Experimental Agriculture最新文献

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Continuous cropping legumes in semi-arid Southern Africa: Legume productivity and soil health implications 南部非洲半干旱地区的连作豆类:豆类生产力和土壤健康影响
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-04-22 DOI: 10.1017/S0014479722000138
A. Jani, T. Motis, J. Longfellow, B. Lingbeek, C. D’Aiuto
{"title":"Continuous cropping legumes in semi-arid Southern Africa: Legume productivity and soil health implications","authors":"A. Jani, T. Motis, J. Longfellow, B. Lingbeek, C. D’Aiuto","doi":"10.1017/S0014479722000138","DOIUrl":"https://doi.org/10.1017/S0014479722000138","url":null,"abstract":"Abstract Legume agronomic research in Southern Africa has often focused on integrating legumes into smallholder cereal cropping systems, but there is limited information available on the feasibility and soil health implications of continuous cropping legumes in the region. Continuous legumes may be suitable in areas with large livestock populations where a premium is placed on high-quality forage, or where efforts are underway to reclaim degraded cropland. Our objectives in this study were to (i) evaluate the performance of diverse legumes under continuous cropping and conservation tillage management with no fertility inputs and (ii) assess the response of soil health parameters to continuous legumes in a semi-arid environment. A 4-year study was conducted in Limpopo, South Africa beginning in the 2011–2012 growing season in which 10 legume and fallow treatments were imposed in the same plots for 4 growing seasons. All legumes responded negatively in varying degrees to continuous cropping in terms of biomass and nutrient accumulation. Lablab (Lablab purpureus L.) was the top-performing legume in the study and accumulated 4.5–13 Mg ha−1 of biomass and 153–345, 11–34, and 75–286 kg ha−1 of N, P, and K, respectively. Lablab often outperformed natural fallow, while other legumes generally performed as well as or inferior to natural fallow, depending on species and growing season. Cowpea (Vigna unguiculata Walp) was especially incompatible with continuous cropping and averaged less than 252 kg ha−1 and 2.1 Mg ha−1 of grain and biomass, respectively, from 2012–2013 to 2014–2015. Continuous cropping did not lead to sustained improvements in soil health. By 2014–2015, soil organic matter for all treatments had either declined or resembled baseline values. Rates of potentially mineralizable N in cowpea, lablab, vining mucuna (Mucuna pruriens var. Utilis), natural fallow, and bare ground plots fell by 70–96% during the study. There was also evidence for lower recovery of leached K by legumes compared to natural fallow species. In conclusion, legumes, such as lablab, should be considered as continuous forages on marginal land in areas where high-quality forage is in demand, but continuous cropping legumes without fertility inputs are not an effective strategy for improving soil health on degraded cropland in this semi-arid region of Southern Africa. Future research efforts may focus on the grazing strategies and baling frequencies required to optimize annual biomass accumulation of continuous lablab to meet livestock demand and support smallholder livelihoods.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49558532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced-efficiency nitrogen fertilizer boosts cauliflower productivity and farmers’ income: Multi-location and multi-year field trials across Nepal 高效氮肥提高花椰菜产量和农民收入:尼泊尔多地点多年田间试验
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-04-13 DOI: 10.1017/S0014479722000060
N. Pandit, Y. K. Gaihre, Shriniwas Gautam, S. Maharjan, S. Vista, D. Choudhary
{"title":"Enhanced-efficiency nitrogen fertilizer boosts cauliflower productivity and farmers’ income: Multi-location and multi-year field trials across Nepal","authors":"N. Pandit, Y. K. Gaihre, Shriniwas Gautam, S. Maharjan, S. Vista, D. Choudhary","doi":"10.1017/S0014479722000060","DOIUrl":"https://doi.org/10.1017/S0014479722000060","url":null,"abstract":"Summary Enhanced-efficiency nitrogen (N) fertilizers (EENFs) such as slow-release polymer-coated urea (PCU) and deep placement of urea briquettes (UBs) improve nitrogen use efficiency (NUE) by reducing N losses and increasing nitrogen uptake by plants. Multilocation field trials (81) with cauliflower were conducted across two agroecological regions covering seven districts during two crop-growing seasons between 2018 and 2020 to assess the potential of three