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Electrochemical and UV/VIS Study of L-Histidine and Its Complexes with Cobalt and Nickel L-组氨酸及其钴镍配合物的电化学及UV/VIS研究
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-30 DOI: 10.5562/CCA3423
Martina Medvidović‐Kosanović, A. Stanković, Marija Jozanović, M. Drulak, Marina Ilić
{"title":"Electrochemical and UV/VIS Study of L-Histidine and Its Complexes with Cobalt and Nickel","authors":"Martina Medvidović‐Kosanović, A. Stanković, Marija Jozanović, M. Drulak, Marina Ilić","doi":"10.5562/CCA3423","DOIUrl":"https://doi.org/10.5562/CCA3423","url":null,"abstract":"In this work oxido-reduction properties of L-histidine were studied by cyclic and differential pulse voltammetry in a pH range from pH 4–10. The results have shown that L-histidine is not electroactive in a pH range from pH 4 to pH 9, while oxidation peak of L-histidine’s imidazole ring at pH 10 was detected with differential pulse voltammetry. It has been found that the oxidation peak current of L-histidine increased with the increase of its concentration in a solution. Adsorption of oxidation product of L-histidine on a glassy carbon electrode surface was also detected. Voltammetric techniques (cyclic and differential pulse voltammetry) and UV/VIS spectroscopy were used to study formation of L-histidine complexes with transition metals. It has been found that L-histidine formed octahedral complex with metal ion (Co2+ and Ni2+) in a 1 : 1 ratio.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"421-426"},"PeriodicalIF":0.3,"publicationDate":"2018-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45424273","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Reduced Graphene Oxide/α-Fe2O3 Fibres as Active Material for Supercapacitor Application 还原氧化石墨烯/α-Fe2O3纤维在超级电容器中的应用
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-30 DOI: 10.5562/CCA3452
Gabrijela Radić, Ivan Šajnović, Željka Petrović, M. K. Roković
{"title":"Reduced Graphene Oxide/α-Fe2O3 Fibres as Active Material for Supercapacitor Application","authors":"Gabrijela Radić, Ivan Šajnović, Željka Petrović, M. K. Roković","doi":"10.5562/CCA3452","DOIUrl":"https://doi.org/10.5562/CCA3452","url":null,"abstract":"The composite hydrogel, composed of reduced graphene oxide and α-Fe2O3 fibres (rGO/α-Fe2O3), was successfully prepared by the hydrothermal procedure starting from GO and α-Fe2O3 nanofibres. According to the SEM and XRD results, α-Fe2O3 fibres are distributed between rGO sheets increasing the inter-sheet space. The rGO/α-Fe2O3 composite was tested as an active material in supercapacitor by means of cyclic voltammetry, galvanostatic charging/discharging and electrochemical impedance spectroscopy in 0.5 mol dm–3 Na2SO4. The obtained results confirmed a positive effect of the α-Fe2O3 addition on capacitive properties. Improved capacitive properties of the composite make this material suitable for supercapacitor application.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"481-490"},"PeriodicalIF":0.3,"publicationDate":"2018-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45163575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Biphasic pKa Values 双相pKa值
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-30 DOI: 10.5562/CCA3405
Sigrid Selberg, Sofja Tshepelevitsh, I. Leito
{"title":"Biphasic pKa Values","authors":"Sigrid Selberg, Sofja Tshepelevitsh, I. Leito","doi":"10.5562/CCA3405","DOIUrl":"https://doi.org/10.5562/CCA3405","url":null,"abstract":"","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"599-602"},"PeriodicalIF":0.3,"publicationDate":"2018-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42111286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Structural Properties of Iron/Titanium Oxide Nanoparticles Synthesized by Sol-gel Method in the Presence of Poly(ethylene glycol) 聚乙二醇存在下溶胶-凝胶法制备铁/钛氧化物纳米粒子的结构性能
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-30 DOI: 10.5562/CCA3441
I. Marić, M. Gotic, T. Jurkin, L. Mikac, E. Tronc, M. Ivanda
{"title":"Structural Properties of Iron/Titanium Oxide Nanoparticles Synthesized by Sol-gel Method in the Presence of Poly(ethylene glycol)","authors":"I. Marić, M. Gotic, T. Jurkin, L. Mikac, E. Tronc, M. Ivanda","doi":"10.5562/CCA3441","DOIUrl":"https://doi.org/10.5562/CCA3441","url":null,"abstract":"Iron/Titanium oxide nanoparticles with initial molar ratio Fe/(Fe+Ti) = 0.05 (low loading of Fe in TiO2) and Fe/(Fe+Ti) = 0.15 (high loading of Fe in TiO2) were synthesized by a modified sol-gel procedure using Ti(IV)-isopropoxide, FeSO4 ∙ 7H2O and poly(ethylene glycol) (PEG) as starting material. The amount of doped iron strongly affected structural properties as well as the degree of dispersion of iron in the Fe- Ti-O system. The highly-doped sample contained poorly crystallized hydrated iron(III)- sulphates or basic iron(III)-sulphates in a considerable amount. The lowly-doped Fe-TiO2 sample contained about 22 wt % of brookite that had taken up iron virtually in the same proportion as anatase. Contrary to quasi- homogeneous distributions of iron in the lowly- doped Fe-TiO2 sample, the uptake of iron in the highly-doped Fe-TiO2 sample heated at 500 °C is significant, but anatase is free from iron, thus suggesting a heterogeneous distribution of iron. The photocatalytic activity of the highly-doped Fe-TiO2 sample was better than that of the lowly-doped Fe-TiO2 sample, but still below the photoactivity of Degussa P25 reference photocatalyst.