 39.5q36 0 56.5 -32t20.5 -83zM365 316q0 76 -35 76\u0000q-31 0 -93.5 -49t-107.5 -110q-12 -37 -17 -70q-9 -65 12 -96.5t59 -31.5q31 0 56 14q53 29 89.5 105t36.5 162z\" /> ) values in the order of 106 M−1. The ligands and their metal complexes were tested for antibacterial and antifungal activities by agar disc diffusion method. Except for complex 4, all complexes showed considerable activity almost equal to the activity of ciprofloxacin. These complexes did not show any effect on Gram-negative bacteria, whereas they showed moderate activity for Gram-positive strains.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"78 1","pages":"1-11"},"PeriodicalIF":0.0,"publicationDate":"2013-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75090087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Synthesis and Characterization of Heteronuclear Copper(II)-Lanthanide(III) Complexes of N,N′-1,3-Propylenebis(Salicylaldiminato) Where Lanthanide(III) = Gd or Eu N,N ' -1,3-丙烯双(水杨酸钠)异核铜(II)-镧系(III)配合物的合成与表征。镧系(III) = Gd或Eu
International Journal of Inorganic Chemistry Pub Date : 2013-05-28 DOI: 10.1155/2013/281270
L. J. Singh, Rajkumar Hemakumar Singh
{"title":"Synthesis and Characterization of Heteronuclear Copper(II)-Lanthanide(III) Complexes of N,N′-1,3-Propylenebis(Salicylaldiminato) Where Lanthanide(III) = Gd or Eu","authors":"L. J. Singh, Rajkumar Hemakumar Singh","doi":"10.1155/2013/281270","DOIUrl":"https://doi.org/10.1155/2013/281270","url":null,"abstract":"Three complexes, namely, [Cu(salbn)] (1), [Cu(salbn)Gd(NO3)3·H2O] (2), and [Cu(salbn)Eu(NO3)3·H2O] (3) where salbn = N,N′-1,3-propylenebis (salicylaldiminato) have been synthesized and characterized by elemental analyses, ICP-AES, IR, UV, NMR, MS, EDX, powder XRD, and EPR spectroscopies. The EDX results suggest the presence of two different metal ions in heteronuclear complexes (2) and (3). The ligand(salbn), complex (1), and complex (3) crystallize in triclinic system while complex (2) crystallizes in monoclinic system. The EPR studies suggest that [Cu(salbn)] complex is tetragonally coordinated monomeric copper(II) complex with unpaired electron in the orbital and spectral features that are the characteristics of axial symmetry while complex (2) in DMF solution at liquid nitrogen temperature exhibits an anisotropic broad signal around g ~ 2.03 which may suggest a weak magnetic spin-exchange interaction between Gd(III) and Cu(II) ions. The fluorescence intensity of Eu(III) decreased markedly in the complex (3).","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"46 20 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2013-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88918863","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Synthesis, Spectroscopic, and Magnetic Studies of Mono- and Polynuclear Schiff Base Metal Complexes Containing Salicylidene-Cefotaxime Ligand 含水杨苷-头孢噻肟配体的单核和多核希夫碱金属配合物的合成、光谱和磁性研究
International Journal of Inorganic Chemistry Pub Date : 2013-04-30 DOI: 10.1155/2013/108740
J. Anacona, Johan Calvo, O. Almanza
{"title":"Synthesis, Spectroscopic, and Magnetic Studies of Mono- and Polynuclear Schiff Base Metal Complexes Containing Salicylidene-Cefotaxime Ligand","authors":"J. Anacona, Johan Calvo, O. Almanza","doi":"10.1155/2013/108740","DOIUrl":"https://doi.org/10.1155/2013/108740","url":null,"abstract":"Metal complexes of a Schiff base ligand derived from cefotaxime and salicylaldehyde were prepared. The salicilydene-cefotaxime ligand (H2L) and mononuclear [M(L)] (M(II) = Co, Ni and Cu), dinuclear [Ag2(L)(OAc)2], and tetranuclear metal complexes [M4(L)(OH)6] (M(II) = Ni, Cu) were characterized on the basis of analytical, thermal, magnetic, and spectral studies (IR, UV-visible, 1H NMR, 13C NMR, and EPR). The electronic spectra of the complexes and their magnetic moments suggesttetrahedral geometry for the isolated complexes. The complexes are nonelectrolytes and insoluble in water and common organic solvents but soluble in DMSO.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"57 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2013-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72697633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
Synthesis, Characterization, and Antibacterial Activity of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) Complexes of Schiff's Base Type Ligands Containing Benzofuran Moiety 含苯并呋喃基团席夫碱型配体Co(II)、Ni(II)、Cu(II)、Zn(II)、Cd(II)和Hg(II)配合物的合成、表征和抗菌活性
