Industrial laboratory. Diagnostics of materials最新文献

{"title":"Application of piezoelectric sensors to aspartame determination in fluids","authors":"A. Y. Vybornyi, O. A. Shuvalova, A. Zyablov, Nhat Linh Cao","doi":"10.26896/1028-6861-2024-90-7-27-31","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-7-27-31","url":null,"abstract":"The study touches the development of piezoelectric sensors based on molecularly imprinted polymers (MIPs) with an aspartame imprint. The values of the imprinting factors and the selectivity coefficients of the developed sensor MIP-E951 in relation to target molecules and other sweeteners were calculated to confirm the ability of MIP -951 to selective detection of aspartame. The range of determined concentrations is 1 – 1 × 10–3 g/liter, the detection limit of aspartame is 5 × 10–4 g/liter. When analyzing model solutions, it was found that foreign components usually present in soft drinks do not interfere with the determination of aspartame using the developed sensor. The obtained sensors were tested for the determination of aspartame in soft drinks. Chromatographic analysis was used as a reference method. The results obtained by both methods indicate that piezo sensors can be successfully used for the analysis of aspartame in liquid media. The error of determination does not exceed 8%.","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141798487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study of the dielectric properties of decomposing materials during heating","authors":"V. P. Krylov, R. A. Chirkov, A. E. Zhitelev, M. O. Zabezhailov","doi":"10.26896/1028-6861-2024-90-5-33-39","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-33-39","url":null,"abstract":"The dielectric properties of materials when heated at ultrahigh frequencies are determined by methods based on the use of waveguide cavity resonators. However, as the sample is in the closed volume during measurements, the dielectric properties of destructive material thus determined can contain errors attributed filling of the resonator volume and depositing products of the sample decomposition on the internal conducting surfaces of the resonator. We present the results of studying the dielectric properties of destructive materials under heating in waveguide resonator cavity using methods that exclude the impact of destruction products on the accuracy of measurement. To reduce the influence of destructive vapors rising from the surface of the sample during the destruction process, additional thin quartz plates, placed on the sample surface were used. In addition, cuvettes with a lid were also used to prevent destruction products from entering the resonator volume. A method for taking into account the effect of plates and cuvettes in calculating the dielectric constant and dielectric loss tangent of a material sample when heated in a cavity resonator is presented. Changes in the dielectric properties of a composite material consisting of quartz fabric impregnated with an aluminochromophosphate binder and fiberglass laminate made of quartz fabric impregnated with a phenol-formaldehyde binder were studied in a temperature range above the onset of the destruction (up to temperatures at which loss of the structural strength of the material is observed). The developed method can be used in studying the thermophysical properties of destructive materials to assess changes in their dielectric characteristics under operation conditions of high-temperature heating.","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141106649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Identification of structural defects and their impact on the magnetic memory, static and cyclic strength of VNS9-SH thin sheet trip-steel","authors":"A. A. Dubov, A. V. Yamchuk, A. A. Sobranin, A. К. Slizov, A. V. Arsenov, D. V. Prosvirnin, A. Yu. Marchenkov","doi":"10.26896/1028-6861-2024-90-5-60-68","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-60-68","url":null,"abstract":"Identification of microstructure defects, which are stress concentrators (SC) during the operation of mechanical engineering products, is an important scientific and practical task relevant for manufacturing enterprises. This problem becomes especially urgent and difficult for critical helicopter parts made of sheet TRIP steel VNS9-Sh (23Kh15N5AM3-Sh) and operating under cyclic loads due to the complex microstructure of the steel and small thickness of strips and sheets. To assess the impact of structural defects on the cyclic strength of products made of the steel under study, the specimens were preliminary sorted proceeding from the results of their testing using the method of metal magnetic memory (MMM) and metallographic studies. The MMM method is a structure-sensitive procedure which provides information about the presence of structural defects that arise during the manufacture. Magnetic anomalies in the form of sharp local changes in the intrinsic stray magnetic field (SSMF) (H) and its gradient |ΔH| along the length of the controlled section Δx, were identified on the surface