Astri Nurwidayati, Putri Ayu Sulastri, Destya Ardiyati, Agus Aktawan
{"title":"Gasifikasi Biomassa Serbuk Gergaji Kayu Mahoni (Swietenia Mahagoni) untuk Menghasilkan Bahan Bakar Gas sebagai Sumber Energi Terbarukan","authors":"Astri Nurwidayati, Putri Ayu Sulastri, Destya Ardiyati, Agus Aktawan","doi":"10.26555/CHEMICA.V5I2.13046","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I2.13046","url":null,"abstract":"Energy cannot be separated from human life. Increased energy needs for human life that are contradictory to existing fossil fuel sources can cause an energy crisis. Biomass is an alternative energy source that is environmentally friendly, economical and renewable. Biomass energy is derived from plants such as wood, rice hulls, corn head, etc. The process of converting biomass into energy can be done in several ways. They are combustion, pyrolysis, and gasification. Gasification is a technology for converting solid materials into syngas (CO, H 2 , and CH 4 ) which can be used as a fuel. One of the gasifiers that have been developed is a downdraft system. The solid material we use in this study is a mahogany wood powder which has a cellulose content of up to 46.8%. Through this research, we can find out the effect of the variable of raw materials weight towards the time of flame, the quality of the fire, and the amount of gas produced. The gas produced was tested visually by lighting the fire and instrumentally tested using a tool called Chromatography Gas to determine the composition of the gas. The biggest yield syngas is 70,71% with the 18,000 seconds gas release time on the variable of mahogany wood powder weight of 3500 grams. The highest CH 4 and CO Gas concentrations were 1,868% and 15.902% on the variable of 3,500 gram mahogany powder weight. While the highest concentration of H2 gas is 20.965% produced with the variable of 2,500 gram mahogany powder weight. The results of this study indicate that the more feed in the gasifier, the greater the number and composition of syngas and the longer the gas release time.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"64 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127610390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Simulasi Optimasi Reactive Distillation untuk Membuat Bioaditif (Triasetin) dari Gliserol dan Asam Asetat dengan Katalis Asam Sulfat Menggunakan Software Aspen Plus","authors":"Chici Wardiani Prasongko, Fitria Ramdani, Zahrul Mufrodi","doi":"10.26555/CHEMICA.V5I2.13000","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I2.13000","url":null,"abstract":"Biodiesel is one product to avoid the energy crisis in the front mass. Oil from plants such as oil palm, coconut, jatropha, or used cooking oil produces glycerol as a by-product of about 10 wt% of biodiesel products. The excess amount of glycerol must be converted into high-value products. Because if glycerol is not processed properly, the price of glycerol in the market will drop and it will become a waste that can pollute the environment. One of the derivatives of glycerol which has a high value is triacetin which is a good bio-additive as an anti-knock substance in vehicles. From this study, the synthesis of triacetin is from glycerol and acetic acid using sulfuric acid as a catalyst using the Reactive Distillation (RD) process. RD can be used as a reaction place and at the same time as a product refining place. RD can separate water with acetic acid as a distillate product for about 75% on the bottom product. The bottom product of RD will produce triacetin and other derivatives which will be separated again using the second column to obtain high purity triacetin. The purpose of this study is to simulate using Aspen Plus software to model the optimization of RD with a continuous system. The feed capacity of 96% glycerol was 4336.4550 kg/hour and 98% acetate acid was 8659.79 kg/hour in the liquid phase with the help of a sulfuric acid catalyst of 115.4592 kg/hour. The feed enters continuously into RD with a temperature of 115 °C and a pressure of 1 atm. The simulation results show that triacetin products can reach 99% as many as 10150.8561 kg/hour with glycerol conversion of 99.8% and 30 stages in RD. Besides that, the simulation results can also show the flow rate of each stage and the dimensions of RD.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122292705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Uji Aktivitas Adsoben Karbon Aktif Tempurung Kelapa Termodifikasi dengan Active Site Fe2O3","authors":"Shinta Amelia, Zahrul Mufrodi","doi":"10.26555/CHEMICA.V5I2.12185","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I2.12185","url":null,"abstract":"The use of dyes in the textile industry has a negative impact, namely water pollution if the waste is discharged directly into the river or not treated properly. Liquid waste from the textile industry generally still contains dyes that are harmful to living things and the environment. In this study the dye adsorption method was used by using modified activated carbon from the coconut shell with the addition of the active site Fe 2 O 3 . Characterization