EENFs, i.e., PCU, sulphur-coated urea (SCU) and UB for increasing curd yields, agronomic NUE (AEN) and economic benefits over conventional urea (CU). Results were compared with farmers’ current nutrient management practice (FP): applying CU at 58.5 kg N ha−1 (ranging from 33 to 88 kg N ha−1). The N rates in three EENF treatments were 33% lower (100 kg N ha−1), considering their higher N use efficiency, than for CU (150 kg N ha−1). We hypothesize that EENFs produce similar or even higher yields compared with CU. For both years, all three EENFs resulted in significantly (p < 0.05) higher curd yields than CU (36.7 ± 1.1 t ha−1). PCU, SCU and UB increased yields by 21, 21 and 24% over those for CU. The yield increment was much higher (PCU, 44%; SCU, 43%; UB, 46%) than for FP. Similarly, PCU, SCU and UB increased the partial factor productivity of N (PFPN) by 91, 90 and 94% and the AEN by 133, 129 and 138%, respectively, compared with CU. The gross margins of all three EENFs were similar: an average 25% more than with CU and 51% more than with FP. These results suggest that EENFs could help increase productivity and farmer income while considerably reducing N input, compared to use of CU. The government of Nepal should promote these EENFs by removing barriers to access for the associated fertilizers and foster their use through extension.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45600291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Impact of improved agricultural extension approaches on technology adoption: Evidence from a randomised controlled trial in rural Tunisia 改进农业推广方法对技术采用的影响:来自突尼斯农村随机对照试验的证据
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-04-13 DOI: 10.1017/S0014479722000084
B. Dhehibi, M. Dhraief, Udo Ruediger, A. Frija, J. Werner, Lisa Straussberger, B. Rischkowsky
{"title":"Impact of improved agricultural extension approaches on technology adoption: Evidence from a randomised controlled trial in rural Tunisia","authors":"B. Dhehibi, M. Dhraief, Udo Ruediger, A. Frija, J. Werner, Lisa Straussberger, B. Rischkowsky","doi":"10.1017/S0014479722000084","DOIUrl":"https://doi.org/10.1017/S0014479722000084","url":null,"abstract":"Summary Low and slow adoption of innovative technologies among smallholder farmers in Tunisia is a key agricultural development problem partly related to the existing technology transfer approach used in the country. The objective of this study is to analyse how to design innovative technology transfer strategies more effective in terms of increasing female and male farmers’ adoption of an improved barley variety, ‘Kounouz’, for small ruminant nutrition. A randomised controlled trial method was used with farmers in Tunisia to implement four extension treatments and to evaluate their effects on adoption of Kounouz. Difference-in-difference estimates showed that intensive agricultural trainings can significantly improve adoption of Kounouz. Technical trainings combined with economic and organisational training and female empowerment courses resulted in a higher adoption rate. This finding has important policy implications, because it suggests that ensuring more widespread and equitable adoption of improved technologies may not require changes in the research system, but rather introduction measures that ensure better access for women to gender-sensitive extension programmes given their positive impacts on technology adoption of the household.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42655958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Yield response of tef (Eragrostis tef) to nitrogen, phosphorus, potassium and sulphur under balanced fertilization on Vertisols in different agroecological zones of Ethiopia 埃塞俄比亚不同农业生态区氮磷钾硫平衡施肥条件下油菜产量的响应
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-03-31 DOI: 10.1017/S0014479722000114
G. Chala, S. Kassa, T. Tadele, K. Assefa, Hailemariam Teshome, G. Agegnehu, W. Abera, Degife Tibebe, G. Sileshi, T. Erkossa