of sheets cut from five different batches. A conventional classification of the identified anomalies was made according to the magnitude of the magnetic field gradient. The specimens of two types were cut in zones of magnetic anomalies and outside them: type 1 — for cyclic tests and type 2 — for metallographic studies. The geometric parameters and field gradient values of magnetic anomalies on specimens of type 1 and type 2 were the same. Metallographic studies in zones of maximum magnetic field gradient on type 2 specimens revealed defects in the form of a strip at the boundary of different structures, which is a structural stress concentrator (SSC) and a source of the inhomogeneity and changes in the magnetic properties. Type 1 specimens with similar magnetic anomalies and Type 1 specimens cut from sheets outside zones of magnetic anomalies were then selected for cyclic testing. Comparative tests for cyclic strength of the specimens with and without specified SSC were carried out. It is shown that the presence of SSC zones in the specimens reduces the number of cycles to failure during cyclic tests by 1 – 2 orders of magnitude compared to the specimens free of SSC. Based on cyclic tensile tests of specimens, a limiting value of the magnetic field gradient was determined that corresponds to the acceptable level of stress concentration on structural defects. This value is recommended for use as a rejection criterion when examining a new tape by the MMM method. ","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141103965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A method for determining the spectral relaxation functions of polymers under single stretching of micro samples","authors":"A. A. Rybin, D. V. Ruban, A. A. Chervyakov, S. A. Ulyanov","doi":"10.26896/1028-6861-2024-90-5-53-59","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-53-59","url":null,"abstract":"The principles of designing products made of the latest complex-structured polymer composite materials necessitate the need to take into account the large-scale structural effects determined by processes at the supramolecular and molecular levels of the polymer: relaxation, kinetic (breaking and recombination of chemical bonds), recrystallization of supramolecular structures, etc. The development of these processes is described by relaxation functions, which, in turn, can be calculated using the functions of relaxation time spectra. The purpose of the work was to develop a specialized equipment for testing micro-samples with a variable working part for uniaxial stretching along with the experimental technique and computational algorithms for processing the obtained measurement data, and experimental approbation of the developed approach to determining spectral relaxation functions. A method is proposed for estimating relaxation functions not at fixed stress levels within linear elasticity, at secant points of deformation diagrams, at fixed values of the linear elasticity modulus, but within an extended range of the sample deformation up to pre-rupture states. A set of test equipment designed for tensile tests of micro-samples with a thickness of the working part of 0.2 – 1.2 mm has been developed. The tooling can be installed on modern high-precision breaking machines. Tensile tests of polyethylene terephthalate micro-samples with a thickness of 50 and 175 μm were carried out taking into account the scale factor. A tensile test of micro-samples that are technologically stabilized by paper frames of a special shape is described. Diagrams illustrating the kinetics of changes in the spectral relaxation functions of oriented polyethylene terephthalate (PET) are constructed proceeding from the data of testing micro-samples with a constant strain rate. A method for using these diagrams in calculations of empirical relaxation time spectra is described. The results of testing micro-samples of polyethylene terephthalate are presented. Illustrative deformation diagrams of the studied polymer samples and calculated diagrams of functions of relaxation time spectra calculated according to the described method are given.","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141105189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-strain rate deformation of aluminum during the Taylor test","authors":"N. V. Melekhin, A. D. Tukalov, A. A. Bobrov, V. V. Balandin, A. V. Nokhrin","doi":"10.26896/1028-6861-2024-90-5-46-52","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-46-52","url":null,"abstract":"The aim of the study is to develop a methodology for assessing changes in the microstructure of aluminum under dynamic deformation in a rather wide range of the strain rate and strain degree. The distribution of the microstructure and the strength properties in the cross-section of pure aluminum samples (A99) after dynamic deformation according to the Taylor test were studied. The tests were carried out at room temperature using a PG-20 light-gas cannon, at sample throwing speeds of 127 and 165 m/sec. An interference microscope (Leica IM DRM) and a scanning