发布求助
文献互助 智能选刊 最新文献

International journal of electrochemistry最新文献

筛选
英文 中文
An Empirical Rate Constant Based Model to Study Capacity Fading in Lithium Ion Batteries 基于经验速率常数的锂离子电池容量衰退模型研究
IF 1.8
International journal of electrochemistry Pub Date : 2015-07-07 DOI: 10.1155/2015/439015
Srivatsan Ramesh, K. Ratnam, Balaji Krishnamurthy
{"title":"An Empirical Rate Constant Based Model to Study Capacity Fading in Lithium Ion Batteries","authors":"Srivatsan Ramesh, K. Ratnam, Balaji Krishnamurthy","doi":"10.1155/2015/439015","DOIUrl":"https://doi.org/10.1155/2015/439015","url":null,"abstract":"A one-dimensional model based on solvent diffusion and kinetics to study the formation of the SEI (solid electrolyte interphase) layer and its impact on the capacity of a lithium ion battery is developed. The model uses the earlier work on silicon oxidation but studies the kinetic limitations of the SEI growth process. The rate constant of the SEI formation reaction at the anode is seen to play a major role in film formation. The kinetics of the reactions for capacity fading for various battery systems are studied and the rate constants are evaluated. The model is used to fit the capacity fade in different battery systems.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2015 1","pages":"1-9"},"PeriodicalIF":1.8,"publicationDate":"2015-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2015/439015","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64967162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Modeling the Lithium Ion/Electrode Battery Interface Using Fick’s Second Law of Diffusion, the Laplace Transform, Charge Transfer Functions, and a [4, 4] Padé Approximant 利用菲克第二扩散定律、拉普拉斯变换、电荷传递函数和[4,4]pad<s:1>近似法对锂离子/电极电池界面进行建模
IF 1.8
International journal of electrochemistry Pub Date : 2015-06-17 DOI: 10.1155/2015/496905
J. Summerfield, Charles N. Curtis
{"title":"Modeling the Lithium Ion/Electrode Battery Interface Using Fick’s Second Law of Diffusion, the Laplace Transform, Charge Transfer Functions, and a [4, 4] Padé Approximant","authors":"J. Summerfield, Charles N. Curtis","doi":"10.1155/2015/496905","DOIUrl":"https://doi.org/10.1155/2015/496905","url":null,"abstract":"This work investigates a one-dimensional model for the solid-state diffusion in a LiC6/LiMnO2 rechargeable cell. This cell is used in hybrid electric vehicles. In this environment the cell experiences low frequency electrical pulses that degrade the electrodes. The model’s starting point is Fick’s second law of diffusion. The Laplace transform is used to move from time as the independent variable to frequency as the independent variable. To better understand the effect of frequency changes on the cell, a transfer function is constructed. The transfer function is a transcendental function so a Pade approximant is found to better describe the model at the origin. Consider .","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2015 1","pages":"1-5"},"PeriodicalIF":1.8,"publicationDate":"2015-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2015/496905","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64999710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes 聚甲基丙烯酸甲酯凝胶电解质膜的结构与电化学分析
IF 1.8
International journal of electrochemistry Pub Date : 2015-01-18 DOI: 10.1155/2015/494308
C. M. Mathew, K. Kesavan, S. Rajendran
{"title":"Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes","authors":"C. M. Mathew, K. Kesavan, S. Rajendran","doi":"10.1155/2015/494308","DOIUrl":"https://doi.org/10.1155/2015/494308","url":null,"abstract":"New gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value  S cm−1 has been achieved. XRD and FT-IR studies have been conducted to investigate the structure and complexation in the polymer gel electrolytes. The FT-IR spectra show that the functional groups C=O and C≡N play major role in ion conduction. Thermal stability of the prepared membranes is found to be about 180°C.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2015 1","pages":"1-7"},"PeriodicalIF":1.8,"publicationDate":"2015-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2015/494308","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64998213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 29
Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes 电催化氧化钒(IV) Salen电极上半胱氨酸的测定
IF 1.8
International journal of electrochemistry Pub Date : 2014-12-28 DOI: 10.1155/2014/316254
P. Sonkar, V. Ganesan, V. Rao
{"title":"Electrocatalytic Oxidation and Determination of Cysteine at Oxovanadium(IV) Salen Coated Electrodes","authors":"P. Sonkar, V. Ganesan, V. Rao","doi":"10.1155/2014/316254","DOIUrl":"https://doi.org/10.1155/2014/316254","url":null,"abstract":"A transition metal complex, oxovanadium(IV) salen (where salen represents N,N′-bis(salicylidene)ethylenediamine) is immobilized on glassy carbon (GC) electrodes and utilized for electrocatalytic oxidation of cysteine. In presence of oxovanadium(IV) salen, increased oxidation current is observed due to the effective oxidation of cysteine by the electrogenerated oxovanadium(V) salen species. The oxidation current linearly varies with the concentration of cysteine from 0.1 to 1.0 mM. The modified electrode has good sensitivity and low limit of detection. These properties make the oxovanadium(IV) salen as an effective electrocatalyst for the determination of cysteine.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2014 1","pages":"1-6"},"PeriodicalIF":1.8,"publicationDate":"2014-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2014/316254","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64438123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Selection of the Best Process Stream to Remove Ca2 选择去除Ca2的最佳工艺流
IF 1.8
International journal of electrochemistry Pub Date : 2014-12-14 DOI: 10.1155/2014/304296
Jogi Ganesh Dattatreya Tadimeti, Shilpi Jain, S. Chattopadhyay, P. Bhattacharya
{"title":"Selection of the Best Process Stream to Remove Ca2","authors":"Jogi Ganesh Dattatreya Tadimeti, Shilpi Jain, S. Chattopadhyay, P. Bhattacharya","doi":"10.1155/2014/304296","DOIUrl":"https://doi.org/10.1155/2014/304296","url":null,"abstract":"Electrodialytic removal of calcium chloride (CaCl2, 25–50 mol·m−3) from 5% sugar solution was executed in batch recirculation mode. Calcium ion removal rate was monitored with (i) applied potential, (ii) feed flow rate, (iii) solution viscosity and conductivity, and (iv) catholyte streams (NaOH or sodium salt of ethylene diamine tetraacetic acid-acetic acid, Na2EDTA-AA). Unsteady state model for ion concentration change was written for the ED cell used. Linearized Nernst-Planck equation instead of Ohm’s law was applied to closely obtain the current density and concentration change theoretically. The model developed could closely predict the experimental observation. Mass transfer coefficients and specific energy densities were estimated for each combination of catholyte stream used. NaOH showed better performance for a short duration over Na2EDTA-acetic acid combination.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2014 1","pages":"1-12"},"PeriodicalIF":1.8,"publicationDate":"2014-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2014/304296","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64430602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Solvent Effects on the Electrochemical Behavior of TAPD-Based Redox-Responsive Probes for Cadmium(II) 溶剂对基于tapd的镉氧化还原响应探针电化学行为的影响
IF 1.8
International journal of electrochemistry Pub Date : 2014-11-25 DOI: 10.1155/2014/305721
Rihab Sahli, J. Bahri, I. Tapsoba, K. Boujlel, N. Raouafi
{"title":"Solvent Effects on the Electrochemical Behavior of TAPD-Based Redox-Responsive Probes for Cadmium(II)","authors":"Rihab Sahli, J. Bahri, I. Tapsoba, K. Boujlel, N. Raouafi","doi":"10.1155/2014/305721","DOIUrl":"https://doi.org/10.1155/2014/305721","url":null,"abstract":"Two tetralkylated phenylenediamines (TAPD) 1 and 2 have been prepared by reductive alkylation of para-dimethylaminoaniline with furfural or thiophene 2-carboxaldehyde, respectively. Their chelation ability has been evaluated as electrochemical guest-responsive chemosensors for Cd(II) in acetonitrile (ACN), dimethylformamide (DMF), propylene carbonate (PC), and nitromethane (NM). The voltamperometric studies