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Kinetic Model for High-Temperature Oxidation of Lubricants 润滑油高温氧化动力学模型
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A601
Satish K. Naidu, E. Klaus, J. L. Duda
{"title":"Kinetic Model for High-Temperature Oxidation of Lubricants","authors":"Satish K. Naidu, E. Klaus, J. L. Duda","doi":"10.1021/I300024A601","DOIUrl":"https://doi.org/10.1021/I300024A601","url":null,"abstract":"L'evaporation et l'oxydation du neopentyl polyolester trimethylopropane triheptanoate sont etudiees en laboratoire. Les constantes cinetiques de l'oxydation primaire et les reactions de polymerisation sont determinees. Les vitesses de reaction sont du premier ordre. Les resultats des essais d'evaporation et d'oxydation sont utilises pour tester l'aptitude du modele cinetique a prevoir correctement la degradation a haute temperature en milieu oxydant des lubrifiants","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"25 1","pages":"596-603"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81629257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 55
Preparation of 3-methyl-4-nitrophenol 3-甲基-4-硝基苯酚的制备
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A016
Ken Ito, H. Kaminaka
{"title":"Preparation of 3-methyl-4-nitrophenol","authors":"Ken Ito, H. Kaminaka","doi":"10.1021/I300024A016","DOIUrl":"https://doi.org/10.1021/I300024A016","url":null,"abstract":"Synthese a partir de m-cresol par esterification avec l'oxychlorure de phosphore, suivie de la nitration par l'acide nitrique et d'une hydrolyse","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"98 4 1","pages":"649-652"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80741783","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
High Boiling and Premium Quality Jet Fuels by Catlytic Dewaxing and Hydrogenation 催化脱蜡加氢制备高沸点优质喷气燃料
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A609
N. Chen, W. Garwood
{"title":"High Boiling and Premium Quality Jet Fuels by Catlytic Dewaxing and Hydrogenation","authors":"N. Chen, W. Garwood","doi":"10.1021/I300024A609","DOIUrl":"https://doi.org/10.1021/I300024A609","url":null,"abstract":"L'etude montre qu'il est possible de produire une large gamme de carbureacteurs de type kerosene, avec de bons rendements, en combinant un deparaffinage catalytique sur zeolite et une hydrogenation moderee. L'auteur etudie les caracteristiques des produits obtenus et compare les resultats obtenus avec les catalyseurs ZSM-S et Erionite","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"53 1","pages":"641-645"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90954472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Aqueous catalyst systems for the water-gas shift reaction. 3. Continuous gas processing results 用于水煤气移位反应的水性催化剂体系。3.连续气体处理结果
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A007
D. Elliott, L. Sealock, R. Butner
{"title":"Aqueous catalyst systems for the water-gas shift reaction. 3. Continuous gas processing results","authors":"D. Elliott, L. Sealock, R. Butner","doi":"10.1021/I300024A007","DOIUrl":"https://doi.org/10.1021/I300024A007","url":null,"abstract":"Procede utilisant des composes divers basiques comme catalyseurs, a moyenne et haute pression","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"85 1","pages":"541-549"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74553910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 14
Comparative study of alumina- and carbon-supported catalysts for hydrogenolysis and hydrogenation of model compounds and coal-derived liquids 氧化铝和碳负载催化剂用于模型化合物和煤衍生液体的氢解和加氢的比较研究
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A004
Cornells K. Groot, Vlncentlus H. J. de Beer, Rod Prlns, Marek Stolarskl, Wleslaw S. Nledzwledr, K. Groot, Laxml Naraln Shll, Subhash Bhatla'