electron microscope (Jeol JSM-6490) were used to study the aluminum microstructure; the microhardness measurements were carried out on an HVS-1000 device to study the uniformity of the strain distribution in samples. It is shown that three characteristic areas can be distinguished in aluminum samples after Taylor test: the elastic deformation zone, the plastic deformation zone, and the zone of severe plastic deformation, which is located in the area of collision of the sample with a steel barrier. It is shown that dynamic deformation reduced the grain structure from 1 – 1.1 mm to 2.5 – 3 μm at high impact velocities. An elongated grain shape is observed in the collision zone. The proposed method provided determination of the critical strain degree necessary for the onset of grain fragmentation and allowed us to explain the formation of zones of weak and severe plastic deformation. It is shown that the critical strain degree corresponding to the beginning of grain fragmentation increases from 0.18 to 0.21 with an increase in the throwing speed of the sample from 127 to 165 m/sec. In the zone of weak deformation, plastic deformation proceeds by intragrain riveting and the initial stages of grain fragmentation. In the zone of severe plastic deformation, a fine-grained microstructure is formed, which leads to an increase in the microhardness of aluminum in accordance with the Hall – Petch equation.","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141105603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Methodological issues of the fuzzy set theory (generalizing article)","authors":"A. I. Orlov","doi":"10.26896/1028-6861-2024-90-5-69-78","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-69-78","url":null,"abstract":"The theory of fuzziness is an important area of modern theoretical and applied mathematics. The methodology of the theory of fuzziness is a doctrine of organizing activities in the field of development and application of the scientific results of this theory. We discuss some methodological issues of the theory of fuzziness, i.e., individual components of the methodology in the area under consideration. The theory of fuzziness is a science of pragmatic (fuzzy) numbers and sets. The ancient Greek philosopher Eubulides showed that the concepts «Heap» and «Bald» cannot be described using natural numbers. E. Borel proposed to define a fuzzy set using a membership function. A fundamentally important step was taken by L. A. Zadeh in 1965. He gave the basic definitions of the algebra of fuzzy sets and introduced the operations of intersection, product, union, sum, negation of fuzzy sets. The main thing he did was demonstration of the possibilities of expanding («doubling») mathematics: by replacing the numbers and sets used in mathematics with their fuzzy counterparts, we obtain new mathematical formulations. In the statistics of non-numerical data, methods of statistical analysis of fuzzy sets have been developed. Interval and triangular fuzzy numbers are often used specific types of membership functions. The theory of fuzzy sets in a certain sense is reduced to the theory of random sets. We think fuzzy and that is the only reason we understand each other. The paradox of the fuzzy theory is that it is impossible to consistently implement the thesis «Everything in the world is fuzzy». For ordinary fuzzy sets, the argument and values of the membership function are crisp. If they are replaced by fuzzy analogues, then their description will require their own clear arguments and membership functions, and so on ad infinitum. System fuzzy interval mathematics proceeds from the need to take into account the fuzziness of the initial data and the prerequisites of the mathematical model. One of the options for its practical implementation is an automated system-cognitive analysis and the intellectual system «Eidos».","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141106841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Alexander Ivanovich Orlov (on his 75th birthday)","authors":"Article Editorial","doi":"10.26896/1028-6861-2024-90-5-88","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-88","url":null,"abstract":"<jats:p>.</jats:p>","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141107123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Descent along nodal straight lines and simplex algorithm: two variants of regression analysis based on the least absolute deviation method","authors":"O. A. Golovanov, A. N. Tyrsin","doi":"10.26896/1028-6861-2024-90-5-79-87","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-79-87","url":null,"abstract":"A comparative analysis of the computational complexity of exact algorithms for estimating linear regression equations was conducted using the least absolute deviation method. The goal of the study is to compare the computational efficiency of exact algorithms for descent along nodal lines and algorithms based on solving linear programming problems. For this purpose, the algorithm of gradient descent along nodal lines and algorithms for solving the equivalent primal