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"577-588"},"PeriodicalIF":0.3,"publicationDate":"2018-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49007111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Production of Surface Active Organic Material and Reduced Sulfur Species During the Growth of Marine Diatom Cylindrotheca closterium 海洋硅藻生长过程中表面活性有机物和还原性硫的产生
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-30 DOI: 10.5562/CCA3433
I. Ciglenečki, J. Dautović, Ana Cvitešić, G. Pletikapić
{"title":"Production of Surface Active Organic Material and Reduced Sulfur Species During the Growth of Marine Diatom Cylindrotheca closterium","authors":"I. Ciglenečki, J. Dautović, Ana Cvitešić, G. Pletikapić","doi":"10.5562/CCA3433","DOIUrl":"https://doi.org/10.5562/CCA3433","url":null,"abstract":"Electrochemical methods at the mercury electrode were used for monitoring production of surface active substances (SAS) and reduced sulfur species (RSS) during growth of marine diatom Cylindrotheca closterium isolated from the Adriatic Sea in the laboratory conditions. In the same culture samples, production of particulate and dissolved organic carbon (POC, DOC) was followed by high temperature catalytic oxidation method (HTCO). The culture growth curve obtained by microscopically counted phytoplankton cells showed an exponential growth phase that lasted 10 days, transition phase until 14 days and stationary phase until 21 days. In these time periods twofold increase of SAS and DOC was followed, while POC increased 41 times. Detail analyses of a.c. out of phase voltammetric curves recorded in original and in acidified phytoplankton culture samples indicate transformation of organic material during growth, from more anionic (negatively charged) to less anionic polymeric surface active material. In culture samples presence of non-volatile RSS were confirmed.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"455-461"},"PeriodicalIF":0.3,"publicationDate":"2018-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43071507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Two Imidazole Based Corrosion Inhibitors for Protection of Bronze from Urban Atmospheres 两种咪唑基缓蚀剂对青铜的城市大气保护作用
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-30 DOI: 10.5562/CCA3440
Katarina Marušić, H. O. Ćurković, Ema Supnišek Lisac, H. Takenouti
{"title":"Two Imidazole Based Corrosion Inhibitors for Protection of Bronze from Urban Atmospheres","authors":"Katarina Marušić, H. O. Ćurković, Ema Supnišek Lisac, H. Takenouti","doi":"10.5562/CCA3440","DOIUrl":"https://doi.org/10.5562/CCA3440","url":null,"abstract":"Two different imidazole based molecules were investigated as corrosion inhibitors for Cu-6Sn bronze in a sulphate/carbonate solution at pH 3 and 5 which simulate a mild and strong polluted urban environment. The tested corrosion inhibitors were 4-methyl-1-phenylimidazole (PMI) and 4- methy1-1-p- tolylimidazole (TMI). The difference between structures is in the additional para positioned methyl, -CH3, group in the phenyl ring of the TMI molecule. Their protective effect was investigated by different electrochemical methods: polarization in wide and narrow potential range and electrochemical impedance spectroscopy. The investigations have shown that both molecules give good protection to the bronze at pH 3, but only TMI showed a good effect at pH 5. Indicating that the para positioned methyl group serves as a link between the inhibitor molecule and substrate bronze.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"435-446"},"PeriodicalIF":0.3,"publicationDate":"2018-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45839000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Synthesis and Evaluation of Antibacterial and Antifungal Activities of 1,3-Disubstituted-4-thioxoimidazolidin-2-one Derivatives 1,3-二取代-4-硫代咪唑烷-2- 1衍生物的合成及抑菌活性评价
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-29 DOI: 10.5562/CCA3354
M. El-Sharief, S. Abbas, Z. Moussa, E. El-Gammal, A. El‐Sharief