{"title":"Yield response of tef (Eragrostis tef) to nitrogen, phosphorus, potassium and sulphur under balanced fertilization on Vertisols in different agroecological zones of Ethiopia","authors":"G. Chala, S. Kassa, T. Tadele, K. Assefa, Hailemariam Teshome, G. Agegnehu, W. Abera, Degife Tibebe, G. Sileshi, T. Erkossa","doi":"10.1017/S0014479722000114","DOIUrl":"https://doi.org/10.1017/S0014479722000114","url":null,"abstract":"Summary Nutrient deficiency is a major constraint in tef (Eragrostis tef (Zucc.) Trotter) production in Ethiopia. In the past, a blanket recommendation of nitrogen (N) and phosphorus (P) fertilizers has been applied regardless of the diversity of agroecological zones and soil types. As crop responses declined with widespread deficiencies of nutrients, farmers have lost interest in applying the recommended fertilizer rates. The present study was conducted with the objective of quantifying the response of tef to different rates of N, P, potassium (K) and sulphur (S) fertilizers under balanced application of the nutrients other than the one under investigation. In each region, the same set of trials was implemented on farmers’ fields for three years. All trials were implemented on Vertisols across four agroecological zones (AEZs). The treatments were seven rates of N, six rates each of P and S and eight rates of K with a basal application of zinc (Zn) and boron (B). The results showed that the most limiting nutrient is N followed by P in each agroecological zone on the Vertisols. There was clear evidence of increases in grain yield with increasing rates of N and P, but the responses to K and S rates did not follow clear trends across AEZs. With balanced application of the other nutrients, 23–92 kg N ha−1 increased grain yield by 11–92%, while 10–40 kg P ha−1 increased yields by 12–33% over the control in the different AEZs. Based on results from dose–response models, it is concluded that the agronomic optimum rates for tef production are 69 kg N, 20 kg P, 30 kg K and 10 kg S ha−1 in the cool sub-moist mid-highlands and the tepid sub-humid mid highlands; 92 kg N, 30 kg P, 15 kg K and 10 kg S ha−1 in tepid moist mid highlands but 69 kg N, 10 kg P, 15 kg K and 10 kg S ha−1 in the tepid sub-moist mid highlands. On Vertisols not covered by this study, these recommendations should be subject to appropriate soil and plant analysis. We also recommend further studies on the nutrient requirement of tef on other soil types and AEZs.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42232598","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Response of maize yield to nitrogen, phosphorus, potassium and sulphur rates on Andosols and Nitisols in Ethiopia 埃塞俄比亚玉米产量对Andosols和Nitisol上氮、磷、钾和硫含量的响应
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-03-22 DOI: 10.1017/S0014479722000035
I. Bekele, B. Lulie, M. Habte, Shiferaw Boke, G. Hailu, Estifanos H. Mariam, J. S. Ahmed, W. Abera, G. Sileshi
{"title":"Response of maize yield to nitrogen, phosphorus, potassium and sulphur rates on Andosols and Nitisols in Ethiopia","authors":"I. Bekele, B. Lulie, M. Habte, Shiferaw Boke, G. Hailu, Estifanos H. Mariam, J. S. Ahmed, W. Abera, G. Sileshi","doi":"10.1017/S0014479722000035","DOIUrl":"https://doi.org/10.1017/S0014479722000035","url":null,"abstract":"Summary The use of fertilizers in balanced and adequate amounts is a prerequisite for increasing crop productivity and production. Unbalanced plant nutrient management continues to be a major factor contributing to low maize (Zea mays L.) yields due to lack of information on the dose–responses to macronutrients on different soil types in Ethiopia. This study was carried out to quantify maize yield response and agronomic efficiency of varying application rates of nitrogen (N), phosphorus (P), potassium (K) and sulphur (S) under balanced application of other nutrients across two soil types in Ethiopia. Field trials were set up on 29 farmers’ fields in four districts of Oromia and Southern Nations, Nationalities and Peoples Region (SNNPR) for three consecutive cropping seasons (2014–2017). The treatments consisted of six rates of N, P and S each and eight rates of K combined with balanced application of the remaining macronutrients, zinc (Zn) and boron (B). The treatments were laid out in randomised complete blocks design with three replicates per farm. Using nutrient dose–response modelling, the agronomic optimum rates of N, P, K and S were estimated at 46, 40, 17 and 10 kg ha−1 on Nitisols, with balanced application of the other nutrients. On Andosols, the optimum rates of N, P and S were estimated at 184, 20 and 30 kg ha−1, respectively, but the optimum K rate could not be estimated. The predicted maximum yields obtained with balanced nutrient application were lower on Andosols (3397–3640 kg ha−1) than on Nitisols (4630–6094 kg ha−1). Using the Mitscherlich dose–response model, the percentage deficiencies of N, P, K and S were estimated to be 1.3–3.3 times more on Nitisols than Andosols. Consequently, agronomic efficiencies of N, P, K and S were significantly lower on Andosols than on Nitisols. It is concluded that balanced application of 46 kg N ha−1, 40 kg P ha−1, 17 kg K ha−1, 10 kg ha−1 S, 2 kg Zn ha−1 and 0.5 kg B ha−1 could be recommended for maize on Nitisols in the study area. Although this recommendation may also apply to Andosol, further research is needed as the productivity of Andosols appears to be limited by constrains other than N, P, K, S, Zn and B. We also recommend a shift from the blanket fertilizer recommendations to site-specific nutrient management based on good understanding of the variations in crop response with soil type and agroecology and appropriate soil and plant analyses.