and dual linear programming problems using the simplex method were considered. The computational complexity of algorithms for implementing the method of least modules in solving direct and dual linear programming problems was estimated. A comparison between the average time for determining the regression coefficients using the primal and dual linear programming problems and the average time for gradient descent along nodal lines was conducted using the Monte Carlo method of statistical experiments. It is shown that both options are significantly inferior behind gradient descent along nodal lines, both in terms of the computational complexity of the algorithms and in terms of computation time, and this advantage increases with the sample size, reaching hundred times or more.","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141107780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Accelerated corrosion tests of a contact pair austenitic stainless steel – titanium alloy","authors":"B. A. Gusev, A. A. Efimov, V. V. Martynov, A. N. Maksimova","doi":"10.26896/1028-6861-2024-90-5-40-45","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-40-45","url":null,"abstract":"The results of accelerated corrosion tests of a pair of austenitic stainless steel — titanium alloy under conditions of elevated temperatures and high concentrations of corrosive agents are presented, conditions for the developing the mechanism of local corrosion being the same. The proposed approach included provoking the appearance of microstress concentrators by three-point loading of test samples with subsequent forced development of local types of corrosion through simultaneous exposure to an increased concentration of corrosive agents and temperatures at a fixed exposure in an autoclave. The results of modeling the corrosion process in a titanium alloy being in contact with stainless steel are assessed proceeding from the data obtained from metallographic studies of the state of surface layers of the metal and the morphology of corrosion products on prepared sections of the surface of templates cut from the samples under study. We considred a pair of steel 08Kh18N10T — titanium alloy VT-5. It is shown that the contact of samples under conditions of accelerated corrosion tests does not lead to a significant development of local types of corrosion of the titanium alloy. On the contrary, analysis of the state of the surface layers of the samples of stainless steel revealed the presence of deep corrosion pits, triggering the intergranular corrosion. In this case, corrosion of austenitic steel, both in the presence and in the absence of contact with titanium, proceeded in three stages: the initiation and fusion of pitting; formation of knife corrosion ulcers; propagation of intergranular cracks into the depth of steel. The proposed methodology of corrosion testing can be used to predict the possible nature of the development of metal corrosion under operating conditions that form local zones of static stresses in structural materials, and for prompt response to extend the design life of the equipment at thermal and nuclear power facilities.","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141104755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synchrotron small-angle X-ray scattering study of flame retardants based on ammonium sulfate and disubstituted ammonium phosphate","authors":"A. Petrakov, Y. Zubavichus, B. A. Makeev","doi":"10.26896/1028-6861-2024-90-5-27-32","DOIUrl":"https://doi.org/10.26896/1028-6861-2024-90-5-27-32","url":null,"abstract":"The use of wood in structural and finishing materials can significantly reduce the time of building construction, but the high flammability of wood limits its use in the building industry. To increase fire resistance, wooden structures are impregnated with flame retardants and the penetrating ability depends on their structure. We present the results of a small-angle X-ray scattering study of the structure of flame retardants based on ammonium sulfate and phosphate. The radii of inertia of hydrated complexes formed when flame retardants are dissolved in water, their shape and type of chains along which hydrated ions are located are determined. It is revealed that the presence of diffraction maxima indicates the presence of an ordering in the arrangement of hydrated ions. Aqueous solutions of ammonium sulfate and disubstituted ammonium phosphate contain two types of hydrated complexes of the same shape but different radius of inertia. At the same time, hydrated ions in complexes are located along persistent chains, and ordering revealed in the arrangement of ions, depended on their type. The results obtained can be used in developing flame retardants with a reduced radius of inertia, which will increase the penetrating capacity of the processing solution and increase the fire safety of wooden structures.","PeriodicalId":13559,"journal":{"name":"Industrial laboratory. Diagnostics of materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141105174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}