and activity testing of iron / porous oxide activated carbon adsorbent will be carried out. The type of porous activated carbon used is coconut shell carbon with micropore characters. The stages of this study consisted of the impregnation process of iron oxide on porous carbon, the methylene blue adsorption process and the characterization of the resulting adsorbent. Based on the research that has been done, it can be concluded that the adsorption of Fe 2 O 3 / coconut shell activated carbon is very effectively applied for the absorption of dye wastewater. The adsorption capacity of methylene blue increased with increasing concentrations of loading of active sites of Fe and the percentage of adsorption capacity in the 180 minute reaction was 89.8% with the loading of iron oxide / coconut shell adsorbent 2%. In addition, from the results of the adsorbent activity test with variations in the mass addition of the adsorbent it can be concluded that the mass increase of the adsorbent significantly affected the yield of blue methylene adsorption.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"27 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133955081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ilham Mufandi, Wasakron Treedet, Piyapong Singbua, Ratchaphon Suntivarakorn
{"title":"Produksi Bio-Oil dari Rumput Gajah dengan Fast Pyrolysis menggunakan Circulating Fluidized Bed Reactor (CFBr) dengan Kapasitas 45 Kg/H","authors":"Ilham Mufandi, Wasakron Treedet, Piyapong Singbua, Ratchaphon Suntivarakorn","doi":"10.26555/CHEMICA.V5I2.12484","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I2.12484","url":null,"abstract":"The objective of this work was to produce the renewable liquid fuel (Bio-oil) form Napier grass by fast pyrolysis in a circulating fluidized bed reactor. The experiment was conducted to improve the bio-oil production (pyrolysis oil) using the condenser. Circulating fluidized bed reactor had a height of 4.5 m, sand as bed material with a diameter 249 nm and Napier grass as the raw material for bio-oil production. The parameter in this work compared with previous research. The experiment was carried out at different temperature ranging from , dan ; feed rate biomass at 45 kg/h and a superficial velocity 7 m/s. The experimental result shown that the maximum yield was 39.60 % at pyrolysis temperature of 480 as the best temperature. While the bio-char production and Non condensable gas (NCG) was at 10.67% and 49.73%. Respectively, these results indicated that the condenser can be improve the bio-oil production yield in the system. Furthermore, the condenser process has been shown to have a direct effect on the bio-oil yield.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123010076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aster Rahayu, Joni Aldilla Fajri, Lee Wah Lim, T. Takeuchi
{"title":"Pembuatan Kolom Monolit Mixed-Mode untuk Pemisahan Fenol dalam Kromatografi Cair Sistem Kapiler","authors":"Aster Rahayu, Joni Aldilla Fajri, Lee Wah Lim, T. Takeuchi","doi":"10.26555/CHEMICA.V5I2.12282","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I2.12282","url":null,"abstract":"A Mixed-Mode monolithic column prepared from Pentaeritrytol Tetraacrylate (PETRA) and Ethylene dimathacrylate (EDMA) was investigated and used in capillary liquid chromatography. The polymer composition was optimized by varying percentage ratio of monomer and porogens. Column A with rasio 35/65 (monomer/porogen) showed the optimum ratio. The polymerization of acrylic groups were conducted by in-situ preparation in capillary fused silica. Three phenol compounds were separated using this monolithic column using acetonitrile 100% as eluent. Monolith PETRA-EDMA also could work to separate polar and non-polar compound simultaneously by HILIC mode using acetonitrile 90% as eluent. The morphology surface of monolith was observed by scanning electron microscope (SEM) and mechanical stability in term of pressure drop was observed as well.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129452829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ilham Mufandi, Isti Nur Azizah, A. Efendi, Zahrul Mufrodi
{"title":"Pengolahan Slurry Sampah melalui Microbial Fuel Cells di Pasar Giwangan Yogyakarta","authors":"Ilham Mufandi, Isti Nur Azizah, A. Efendi, Zahrul Mufrodi","doi":"10.26555/CHEMICA.V5I1.11868","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I1.11868","url":null,"abstract":"The vegetable waste is one of the biomass types that it can produce electrical energy. This article focused on electrical production of vegetable waste using microbial fuel cells (MFCS) MFCs is the primary type of the bioelectrochemical system (BECs) that to replaces the biomass to electrical energy spontaneously by activity metabolism of the microorganism. The objectives of this work were to investigate the process of electrical production from Chinese cabbage and the combination of the materials to produce the electrical energy. The experiment was carried out in a laboratory-sall such as mini reactor MFCs, Chinese cabbage as the material of vegetable waste and EM4 as the fermentation. Sample combination was consist of two parts that the first part was used 1 kg Chinese cabbage, 2 liter water and 20 ml EM4. The second part was used 2 kg Chinese cabbage, 1 liter water and 20 ml EM4. The result showed that the electrical voltage in part 1 at 0.362 V and pH at 6 was lower than the electrical voltage in part 2 at 0.724 V and pH at 7. Declining electric energy is influenced by pH as microorganisms living place and the formation process of attached media at the electrode.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"113 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123325340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gita Indah Budiarti, Lukhi Mulia Shytophyta, Dika Fajariyanto, Y. Nugroho