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43279242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
A data-mining approach for developing site-specific fertilizer response functions across the wheat-growing environments in Ethiopia 一种数据挖掘方法,用于在埃塞俄比亚的小麦生长环境中开发特定地点的肥料响应函数
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-03-11 DOI: 10.1017/S0014479722000047
W. Abera, L. Tamene, K. Tesfaye, Daniel Jiménez, Hugo Dorado, T. Erkossa, J. Kihara, J. S. Ahmed, T. Amede, J. Ramirez-Villegas
{"title":"A data-mining approach for developing site-specific fertilizer response functions across the wheat-growing environments in Ethiopia","authors":"W. Abera, L. Tamene, K. Tesfaye, Daniel Jiménez, Hugo Dorado, T. Erkossa, J. Kihara, J. S. Ahmed, T. Amede, J. Ramirez-Villegas","doi":"10.1017/S0014479722000047","DOIUrl":"https://doi.org/10.1017/S0014479722000047","url":null,"abstract":"Summary The use of chemical fertilizers is among the main innovations brought by the 1960s Green Revolution. In Ethiopia, fertilizer application during the last four decades has led to significant yield gains, yet yield remains below its potential across much of the country. One of the main challenges responsible for low yield response to fertilizer application has been the use of ‘blanket’ recommendations, whereby no tailoring of fertilizer amount and frequency is done based on soil requirements. As a result, the amount of fertilizer applied ranges widely, and can be either sub- or supra-optimal. There is thus an increasing need for site-specific fertilizer recommendations which take into account site characteristics such as climate variables (temperature, rainfall, and solar radiation); soil factors (soil organic carbon, moisture, pH, texture, cation exchange capacity, and level of macro- and micronutrients); and topographic position indices. This article reports on a data-mining approach we developed on a large dataset of 6585 wheat (Triticum aestivum) field trials. The dataset includes detailed, site-specific biophysical variables to create nutrient response functions that can guide optimal site-specific fertilizer application. The approach used a machine-learning model (random forest) to capture the relationship between nutrients – nitrogen (N), phosphorous (P), potassium (K), and sulfur (S) – and wheat yield. The model explained about 83, 82, 47, and 69% of variances of yield for N, P, K, and S omission, respectively, with consistent performance across training and testing datasets. Expectedly, for N and P omission data, the most important explanatory variables are nutrient rate, followed by soil organic carbon and soil pH. For K and S, however, climatic variables played an important role alongside nutrient rates. The site-specific yield–fertilizer response curves derived from our model are highly variable from location to location, as they are affected by the climatic, soil, or topographic conditions of the site. Importantly, using principal component analysis, we showed that the shape of the fertilizer response curves is a result of the multiple environmental factors (including soil, topography, and climate) that are at play at a given site, rather than of a specific dominant one. The research output is expected to respond to the national policy demands for a sound method to identify the optimal fertilizer rate to increase economic returns of fertilizer investments and take fertilizer utilization research one step further.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46838247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Sorghum yield response to NPKS and NPZn nutrients along sorghum-growing landscapes 高粱生长景观对NPKS和NPZn养分的产量响应
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-03-11 DOI: 10.1017/S0014479722000072
G. Desta, T. Amede, Tadesse Gashaw, G. Legesse, G. Agegnehu, Kindu Mekonnen, A. Whitbread
