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Reactions of 2-Methoxytetrafluoropropanoic Acid Derivatives with Amines 2-甲氧基四氟丙烷酸衍生物与胺的反应
Fluorine Notes Pub Date : 2022-12-24 DOI: 10.17677/fn20714807.2022.06.03
V. Dyachenko
{"title":"Reactions of 2-Methoxytetrafluoropropanoic Acid Derivatives with Amines","authors":"V. Dyachenko","doi":"10.17677/fn20714807.2022.06.03","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.06.03","url":null,"abstract":"","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"295 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81556890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fluorine-Containing Acrylic Polymers With DR1 Electro-Optical Chromophore In The Side Chain 侧链上带有DR1电光发色团的含氟丙烯酸聚合物
Fluorine Notes Pub Date : 2022-12-24 DOI: 10.17677/fn20714807.2022.06.01
S. Molchanova
{"title":"Fluorine-Containing Acrylic Polymers With DR1 Electro-Optical Chromophore In The Side Chain","authors":"S. Molchanova","doi":"10.17677/fn20714807.2022.06.01","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.06.01","url":null,"abstract":"","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"22 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83558489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
INVESTIGATION OF OPTICAL PROPERTIES OF AMORPHOUS COPOLYMERS OF PERFLUORO-2,2-DIMETHYL-1,3-DIOXOL AND PERFLUORO-(2-CYCLOPENTYL) ETHYLVINYL ETHER OBTAINED AT ULTRAHIGH PRESSURE 超高压制备的全氟-2,2-二甲基-1,3-二醇和全氟-(2-环戊基)乙基乙烯醚非晶态共聚物的光学性质研究
Fluorine Notes Pub Date : 2022-10-26 DOI: 10.17677/fn20714807.2022.05.02
S. Molchanova
{"title":"INVESTIGATION OF OPTICAL PROPERTIES OF AMORPHOUS COPOLYMERS OF PERFLUORO-2,2-DIMETHYL-1,3-DIOXOL AND PERFLUORO-(2-CYCLOPENTYL) ETHYLVINYL ETHER OBTAINED AT ULTRAHIGH PRESSURE","authors":"S. Molchanova","doi":"10.17677/fn20714807.2022.05.02","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.05.02","url":null,"abstract":"","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79155243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
DECAY SEQUENCES - ION SERIES OF MASS SPECTRA HEXAMETHYLBENZENE AND HEXAKIS(TRIFLUOROMETHYL)BENZENE 衰变序列。质谱中六甲基苯和六(三氟甲基)苯的离子序列
Fluorine Notes Pub Date : 2022-10-26 DOI: 10.17677/fn20714807.2022.05.01
Nikolay D. Kagramanov
{"title":"DECAY SEQUENCES - ION SERIES OF MASS SPECTRA HEXAMETHYLBENZENE AND HEXAKIS(TRIFLUOROMETHYL)BENZENE","authors":"Nikolay D. Kagramanov","doi":"10.17677/fn20714807.2022.05.01","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.05.01","url":null,"abstract":": This report on the results of the analysis of decay sequences - ion series of mass spectra: hexamethylbenzene and hexakis(trifluoromethyl)-benzene, is a continuation of the article on the ion series of benzene and hexafluorobenzene. In contrast to the six ion series of the mass spectrum of benzene, the mass spectrum of hexamethylbenzene consists of eleven series of ions. The first three ionic series of the mass spectrum of hexamethylbenzene + . M 1-3 , including the elimination of groups: ( . CH 3 +6 . H), (C 2 H 4 + 7 . H) and (C 3 H 6 + 5 . H) with the formation of ions + С 11 H 9 , + С 10 H 7 and + C 9 H 7 - the result of agmentation of methyl substituents that occur without rearrangement of the existing π - conjugations of the six-membered ring. The four final series of + . M 8-11 ions are formed upon detachment of neutral molecules C 8 H 11 and C 9 H 13 , as well as radicals . C 10 H 13 and . C 11 H 15 , in which the 6-membered ring is also retained. As a result of four series + . M 8-11 , ions + C 4 H 7 m/z 55, + C 3 H 5 m/z 41, + C 2 H 5 m/z 29 and + CH 3 m/z 15 appear. Two intermediate series","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75538737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A new method for preparing of 1,2,2-trifluorostyrene 制备1,2,2-三氟苯乙烯的新方法
Fluorine Notes Pub Date : 2022-08-28 DOI: 10.17677/fn20714807.2022.04.03
S. Igumnov
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引用次数: 0
Synthesis of 2-or 4- fluorine-substituted arylamides 2-或4-氟取代芳基酰胺的合成
Fluorine Notes Pub Date : 2022-08-28 DOI: 10.17677/fn20714807.2022.04.02
V. Dyachenko
{"title":"Synthesis of 2-or 4- fluorine-substituted arylamides","authors":"V. Dyachenko","doi":"10.17677/fn20714807.2022.04.02","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.04.02","url":null,"abstract":"","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84603633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Iodine(III) tris(trifluoroacetate) in reactions of iodo- and bromotrifluoroacetoxylation of fluoroolefins 碘(III)在氟烯烃碘和溴三氟乙酰氧基化反应中的三(三氟乙酸)
Fluorine Notes Pub Date : 2022-08-28 DOI: 10.17677/fn20714807.2022.04.01
A. Tyutyunov
{"title":"Iodine(III) tris(trifluoroacetate) in reactions of iodo- and bromotrifluoroacetoxylation of fluoroolefins","authors":"A. Tyutyunov","doi":"10.17677/fn20714807.2022.04.01","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.04.01","url":null,"abstract":"","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"39 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81903839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Decay sequences - ion series of mass spectra of benzene, 1,3,5,7-cyclooctatetraene, [18]-annulene, hexafluorobenzene and its isomers 苯、1,3,5,7-环四烯、[18]-环烯、六氟苯及其异构体质谱的衰变序列-离子序列
