{"title":"1, 4-Diazabicyclo[2.2.2]octanium diacetate: An effective, mild and reusable catalyst for the synthesis of 2,4,5–trisubstituted imidazoles","authors":"L. Fekri, Maryam Nateghi","doi":"10.22034/CRL.2020.252558.1084","DOIUrl":"https://doi.org/10.22034/CRL.2020.252558.1084","url":null,"abstract":"1, 4-Diazabicyclo[2.2.2]octanium diacetate supplies an environmentally friendly procedure for the synthesis of 2,4,5-trisubstituted imidazoles through one-pot multicomponent condensation of benzyl or benzoin and ammonium acetate with various aldehydes. These compounds were obtained in high yields and short reaction times. The catalyst could be easily recovered and reused for five cycles with almost consistent activity. All of synthesized compounds were characterized by their physical constant, comparison with authentic samples, IR, 1H NMR, 13C NMR spectroscopy and elemental analysis.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"42 1","pages":"37-42"},"PeriodicalIF":1.8,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91310144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of 2, 4 disubstituted 1, 5 benzodiazepines promoted by efficient Silica-Alumina Catalyst","authors":"D. Tayde, M. Lande","doi":"10.22034/CRL.2020.255303.1089","DOIUrl":"https://doi.org/10.22034/CRL.2020.255303.1089","url":null,"abstract":"An efficient and environment friendly valuable synthon of 1, 5 benzodiazepine derivatives were synthesized having unique physical and medicinal properties. This reaction is performed by mesoporous binary mixed metal oxide SiO2-Al2O3 which is synthesized by hydrothermal method at high temperature. This mesoporous material is investigated by XRD, SEM, EDS, TEM, TPD and BET surface area. Present method offers several remarkable advantages such as non-toxic, noncorrosive and easy work-up procedure for the purification of product with non-chromatographic method, ecofriendly reaction condition.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"38 1","pages":"30-36"},"PeriodicalIF":1.8,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82077369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"In Pursuit of My Book","authors":"B. Geffert","doi":"10.5860/crl.82.6.786","DOIUrl":"https://doi.org/10.5860/crl.82.6.786","url":null,"abstract":"","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"24 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83830647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Patterns of Differentiation of Students’ Competencies: A Comparative Study","authors":"E. Glowacka, M. Kisilowska, Magdalena Paul","doi":"10.5860/CRL.81.7.1061","DOIUrl":"https://doi.org/10.5860/CRL.81.7.1061","url":null,"abstract":"The study focuses on the issue of how much information competencies are universal in the globalized, internet-connected world, and/or to what extent their perception depends on local conditions and individual needs. The aim of the project is threefold. First, it offers a comparative analysis of the information literacy skills of Polish and Spanish students, regarding both their self-assessment and belief in the importance of information literacy. Second, it focuses on differences and unique IL needs of students of courses rooted in social sciences and/or humanities. And third, due to these differences, it discusses the role of academic librarians in profiled IL training, integrated with the specific courses. Quantitative methodology was applied. The comparative study covered subgroups of humanities and social science students from Poland and Spain. Competencies in information searching, processing, evaluation, and communication/dissemination were taken into account. The results indicate some common ways of perception of valuing information competencies and major differences in assessment of IL self-efficacy. Students’ reluctance to visit libraries is another argument to enhance profiled IL training being realized in close cooperation of academic librarians and the faculty.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"36 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2020-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77737372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Behlol Hashemzadeh, L. Edjlali, P. D. Nezhad, E. Vessally