{"title":"Synthesis and Evaluation of Antibacterial and Antifungal Activities of 1,3-Disubstituted-4-thioxoimidazolidin-2-one Derivatives","authors":"M. El-Sharief, S. Abbas, Z. Moussa, E. El-Gammal, A. El‐Sharief","doi":"10.5562/CCA3354","DOIUrl":"https://doi.org/10.5562/CCA3354","url":null,"abstract":"1,3-Disubstituted-4-thioxoimidazolidin-2-one derivatives with various substituents at N1 and N3 were synthesized with high yields and excellent purity by the reaction of various N-arylcyanothioformamide derivatives with isocyanate derivatives. The activity of these products as antibacterial and antifungal agents was studied to through some light on structural activity relationship. Some of synthesized compounds showed significant antibacterial and antifungal activities. Most of the imidazole derivatives possess significant antifungal activity aginst S. cerevisiae (MIC 1–10 μg mL–1). As comparision with ketoconazole, most of the imidazole derivatives showed activity ranging from 50 % less activity to fourfold activity.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"335-340"},"PeriodicalIF":0.3,"publicationDate":"2018-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.5562/CCA3354","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46728106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Impact of anticoagulants on assessment of zinc in plasma 抗凝剂对血浆锌评估的影响
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-29 DOI: 10.5562/CCA3321
J. Jablan, M. Rajković, S. Inić, R. Petlevski, A. Domijan
{"title":"Impact of anticoagulants on assessment of zinc in plasma","authors":"J. Jablan, M. Rajković, S. Inić, R. Petlevski, A. Domijan","doi":"10.5562/CCA3321","DOIUrl":"https://doi.org/10.5562/CCA3321","url":null,"abstract":"The aim of this study was to compare zinc (Zn) level in EDTA, heparin, citrate plasma and serum. The blood samples from the same healthy volunteers (n","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"317-321"},"PeriodicalIF":0.3,"publicationDate":"2018-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.5562/CCA3321","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48570033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Synthesis and Pharmacological Evaluation of Pyrazoline and Pyrimidine Analogs of Combretastatin-A4 as Anticancer, Anti-inflammatory and Antioxidant Agents 康布他汀- a4的吡唑啉和嘧啶类似物抗癌、抗炎和抗氧化的合成及药理评价
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-29 DOI: 10.5562/CCA3393
Sadanand N. Shringare, H. Chavan, Pravin S. Bhale, Sakharam B. Dongare, Yoginath B. Mule, Nishikant D. Kolekar, B. Bandgar
{"title":"Synthesis and Pharmacological Evaluation of Pyrazoline and Pyrimidine Analogs of Combretastatin-A4 as Anticancer, Anti-inflammatory and Antioxidant Agents","authors":"Sadanand N. Shringare, H. Chavan, Pravin S. Bhale, Sakharam B. Dongare, Yoginath B. Mule, Nishikant D. Kolekar, B. Bandgar","doi":"10.5562/CCA3393","DOIUrl":"https://doi.org/10.5562/CCA3393","url":null,"abstract":"","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"357-366"},"PeriodicalIF":0.3,"publicationDate":"2018-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45272596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Influence of Titanium Dioxide Preparation Method on Photocatalytic Degradation of Organic Dyes 二氧化钛制备方法对有机染料光催化降解的影响
IF 0.3 4区 化学
Croatica Chemica Acta Pub Date : 2018-12-29 DOI: 10.5562/CCA3292
V. Gilja, L. K. Krehula, Z. Katančić, S. Krehula, Z. Hrnjak-Murgić, J. Travas-sejdic
{"title":"Influence of Titanium Dioxide Preparation Method on Photocatalytic Degradation of Organic Dyes","authors":"V. Gilja, L. K. Krehula, Z. Katančić, S. Krehula, Z. Hrnjak-Murgić, J. Travas-sejdic","doi":"10.5562/CCA3292","DOIUrl":"https://doi.org/10.5562/CCA3292","url":null,"abstract":"Titanium catalysts (TiO2) were synthesized by three different methods. Their photocatalytic activity was validated through photodegradation of Reactive Red 45 (RR45) azo dye and Acid Blue 25 (AB25) anthraquinone dye in an aqueous solution under UV irradiation. TiO2 photocatalysts were characterized by FTIR, XRD and SEM. Photosensitivity and TiO2 activity range were characterized by UV/Vis spectroscopy. Photocatalytic validation has been made by way of determining the degree of RR45 and AB25 removal. TOC was determined as a measure of the mineralization of RR45 and AB25 by photocatalysis. The stability of TiO2 catalysts and a possibility of using them in consecutive photocatalysis cycles have also been studied. The results show that the photocatalytic efficiency depends on the crystal structure of TiO2. The size of crystallites depends on synthesis conditions. From the results of photocatalytic efficiency it is concluded that the chemical interaction between a catalyst and a dye strongly depends on the dye chemical structure.","PeriodicalId":10822,"journal":{"name":"Croatica Chemica Acta","volume":"91 1","pages":"323-334"},"PeriodicalIF":0.3,"publicationDate":"2018-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.5562/CCA3292","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46408366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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