Fluorine Notes Pub Date : 2022-06-24 DOI: 10.17677/fn20714807.2022.03.03
Nikolay D. Kagramanov
{"title":"Decay sequences - ion series of mass spectra of benzene, 1,3,5,7-cyclooctatetraene, [18]-annulene, hexafluorobenzene and its isomers","authors":"Nikolay D. Kagramanov","doi":"10.17677/fn20714807.2022.03.03","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.03.03","url":null,"abstract":": This research is devoted to the results of the analysis of decay sequences - ion mass spectra of benzene, 1,3,5,7-cyclooctatetraene, [18]-annulene, as well as hexafluorobenzene and its homologues. The difference between the primary abstraction groups in the spectra of benzene: . H, CH, . C 2 H,C 3 H 3 , C 4 H 2 , . C 5 H 3 and hexafluorobenzene: . F and CF contradicts the analogy of their fragmentation pathways. Upon ionization and removal of one of the six π -electrons of benzene, its + . M cation-radical arises with the corresponding excitation energy and one of five variants of rearrangement of conjugations of π -electrons of its carbon core. The mass spectrum of benzene consists of six series of fragment ions. The first series of ions, including the successive detachment of six hydrogen atoms with the formation of the + C 6 ion, is the result of the fragmentation of the excited + . M 1 , in which the existing π -conjugations of the carbon cycle are preserved and their rearrangement does not occur. The primary detachments of the CH, . C 2 H, C 3 H 2 , C 4 H 2 , and . C 5 H 3 groups of five other ionic series confirm that in excited + . M benzene, five variants of rearrangement of π consist of 6, 18, and 8 series of ions, respectively, the number of which corresponds to the number of carbon atoms of these cycles. This coincidence is the result of the fact that, during the fragmentation of excited molecular radical cations, all possible variants of the rearrangement of their π -conjugations are realized, as well as the fragmentation variant-with the preservation of existing conjugations, when only the abstraction of hydrogen atoms occurs. The ionic series of benzene, 1,3,5,7-cyclooctatetraene C 8 H 8 , and [18]-annulene C 18 H 18 fragment without branching or intersecting. In contrast to the six ionic series of benzene, hexafluorobenzene fragments with the formation of two series, that differ in the sequence of detachments. One of the series of ions includes successive abstractions of four fluorine atoms, CF and . F to form the + C 5 ion. The other, after the primary detachment of the CF, branches, fragmenting both with the detachment of the CF and with the detachment of the . F. In contrast to the ionic series of the mass spectrum of benzene, in the spectra of hexafluorobenzene and its isomers, the rearrangement of π -conjugations of the ring does not occur, since none of the two ionic series formed is the result of the appearance of any new π -conjugation.","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"32 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88409140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Preparation of organoclay based on 1Н,1Н,13Н-trihydroperfluorotridecan-1-ol and montmorillonite 基于1Н、1Н、13Н-trihydroperfluorotridecan-1-ol和蒙脱土的有机粘土的制备
Fluorine Notes Pub Date : 2022-06-24 DOI: 10.17677/fn20714807.2022.03.01
S. Kudashev
{"title":"Preparation of organoclay based on 1Н,1Н,13Н-trihydroperfluorotridecan-1-ol and montmorillonite","authors":"S. Kudashev","doi":"10.17677/fn20714807.2022.03.01","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.03.01","url":null,"abstract":"","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"9 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80936454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Activation energy and thermal effect of initiation reaction of cationic isobutylene polymerization in the presence of complex catalyst “boron fluoride – water” in heptane 庚烷中“氟化硼-水”络合催化剂存在下阳离子异丁烯聚合引发反应的活化能和热效应
Fluorine Notes Pub Date : 2022-04-27 DOI: 10.17677/fn20714807.2022.02.02
A. Rakhimov
{"title":"Activation energy and thermal effect of initiation reaction of cationic isobutylene polymerization in the presence of complex catalyst “boron fluoride – water” in heptane","authors":"A. Rakhimov","doi":"10.17677/fn20714807.2022.02.02","DOIUrl":"https://doi.org/10.17677/fn20714807.2022.02.02","url":null,"abstract":": This paper presents data on activation energy and thermal effects at the stage of initiation of cationic isobutylene polymerization in the presence of complex catalyst boron fluoride – water in heptane with various stoichiometric composition, obtained by quantum chemical calculation using ab initio method. It has been established that increase in heptane amount leads to decrease in activation energy of reaction studied.","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"2015 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86860052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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