{"title":"A DFT studies on a potential anode compound for Li-ion batteries: Hexa-cata-hexabenzocoronene nanographen","authors":"Behlol Hashemzadeh, L. Edjlali, P. D. Nezhad, E. Vessally","doi":"10.22034/CRL.2020.187273.1087","DOIUrl":"https://doi.org/10.22034/CRL.2020.187273.1087","url":null,"abstract":"In this work, the possible apply of a hexa-cata-hexabenzocoronene HCor as anode material was studied for Li-ion batteries (LIBs) using the B3LYP/6-31G* level. The planar structure of HCor is less stable (by about 0.243 hartree) in comparison with the twisted structure. The Li cation and neutral are suitably adsorbed high up the middle of a HCor hexagonal ring with the adsorption energy of -120.3 and -2.7 kcal/mol, respectively. The calculated specific storage capacity of HCor is 450.1 mAh/g and the great cell voltage is 2.63 V generated by the interaction between Li+ and HCor. The HCOR is considered an ideal candidate to be used as an anode material in LIBs because of high storage capacity and ion mobility.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"763 1","pages":""},"PeriodicalIF":1.8,"publicationDate":"2020-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76920294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mohammad Reza Jalali Sarvestani, R. Ahmadi, Behnam Farhang Rik
{"title":"Procarbazine adsorption on the surface of single walled carbon nanotube: DFT studies","authors":"Mohammad Reza Jalali Sarvestani, R. Ahmadi, Behnam Farhang Rik","doi":"10.22034/CRL.2020.110451","DOIUrl":"https://doi.org/10.22034/CRL.2020.110451","url":null,"abstract":"In this research, the performance of single-walled carbon nanotube (SWCN) as a sensor and nanocarrier for procarbazine (PC) was investigated by infra-red (IR), natural bond orbital (NBO), frontier molecular orbital (FMO) computations. All of the computations were done using the density functional theory method in the B3LYP/6-31G (d) level of theory The calculated negative values of adsorption energy, enthalpy changes, Gibbs free energy changes showed the PC interaction with SWCN is exothermic, spontaneous and experimentally possible. The increasing of specific heat capacity (CV) of SWCN after adsorption of PC showed the thermal conductivity improved during the interaction process and this nanostructure is an excellent sensing material for the detection of PC. The NBO results demonstrate in all of the evaluated conformers a chemical bond with SP3 hybridization is formed between the medicine and SWCN. The great values of thermodynamic constants showed the adsorption process is irreversible and SWCN is not a suitable nanocarrier for delivery of PC. The density of states (DOS) spectrums showed the bandgap of SWCN decreased sharply after the adsorption of PC and this nanomaterial can be used as a sensor for electrochemical detection of PC.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"116 1","pages":"175-179"},"PeriodicalIF":1.8,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80248905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fatemeh Maleki, Meghdad Payab, A. Baghban, H. Sheikhloie
{"title":"Determination of Fenvalerate reside in raisin via vortex-assisted surfactant-enhanced emulsification liquid–liquid microextraction (VSLLME) method by using HPLC system","authors":"Fatemeh Maleki, Meghdad Payab, A. Baghban, H. Sheikhloie","doi":"10.22034/CRL.2020.233886.1064","DOIUrl":"https://doi.org/10.22034/CRL.2020.233886.1064","url":null,"abstract":"In this project, ultra-trace amounts of Fenvalerate residue in raisin, were determined via vortex-assisted surfactant-enhanced emulsification liquid–liquid micro extraction (VSLLME) method and by using HPLC-PDA detector at 225nm. In the VSLLME method, the extraction solvent is dispersed into the aqueous samples by assistance of vortex agitator. Meanwhile, the addition of a surfactant, which was used as an emulsifier, could enhance the rate of the mass-transfer from aqueous samples to the extraction solvent. The main parameters relevant to this method were investigated and the optimum conditions were established: 20 µL chlorobenzene was used as extraction solvent, 0.9 mmol.L-1CTAB was selected as the surfactant, the extraction time was fixed at 60s, 2% sodium chloride was added and the extraction process was performed under the room temperature. Under the optimum conditions, limit of detection (LOD) was 0.3 ng mL-1. The relative standard deviation (RSD, n=6) was 2.87%. The linearity was obtained by five points in the concentration range of 0.3 to 100.0 ng mL-1. Correlation coefficients (R2) was 0.9997, and the enrichment factor (EF) was 114. Finally, the proposed method has been successfully applied for determination of Fenvalerate in real samples. The recoveries of the target analyte in raisins samples were between 84.13% and 92.12%.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"232 1","pages":"161-167"},"PeriodicalIF":1.8,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77698689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Pirsa, Parisa Abdolsattari, S. J. Peighambardoust, S. H. Fasihnia, S. Peighambardoust