{"title":"Sorghum yield response to NPKS and NPZn nutrients along sorghum-growing landscapes","authors":"G. Desta, T. Amede, Tadesse Gashaw, G. Legesse, G. Agegnehu, Kindu Mekonnen, A. Whitbread","doi":"10.1017/S0014479722000072","DOIUrl":"https://doi.org/10.1017/S0014479722000072","url":null,"abstract":"Summary Grain sorghum [Sorghum bicolor (L.) Moench] is the major cereal crop used as staple crop in the arid and semi-arid regions of Ethiopia. Low sorghum yields are attributed to soil, climate and topographic factors. We investigated sorghum yield response to factorial combination of nitrogen and phosphorous (NP) as well as potassium (K), sulphur (S) and zinc (Zn), and how the position of farmers’ fields belonging to different landscape positions (i.e., upslope, mid-slope, and foot slope) could explain fertilizer response and yield variability. The analysis in this study made use of dataset from two sets of on-farm experiments where trials were set at two farmers’ fields for NPKS and three farmers’ fields for NPZn experiments in each landscape position. The experiments were implemented at two sorghum-growing locations (i.e., Hayk and Sirinka) in parts of the north-eastern Amhara region in Ethiopia. Sorghum yield response to fertilizer application was strongly linked to the spatial variation along landscape positions and varied over locations. Fertilizer response was significantly higher at foot slopes compared to mid-slopes and upslope positions, where fields at foot slopes exhibited relatively homogeneous responses. Application of combined nitrogen (N) and phosphorus (P) fertilizers, landscape position and the interaction of fertilizer application and landscape positions strongly affected sorghum yield. There was a linear and significant increase in sorghum yield with the increase in the NP rates. The combined application of NP with different levels of KS as well as NP with Zn fertilizer rates did not result in significant yield difference. The results indicated that local factors were much more influential when accounting for the heterogeneity in sorghum yield response to fertilizer. This further acknowledges the importance of a landscape-based fertilizer management approach to respond yield potential variability related with the farmers’ fields and landscape environment. Further investigation is needed to develop homogeneous fertilizer response units based on spatial variability of soil and topographic attributes along the landscape.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43921913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
[Rapid and simultaneous determination of glyphosate, glufosinate, and their metabolites in soil by high performance liquid chromatography-tandem mass spectrometry]. [高效液相色谱-串联质谱法快速、同时测定土壤中的草甘膦、草胺膦及其代谢物]。
IF 0.7 4区 农林科学
Experimental Agriculture Pub Date : 2022-03-08 DOI: 10.3724/SP.J.1123.2021.08005
Hua Ping, Fang Zhao, Cheng Li, Beihong Wang, Hongling Kong, Yang Li, Zhihong Ma
{"title":"[Rapid and simultaneous determination of glyphosate, glufosinate, and their metabolites in soil by high performance liquid chromatography-tandem mass spectrometry].","authors":"Hua Ping, Fang Zhao, Cheng Li, Beihong Wang, Hongling Kong, Yang Li, Zhihong Ma","doi":"10.3724/SP.J.1123.2021.08005","DOIUrl":"10.3724/SP.J.1123.2021.08005","url":null,"abstract":"&lt;p&gt;&lt;p&gt;Glyphosate (GLY) and glufosinate (GLUF) are non-selective translocated herbicides that are used in agricultural and non-agricultural land worldwide. The extensive use of GLY and GLUF may lead to their accumulation in soil, which causes soil pollution and affects the soil micro-ecological environment; the accumulated GLY and GLUF also migrate to groundwater via leaching. However, GLY, GLUF, and their metabolites are highly water-soluble and lack chromogenic and fluorescent groups, making them difficult to analyze. Currently, derivatization methods are mostly used to detect GLY, GLUF, and their metabolites. However, these methods also have some drawbacks, such as complex operation, long time consumption, and poor stability. In addition, these compounds are easily passivated and made inactive in soil; they also react with organic matter, humic acid, metal oxides, and heavy metal ions, making their extraction from soil difficult. To date, the method for the determination of GLY, GLUF, and their metabolites in soil is limited. Therefore, it is necessary to establish a quick and sensitive method to determine the residues of GLY, GLUF, and their metabolites in soil. In this study, a