{"title":"Pengaruh Total Solid dan Perbandingan Bahan Baku dengan Inokulum terhadap Produksi Biogas dari Jerami Jagung","authors":"Gita Indah Budiarti, Lukhi Mulia Shytophyta, Dika Fajariyanto, Y. Nugroho","doi":"10.26555/CHEMICA.V5I1.9891","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I1.9891","url":null,"abstract":"The effect of total solid (TS) content and feedstock/inoculum (F/I) ratio on biogas production from corn stover by solid ‐ state anaerobic digestion (SS ‐ AD) were studied. At a F/I ratio of 2, c onversion of corn stover under room temperature resulting in higher biogas yield. SS ‐ AD performed as expected at the TS content of 20%, 22%, 24%. The highest biogas yield of 200 L kg ‐ 1 volatile solids (VS) was obtained at TS content of 22%, F/I ratio of 2.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125140841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Identifikasi Pengaruh Umur Simpan dan Antioksidan Terhadap Kandungan Karbohidrat dan Kadar Air Pada Mie Tapioka Basah","authors":"Titisari Juwitaningtyas, Amalya Nurul Khairi","doi":"10.26555/CHEMICA.V5I1.11837","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I1.11837","url":null,"abstract":"Wet tapioca noodles are a typical food in one of the regions in DIY Province. Traditional processing results in a limited shelf life. Gambir ( Uncaria gambir roxb ) plants are popular plants to be processed into herbal medicines and nutritious plants. Based on research, gambir has the ability as an antimicrobial and natural antioxidant because of the content of catechins in it. This study aims to identify the effectiveness of using gambir extract as a natural antioxidant in wet tapioca noodle samples. The methodology in this study was carried out by mixing 7% gambir extract into 50 grams of wet tapioca noodles. The finished sample is then treated with storage for 0 days, 3 days, and 5 days. The result of the analysis are in 0 day storage, sample contains antioxidant 80,624 ic50, carbodydrate 41,048 mg, and water 58,575 %. In 3 days storage, sample contains antioxidant 91,048 ic50, carbohydrate 45,744 mg, and water 53,415 %. In 5 days storage, sample contains 94,876 ic50, carbohydrate 60,547 mg, and water 39,100 %. Based on the tests conducted, it appears that there is an increase in the number of antioxidants during the storage period. This is accompanied by increasing carbohydrate content and decreasing water content. Decreasing water content will have an impact on the stability of microbial activity so that it extends shelf life. These results provide the conclusion that gambir extract can provide a longer shelf life effect.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"136 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115584144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Distantina, Nuril Nasdhofa Ayuni, V. S. Y. Sarjani
{"title":"Karakter Edible Film Ulva lactuca-kitosan sebagai Pengemas Bumbu Mi Instan","authors":"S. Distantina, Nuril Nasdhofa Ayuni, V. S. Y. Sarjani","doi":"10.26555/CHEMICA.V5I1.9683","DOIUrl":"https://doi.org/10.26555/CHEMICA.V5I1.9683","url":null,"abstract":"In this research, the edible films based on Ulva lactuca flour, chitosan, corn starch, and glycerol were prepared. The edible films was for wrapping of instant noodle seasoning. The aim of this research was to investigate the effect of weight ratio of Ulva lactuca flour-chitosan on the properties of the prepared edible flims. Innitialy, the mixture of Ulva lactuca flour, corn starch, and chitosan were stirred in acetic acid solution 1%. After the chitosan was dissolved, the glycerol was added. The mixture was heated at 80 O C and stirred for 30 minutes. The obtained edible film solution was then poured into antisticky surface and dried at oven until a constant weight was attained. The dried films were characterized, including moisture content, E. coli resistivity, hydration index, thickness, and solubility in hot water. Based on experimental data, it was found that the best composition of edible film was 2 g Ulva lactuca flour, 2 g Chitosan, 2 g corn starch, 100 ml acetic acid 1%, and 1 mL glycerol.","PeriodicalId":118085,"journal":{"name":"CHEMICA: Jurnal Teknik Kimia","volume":"9 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2018-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126899693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}