showed that these compounds are able to bind the Cd(II) cation with strong affinities except in DMF. The redox features of the chemosensors changed drastically when they are bounded to Cd(II) to undergo important anodic potential peak shifts comprised between ca. 500 and ca. 900 mV depending on the solvent. The addition of ∼4–10% molar triflic acid (TfOH) was found to be necessary to achieve rapidly the cation chelation which is slow without the acid. The electrochemical investigations suggested the formation of 1 : 2 stoichiometry complexes [Cd(L)2]2","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2014 1","pages":"1-9"},"PeriodicalIF":1.8,"publicationDate":"2014-11-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2014/305721","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64430792","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Action of Chicory Fructooligosaccharides on Biomimetic Membranes 菊苣低聚果糖对仿生膜的作用
IF 1.8
International journal of electrochemistry Pub Date : 2014-11-16 DOI: 10.1155/2014/186109
A. F. Barbosa, R. Henrique, A. M. Lucho, V. Paffaro, J. Schneedorf
{"title":"Action of Chicory Fructooligosaccharides on Biomimetic Membranes","authors":"A. F. Barbosa, R. Henrique, A. M. Lucho, V. Paffaro, J. Schneedorf","doi":"10.1155/2014/186109","DOIUrl":"https://doi.org/10.1155/2014/186109","url":null,"abstract":"Fructooligosaccharides from chicory (FOSC) are functional prebiotic foods recognized to exert several well-being effects in human health and animal production, as decreasing blood lipids, modulating the gut immune system, enhancing mineral bioavailability, and inhibiting microbial growth, among others. Mechanisms of actions directly on cell metabolism and structure are however little known. In this sense this work was targeted to investigate the interaction of FOSC with biomimetic membranes (liposomes and supported bilayer membrane; s-BLM) through cyclic voltammetry, impedance spectroscopy, spectrofluorimetry, and microscopy. FOSC was able to disrupt the membrane structure of liposomes and s-BLM from the onset of molecular pores induced on it. The mechanism of interaction of fructans with biomimetic membranes suggests hydrogen bonding between the polyhydroxylated structure of the oligosaccharides and the negative polar group of L--phosphatidylcholine (PC) present in both liposomes and s-BLM.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2014 1","pages":"1-8"},"PeriodicalIF":1.8,"publicationDate":"2014-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2014/186109","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64382006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Low Cobalt Loading on TiO2 Nanotube Arrays for Water-Splitting 低钴负载对TiO2纳米管阵列水分解的影响
IF 1.8
International journal of electrochemistry Pub Date : 2014-11-09 DOI: 10.1155/2014/904128
A. Pozio
{"title":"Effect of Low Cobalt Loading on TiO2 Nanotube Arrays for Water-Splitting","authors":"A. Pozio","doi":"10.1155/2014/904128","DOIUrl":"https://doi.org/10.1155/2014/904128","url":null,"abstract":"This work is intended to define a new possible methodology for the TiO2 doping through the use of an electrochemical deposition of cobalt directly on the titanium nanotubes obtained by a previous galvanostatic anodization treatment in an ethylene glycol solution. This method does not seem to cause any influence on the nanotube structure, showing final products with news and interesting features with respect to the unmodified sample. Together with an unmodified photoconversion efficiency under UV light, the cobalt doped specimen reports an increase of the electrocatalytic efficiency for the oxygen evolution reaction (OER).","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2014 1","pages":"127-133"},"PeriodicalIF":1.8,"publicationDate":"2014-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2014/904128","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64731329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Synthesis and Characterization of Electrodeposited C-PANI-Pd-Ni Composite Electrocatalyst for Methanol Oxidation 电沉积C-PANI-Pd-Ni复合甲醇氧化电催化剂的合成与表征
IF 1.8