{"title":"Comparative study of alumina- and carbon-supported catalysts for hydrogenolysis and hydrogenation of model compounds and coal-derived liquids","authors":"Cornells K. Groot, Vlncentlus H. J. de Beer, Rod Prlns, Marek Stolarskl, Wleslaw S. Nledzwledr, K. Groot, Laxml Naraln Shll, Subhash Bhatla'","doi":"10.1021/I300024A004","DOIUrl":"https://doi.org/10.1021/I300024A004","url":null,"abstract":"Carbon- and alumina-supported Fe, Mo, Fe-Mo, and Co-Mo sulfide catalysts were compared for their ability to catalyze hydrotreating reactions such as dibenzothiophene hydrodesulfurization, quinoline hydrodenitrogenation, dibenzofuran hydrodeoxygenation, and hydrogenation of butenes, naphthalene, biphenyl, and coal extract. The temperature and pressure varied from 653 to 703 K and from 1 to 300 bar of H,, respectively. Below 50 bar of H, the carbon-supported catalysts were more active for hydrogenolysis and hydrogenation than the aluminasupported ones. However, further H, pressure increase was most effective for the latter catalysts. The activity differences between carbon- and alumina-supported catalysts are ascribed to differences in active phase-support interaction. Generally, iron sulfide was found less active than molybdenum sulfide, and iron sulfide also appeared to be less effective than cobalt sulfide in promoting molybdenum sulfide. However, the Fe-Mo sulfide showed the higher selectivity for hydrogenation relative to hydrodesulfurization. Carboksupported iron sulfide (low-cost catalyst) had considerable activity for coal extract hydrogenation.","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"141 3 1","pages":"522-530"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77231204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 45
Kinetics and Mechanism of the NOx Reduction with NH3 on V2O5 - WO3-TiO2 Catalyst V2O5 - WO3-TiO2催化剂上NH3还原NOx的动力学及机理
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A607
Gerard Tuenter, W. F. V. Leeuwen, Leo Snepvangers
{"title":"Kinetics and Mechanism of the NOx Reduction with NH3 on V2O5 - WO3-TiO2 Catalyst","authors":"Gerard Tuenter, W. F. V. Leeuwen, Leo Snepvangers","doi":"10.1021/I300024A607","DOIUrl":"https://doi.org/10.1021/I300024A607","url":null,"abstract":"","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"8 1","pages":"633-636"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89210614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 84
Long-acting androgens: esters of testosterone with bile acids 长效雄激素:含胆汁酸的睾酮酯
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A018
J. Herz, J. Sandoval
{"title":"Long-acting androgens: esters of testosterone with bile acids","authors":"J. Herz, J. Sandoval","doi":"10.1021/I300024A018","DOIUrl":"https://doi.org/10.1021/I300024A018","url":null,"abstract":"","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"248 1","pages":"664-665"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80637961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Cure studies of styrene-terminated polysulfone oligomers 端苯乙烯聚砜低聚物的固化研究
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A011
Dana Garcia
{"title":"Cure studies of styrene-terminated polysulfone oligomers","authors":"Dana Garcia","doi":"10.1021/I300024A011","DOIUrl":"https://doi.org/10.1021/I300024A011","url":null,"abstract":"","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"7 1","pages":"569-571"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82555943","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetics of gelation in model polycondensates 模型缩聚物凝胶动力学
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A013
D. Argyropoulos, H. Bolker
{"title":"Kinetics of gelation in model polycondensates","authors":"D. Argyropoulos, H. Bolker","doi":"10.1021/I300024A013","DOIUrl":"https://doi.org/10.1021/I300024A013","url":null,"abstract":"Polycondensation modele de l'acide benzenetriacetique-1,3,5 avec le decamethyleneglycol et l'hexadecaneglycol","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"14 1","pages":"578-582"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79293602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Role of nickel crystallite in nickel zeolite catalysts: n-hexane isomerization 镍晶在镍沸石催化剂中的作用:正己烷异构化
Industrial & Engineering Chemistry Product Research and Development Pub Date : 1986-12-01 DOI: 10.1021/I300024A005
L. N. Shil, S. Bhatia
{"title":"Role of nickel crystallite in nickel zeolite catalysts: n-hexane isomerization","authors":"L. N. Shil, S. Bhatia","doi":"10.1021/I300024A005","DOIUrl":"https://doi.org/10.1021/I300024A005","url":null,"abstract":"","PeriodicalId":13540,"journal":{"name":"Industrial & Engineering Chemistry Product Research and Development","volume":"10 1","pages":"530-537"},"PeriodicalIF":0.0,"publicationDate":"1986-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79419948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
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