high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) method was developed for the determination of GLY, GLUF, and their metabolites in soil. Parameters like extraction solvent, extraction temperature, extraction time, and adsorbents, which affected the extraction efficiencies, were optimized. Finally, the soil samples were extracted with 0.5 mol/L ammonia solution in a bath shaker at 50 ℃, and then centrifuged at 10000 r/min for 5 min. The supernatant was filtered through 0.2-μm syringe filters and then determined by HPLC-MS/MS. A Dikma Polyamino HILIC column (150 mm×2.0 mm, 5 μm) was used for chromatographic separation with good peak shape and high response of the target compounds. Ammonium acetate (0.2 mmol/L) with 0.07% ammonia aqueous solution and acetonitrile were used as the mobile phase. The flow rate of the elute was 0.25 mL/min. MS/MS was conducted under multiple reaction monitoring (MRM) mode using an electrospray ionization (ESI) source, and was quantified by the external standard method using matrix-matched calibration curves. All the target compounds were ionized in the negative ionization mode. The linear ranges of GLY and its metabolites were between 5.0 and 500 μg/L, and those of GLUF and its metabolites were between 2.0 and 500 μg/L. Linear correlation coefficients were greater than 0.99. The limit of detection (LOD) and limit of quantification (LOQ) were assessed using signal-to-noise (S/N) ratios of 3 and 10, respectively. The LOD and LOQ values of both GLY and (aminomethyl)phosphonic acid (AMPA) were 4.0 and 13.3 μg/kg, respectively. The LOD and LOQ values of GLUF, MPP, and N-acetyl glufosinate (NAG) were 2.0 and 6.7 μg/kg, respectively. Method accuracy was acquired by recovery test at three spiked levels (0.02, 0.05, 0.2 mg/","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":"31 1","pages":"273-280"},"PeriodicalIF":0.7,"publicationDate":"2022-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9404154/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78993812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimal biochar application rates for mitigating global warming and increasing rice yield in a subtropical paddy field – ERRATUM 缓解全球变暖和提高亚热带稻田水稻产量的最佳生物炭施用量-勘误
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-02-23 DOI: 10.1017/s0014479722000059
Xiang Yang, T. Vancov, J. Peñuelas, J. Sardans, A. Singla, A. Alrefaei, Xuening Song, Yunying Fang, Weiqi Wang
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引用次数: 0
Measuring the value of data governance in agricultural investments: A case study 衡量农业投资中数据治理的价值:一个案例研究
IF 1.6 4区 农林科学
Experimental Agriculture Pub Date : 2022-02-21 DOI: 10.1017/S0014479721000314
D. Whittard, F. Ritchie, R. Musker, M. Rose
{"title":"Measuring the value of data governance in agricultural investments: A case study","authors":"D. Whittard, F. Ritchie, R. Musker, M. Rose","doi":"10.1017/S0014479721000314","DOIUrl":"https://doi.org/10.1017/S0014479721000314","url":null,"abstract":"Summary The study at hand measures the value of improving data governance and access in the Supporting Soil Health Interventions (SSHI) project in Ethiopia. We applied two separate but interlinked models, one qualitative and one quantitative, to create a new framework enhancing the traditional cost–benefit analysis. The qualitative analysis provided novel insights into the specific types of value and the mechanisms through which they are generated. These results underpinned the development of an innovative framework to measure this perceived value quantitatively. By combining the quantitative and qualitative framework, the study demonstrated that it is possible to generate plausible and credible quantitative estimates of both costs and benefits of data governance and access. While acknowledging that the estimates are only illustrative, the case study results suggested on a direct cost measure, at a particular point in time, the SSHI data governance activities yielded a negative return. However, indirect social and public benefits are rarely quantified, but this paper shows that relatively few “indirect” benefits (current but unmeasured, or measurable but in the future) are necessary to reverse that view, at least from the point of the economy more generally.","PeriodicalId":12245,"journal":{"name":"Experimental Agriculture","volume":" ","pages":""},"PeriodicalIF":1.6,"publicationDate":"2022-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43974639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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