International journal of electrochemistry Pub Date : 2014-10-16 DOI: 10.1155/2014/383892
S. Mahapatra, S. Shekhar, B. Thakur, H. Priyadarshi
{"title":"Synthesis and Characterization of Electrodeposited C-PANI-Pd-Ni Composite Electrocatalyst for Methanol Oxidation","authors":"S. Mahapatra, S. Shekhar, B. Thakur, H. Priyadarshi","doi":"10.1155/2014/383892","DOIUrl":"https://doi.org/10.1155/2014/383892","url":null,"abstract":"Electropolymerization of aniline at the graphite electrodes was achieved by potentiodynamic method. Electrodeposition of Pd (C-PANI-Pd) and Ni (C-PANI-Ni) and codeposition of Pd-Ni (C-PANI-Pd-Ni) microparticles into the polyaniline (PANI) film coated graphite (C-PANI) were carried out under galvanostatic control. The morphology and composition of the composite electrodes were obtained using scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX) techniques. The electrochemical behavior and electrocatalytic activity of the electrode were characterized using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometric (CA) methods in acidic medium. The C-PANI-Pd-Ni electrode showed an improved catalytic performance towards methanol oxidation in terms of lower onset potential, higher anodic oxidation current, greater stability, lower activation energy, and lower charge transfer resistance. The enhanced electrocatalytic activity might be due to the greater permeability of C-PANI films for methanol molecules, better dispersion of Pd-Ni microparticles into the polymer matrixes, and the synergistic effects between the dispersed metal particles and their matrixes.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2014 1","pages":"1-8"},"PeriodicalIF":1.8,"publicationDate":"2014-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2014/383892","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64471655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Role of Indium Alloying with Lead as a Means to Reduce the Passivation Phenomena in Lead/Acid Batteries 铟与铅合金化在减少铅酸电池钝化现象中的作用
IF 1.8
International journal of electrochemistry Pub Date : 2014-09-23 DOI: 10.1155/2014/932654
A. El-Sayed, H. Mohran, H. A. Shilkamy
{"title":"Role of Indium Alloying with Lead as a Means to Reduce the Passivation Phenomena in Lead/Acid Batteries","authors":"A. El-Sayed, H. Mohran, H. A. Shilkamy","doi":"10.1155/2014/932654","DOIUrl":"https://doi.org/10.1155/2014/932654","url":null,"abstract":"The influence of indium content on the anodic behaviour of Pb-In alloys in 4 M H2SO4 solution is investigated by potentiodynamic, potentiostatic, chronopotentiometric, and cyclic voltammetric techniques. The composition and microstructure of the corrosion layer on Pb-In alloys are characterized by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy analysis (EDX), and scanning electron microscopy (SEM). The potentiodynamic and chronopotentiometric curves show that the anodic behavior of all investigated electrodes exhibits active/passive transition. The active dissolution (except for alloy I) and passive currents increase with increasing both In content and temperature. This indicates that the conductivity of the anodic film on Pb-In alloy is enhanced. This study exhibits that indium catalyses the oxidation of Pb (II) to Pb (IV) and facilitates the formation of a more highly conductive corrosion layer on lead. Alloy I (0.5% In) exhibits that the corrosion rate is lower, while the passive current is higher than that of Pb. XRD, EDX, and SEM results reveal that the formation of both PbSO4 and PbO on the surface decreases gradually with increasing In level in the alloy and completely disappear at higher In content (15% In). Therefore, recharge of the battery will be improved due to indium addition to Pb.","PeriodicalId":13933,"journal":{"name":"International journal of electrochemistry","volume":"2014 1","pages":"1-16"},"PeriodicalIF":1.8,"publicationDate":"2014-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1155/2014/932654","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"64750143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
首页 上一页 下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：604180095
Book学术官方微信
小红书