International Journal of Inorganic Chemistry Pub Date : 2013-04-24 DOI: 10.1155/2013/614628
N. Reddy, B. Shankara, P. M. Krishana, C. Basavaraj, B. Mahesh
{"title":"Synthesis, Characterization, and Antibacterial Activity of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) Complexes of Schiff's Base Type Ligands Containing Benzofuran Moiety","authors":"N. Reddy, B. Shankara, P. M. Krishana, C. Basavaraj, B. Mahesh","doi":"10.1155/2013/614628","DOIUrl":"https://doi.org/10.1155/2013/614628","url":null,"abstract":"Six new complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) with substituted benzofuran derivatives have been synthesized and characterized by elemental analysis, magnetic moments, conductance measurements, spectral characterization, and so forth. Elemental data coincide with the general formula , where L = (E)-7-Methoxy-N1-(2,4,5-trimethoxy benzylidene) benzofuran-2-carbohydrazide (L1) or (E)-N1-(2,6-dichloro benzylidene)-7-methoxy benzofuran-2-carbohydrazide (L2), of the complexes. The ligands coordinate to the metal ions through the oxygen of the carbonyl group and the nitrogen of the hydrazine group. Electronic spectral data of the complexes suggests the probable geometry is octahedral in nature. All the complexes and ligands were screened for their antibacterial activity. Among them, Co, Ni, and Cu complexes of L2 showed good activity against all microbes.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"2013 1","pages":"1-10"},"PeriodicalIF":0.0,"publicationDate":"2013-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87874584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Syntheses and Characterization of the Coordination Compounds of N-(2-hydroxymethylphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one N-(2-羟基甲基苯基)- c -(3′-羧基-2′-羟基苯基)噻唑烷-4-酮配位化合物的合成与表征
International Journal of Inorganic Chemistry Pub Date : 2013-03-11 DOI: 10.1155/2013/524179
Dinesh Kumar, Amit Kumar, D. Dass
{"title":"Syntheses and Characterization of the Coordination Compounds of N-(2-hydroxymethylphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one","authors":"Dinesh Kumar, Amit Kumar, D. Dass","doi":"10.1155/2013/524179","DOIUrl":"https://doi.org/10.1155/2013/524179","url":null,"abstract":"A dry benzene solution of the Schiff base N-(2-hydroxymethylphenyl)-3′-carboxy-2′-hydroxybenzylideneimine upon reacting with mercaptoacetic acid undergoes cyclization and forms N-(2-hydroxymethylphenyl)-C-(3′-carboxy-2′-hydroxyphenyl)thiazolidin-4-one, LH3 (I). A MeOH solution of I reacts with Co(II), Ni(II), Cd(II), Zr(OH)2(IV), and UO2(VI) ions and forms the monomeric coordination compounds, [M(LH)(MeOH)3] [where M = Co(II), Ni(II)], [M′(LH)(MeOH)] [here M′ = Cd(II), UO2(VI)] and [Zr(OH)2(LH)(MeOH)]. The coordination compounds have been characterized on the bases of elemental analyses, molar conductance, molecular weight, spectral (IR, NMR, and reflectance) studies, and magnetic susceptibility measurements. I behaves as a dibasic tridentate OOS donor ligand in these compounds. The compounds are nonelectrolytes ( = 3.8–8.9 mho cm2 mol−1) in DMF. A tetrahedral structure for [Cd(LH)(MeOH)] and an octahedral structure for the remaining compounds are suggested.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"1 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82141243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Detection of Metal Ions and Protons with a New Blue Fluorescent Bis(1,8-Naphthalimide) 新型蓝色荧光双(1,8-萘酰亚胺)检测金属离子和质子
International Journal of Inorganic Chemistry Pub Date : 2013-02-28 DOI: 10.1155/2013/628946
S. Yordanova, S. Stoianov, I. Grabchev, I. Petkov
{"title":"Detection of Metal Ions and Protons with a New Blue Fluorescent Bis(1,8-Naphthalimide)","authors":"S. Yordanova, S. Stoianov, I. Grabchev, I. Petkov","doi":"10.1155/2013/628946","DOIUrl":"https://doi.org/10.1155/2013/628946","url":null,"abstract":"The synthesis of a new blue fluorescent bis(1,8-naphthalimide) has been described and its basic photophysical characteristics have been investigated in organic solvents of different polarity. The detection of protons and different metal cations (Ag","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"13 1","pages":"1-6"},"PeriodicalIF":0.0,"publicationDate":"2013-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74244968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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