{"title":"Investigating microbial properties of traditional Iranian white cheese packed in active LDPE films incorporating metallic and organoclay nanoparticles","authors":"S. Pirsa, Parisa Abdolsattari, S. J. Peighambardoust, S. H. Fasihnia, S. Peighambardoust","doi":"10.22034/CRL.2020.231587.1059","DOIUrl":"https://doi.org/10.22034/CRL.2020.231587.1059","url":null,"abstract":"Iranian white Cheese is a traditional type of cheese in Iran which is popular and widely consumed because of its pleasant organoleptic properties. To manufacture this cheese, raw milk is heated below pasteurization temperature, therefore, pathogenic and spoilage bacteria remain and cause several diseases in public health. In this research three kinds of nanocomposite films based on LDPE incorporated 1) Ag, CuO, ZnO, 2) Cloisite 15A, Cloisite 20A, Cloisite 30B that produced by extrusion method were used for packaging of the cheese and kept in 4°C during 28 days. Data analysis carried out using SPSS statistical software based on a completely randomized design. The results showed the nanocomposite films incorporated with metal nanoparticles had a significant decrease in the growth of Staphylococcus aureus, coliform, mold and yeast after 28 days, while, the growth of lactic acid bacteria decreased but less than control film. Sensory properties of cheese samples packed in active films were not significantly changed. However, physicochemical characteristics such as pH and moisture content were affected significantly by active films. Overall migration of packaging active films in food simulants were within amounts allowed by national and international legislations.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"82 1","pages":"168-174"},"PeriodicalIF":1.8,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83774727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Short Chronological Review on the Syntheses of Amine-Boranes","authors":"D. O. Reddy","doi":"10.22034/CRL.2020.238849.1070","DOIUrl":"https://doi.org/10.22034/CRL.2020.238849.1070","url":null,"abstract":"Since their discovery by Burg and Schlesinger in 1937, amine-boranes have enjoyed a rich preparative history and have experienced reinvigorated interest as valuable compounds. These borane complexes have been implemented in a variety of applications, spanning from reagents in organic syntheses to hydrogen storage materials. The importance of amine-boranes derives especially from their reductive abilities. Given the utility of amine-boranes and their current resurgence, a mini review on their general properties and notable preparations is both timely and potentially of interest to organic and materials chemists alike.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"83 1","pages":"184-191"},"PeriodicalIF":1.8,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77402190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Converting polymeric mixture waste of a car breaker company to hydrocarbon by designed high performance co-pyrolysis system","authors":"A. Khani, Shahram Mohammadi, Hamed Rasoolzadeh","doi":"10.22034/CRL.2020.242630.1075","DOIUrl":"https://doi.org/10.22034/CRL.2020.242630.1075","url":null,"abstract":"Waste produced from car breaker companies severely affects the environment. So far, the only way to manage this complex waste is to bury it. In this research, the waste converted to hydrocarbons and carbon black by co-pyrolysis process in the designed high performance co-pyrolysis system. The results showed that the as-obtained maximum yield of heavy oil and light hydrocarbon wax, carbon black and non-condensable gas can be listed as mass basis of 8, 34, 3, 40 and 15%, respectively. The ratio of 5 W/W% treated expanded perlite as catalyst to waste increased the amount of light hydrocarbons to 34 W/W%.","PeriodicalId":10686,"journal":{"name":"College & Research Libraries","volume":"14 1","pages":"180-183"},"PeriodicalIF":1.8,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86533756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}